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    • 6. 发明授权
    • Low coefficient of thermal expansion cermet compositions
    • 低的热膨胀系数金属陶瓷组合物
    • US08323372B1
    • 2012-12-04
    • US09494877
    • 2000-01-31
    • Zhigang FangAnthony GriffoGregory T. LockwoodDah-Ben Liang
    • Zhigang FangAnthony GriffoGregory T. LockwoodDah-Ben Liang
    • C22C29/00
    • E21B10/46B22F3/156B22F2998/00C22C29/00C22C29/06E21B10/52
    • Low coefficient of thermal expansion (CTE) cermet compositions of this invention generally comprise a hard phase material and a ductile phase formed from a binder alloy, wherein the binder alloy is specially designed having a CTE that is closely matched to the hard phase material. Hard phase materials used to form low CTE compositions of this invention are selected from the group of carbides consisting of W, Ti, Mo, Nb, V, Si, Hf, Ta, and Cr carbides. The binder alloy is formed from a mixture of metals selected from the group consisting of Co, Ni, Fe, W, Mo, Ti, Ta, V, Nb, C, B, Cr, and Mn. In a preferred embodiment, low CTE compositions comprises WC as the hard phase material, and a ductile phase binder alloy formed from a mixture of Fe, Co, and Ni. The so-formed low CTE composition has a coefficient of thermal expansion that is less than that of conventional WC—Co at the same temperature and having the same metal content, thereby providing improved resistance to thermal shock and thermal fatigue related failure.
    • 本发明的低热膨胀系数(CTE)金属陶瓷组合物通常包括由粘合剂合金形成的硬质相和材料,其中粘合剂合金被特别设计成具有与硬相材料紧密匹配的CTE。 用于形成本发明的低CTE组合物的硬相材料选自由W,Ti,Mo,Nb,V,Si,Hf,Ta和Cr碳化物组成的碳化物组。 粘合剂合金由选自Co,Ni,Fe,W,Mo,Ti,Ta,V,Nb,C,B,Cr和Mn的金属的混合物形成。 在优选实施方案中,低CTE组合物包含WC作为硬相材料,以及由Fe,Co和Ni的混合物形成的延性相粘合剂合金。 如此形成的低CTE组合物在相同温度下具有比常规WC-Co低的热膨胀系数,并且具有相同的金属含量,从而提供对热冲击和热疲劳相关故障的改进的抗性。