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1. 发明授权

US06228952B1 Process for the hydrogenation of diene (co)polymers 有权
标题翻译：二烯（共）聚合物氢化方法
公开(公告)号：US06228952B1
公开(公告)日：2001-05-08
申请号：US09184114
申请日：1998-11-02
申请人： Gian Tommaso Viola , Andrea Vallieri , Claudio Cavallo
发明人： Gian Tommaso Viola , Andrea Vallieri , Claudio Cavallo
IPC分类号： C08F804
CPC分类号： C08F8/04 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/2295 , B01J2231/645 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08C19/02
摘要： Catalytic composition effective in the hydrogenation of olefinic double bonds prepared by reaction between: (A) at least one cyclopentadienyl complex of a transition metal having general formula (I) (R)(R1)M1(R2)(R3) wherein R is an anion containing an &eegr;5-cyclopentadienyl ring coordinated to M1; M1 is selected from titanium, zirconium and hafnium; R2 and R3, the same or different, are organic or inorganic anion groups bound to M1; R1 is selected from cyclopentadienyl and R2; (B) an alkylating composition essentially consisting of: (b1) an organometallic compound having general formula (II) M2 (R4)(R5), wherein M2 is selected from Zn and Mg; (b2) an organoderivative of aluminum having general formula (III) Al(R6)3.
摘要翻译：通过以下反应制备的烯烃双键氢化的催化组合物：（A）至少一种具有通式（I）（R）（R）（R 1）（R 2）（R 3）的过渡金属的环戊二烯基配合物，其中R为含有与M1配位的η5-环戊二烯基环的阴离子; M1选自钛，锆和铪; R2和R3相同或不同，是与M1结合的有机或无机阴离子基团; R1选自环戊二烯基和R2;（B）烷基化组合物，其基本上由以下组成：（b1）具有通式（II）的有机金属化合物M2（R4）（R5），其中M2选自Zn和Mg;（b2）具有通式（III）Al（R6）3的铝的有机化合物。

2. 发明授权

US5948869A Process for the preparation of a catalyst useful for the hydrogenation of styrene-butadiene copolymers 失效
标题翻译：制备可用于苯乙烯 - 丁二烯共聚物氢化的催化剂的方法
公开(公告)号：US5948869A
公开(公告)日：1999-09-07
申请号：US882748
申请日：1997-06-26
申请人： Andrea Vallieri , Claudio Cavallo , Gian Tommaso Viola
发明人： Andrea Vallieri , Claudio Cavallo , Gian Tommaso Viola
IPC分类号： B01J31/12 , C08C19/02 , C08F4/614 , C08F8/04 , C08F297/04 , C07C19/02
CPC分类号： C08C19/02 , C08F8/04 , Y10S525/94
摘要： Catalytic composition effective in the selective hydrogenation of olefinic double bonds prepared by the reaction between:(A) at least one bis(cyclopentadienyl)Titanium derivative having the general formula (I) (C.sub.5 H.sub.5).sub.2 Ti(R) (R.sub.1) wherein R and R.sub.1, the same or different, are halogens; the above compound (I) being solid or dispersed in one or more non-solvent diluents;(B) at least one organo derivative having general formula (II) M(R.sub.2) (R.sub.3) wherein M is selected from Zinc and Magnesium, and R.sub.2 and R.sub.3, the same or different, are selected from C.sub.1 -C.sub.16 alkyls;(C) at least one modifier.
摘要翻译：通过以下反应制备的烯烃双键的选择性氢化的催化组合物：（A）至少一种具有通式（I）（C 5 H 5）2 Ti（R）（R 1）的双（环戊二烯基）钛衍生物，其中R和R 1 相同或不同的是卤素; 上述化合物（I）是固体或分散在一种或多种非溶剂稀释剂中; （B）至少一种具有通式（II）M（R2）（R3）的有机衍生物，其中M选自锌和镁，R2和R3相同或不同，选自C 1 -C 16烷基; （C）至少一种改性剂。

