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1. 发明授权

US4609612A Photopolymerizable composition and process with liquid mixture of photoinitiators and ethylenically unsaturated compound 失效
标题翻译：光聚合组合物和光引发剂与烯属不饱和化合物的液体混合物的方法
公开(公告)号：US4609612A
公开(公告)日：1986-09-02
申请号：US784429
申请日：1985-10-04
申请人： Godwin Berner , Aloysius H. Manse
发明人： Godwin Berner , Aloysius H. Manse
IPC分类号： C09K3/00 , C08F2/00 , C08F2/50 , C09D4/00 , C09D5/00 , C09D11/00 , C09D11/10 , G03F7/028 , G03F7/031 , G03C1/76
CPC分类号： C08F2/50 , G03F7/031 , Y10S430/123 , Y10S430/124 , Y10S430/125 , Y10S430/126
摘要： There are obtained by mixing together approximately equal parts of 1-benzoylcyclohexanol and benzophenone or a benzophenone derivative liquid mixtures which possess a high activity as photoinitiators for the polymerization of ethylenically unsaturated compounds. The level of activity is higher than that of the individual components taken separately.
摘要翻译：通过将大约等份的1-苯甲酰基环己醇和二苯甲酮或具有高活性的二苯甲酮衍生物液体混合物混合在一起获得，所述液体混合物作为光引发剂用于烯键式不饱和化合物的聚合。活动水平高于单独采取的单个组件。

2. 发明授权

US5510539A Liquid photoinitiator mixtures 失效
标题翻译：液体光引发剂混合物
公开(公告)号：US5510539A
公开(公告)日：1996-04-23
申请号：US315991
申请日：1994-09-30
申请人： Godwin Berner , Franciszek Sitek , Rinaldo Husler
发明人： Godwin Berner , Franciszek Sitek , Rinaldo Husler
IPC分类号： C07F7/28 , C07C45/00 , C07C49/84 , C07C67/00 , C07C69/675 , C07C213/00 , C07C217/10 , C07D317/26 , C07D317/72 , C07D407/04 , C08F2/48 , C08F2/50 , C08F4/42 , C09D4/00 , C09D5/00 , C09D11/00 , G03F7/028 , G03F7/029
CPC分类号： C08F2/50 , G03F7/029
摘要： Liquid highly active photoinitiators are obtained by dissolving a solid photoinitiator of the titanocene type in liquid photoinitiators of the acetal or ketal type. The liquid mixtures have a long dark storage stability.
摘要翻译：通过将二茂钛型固体光引发剂溶解在缩醛或缩酮类的液体光引发剂中来获得液体高活性光引发剂。液体混合物具有长的暗储存稳定性。

3. 发明授权

US5145885A Photopolymerizable compositions containing aminoaryl ketone photoinitiators 失效
标题翻译：含有氨基芳基酮光引发剂的光聚合组合物
公开(公告)号：US5145885A
公开(公告)日：1992-09-08
申请号：US612752
申请日：1990-11-13
申请人： Godwin Berner , Kurt Meier , Kurt Dietliker , Rinaldo Husler
发明人： Godwin Berner , Kurt Meier , Kurt Dietliker , Rinaldo Husler
IPC分类号： C08F2/50 , G03F7/031
CPC分类号： G03F7/031 , C08F2/50
摘要： The photopolymerizable composition described containsA) at least one ethylenically unsaturated photopolymerizable compound,B) a photoinitiator of the formula I ##STR1## and C) a photosensitizer from the group of aromatic carbonyl compounds having a triplet energy of 225-310 kJ/mol, for example xanthones, thioxanthones, coumarins, phthalimides, phenones and the like.Ar is phenyl substituted in the 4-position by a substituted amino group, R.sup.1 and R.sup.2 are alkyl, R.sup.3 and R.sup.4 are alkyl or alkoxyalkyl, or R.sup.3 and R.sup.4 together are 3-oxapentamethylene. Said sensitizers C) raise the activity of said photoinitiators (B) without shortening the shelf life of the mixtures. The photocurable mixtures are used especially as binders for printing inks or paints.
摘要翻译：所述的可光聚合组合物包含A）至少一种烯属不饱和光聚合化合物，B）式I的光引发剂，和C）来自具有225-310的三线态能量的芳族羰基化合物的光敏剂 kJ / mol，例如呫吨酮，噻吨酮，香豆素，邻苯二甲酰亚胺，苯酮等。 Ar是在4位被取代的氨基取代的苯基，R 1和R 2是烷基，R 3和R 4是烷基或烷氧基烷基，或者R 3和R 4一起是3-氧杂五亚甲基。所述敏化剂C）提高所述光引发剂（B）的活性，而不会缩短混合物的保质期。可光固化的混合物特别用作印刷油墨或涂料的粘合剂。

