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1. 发明授权

US5756637A Polymeric materials suitable as dispersing resins 失效
标题翻译：适合作为分散树脂的聚合材料
公开(公告)号：US5756637A
公开(公告)日：1998-05-26
申请号：US643587
申请日：1996-05-06
申请人： Gregor Brodt , Josef Schelble , August Lehner , Franz Weingart , Albert Kohl , Ria Kress , Norbert Schneider
发明人： Gregor Brodt , Josef Schelble , August Lehner , Franz Weingart , Albert Kohl , Ria Kress , Norbert Schneider
IPC分类号： C08L75/04 , C08G18/10 , C08G18/62 , C08G18/65 , C08G18/83 , C08L75/00 , C08L101/00 , C08L101/12 , C09D5/23 , G11B5/702 , G11B5/73
CPC分类号： G11B5/7021 , C08G18/10 , C08G18/6245 , C08G18/831 , Y10S428/90
摘要： A polymeric material I is obtainable by reacting 1) a polymer II of a) from 80 to almost 100 mol % of a C.sub.1 -C.sub.25 -alkyl ester of an .alpha.,.beta.-unsaturated carboxylic acid, b) from 0 to 20 mol % of one or more further monomers and c) an initiator and/or regulator by means of which the majority of the polymer chains of the polymer II are terminated at one of their ends by a hydroxyl group, 2) with a polyfunctional nonaromatic isocyanate III to give a reaction product IV, the amount of isocyanate groups being from 1.2 to 3.9 mol per mole of the hydroxyl groups in II, 3) reacting IV with a) a compound V, containing groups reactive toward isocyanates, to give a reaction product VI, the amount of reactive groups being from 2 to 7 mol per mole of the free isocyanate groups still present in IV, and reacting VI with a compound VII to give the polymer I, which reacts with the reactive groups which are still free in VI and by means of which acidic groups are introduced into VI, or b) a compound VIII which contains groups reactive toward isocyanates and by means of which the acidic groups are introduced into IV, to give the polymer I. The polymeric materials can be used as dispersing resin for pigment-containing coatings, in particular for the production of magnetic recording materials.
摘要翻译：聚合物材料I可通过以下步骤获得：a）a）80至几乎100摩尔％的α，β-不饱和羧酸的C 1 -C 25烷基酯的聚合物II，b）0至20摩尔％一个或多个另外的单体和c）引发剂和/或调节剂，聚合物II的大部分聚合物链通过羟基在其一端终止，2）与多官能非芳族异氰酸酯III一起给出反应产物IV，II中每摩尔羟基的异氰酸酯基团的量为1.2至3.9摩尔，3）使IV与a）包含对异氰酸酯反应的基团的化合物V反应，得到反应产物VI，反应基团的量相对于IV中仍然存在的每摩尔游离异氰酸酯基团为2至7摩尔，并且使VI与化合物VII反应，得到聚合物I，其与VI中仍具有自由基的反应性基团反应，其中酸性基团被引入VI中，或b）化合物V III，其含有对异氰酸酯具有反应性的基团，并且通过其将酸性基团引入到IV中，得到聚合物I.聚合物材料可用作含颜料的涂料的分散树脂，特别是用于制备磁性记录材料。