3. 发明授权

US07473741B2 Process for the selective hydrogenation of unsaturated (co)polymers 有权
标题翻译：不饱和（共）聚合物的选择性氢化方法
公开(公告)号：US07473741B2
公开(公告)日：2009-01-06
申请号：US11381469
申请日：2006-05-03
申请人： Gian Tommaso Viola , Claudio Cavallo
发明人： Gian Tommaso Viola , Claudio Cavallo
IPC分类号： C08C19/02 , C08F36/02
CPC分类号： C08F8/04 , C08F297/04
摘要： Process for the selective hydrogenation of double olefinic bonds present in polymers and copolymers of conjugated dienes, which comprises: (a) preparation of a hydrocarbon solution of the (co)polymer to be hydrogenated, optionally containing a modifier (C); (b) addition to the above solution of the (co)polymer to be hydrogenated of a catalytic solution formed “in situ” comprising: (b1) at least one bis-(cyclopentadienyl)titanium derivative having general formula (I) (C5H5)2Ti (R) (R1), wherein R and R1, the same or different, are halogens, preferably R═R1═Cl; the above compound (I) being dispersed in one or more non-solvent diluents; (b2) at least one organo-derivative having general formula (II) M(R2)(R3), wherein M is selected from zinc and magnesium, and R2 and R3, the same or different, are selected from C1-C16 alkyls, preferably C1-C8; (b3) at least one modifier (C); the above selective hydrogenation being carried out in a hydrogen atmosphere until the disappearance of the double olefinic bonds.
摘要翻译：存在于共轭二烯的聚合物和共聚物中的双烯键的选择性氢化方法，其包括：（a）制备待氢化的（共）聚合物的烃溶液，任选地含有改性剂（C）; （b）向上述“原位”形成的催化剂溶液中加入待氢化的（共）聚合物的上述溶液，包括：（b1）至少一种具有通式（I）（C5H5）的双 - （环戊二烯基） 2 Ti（R）（R 1），其中R和R 1相同或不同，为卤素，优选R-R1-Cl; 上述化合物（I）分散在一种或多种非溶剂稀释剂中; （b2）至少一种具有通式（II）M（R2）（R3）的有机衍生物，其中M选自锌和镁，R2和R3相同或不同，选自C 1 -C 16烷基，优选C1-C8; （b3）至少一种改性剂（C）; 上述选择性氢化在氢气气氛中进行，直到双重烯键失去。

4. 发明授权

US06235841B1 Hydrogenated block copolymers having a partially branched structure 有权
标题翻译：具有部分支化结构的氢化嵌段共聚物
公开(公告)号：US06235841B1
公开(公告)日：2001-05-22
申请号：US09387798
申请日：1999-09-01
申请人： Claudio Cavallo , Sergio Custro , Gian Tommaso Viola
发明人： Claudio Cavallo , Sergio Custro , Gian Tommaso Viola
IPC分类号： C08L5302
CPC分类号： C08L53/025 , C08F297/04
摘要： Composition of vinylarene/hydrogenated diene block copolymers, the latter being selected from ethylene-butene and ethylene-propylene, characterized in that it comprises: a) copolymers having linear structures from 30% to 60% by weight, preferably from 35% to 50%; b) copolymers having branched structures from 70% to 40% by weight, preferably from 65% to 50%; the sum of components (a) and (b) being equal to 100; the weight average molecular weight of the above composition ranging from 30,000 to 400,000, preferably from 50,000 to 200,000.
摘要翻译：乙烯基芳烃/氢化二烯嵌段共聚物的组成，后者选自乙烯 - 丁烯和乙烯 - 丙烯，其特征在于它包括：a）具有30％至60％（重量），优选35％至50％（重量） ; b）具有70重量％至40重量％，优选65重量％至50重量％的支链结构的共聚物;组分（a）和（b）的总和等于100; 上述组合物的重均分子量为30,000〜400,000，优选为50,000〜200,000。

5. 发明申请

US20100130639A1 VULCANIZABLE BLEND COMPRISING PARTIALLY HYDROGENATED VINYLARENE-CONJUGATED DIENE BRANCHED POLYMERS 有权
标题翻译：包含部分加氢乙烯共聚二烯基支化聚合物的VULCANIZABLE BLIP
公开(公告)号：US20100130639A1
公开(公告)日：2010-05-27
申请号：US12593662
申请日：2008-03-18
申请人： Gian Tommaso Viola , Luca Soddu , Fabio Bacchelli
发明人： Gian Tommaso Viola , Luca Soddu , Fabio Bacchelli
IPC分类号： C08J5/14
CPC分类号： B60C1/0016 , C08C19/02 , C08K3/36 , C08K5/548 , C08L9/00 , C08L9/06 , C08L15/00 , C08L21/00 , C08L2666/08
摘要： A raw elastomeric composition includes: (a1) from 30 to 90% by weight of a partially hydrogenated vinylarene-conjugated diene random elastomeric copolymer; (a2) from 10 to 70% by weight of one or more diene rubbers; (b) from 10 to 150 phr of silica; (c) from 0.1 to 20 phr of a coupling agent based on silane; (d) from 0.1 to 10 phr of a vulcanization agent; wherein the partially hydrogenated vinylarene-conjugated diene random copolymer has a structure which has nodes statistically distributed in the macromolecule, from which polymeric chains branch out, the bond between the nodes and the branches being a carbon-carbon bond.
摘要翻译：原始弹性体组合物包括：（a1）30至90重量％的部分氢化的乙烯基芳烃 - 共轭二烯无规弹性体共聚物; （a2）10〜70重量％的一种或多种二烯橡胶; （b）10至150phr二氧化硅; （c）0.1-20phr基于硅烷的偶联剂; （d）0.1〜10phr硫化剂; 其中部分氢化的乙烯基芳烃 - 共轭二烯无规共聚物具有统计分布在大分子中的结点，聚合物链从该聚合物链分支出来，节点和分支之间的键为碳 - 碳键。