4. 发明授权

US4952620A Photolytically cleavable N-acylated sterically hindered amines 失效
标题翻译：可光解裂解的N-酰化空间位阻胺
公开(公告)号：US4952620A
公开(公告)日：1990-08-28
申请号：US231315
申请日：1988-08-12
申请人： Godwin Berner , Mario Slongo
发明人： Godwin Berner , Mario Slongo
IPC分类号： C07D211/46 , C07D235/02 , C07D241/08 , C07D471/10 , C07D491/113 , C08K5/3435
CPC分类号： C07D235/02 , C07D211/46 , C07D471/10 , C08K5/3435
摘要： Sterically hindered cyclic amines which are substituted by a photoactivatable acyl group at the basic nitrogen atom can be deacylated by irradiation with UV light. This is advantageous if the basicity of the amines proves troublesome during application. Examples of such photoactivatable acyl groups are phenylglyoxyl, phenylacetyl or naphthylacetyl groups.

5. 发明授权

US4785102A Photolytically cleavable, N-acylated sterically hindered amines 失效
标题翻译：可光解裂解的N-酰化空间位阻胺
公开(公告)号：US4785102A
公开(公告)日：1988-11-15
申请号：US899133
申请日：1986-08-21
申请人： Godwin Berner , Mario Slongo
发明人： Godwin Berner , Mario Slongo
IPC分类号： C07D211/46 , C07D235/02 , C07D241/08 , C07D471/10 , C07D491/113 , C08K5/3435
CPC分类号： C07D235/02 , C07D211/46 , C07D471/10 , C08K5/3435
摘要： Sterically hindered cyclic amines which are substituted by a photoactivatable acyl group at the basic nitrogen atom can be deacylated by irradiation with UV light. This is advantageous if the basicity of the amines proves troublesome during application. Examples of such photoactivatable acyl groups are phenylglyoxyl, phenylacetyl or naphthylacetyl groups.
摘要翻译：在碱性氮原子上被可光活化的酰基取代的受阻的环胺可以通过用UV光照射而脱酰基化。如果在施用期间胺的碱度证明是麻烦的，这是有利的。这种可光活化酰基的实例是苯基乙二醛酰基，苯乙酰基或萘基乙酰基。

6. 发明授权

US4344876A Stabilization of acid catalyzed stoving lacquers 失效
标题翻译：酸催化烤漆的稳定化
公开(公告)号：US4344876A
公开(公告)日：1982-08-17
申请号：US211480
申请日：1980-11-28
申请人： Godwin Berner
发明人： Godwin Berner
IPC分类号： C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/3435 , C08L33/00 , C08L33/02 , C08L33/04 , C08L67/00 , C09D7/12 , C09D133/04 , C09D133/08 , C09D167/00 , C09D201/00 , C09D3/28 , C09D3/81
CPC分类号： C08K5/3435 , C09D7/1241 , Y10T428/31688
摘要： Use of N-substituted 2,2,6,6-tetraalkylpiperidine compounds, their acid addition salts or complexes with metal compounds, optionally together with further stabilizers, for stabilizing acid catalyzed stoving lacquers based on hot cross-linkable acrylic or alkyd resins against the action of light, moisture and oxygen.
摘要翻译：使用N-取代的2,2,6,6-四烷基哌啶化合物，其酸加成盐或与金属化合物的络合物，任选地与其它稳定剂一起，用于基于可热交联的丙烯酸或醇酸树脂对酸催化的烘烤漆进行稳定光，水分和氧气的作用。

7. 发明授权

US4336366A Thermally polymerizable mixtures and processes for the thermally-initiated polymerization of cationically polymerizable compounds 失效
标题翻译：用于阳离子聚合的化合物的热引发聚合的热可聚合混合物和方法
公开(公告)号：US4336366A
公开(公告)日：1982-06-22
申请号：US236465
申请日：1981-02-20
申请人： Godwin Berner , Rudolf Kirchmayr
发明人： Godwin Berner , Rudolf Kirchmayr
IPC分类号： C08F2/50 , C08F4/00 , C08F4/06 , C08G59/00 , C08G59/68 , C08G65/10 , C08G75/06 , C08G85/00 , C08L33/00 , C08L33/02 , C08L61/00 , C08L61/04 , C08L61/20 , C08L67/00 , C08K5/06 , C08K5/11
CPC分类号： C08G59/68 , C08G65/105 , C08G75/06 , C08G85/00
摘要： Cationically polymerizable compounds, for example cyclic ethers, can be thermally polymerised if an aromatic iodonium salt of the formula I[(Ar.sup.1)(Ar.sup.2)I].sup.+ [MX.sub.n ].sup.- (I)in which Ar.sup.1 Ar.sup.2, M, X and n are as defined in claim 1, is used as the catalyst and an agent which forms free radicals on heating and has the formula III or IV ##STR1## in which R.sup.2, R.sup.3, R.sup.5, R.sup.6, R.sup.8 and m are as defined in claim 1, for example a benzpinacol silyl ether, is used as the co-catalyst. The process is of particular importance for heat-curing epoxide resins as a one-component system.
摘要翻译：如果式I [（Ar1）（Ar2）I] + [MXn] - （I）的芳族碘鎓盐，其中Ar1 + L，Ar2，M，X 和n如权利要求1中所定义，用作催化剂和在加热时形成自由基并具有式III或IV（IV）的试剂，其中R2，R3，R5， R 6，R 8和m如权利要求1所定义，例如苯并三氢甲硅烷基醚用作助催化剂。该方法对于作为单组分体系的环氧树脂的热固化是特别重要的。