2. 发明授权

US5543226A Magnetic recording media 失效
标题翻译：磁记录媒体
公开(公告)号：US5543226A
公开(公告)日：1996-08-06
申请号：US992742
申请日：1992-12-18
申请人： Michael Bobrich , August Lehner , Hermann Roller , Rudolf Suettinger , Ria Kress , Norbert Schneider , Werner Lenz , Peter Engelhardt , Peter Rudolf , Gregor Brodt , Werner Balz , Albert Kohl
发明人： Michael Bobrich , August Lehner , Hermann Roller , Rudolf Suettinger , Ria Kress , Norbert Schneider , Werner Lenz , Peter Engelhardt , Peter Rudolf , Gregor Brodt , Werner Balz , Albert Kohl
IPC分类号： C09D175/16 , C08G18/10 , C08G18/62 , C09D4/02 , C09D5/23 , C09D175/14 , G11B5/702 , G11B5/66 , B32B27/00
CPC分类号： G11B5/7021 , C08G18/10 , C08G18/6229 , Y10S428/90 , Y10T428/31551 , Y10T428/31609
摘要： Magnetic recording media consist of a nonmagnetic substrate and at least one magnetizable layer bonded thereon and based on a magnetic material dispersed in at least one polyurethane and one polyurethaneurea (meth)acrylate, the polyurethaneurea (meth)acrylate being obtained by reacting a hydroxyl-containing poly(meth)acrylate with a mixture of di- and polyisocyanates and converting the remaining NCO groups with ammonia or primary or secondary amines into urea groups.
摘要翻译：磁记录介质由非磁性基片和至少一个可磁化层组成，并且基于分散在至少一种聚氨酯和一种聚氨酯脲（甲基）丙烯酸酯中的磁性材料，所述聚氨酯脲（甲基）丙烯酸酯是通过使含羟基的聚（甲基）丙烯酸酯与二异氰酸酯和多异氰酸酯的混合物，并将剩余的NCO基团与氨或伯或仲胺转化成脲基团。

3. 发明授权

US5922469A Materials suitable as crosslinkable binder components 失效
标题翻译：适合作为可交联粘合剂组分的材料
公开(公告)号：US5922469A
公开(公告)日：1999-07-13
申请号：US839703
申请日：1997-04-15
申请人： Thomas Wunsch , Gregor Brodt , Ria Kress , Norbert Schneider , Albert Kohl , August Lehner , Werner Balz
发明人： Thomas Wunsch , Gregor Brodt , Ria Kress , Norbert Schneider , Albert Kohl , August Lehner , Werner Balz
IPC分类号： C08G18/12 , C08G18/61 , C08G18/65 , C08G18/66 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702 , B32B27/40
CPC分类号： G11B5/7021 , C08G18/12 , C08G18/61 , C08G18/6517 , C08G18/6535 , C08G18/6637 , Y10S428/90 , Y10T428/31609
摘要： Preparation of materials (I) having an average molecular weight from 4000 to 30,000, obtainable by reacting1) a polyurethane (II) comprisinga) 1 mol of a diol (III) having an average molecular weight of from 400 to 4000,b) from 0.3 to 9 mol of an aliphatic or cycloaliphatic diol (IV) of 2 to 18 carbon atoms,c) from 0.3 to 9 mol of an aromatic diol (V) of 8 to 30 carbon atoms,d) from 0.01 to 1 mol of a trihydric alcohol (VI) of 3 to 18 carbon atoms,e) from 0.001 to 1 mol of a polyhydric alcohol (VII) of 3 to 14 carbon atoms which contains a tertiary amino group andf) an amount of a diisocyanate (VIII) of 6 to 30 carbon atoms such that the molar ratio of the isocyanate groups to the total number of hydroxyl groups in (III) to (VII) is from 1.05:1 to 1.4:1with2) a compound (IX) which contains one or more hydroxyl groups and one or more amino groups reactive toward isocyanate groups, the amount of (IX) being such that the number of reactive amino groups corresponds to the number of isocyanate groups in the polyurethane (II).The materials may be used as crosslinkable binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
摘要翻译：制备平均分子量为4000〜30,000的材料（I），其可通过使1）包含a）1摩尔平均分子量为400至4000的二醇（III）的聚氨酯（II）得到，b） 2〜18个碳原子的脂肪族或脂环族二醇（Ⅳ）为0.3〜9摩尔，c）0.3〜9摩尔碳原子数为8〜30的芳香族二醇（Ⅴ），d）0.01〜1摩尔 3〜18个碳原子的三元醇（Ⅵ），e）0.001〜1摩尔含有叔氨基的3〜14个碳原子的多元醇（Ⅶ），f）二异氰酸酯（Ⅷ）（III）至（VII）中的异氰酸酯基团与羟基的总摩尔比为1.05:1至1.4:1，其中2）含有一个或多个的化合物（IX）或更多的羟基和一个或多个对异氰酸酯基反应的氨基，（IX）的量使得反应性氨基的数量对应于数目o 聚氨酯（II）中的异氰酸酯基团。这些材料可以用作含颜料的涂料的可交联粘合剂组分，特别是用于生产磁记录材料。

