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    • 2. 发明授权
    • Non-uniform etching of anode foil to produce higher capacitance gain without sacrificing foil strength
    • 阳极箔的不均匀蚀刻产生较高的电容增益而不牺牲箔强度
    • US06736956B1
    • 2004-05-18
    • US09851298
    • 2001-05-07
    • Ralph Jason HemphillThomas V. GrahamThomas Flavian Strange
    • Ralph Jason HemphillThomas V. GrahamThomas Flavian Strange
    • B23H1100
    • H01G9/055B23H9/00C25D3/04C25D3/08
    • The present invention is directed to a method of etching anode foil in a non-uniform manner which increases the overall capacitance gain of the foil while retaining foil strength. In particular, by using a mask to protect a mesh grid of the foil from further etching, a previously etched foil can be further etched, prior to the widening step. Alternatively, the mask may be used in the initial etch, eliminating the need for the second process. In effect the foil may be etched to a higher degree in select regions, leaving a web of more lightly etched foil defined by the mask to retain strength. According to the present invention, the foil is placed between two masks with a grid of openings which expose the foil in these areas to the etching solution. The exposed area can be as little as 10% of the total foil to as much as 95% of the total foil, preferably 30% to 70% of the total foil area. The pattern is configured in such a way that the enhanced area does not create large scale strength defects such as perforation holes and is held in a pattern such as a hexagonal array, random array or radial burst array, such that the exposed area perimeter can be round, square, hexagonal, or triangular. The higher surface area in the exposed areas does not significantly decrease the strength of the foil as a whole, such that the method according to the present invention increases capacitance of the anode foil without significantly decreasing the strength of the foil.
    • 本发明涉及一种以不均匀的方式蚀刻阳极箔的方法,其增加箔的整体电容增益同时保持箔强度。 特别地,通过使用掩模来保护箔的网格网进一步蚀刻,可以在加宽步骤之前进一步蚀刻预蚀刻的箔。 或者,可以在初始蚀刻中使用掩模,消除对第二工艺的需要。 实际上,箔可以在选择区域中被蚀刻到较高程度,留下由掩模限定的更轻微蚀刻的箔的网以保持强度。 根据本发明,箔被放置在具有开口格栅的两个掩模之间,这些开口将这些区域中的箔暴露于蚀刻溶液。 曝光面积可以少于总箔的10%,高达总箔的95%,优选总箔面积的30%至70%。 该图案被配置成使得增强区域不产生诸如穿孔的大规模强度缺陷,并且被保持在诸如六边形阵列,随机阵列或径向突发阵列的图案中,使得暴露的区域周长可以是 圆形,正方形,六边形或三角形。 暴露区域中较高的表面积并不会显着降低箔的整体强度,使得根据本发明的方法增加了阳极箔的电容而不显着降低箔的强度。
    • 3. 发明授权
    • Method for producing an electrode for a capacitor from foil
    • 从箔制造电容器用电极的方法
    • US07150767B1
    • 2006-12-19
    • US10701233
    • 2003-11-03
    • Clinton W. SchneiderR. Jason HemphillKatherine E. SudduthThomas V. GrahamThomas F. Strange
    • Clinton W. SchneiderR. Jason HemphillKatherine E. SudduthThomas V. GrahamThomas F. Strange
    • H01G9/00
    • H01G9/055H01G9/045Y10T29/417Y10T29/435Y10T29/49099
    • A method of producing an electrode for use in the manufacture of electrolytic capacitors for implantable cardioverter defibrillators comprises first coating the foil with a photoresist, second, applying a holographic image to the photoresist, third, removing a portion of the photoresist to expose a portion of the foil and create a pattern of photoresist on the foil and etching the foil. Alternatively, the method comprises applying an oxide or metal layer to the exposed foil surface, removing the pattern of photoresist to create a pattern of oxide or metal and etching the foil. The patterns of photoresist, oxide or metal all retard or prevent etching of the foil where the foil surface is covered. This results in a pattern of unetched foil with the remaining area being heavily etched. The resulting patterns stop crack propagation through the etched portions to yield foils with high gain and improved strength.
    • 一种用于制造用于可植入心律转复除颤器的电解电容器的电极的制造方法包括首先用光致抗蚀剂涂覆该箔片,其次,将该全息图像施加到该光致抗蚀剂上;第三,去除一部分光致抗蚀剂以暴露一部分 并且在箔上形成光刻胶图案并蚀刻箔。 或者,该方法包括将氧化物或金属层施加到暴露的箔表面上,去除光致抗蚀剂的图案以产生氧化物或金属的图案并蚀刻箔。 光致抗蚀剂,氧化物或金属的图案都延迟或防止箔覆盖箔的蚀刻。 这导致未蚀刻箔的图案,其余区域被严重蚀刻。 所得到的图案阻止了通过蚀刻部分的裂纹扩展,以产生具有高增益和改进强度的箔。
    • 4. 发明授权
    • Floating anode DC electrolytic capacitor
    • 浮阳极直流电解电容器
    • US06815306B1
    • 2004-11-09
    • US10075711
    • 2002-02-13
    • Thomas F. StrangeTimothy R. MarshallThomas V. Graham
    • Thomas F. StrangeTimothy R. MarshallThomas V. Graham
    • H01L2120
    • H01G9/04A61N1/3956H01G9/00
    • The present invention is directed to an electrolytic capacitor having a novel floating anode between the cathode and the powered anode of the capacitor, resulting in a single capacitor having a working voltage double that of the formation voltage of the powered anode. The floating anode acts as cathode to the powered anode and as an anode to the cathode, such that the capacitor according to the present invention supports half the working voltage between the cathode and the floating anode and half the working voltage between the floating anode and the powered anode. The arrangement of the cathode, floating anode and powered anode according to the present invention results in a single capacitor with half the capacitance and twice the voltage of a single anode device.