6. 发明授权

US08664344B2 Process for the preparation of branched polybutadiene with a high content of 1,4-cis units 有权
标题翻译：制备具有高含量1,4-顺式单元的支化聚丁二烯的方法
公开(公告)号：US08664344B2
公开(公告)日：2014-03-04
申请号：US12935780
申请日：2009-03-19
申请人： Gian Tommaso Viola , Marianna Zinna
发明人： Gian Tommaso Viola , Marianna Zinna
IPC分类号： C08F4/44 , C08F4/52 , C08F36/06
CPC分类号： C08F36/06 , C08F4/545
摘要： Process for the preparation of polybutadiene effected by the polymerization of butadiene in an aliphatic and/or cyclo-aliphatic solvent in the presence of a catalytic system prepared in situ which comprises: (i) a carboxylate of neodymium soluble in the process solvent containing a variable quantity of water, the H2O/Nd molar ratio ranging from 0.001/1 to 0.50/1; (ii) an alkyl compound of aluminum; (iii) an alkyl compound of aluminum in which at least one bond of Al consists of an Al—Cl bond; The total Al/Nd molar ratio ranging from 4/1 to 12/1, and the Cl/Nd molar ratio ranging from 2/1 to 6/1.
摘要翻译：通过在原位制备的催化体系存在下，通过在脂族和/或环脂族溶剂中聚合丁二烯来制备聚丁二烯的方法，该方法包括：（i）可溶于含有可变的过程溶剂的钕的羧酸盐水量，H2O / Nd摩尔比范围为0.001 / 1〜0.50 / 1; （ii）铝的烷基化合物; （iii）铝的烷基化合物，其中Al的至少一个键由Al-Cl键组成; 总Al / Nd摩尔比范围为4/1至12/1，Cl / Nd摩尔比范围为2/1至6/1。

7. 发明授权

US08367778B2 Process for the elimination of residual mercaptans from nitrile rubbers 有权
标题翻译：从丁腈橡胶中消除残余硫醇的方法
公开(公告)号：US08367778B2
公开(公告)日：2013-02-05
申请号：US12540791
申请日：2009-08-13
申请人： Gian Tommaso Viola , Davide De Santi , Romano Lima
发明人： Gian Tommaso Viola , Davide De Santi , Romano Lima
IPC分类号： C08F20/44 , C08F2/26 , C08F8/34 , C08F36/00
CPC分类号： C08C1/04 , C08C1/14 , C08K3/06 , C08L9/04
摘要： Process for the elimination of residual mercaptans from nitrile rubbers, comprising: a. adding a colloidal emulsion of sulfur to a nitrile latex emulsion (NBR rubber latex) containing free mercaptan and with a pH of between 7 and 14, at a temperature ranging from 30 to 120° C.; b. coagulating the nitrile latex c. washing with demineralized water and drying the NBR rubber recovered after coagulation.
摘要翻译：从丁腈橡胶中除去残余硫醇的方法，包括：a。在含有游离硫醇的腈胶乳乳液（NBR橡胶胶乳）中，在30至120℃的温度范围内加入硫的胶态乳液。 b。凝固腈胶乳c。用软化水洗涤并干燥凝结后回收的NBR橡胶。

8. 发明授权

US08394883B2 Vulcanizable blend comprising partially hydrogenated vinylarene-conjugated diene branched polymers 有权
标题翻译：包含部分氢化的乙烯基芳烃共轭二烯支链聚合物的可硫化混合物
公开(公告)号：US08394883B2
公开(公告)日：2013-03-12
申请号：US12593662
申请日：2008-03-18
申请人： Gian Tommaso Viola , Luca Soddu , Fabio Bacchelli
发明人： Gian Tommaso Viola , Luca Soddu , Fabio Bacchelli
IPC分类号： B60C11/00 , B60C1/00 , C08K3/36 , C08K3/04
CPC分类号： B60C1/0016 , C08C19/02 , C08K3/36 , C08K5/548 , C08L9/00 , C08L9/06 , C08L15/00 , C08L21/00 , C08L2666/08
摘要： A raw elastomeric composition includes: (a1) from 30 to 90% by weight of a partially hydrogenated vinylarene-conjugated diene random elastomeric copolymer; (a2) from 10 to 70% by weight of one or more diene rubbers; (b) from 10 to 150 phr of silica; (c) from 0.1 to 20 phr of a coupling agent based on silane; (d) from 0.1 to 10 phr of a vulcanization agent; wherein the partially hydrogenated vinylarene-conjugated diene random copolymer has a structure which has nodes statistically distributed in the macromolecule, from which polymeric chains branch out, the bond between the nodes and the branches being a carbon-carbon bond.
摘要翻译：原始弹性体组合物包括：（a1）30至90重量％的部分氢化的乙烯基芳烃 - 共轭二烯无规弹性体共聚物; （a2）10〜70重量％的一种或多种二烯橡胶; （b）10至150phr二氧化硅; （c）0.1-20phr基于硅烷的偶联剂; （d）0.1〜10phr硫化剂; 其中部分氢化的乙烯基芳烃 - 共轭二烯无规共聚物具有统计分布在大分子中的结点，聚合物链从该聚合物链分支出来，节点和分支之间的键为碳 - 碳键。