4. 发明授权

US5556918A Polymeric materials suitable as dispersing resins 失效
标题翻译：适合作为分散树脂的聚合材料
公开(公告)号：US5556918A
公开(公告)日：1996-09-17
申请号：US370977
申请日：1995-01-10
申请人： Gregor Brodt , August Lehner , Alfred Lindner , Hermann Graf , Michael Bobrich , Ria Kress , Norbert Schneider , Albert Kohl , Werner Loch
发明人： Gregor Brodt , August Lehner , Alfred Lindner , Hermann Graf , Michael Bobrich , Ria Kress , Norbert Schneider , Albert Kohl , Werner Loch
IPC分类号： C08G18/65 , B01F17/00 , B01F17/52 , C08F2/38 , C08F8/30 , C08F8/32 , C08G18/10 , C08G18/62 , C08G18/78 , C09D5/23 , C09D7/45 , C09D17/00 , C09D175/04 , G11B5/70 , G11B5/702
CPC分类号： G11B5/7023 , B01F17/0028 , C08F8/30 , C08F8/32 , C08G18/10 , C08G18/6245 , C08G18/7831 , C09D17/00 , C09D7/02 , G11B5/7013 , G11B5/7022
摘要： Polymeric materials (I) are obtainable by reacting1. a polymer II comprisinga) from 80 to almost 100 mol % of a C.sub.1 -C.sub.25 -alkyl ester of an .alpha.,.beta.-unsaturated carboxylic acid,b) from 0 to 20 mol % of a further monomer,c) tetrahydrofuran hydroperoxide as polymerization initiator and, if required,d) a further polymerization initiator and/or regulator by means of which the majority of the polymer chains of the polymer II are terminated at one of their ends by a hydroxyl group,2. with a polyfunctional isocyanate III to give a reaction product IV, the amount of isocyanate groups being from 1.2 to 3.0 mol per mol of hydroxyl groups of II, and3. reacting IV with ammonia or with a compound V which has an amino function reactive toward isocyanates.The polymeric materials can be used as dispersing resins for pigment-containing coatings, in particular for the production of magnetic recording materials.
摘要翻译：聚合材料（I）可通过以下方式获得：1.包含a）80至几乎100摩尔％的α，β-不饱和羧酸的C 1 -C 25烷基酯的聚合物II，b）0至20摩尔％的另外的单体，c）四氢呋喃氢过氧化物作为聚合引发剂，如果需要，d）另外的聚合引发剂和/或调节剂，聚合物II的大部分聚合物链通过其一端终止于羟基，2.与多官能异氰酸酯III反应，得到反应产物IV，异氰酸酯基团的量为每摩尔II的羟基为1.2-3.0摩尔，和3.将IV与氨或与化合物V反应对异氰酸酯反应的氨基官能团。聚合物材料可以用作含颜料的涂料的分散树脂，特别是用于生产磁记录材料。

5. 发明授权

US5424132A Magnetic recording media 失效
标题翻译：磁记录媒体
公开(公告)号：US5424132A
公开(公告)日：1995-06-13
申请号：US132856
申请日：1993-10-07
申请人： Michael Bobrich , Gregor Brodt , Ria Kress , Milena Melzer , Norbert Schneider
发明人： Michael Bobrich , Gregor Brodt , Ria Kress , Milena Melzer , Norbert Schneider
IPC分类号： C09D5/23 , C08G18/10 , C08G18/62 , C09D175/04 , G11B5/702 , G11B5/842 , G11B5/00
CPC分类号： G11B5/7021 , C08G18/10 , C08G18/6229 , Y10S428/90 , Y10T428/31609
摘要： Magnetic recording media consist of a nonmagnetic substrate and at least one magnetizable layer which is firmly applied thereon is based on a magnetic material dispersed in at least one polyureaurethane and a polyurethaneurea (meth)acrylate, the polyurethaneurea (meth)acrylate being obtained by reacting a polyacrylate with a mixture of di- and polyisocyanates and converting the remaining NCO groups into substituted urea groups with aminoalkyltrialkoxysilanes.
摘要翻译：磁性记录介质由非磁性基材组成，并且至少一个可牢固涂覆在其上的可磁化层基于分散在至少一种聚脲氨酯和聚氨酯脲（甲基）丙烯酸酯中的磁性材料，聚氨酯脲（甲基）丙烯酸酯通过使聚丙烯酸酯与二异氰酸酯和多异氰酸酯的混合物，并将氨基烷基三烷氧基硅烷转化成取代的脲基团。