8. 发明授权

US5476882A Light-stabilized polymer microparticles 失效
标题翻译：光稳定的聚合物微粒
公开(公告)号：US5476882A
公开(公告)日：1995-12-19
申请号：US139603
申请日：1993-10-18
申请人： Godwin Berner , Manfred Rembold , Jean Rody , Mario Slongo
发明人： Godwin Berner , Manfred Rembold , Jean Rody , Mario Slongo
IPC分类号： C08F2/44 , C08G63/685 , C08K5/00 , C08K5/3435 , C09D7/12 , C08K5/34
CPC分类号： C08F2/44 , C08G63/685 , C08K5/005 , C08K5/3435 , C09D5/024 , C09D7/1241 , C09D7/1266 , C09D7/1275 , C09D7/1283 , C09D7/1291 , C08K5/3475
摘要： Light-stabilized polymer microparticles, which contain at least one light stabilizer, and processes for the preparation of these microparticles by polymerization of suitable monomers, at least a part of the polymerization being carried out in the presence of at least one light stabilizer, are described. The polymer microparticles can be used in coating compositions which comprise a disperse phase containing these particles and a liquid continuous phase.Coatings and finishes based on the compositions according to the invention are distinguished by improved weathering resistance, in particular by a high light stability.
摘要翻译：含有至少一种光稳定剂的光稳定化聚合物微粒和通过合适的单体的聚合制备这些微粒的方法，在至少一种光稳定剂的存在下进行至少一部分聚合。。聚合物微粒可用于包含含有这些颗粒的分散相和液体连续相的涂料组合物中。基于根据本发明的组合物的涂层和表面处理的特征在于改善耐候性，特别是通过高的光稳定性。

9. 发明授权

US5387304A Application of a painted carrier film to a three-dimensional substrate 失效
标题翻译：将涂漆的载体膜应用于三维基材
公开(公告)号：US5387304A
公开(公告)日：1995-02-07
申请号：US32152
申请日：1993-03-15
申请人： Godwin Berner , Ljubomir Misev
发明人： Godwin Berner , Ljubomir Misev
IPC分类号： B29C35/08 , B29C37/00 , B29C43/18 , B29C63/00 , B29C63/22 , C08J5/12 , C08J7/04 , C09J7/02 , B32B27/16
CPC分类号： B29C37/0025 , B29C35/08 , B29C63/0065 , B29C63/22 , C08J5/124 , C08J7/047 , C09J7/0264 , B29C2035/0827 , B29C2035/0833 , B29C2035/0877 , B29C2037/0042 , B29C2791/001 , B29C43/183 , B29K2105/24 , B29K2105/243 , B29L2031/3055 , C08J2433/00 , Y10T156/1028
摘要： A carrier film is coated on one side with a radiation curable paint and on the other with an adhesive. The paint is partially cured by irradiation, the carrier film is heated and, in the thermoplastic state, applied by deep drawing to a three-dimensional substrate. In a final step the paint is completely cured by heat.
摘要翻译：载体膜在一面上涂覆有可辐射固化涂料，另一面涂覆有粘合剂。通过照射部分地固化涂料，载体膜被加热，并且在热塑性状态下通过深拉伸施加到三维基材。在最后一步中，油漆被热量完全固化。

10. 再颁专利

USRE33489E Photolytically cleavable, N-acylated sterically hindered amines 失效
标题翻译：可光解裂解的N-酰化空间位阻胺
公开(公告)号：USRE33489E
公开(公告)日：1990-12-11
申请号：US411962
申请日：1989-09-25
申请人： Godwin Berner , Mario Slongo
发明人： Godwin Berner , Mario Slongo
IPC分类号： C07D211/46 , C07D235/02 , C07D241/08 , C07D471/10 , C07D491/113 , C08K5/3435
CPC分类号： C07D235/02 , C07D211/46 , C07D471/10 , C08K5/3435
摘要： Sterically hindered cyclic amines which are substituted by a photoactivatable acyl group at the basic nitrogen atom can be deacylated by irradiation with UV light. This is advantageous if the basicity of the amines proves troublesome during application. Examples of such photoactivatable acyl groups are phenylglyoxyl, phenylacetyl or naphthylacetyl groups.

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