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1. 发明授权

US06683225B2 Oxidic aluminum/zinc catalysts and a process of producing unsaturated fatty alcohols 失效
标题翻译：氧化铝/锌催化剂和不饱和脂肪醇的生产方法
公开(公告)号：US06683225B2
公开(公告)日：2004-01-27
申请号：US09835657
申请日：2001-04-16
申请人： Guenther Demmering , Lothar Friesenhagen , Stephan Heck , Hans Peter Kubersky
发明人： Guenther Demmering , Lothar Friesenhagen , Stephan Heck , Hans Peter Kubersky
IPC分类号： C07C2704
CPC分类号： C07C29/149 , C07C31/02
摘要： Oxidic catalysts containing 20 to 25% by weight of aluminum and 40 to 50% by weight of zinc which are suitable for the production of unsaturated fatty alcohols containing 8 to 22 carbon atoms by hydrogenation of unsaturated fatty acids, fatty acid lower alkyl esters or unsaturated fatty acid glycerides are disclosed. A process for the production of the oxidic aluminum/zinc catalysts is also disclosed.
摘要翻译：含有20〜25重量％的铝和40〜50重量％的锌的氧化催化剂适用于通过不饱和脂肪酸，脂肪酸低级烷基酯或不饱和脂肪酸的氢化生产含有8〜22个碳原子的不饱和脂肪醇公开了脂肪酸甘油酯。还公开了生产氧化铝/锌催化剂的方法。

2. 发明授权

US06683224B1 Process for the production of fatty alcohols 失效
标题翻译：生产脂肪醇的方法
公开(公告)号：US06683224B1
公开(公告)日：2004-01-27
申请号：US10304445
申请日：2002-11-26
申请人： Roland Hourticolon , Guenther Demmering , Hans-Peter Kubersky , Lothar Friesenhagen , Friedrich Hommers , Juergen Latzel , Eberhard Peukert , Hans-Guenther Richard , Udo Kreutzer
发明人： Roland Hourticolon , Guenther Demmering , Hans-Peter Kubersky , Lothar Friesenhagen , Friedrich Hommers , Juergen Latzel , Eberhard Peukert , Hans-Guenther Richard , Udo Kreutzer
IPC分类号： C07C29136
CPC分类号： C07C29/149 , C07C31/125 , C07C33/02
摘要： Naturally occurring fats, oils and fatty derivatives are continuously hydrogenated to fatty alcohols in a fixed-bed reactor in the presence of hydrogen in excess and hydrogenation catalysts under static pressures of 50 to 300 bar and at temperatures of 160 to 320° C. The liquid product is cooled and the excess hydrogen is returned to the reactor entrance by a gas circulation pump as a recycle gas after separation of the liquid product. The expense involved in cooling and reheating the recycle gas is eliminated without any reduction in the quality of the fatty alcohol produced providing the recycle gas is returned to the reactor entrance without reheating and the hydrogenation reaction is carried out under static pressures of at least 200 bar.
摘要翻译：天然存在的脂肪，油和脂肪衍生物在固定床反应器中在过量的氢气和氢化催化剂的存在下，在50至300巴的静态压力和160至320℃的温度下，连续氢化成脂肪醇。液体产物被冷却，并且在分离液体产物之后，过量的氢气作为循环气体由气体循环泵返回到反应器入口。除去循环气体的冷却和再加热所涉及的费用被消除，而不会降低所产生的脂肪醇的质量，提供循环气体将不再重新加热而返回到反应器入口，氢化反应在至少200巴的静压下进行。