9. 发明授权

US06858683B2 Process for the preparation of SBR rubbers with an improved processability and a lower rolling resistance 有权
标题翻译：具有改进的加工性和较低滚动阻力的SBR橡胶的制备方法
公开(公告)号：US06858683B2
公开(公告)日：2005-02-22
申请号：US10257395
申请日：2001-04-05
申请人： Gian Tommaso Viola , Luca Soddu , Sabrina Isidori , Attilio Taccioli , Francesco Masi
发明人： Gian Tommaso Viola , Luca Soddu , Sabrina Isidori , Attilio Taccioli , Francesco Masi
IPC分类号： C08F2/00 , C08C19/00 , C08C19/44 , C08F8/00 , C08F212/00 , C08F236/00 , C08F236/10 , C08F2/04
CPC分类号： C08C19/44 , C08C19/00 , C08F236/10
摘要： Process for the production of statistic elastomeric conjugated diene-vinyl arene copolymers having a branched structure which comprises: (1) anionic copolymerization in solution of the conjugated diene and vinyl arene monomers, in the presence of randomizing agents and an initiator selected from the group of Lithium alkyls, the copolymerization being carried out until the almost total disappearance of the monomers; (2) addition to the solution of step (1) of a quantity of Lithium alkyl from 1 to 4 times the molar quantity of the Lithium alkyl of step (1); (3) addition to the polymeric solution of step (2) of a compound having the general formula R—Br, the molar ratio between R—Br and the total Lithium alkyl ranging from 0.6/1 to 1/1, preferably from 0.7/1 to 0.9/1, thus obtaining an elastomeric branched copolymer.
摘要翻译：制备具有支链结构的统计弹性共轭二烯 - 乙烯基芳烃共聚物的方法，其包括：（1）在共存二烯和乙烯基芳烃单体的溶液中的阴离子共聚，在随机化剂和选自烷基锂，进行共聚直至几乎全部消失; （2）向步骤（1）的溶液中加入一定量的步骤（1）的烷基锂的摩尔量的1至4倍的烷基锂; （3）向具有通式R-Br的化合物的步骤（2）的聚合物溶液中加入R-Br与总烷基锂之间的摩尔比为0.6 / 1至1/1，优选为0.7 / 1至0.9 / 1，从而获得弹性体支化共聚物。

10. 发明授权

US5914378A Anionic copolymerization of conjugated dienes and vinyl arenes in the presence of alkyl ethers of tetrahydropyranyl methanol 失效
标题翻译：在四氢吡喃甲醇的烷基醚存在下，共轭二烯和乙烯基芳烃的阴离子共聚
公开(公告)号：US5914378A
公开(公告)日：1999-06-22
申请号：US852688
申请日：1997-05-07
申请人： Gian Tommaso Viola , Claudio Trombini , Lorenzo Musiani
发明人： Gian Tommaso Viola , Claudio Trombini , Lorenzo Musiani
IPC分类号： C08F2/38 , C08F4/48 , C08F36/04 , C08F236/10
CPC分类号： C08F36/04
摘要： Process for the preparation of a polymer by the polymerization of:(A) from 50 to 100 percent by weight of at least one diene monomer,(B) from 0 to 50 percent by weight of at least one ethylenically unsaturated monomer,the above polymerization being carried out in an inert solvent in the presence of a catalytic system which comprises:(a) at least one anionic initiator essentially consisting of a Lithium derivative,(b) at least one modifier belonging to the group of tetrahydropyranyl ethers.
摘要翻译：通过以下聚合制备聚合物的方法：（A）50至100重量％的至少一种二烯单体，（B）0至50重量％的至少一种烯属不饱和单体，上述聚合在惰性溶剂中，在催化体系存在下进行，该催化体系包含：（a）至少一种基本上由锂衍生物组成的阴离子引发剂，（b）至少一种属于四氢吡喃基醚类的改性剂。

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