6. 发明授权

US5473042A Materials suitable as crosslinkable binder components 失效
标题翻译：适合作为可交联粘合剂组分的材料
公开(公告)号：US5473042A
公开(公告)日：1995-12-05
申请号：US370608
申请日：1995-01-10
申请人： Gregor Brodt , Thomas Wunsch , August Lehner , Albert Kohl
发明人： Gregor Brodt , Thomas Wunsch , August Lehner , Albert Kohl
IPC分类号： C08G18/12 , C08G18/65 , C09D5/23 , G11B5/702 , C08G18/10
CPC分类号： G11B5/7021 , C08G18/12 , C08G18/6517 , C08G18/6535
摘要： A material suitable as crosslinking binder component for pigment-containing coatings and having an average molecular weight of from 25,000 to 150,000, obtainable by reacting a polyurethane comprising a diol having a molecular weight between 400 and 4,000, an aliphatic or cycloaliphatic diol of 2-18 carbon atoms, an aromatic diol of 8-36 carbon atoms, a trihydric or polyhydric alcohol of 3-18 carbon atoms, a polyhydric alcohol of 3-40 carbon atoms containing a tertiary amino group, and a diisocyanate of 3-34 carbon atoms with a compound containing one or more hydroxyl groups and one or more amino groups reactive toward isocyanate groups. The materials may be used as crosslinkable binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
摘要翻译：适合作为含颜料的涂料的交联粘合剂组分的材料，其平均分子量为25,000至150,000，可通过使包含分子量为400至4000的二醇的聚氨酯，2-18的脂族或脂环族二醇碳原子，8-36个碳原子的芳族二醇，3-18个碳原子的三元或多元醇，含有叔氨基的3-40个碳原子的多元醇和3-34个碳原子的二异氰酸酯与含有一个或多个羟基和一个或多个对异氰酸酯基团反应的氨基的化合物。这些材料可以用作含颜料的涂料的可交联粘合剂组分，特别是用于生产磁记录材料。

7. 发明授权

US5552229A Magnetic recording medium containing magnetic material dispersed in a polyurethaneurea-polyurethane binder 失效
标题翻译：含有分散在聚氨酯脲 - 聚氨酯粘合剂中的磁性材料的磁记录介质
公开(公告)号：US5552229A
公开(公告)日：1996-09-03
申请号：US314956
申请日：1994-09-29
申请人： Gregor Brodt , Attila Vass , Werner Loch , August Lehner , Werner Lenz , Norbert Schneider
发明人： Gregor Brodt , Attila Vass , Werner Loch , August Lehner , Werner Lenz , Norbert Schneider
IPC分类号： C08G18/10 , C08G18/62 , C08G18/78 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702
CPC分类号： G11B5/7021 , C08G18/10 , C08G18/6245 , C08G18/7831 , C09D175/04 , Y10S428/90 , Y10T428/31609
摘要： In magnetic recording media consisting of a nonmagnetic substrate and at least one magnetizable layer firmly applied thereon and based on magnetic material dispersed in a binder mixture which contains at least one hydroxyl-containing, preferably low molecular weight polyureaurethane and one polyurethaneurea (meth)acrylate, the polyurethaneurea (meth)acrylate is obtained by reacting a poly(meth)acrylate having up to 2 terminal OH groups per mol and a molecular weight of from 200 to 50,000 with a mixture of aliphatic polyisocyanates having an average functionality of from 3.0 to 6.0 NCO groups per mol, consisting offrom 0.1 to 10% by weight of a diisocyanate, from 30 to 80% by weight of a triisocyanate and from 20 to 60% by weight of an isocyanate having a functionality of from 4 to 10, with the proviso that from 1.2 to 3.0 NCO groups react per OH group and the remaining NCO groups are converted into substituted terminal urea groups with a polyfunctional amine or with a mixture of different polyfunctional amines.
摘要翻译：在由非磁性基材和至少一个可牢固施加的可磁化层组成的磁记录介质中，并且基于分散在包含至少一种含羟基，优选低分子量聚脲氨酯和一种聚氨酯脲（甲基）丙烯酸酯的粘合剂混合物中的磁性材料，聚氨酯脲（甲基）丙烯酸酯通过使平均官能度为3.0〜6.0NCO的脂肪族聚异氰酸酯的混合物使每摩尔具有2个末端OH基的分子量为200〜50,000的聚（甲基）丙烯酸酯与分子量为200〜由0.1至10重量％的二异氰酸酯，30至80重量％的三异氰酸酯和20至60重量％的官能度为4至10的异氰酸酯组成，其条件是 1.2至3.0个NCO基团每OH基团反应，剩余的NCO基团用多官能胺或与diffe的混合物转化为取代的末端脲基团租用多官能胺。