3. 发明授权

US5364986A Process for the production of fatty alcohols 失效
标题翻译：生产脂肪醇的方法
公开(公告)号：US5364986A
公开(公告)日：1994-11-15
申请号：US150931
申请日：1993-11-10
申请人： Guenther Demmering , Stephan Heck , Lothar Friesenhagen
发明人： Guenther Demmering , Stephan Heck , Lothar Friesenhagen
IPC分类号： B01F17/02 , B01F17/42 , B01J8/06 , B01J23/80 , C07C29/149 , C07C31/125 , C07C29/136 , C07C31/20
CPC分类号： B01J23/80 , B01J8/06 , C07C29/149
摘要： C.sub.8-22 fatty alcohols are produced by a process which comprises contacting a triglyceride with hydrogen in the presence of a copper-zinc catalyst and in a reaction zone. The hydrogen pressure in the reaction zone is from about 200 to about 280 bar, the temperature of the entrance of the reaction zone is from about 200.degree. C. to about 230.degree. C., and the temperature of the exit of the reaction zone is from about 190.degree. C. to about 220.degree. C. The amount of 1,2-propanediol formed is optimized by the lower temperature of the exit portion of the reaction zone.
摘要翻译： C8-22脂肪醇通过包括使甘油三酯与氢在铜 - 锌催化剂存在下和在反应区中接触的方法制备。反应区中的氢气压力为约200至约280巴，反应区入口温度为约200℃至约230℃，反应区出口温度为约190℃至约220℃。通过反应区的出口部分的较低温度优化形成的1,2-丙二醇的量。

4. 发明授权

US5709739A Release agents for hydraulic binders 失效
标题翻译：液压粘合剂脱模剂
公开(公告)号：US5709739A
公开(公告)日：1998-01-20
申请号：US666496
申请日：1996-08-16
申请人： Leonhard Wittich , Stephan Heck , Lothar Friesenhagen , Guenther Demmering , Horst-Dieter Komp , Michael Koehler , Ingo Wegener , Hans-Juergen Sladek
发明人： Leonhard Wittich , Stephan Heck , Lothar Friesenhagen , Guenther Demmering , Horst-Dieter Komp , Michael Koehler , Ingo Wegener , Hans-Juergen Sladek
IPC分类号： B28B7/38 , C10M105/12 , C10M173/00 , B28B7/36
CPC分类号： B28B7/384 , C10M105/12 , C10M173/00 , C10M2201/02 , C10M2201/085 , C10M2203/10 , C10M2203/102 , C10M2203/104 , C10M2203/106 , C10M2203/108 , C10M2205/14 , C10M2205/16 , C10M2205/17 , C10M2207/021 , C10M2207/022 , C10M2207/023 , C10M2207/04 , C10M2207/046 , C10M2207/121 , C10M2207/122 , C10M2207/125 , C10M2207/126 , C10M2207/127 , C10M2207/129 , C10M2207/14 , C10M2207/141 , C10M2207/142 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/284 , C10M2207/286 , C10M2207/289 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/04 , C10M2209/06 , C10M2209/062 , C10M2209/084 , C10M2209/104 , C10M2209/107 , C10M2209/108 , C10M2209/109 , C10M2209/12 , C10M2215/04 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/12 , C10M2215/122 , C10M2215/22 , C10M2215/221 , C10M2215/223 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/28 , C10M2215/30 , C10M2217/04 , C10M2219/04 , C10M2219/044 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10N2210/01 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2250/02 , C10N2270/02
摘要： A composition useful as a release agent for hydraulic binders is provided. The composition comprises water, an oil component comprising a water-immiscible monohydric alcohol component liquid at temperatures of 5.degree. to 15.degree. C. and selected from the group consisting of unsaturated fatty alcohols containing 12 to 22 carbon atoms and having iodine values of 40 to 170, Guerbet alcohols containing 16 to 28 carbon atoms, oxoalcohols containing 8 to 15 carbon atoms, and saturated alcohols containing 6 to 10 carbon atoms, and 0.5 to 5% by weight of an emulsifier, based on the oil component. The release agent is particularly useful for the treatment of formwork material in concrete construction.
摘要翻译： PCT No.PCT / EP94 / 04324 Sec。 371日期：1996年8月16日 102（e）日期1996年8月16日PCT 1994年12月27日PCT公布。 WO95 / 18704 PCT出版物日期1995年7月13日提供了可用作水硬性粘合剂的脱模剂的组合物。该组合物包含水，油组分，其包含在5至15℃温度下的与水不混溶的一元醇组分液体，并且选自含有12至22个碳原子的不饱和脂肪醇，碘值为40至 170，含有16至28个碳原子的格尔伯特醇，含有8至15个碳原子的多元醇，以及含有6至10个碳原子的饱和醇和0.5-5重量％的乳化剂。脱模剂对于混凝土结构中的模板材料的处理特别有用。