    • 本发明涉及一种在电容器的阴极和有源阳极之间具有新颖的浮动阳极的电解电容器,从而产生一个单个电容器,其工作电压与受电阳极的地层电压的两倍。 浮动阳极充当电源阳极的阴极和作为阴极的阳极,使得根据本发明的电容器支持阴极和浮动阳极之间的工作电压的一半,并且浮动阳极与浮动阳极之间的工作电压的一半 电动阳极。 根据本发明的阴极,浮动阳极和动力阳极的布置导致具有单个阳极器件的电容的一半和两倍的单个电容器。
    • 5. 发明授权
    • Creation of porous anode foil by means of an electrochemical drilling process
    • 通过电化学钻孔工艺制造多孔阳极箔
    • US06802954B1
    • 2004-10-12
    • US10199846
    • 2002-07-18
    • Ralph Jason HemphillThomas V. GrahamThomas F. Strange
    • Ralph Jason HemphillThomas V. GrahamThomas F. Strange
    • B23H1100
    • G06Q10/10C25F3/02C25F3/04C25F3/14H01G9/055
    • The present invention is directed to a method of creating porous anode foil for use in multiple anode stack configuration electrolytic capacitors, producing a pore structure that is microscopic in pore diameter and spacing, allowing for increased energy density with a minimal increase in ESR. Initially, an anode metal foil is etched, according to a conventional etch process, to produce an enlargement of surface area. The etched foil is then placed into the electrochemical drilling solution of the present invention. Alternatively, the etched foil may be masked, so that only small areas of the etched foil are exposed, prior to being placed in the electrochemical drilling solution. A DC power supply is used to electrochemically etch the masked or unmasked foil in the electrochemical drilling solution of the present invention such that pores on the order of a few microns diameter are produced through the foil. The electrochemical drilling solution of the present invention consists of 1 to 15% by weight sodium chloride, preferably 5% by weight, and 10 to 5000 PPM of a surface passivator, such as sodium nitrate or phosphoric acid, preferably 500 PPM. Finally, the foil pores are widened and the foil is formed to the intended use voltage according to conventional widening and forming processes. When used in conjunction with an electrochemical etch preceding it and an electrochemical widening step following it, the electrochemical drilling step of the present invention results in an electrically porous foil which maintains the high capacitance gain produced by the etching and widening steps alone, but, when used in a multiple anode stack configuration, exhibits a reduced equivalent series resistance.
    • 本发明涉及一种用于多阳极堆叠配置电解电容器的多孔阳极箔的制造方法,其产生孔径和间距微观的孔结构,从而允许以ESR最小增加的能量密度增加。 首先,根据常规的蚀刻工艺蚀刻阳极金属箔,以产生表面积的增大。 然后将蚀刻的箔放入本发明的电化学钻井溶液中。 或者,蚀刻的箔可以被掩蔽,使得在被放置在电化学钻井溶液中之前,只有小的蚀刻箔的面积被暴露。 直流电源用于电化学蚀刻本发明的电化学钻井溶液中的掩蔽或未掩模的箔,使得通过箔产生约几微米直径的孔。 本发明的电化学钻井溶液由1至15重量%的氯化钠,优选5重量%和10至5000PPM的表面钝化剂,例如硝酸钠或磷酸,优选500PPM组成。 最后,根据传统的加宽和成形方法,箔片孔被加宽并且箔形成为预期的使用电压。 当与其前面的电化学蚀刻和其后的电化学扩展步骤结合使用时,本发明的电化学钻孔步骤产生电极多孔箔,其保持仅由蚀刻和扩大步骤产生的高电容增益,但是当 用于多重阳极堆叠配置中,具有降低的等效串联电阻。
    • 6. 发明授权
    • Floating anode DC electrolytic capacitor
    • 浮阳极直流电解电容器
    • US06377442B1
    • 2002-04-23
    • US09668018
    • 2000-09-21
    • Thomas F. StrangeTimothy R. MarshallThomas V. Graham
    • Thomas F. StrangeTimothy R. MarshallThomas V. Graham
    • H01G904
    • H01G9/04A61N1/3956H01G9/00
    • The present invention is directed to an electrolytic capacitor having a novel floating anode between the cathode and the powered anode of the capacitor, resulting in a single capacitor having a working voltage double that of the formation voltage of the powered anode. The floating anode acts as cathode to the powered anode and as an anode to the cathode, such that the capacitor according to the present invention supports half the working voltage between the cathode and the floating anode and half the working voltage between the floating anode and the powered anode. The arrangement of the cathode, floating anode and powered anode according to the present invention results in a single capacitor with half the capacitance and twice the voltage of a single anode device.
    • 本发明涉及一种在电容器的阴极和有源阳极之间具有新颖的浮动阳极的电解电容器,从而产生一个单个电容器,其工作电压与受电阳极的地层电压的两倍。 浮动阳极充当电源阳极的阴极和作为阴极的阳极,使得根据本发明的电容器支持阴极和浮动阳极之间的工作电压的一半,并且浮动阳极与浮动阳极之间的工作电压的一半 电动阳极。 根据本发明的阴极,浮动阳极和动力阳极的布置导致具有单个阳极器件的电容的一半和两倍的单个电容器。