8. 发明申请

US20050245427A1 Use of compolymer containing alkylene oxide units, as an additive in detergents and cleansers 审中-公开
标题翻译：使用含有烯化氧单元的复合物作为洗涤剂和清洁剂中的添加剂
公开(公告)号：US20050245427A1
公开(公告)日：2005-11-03
申请号：US10516201
申请日：2003-06-04
申请人： Pia Baum , Kathrin Michl , Franz Weingart , Stephan Nied , Gregor Brodt
发明人： Pia Baum , Kathrin Michl , Franz Weingart , Stephan Nied , Gregor Brodt
IPC分类号： C08F290/06 , C11D3/37
CPC分类号： C11D3/3757
摘要： Use of copolymers containing alkylene oxide units which comprise (a) 50 to 93 mol % of acrylic acid and/or a water-soluble salt of acrylic acid, (b) 5 to 30 mol % of methacrylic acid and/or a water-soluble salt of methacrylic acid and (c) 2 to 20 mol % of at least one nonionic monomer of formula I in which the variables have the following meanings: R1 is hydrogen or methyl; R2 is a chemical bond or unbranched or branched C1-C6-alkylene; R3 are identical or different unbranched or branched C2-C4-alkylene radicals; R4 is unbranched or branched C1-C6-alkyl; n is 3 to 50, in random or block copolymerized form, as additive for detergents and cleaners.
摘要翻译：使用包含环氧烷单元的共聚物，其包含（a）50-93摩尔％的丙烯酸和/或丙烯酸的水溶性盐，（b）5-30摩尔％的甲基丙烯酸和/或水溶性甲基丙烯酸的盐和（c）2-20摩尔％的至少一种式I的非离子单体，其中变量具有以下含义：R 1是氢或甲基; R 2是化学键或无支链或支链C 1 -C 6 - 亚烷基; R 3是相同或不同的未支链或支链C 2 -C 4 - 亚烷基; R 4是非支链或支链C 1 -C 6 - 烷基; n为3至50，以无规或嵌段共聚形式，作为洗涤剂和清洁剂的添加剂。