5. 发明授权

US5773636A Process for the production of fatty acid lower alkyl esters 失效
标题翻译：生产脂肪酸低级烷基酯的方法
公开(公告)号：US5773636A
公开(公告)日：1998-06-30
申请号：US640921
申请日：1996-08-05
申请人： Guenther Demmering , Christian Pelzer , Lothar Friesenhagen
发明人： Guenther Demmering , Christian Pelzer , Lothar Friesenhagen
IPC分类号： C07C67/03 , C11C1/00
CPC分类号： C07C67/03
摘要： A process for the production of fatty acid lower alkyl esters comprising the steps of: A) treating at least one fatty acid ester of glycerol with from about 0.3 to about 3% by weight, based on the weight of ester, of an acid at an elevated temperature; B) removing said acid from the treated fatty acid ester; and C) reacting the treated fatty acid ester with at least one lower aliphatic alcohol to transesterify the fatty acid ester.
摘要翻译：一种用于生产脂肪酸低级烷基酯的方法，包括以下步骤：A）以至少一种甘油脂肪酸酯的量处理至少一种脂肪酸酯，所述脂肪酸酯以约0.3至约3重量％（基于酯的重量计）的酸在升温 B）从处理的脂肪酸酯中除去所述酸; 和C）使经处理的脂肪酸酯与至少一种低级脂族醇反应以酯交换脂肪酸酯。

6. 发明授权

US5455370A Process for the production of fatty acid lower alkyl esters 失效
标题翻译：生产脂肪酸低级烷基酯的方法
公开(公告)号：US5455370A
公开(公告)日：1995-10-03
申请号：US178281
申请日：1994-01-10
申请人： Guenther Demmering , Christian Pelzer , Lothar Friesenhagen
发明人： Guenther Demmering , Christian Pelzer , Lothar Friesenhagen
IPC分类号： C07C69/30 , C07C67/03 , C11C3/04 , C11C3/10 , C11C3/00
CPC分类号： C11C3/04 , C07C67/03
摘要： Fatty acid glycerides can be transesterified with lower aliphatic alcohols if the reaction is carried out in the presence of fatty acids corresponding to formula (II):R.sup.2 --COOH (II),in which R.sup.2 is an aliphatic hydrocarbon moiety containing 11 to 17 carbon atoms and 0, 1 or 2 double bonds. The products are distinguished by a low content of bound glycerol and a low acid value. Removal or neutralization of the catalyst is unnecessary because, after the transesterification, the fatty acids are also present in the form of their esters.
摘要翻译： PCT No.PCT / EP92 / 01463 Sec。 371日期1994年1月10日 102（e）日期1994年1月10日PCT提交1992年6月29日PCT公布。出版物WO93 / 01263 如果反应在对应于式（II）的脂肪酸存在下进行，则其中R2是脂族烃（II），R2-COOH（Ⅱ）部分含有11至17个碳原子和0,1或2个双键。产品的特征在于低含量的结合甘油和低酸值。催化剂的去除或中和是不必要的，因为在酯交换之后，脂肪酸也以它们的酯的形式存在。