9. 发明授权

US07645345B2 Use of copolymers containing sulfonic acid groups, as an additive in detergents and cleansers 失效
标题翻译：使用含有磺酸基团的共聚物作为洗涤剂和清洁剂中的添加剂
公开(公告)号：US07645345B2
公开(公告)日：2010-01-12
申请号：US12181900
申请日：2008-07-29
申请人： Pia Baum , Kathrin Michl , Franz Weingart , Stephan Nied , Gregor Brodt
发明人： Pia Baum , Kathrin Michl , Franz Weingart , Stephan Nied , Gregor Brodt
IPC分类号： B08B3/04 , C11D3/37
CPC分类号： C11D3/378
摘要： Use of copolymers containing sulfonic acid groups which comprise (a) 30 to 95 mol % of at least one monoethylenically unsaturated carboxylic acid, one monoethylenically unsaturated carboxylic ester or one water-soluble salt of a monoethylenically unsaturated carboxylic acid, (b) 3 to 35 mol % of at least one monomer containing sulfonic acid groups of the formula I in which the variables have the following meanings: R is hydrogen or methyl; X is a chemical bond or —COO—R1—; R1 is unbranched or branched C1-C4-alkylene; M is hydrogen, alkali metal or ammonium, and (c) 2 to 35 mol % of at least one nonionic monomer of the formula II in which the variables have the following meanings: R2 is hydrogen or methyl; R3 is a chemical bond or unbranched or branched C1-C6-alkylene; R4 are identical or different unbranched or branched C2-C4-alkylene radicals; R5 is unbranched or branched C1-C6-alkyl, C5-C8-cycloalkyl or aryl; n is 3 to 50, in random or block copolymerized form, as additive for detergents and cleaners.
摘要翻译：使用包含（a）30-95摩尔％至少一种单烯属不饱和羧酸，一种单烯属不饱和羧酸酯或一种单烯属不饱和羧酸的一种水溶性盐的磺酸基团的共聚物，（b）3-35 mol％的至少一种含有式I磺酸基的单体，其中变量具有以下含义：R是氢或甲基; X是化学键或-COO-R 1; R1是无支链或支链C1-C4-亚烷基; M是氢，碱金属或铵，和（c）2-35mol％的至少一种式II的非离子单体，其中变量具有以下含义：R 2是氢或甲基; R3是化学键或无支链或支链C1-C6-亚烷基; R4是相同或不同的非支链或支链C 2 -C 4 - 亚烷基; R5是无支链或支链C 1 -C 6 - 烷基，C 5 -C 8 - 环烷基或芳基; n为3至50，以无规或嵌段共聚形式，作为洗涤剂和清洁剂的添加剂。

10. 发明申请

US20080281053A1 USE OF COPOLYMERS CONTAINING SULFONIC ACID GROUPS, AS AN ADDITIVE IN DETERGENTS AND CLEANSERS 失效
标题翻译：含有硫酸组合物的共聚物作为添加剂在洗涤剂和清洁剂中的应用
公开(公告)号：US20080281053A1
公开(公告)日：2008-11-13
申请号：US12181900
申请日：2008-07-29
申请人： Pia Baum , Kathrin Michl , Franz Weingart , Stephan Nied , Gregor Brodt
发明人： Pia Baum , Kathrin Michl , Franz Weingart , Stephan Nied , Gregor Brodt
IPC分类号： C08F228/02 , C08F230/04
CPC分类号： C11D3/378
摘要： Use of copolymers containing sulfonic acid groups which comprise (a) 30 to 95 mol % of at least one monoethylenically unsaturated carboxylic acid, one monoethylenically unsaturated carboxylic ester or one water-soluble salt of a monoethylenically unsaturated carboxylic acid, (b) 3 to 35 mol % of at least one monomer containing sulfonic acid groups of the formula I in which the variables have the following meanings: R is hydrogen or methyl; X is a chemical bond or —COO—R1—; R1 is unbranched or branched C1-C4-alkylene; M is hydrogen, alkali metal or ammonium, and (c) 2 to 35 mol % of at least one nonionic monomer of the formula II in which the variables have the following meanings: R2 is hydrogen or methyl; R3 is a chemical bond or unbranched or branched C1-C6-alkylene; R4 are identical or different unbranched or branched C2-C4-alkylene radicals; R5 is unbranched or branched C1-C6-alkyl, C5-C8-cycloalkyl or aryl; n is 3 to 50, in random or block copolymerized form, as additive for detergents and cleaners.
摘要翻译：使用包含（a）30-95摩尔％至少一种单烯属不饱和羧酸，一种单烯属不饱和羧酸酯或一种单烯属不饱和羧酸的一种水溶性盐的磺酸基团的共聚物，（b）3-35 mol％的至少一种含有式I磺酸基的单体，其中变量具有以下含义：R是氢或甲基; X是化学键或-COO-R 1 - R 1是非支链或支链C 1 -C 4 - 亚烷基; M是氢，碱金属或铵，和（c）2-35mol％的至少一种式II的非离子单体，其中变量具有以下含义：R 2是氢或甲基 ; R 3是化学键或无支链或支链C 1 -C 6 - 亚烷基; R 4是相同或不同的未支链或支链C 2 -C 4 - 亚烷基; R 5是非支链或支链C 1 -C 6 - 烷基，C 5 -C 8 环烷基或芳基; n为3至50，以无规或嵌段共聚形式，作为洗涤剂和清洁剂的添加剂。

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