7. 发明授权

US07169749B1 Method for producing alkyl-substituted butenols 有权
标题翻译：烷基取代丁烯醇的制备方法
公开(公告)号：US07169749B1
公开(公告)日：2007-01-30
申请号：US10088385
申请日：2000-09-08
申请人： Lothar Friesenhagen , Stephan Heck , Norbert Klein , Thomas Markert , Gerrit Pelzer , Markus Schneider
发明人： Lothar Friesenhagen , Stephan Heck , Norbert Klein , Thomas Markert , Gerrit Pelzer , Markus Schneider
IPC分类号： C07C27/22
CPC分类号： C07C45/74 , C07C29/141 , C07C2601/10 , C07C47/225 , C07C33/12
摘要： Alkyl-substituted butenols having the formula (I): R1—CH2—CH═CR2—CH2OH (I) wherein R1 is a saturated or olefinically unsaturated alkyl or cycloalkyl group having from 4 to 16 carbon atoms and wherein R1 is optionally substituted by an alkyl, cycloalkyl, aryl or alkaryl having up to 12 carbon atoms; R2 is hydrogen or an alkyl group having from 1 to about 6 carbon atoms are produced by a process which comprises: (1) reacting an aldehyde of the formula (II): R1—CH2—CHO (II) wherein R1 has the same meaning as in formula (I), with the corresponding lower aldehyde to form an unsaturated aldehyde in an inert organic solvent; (2) continuously contacting an optionally calcined copper/zinc catalyst with the unsaturated aldehyde under isothermal conditions at temperatures of from about 45 to about 60° C. and under a hydrogen pressure of from 1 to about 300 bar.
摘要翻译：具有式（I）的烷基取代的丁烯醇：<？in-line-formula description =“In-line formula”end =“lead”？> R SUB-CH-CR 2 -CH 2 OH（I）<βin-line-formula description =“In-line Formulas”end =“tail”？> 其中R 1是具有4至16个碳原子的饱和或烯属不饱和的烷基或环烷基，并且其中R 1任选被烷基，环烷基，芳基或烷芳基取代具有多达12个碳原子; R 2是氢或具有1至约6个碳原子的烷基，其方法包括：（1）使式（II）的醛：公式描述=“在线公式”end =“lead”？> R -CH 2 -CHO（II）<？in-line-formula description =“ 其中R 1具有与式（I）中相同的含义，其中相应的低级醛在惰性有机溶剂中形成不饱和醛; （2）在约45至约60℃的温度和1至约300巴的氢气压力的等温条件下，将任选煅烧的铜/锌催化剂与不饱和醛连续接触。

8. 发明授权

US06897342B2 Method for producing aldehydes 失效
标题翻译：醛的生产方法
公开(公告)号：US06897342B2
公开(公告)日：2005-05-24
申请号：US10311838
申请日：2001-06-19
申请人： Albrecht Schwerin , Gerrit Pelzer , Lothar Friesenhagen , Bernhard Gutsche
发明人： Albrecht Schwerin , Gerrit Pelzer , Lothar Friesenhagen , Bernhard Gutsche
IPC分类号： C07C45/29 , C07B61/00 , C07C45/00 , C07C47/02
CPC分类号： C07C45/002
摘要： A process for making aldehydes involving: (a) providing a fatty alcohol; (b) providing an oxidic copper/zinc catalyst; and (c) continuously dehydrogenating the fatty alcohol, in the presence of the oxidic copper/zinc catalyst, at a temperature of from about 200 to 280° C. and a pressure of from about 10 mbar to 1 bar.
摘要翻译：制备醛的方法，涉及：（a）提供脂肪醇; （b）提供氧化铜/锌催化剂; 和（c）在氧化铜/锌催化剂的存在下，在约200至280℃的温度和约10毫巴至1巴的压力下使脂肪醇连续脱氢。

9. 发明授权

US06548717B1 Process for making branched, substantially unsaturated fatty alcohols 失效
标题翻译：制备支链，基本不饱和脂肪醇的方法
公开(公告)号：US06548717B1
公开(公告)日：2003-04-15
申请号：US09602988
申请日：2000-06-23
申请人： Alfred Westfechtel , Norbert Huebner , Lothar Friesenhagen , Gerrit Pelzer , Norbert Klein , Ansgar Behler , Thomas B. Downing , Steven A. Kennedy , C. William Blewett
发明人： Alfred Westfechtel , Norbert Huebner , Lothar Friesenhagen , Gerrit Pelzer , Norbert Klein , Ansgar Behler , Thomas B. Downing , Steven A. Kennedy , C. William Blewett
IPC分类号： C07C2704
CPC分类号： A61K8/342 , A61K47/10 , A61Q19/00 , C07C29/149 , C11D3/2031 , C07C33/035 , C07C33/02
摘要： A process for making branched, substantially unsaturated fatty alcohols involving: (a) providing a C16-22 fatty acid; (b) dimerizing the C16-22 fatty acid to form a monomer fraction containing branched, substantially unsaturated fatty acids; (c) removing the monomer fraction; (d) esterifying the branched, substantially unsaturated fatty acids contained in the monomer fraction into branched, substantially unsaturated fatty acid methyl esters; and (e) hydrogenating the branched, substantially unsaturated fatty acid methyl esters with their double bonds intact, to form the branched, substantially unsaturated fatty alcohols.
摘要翻译：一种制备支化的，基本上不饱和的脂肪醇的方法，包括：（a）提供C16-22脂肪酸; （b）使C16-22脂肪酸二聚以形成含有支链，基本上不饱和脂肪酸的单体级分; （c）除去单体馏分; （d）将单体部分中所含的支化的，基本上不饱和的脂肪酸酯化成支链的，基本上不饱和的脂肪酸甲酯; 和（e）使其支链，基本上不饱和的脂肪酸甲酯以其双键完整氢化，形成支链的，基本上不饱和的脂肪醇。

10. 发明授权

US4652406A Process for the production of fatty acid alkyl esters 失效
标题翻译：生产脂肪酸烷基酯的方法
公开(公告)号：US4652406A
公开(公告)日：1987-03-24
申请号：US806074
申请日：1985-12-06
申请人： Herbert Lepper , Lothar Friesenhagen
发明人： Herbert Lepper , Lothar Friesenhagen
IPC分类号： C07C67/03 , C07C67/58 , C07C69/24 , C07C69/52 , C07C69/58 , C11C3/00 , C11C3/04 , C11C1/08
CPC分类号： C11C3/003 , C11C3/04
摘要： Fatty acid alkyl esters are produced by catalytic transesterification of natural fats and oils containing free fatty acids. In a preliminary esterifying step, the free fatty acids present are reacted with a C.sub.1 -C.sub.4 alkanol (e.g., methanol) in the presence of an acidic esterification catalyst, at a temperature of about 50.degree. to 120.degree. C. and at substantially atmospheric pressure. The resulting reaction mixture is allowed to separate into two phases: (1) an alcohol phase containing the acidic esterification catalyst and part of the water of reaction and (2) an oil phase. These phases separately recovered. The oil phase is then extracted with an immiscible extractant, preferably comprising a mixture of glycerol and methanol, to remove residual water of reaction. In the final step the extracted oil phase is transesterified with a C.sub.1 -C.sub.4 alkanol, e.g. methanol, in the presence of an aklali catalyst and at substantially atmospheric pressure.
摘要翻译：脂肪酸烷基酯通过天然脂肪和含有游离脂肪酸的油的酯交换反应产生。在预酯化步骤中，存在的游离脂肪酸在酸性酯化催化剂存在下，在约50-120℃和基本上大气压下与C 1 -C 4烷醇（例如甲醇）反应。将所得反应混合物分离成两相：（1）含有酸性酯化催化剂和部分反应水的醇相，和（2）油相。这些阶段分别回收。然后用不混溶的萃取剂萃取油相，优选包含甘油和甲醇的混合物，以除去残留的反应水。在最后一步中，萃取的油相用C1-C4链烷醇酯交换反应。甲醇，在碱性催化剂存在下并且在基本上大气压下进行。

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