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    • 3. 发明申请
    • Electrochemical Cell Based on Lithium Technology with Internal Reference Electrode, Process for Its Production and Methods for Simultaneous Monitoring of the Voltage or Impedance of the Anode and the Cathode Thereof
    • 基于具有内参参比电极的锂技术的电化学电池,其生产工艺及同时监测阳极及其阴极的电压或阻抗的方法
    • US20130323542A1
    • 2013-12-05
    • US13879293
    • 2011-10-12
    • Charles WijayawardhanaGerold NeumannPeter Gulde
    • Charles WijayawardhanaGerold NeumannPeter Gulde
    • G01R31/36H01M10/04H01M10/48
    • G01R31/382H01M4/00H01M4/13H01M6/5005H01M10/04H01M10/052H01M10/0585H01M10/48Y10T29/49115
    • The present invention is directed to an electrochemical cell based on lithium technology, comprising the following components: a positive electrode containing a cathode material, a separator made of an electrically insulating material, a negative a electrode containing an anode material, the electrodes and the separator having layer or sheet form, a liquid and/or solid ion conductor material for transportation of lithium ions between the positive and the negative electrode, the said components being sealed within a casing, wherein the positive and the negative electrode each comprise an electrically conducting structure extending through a wall of the casing for further electrical connection, characterized in that it further comprises: a reference electrode within the said casing which is electrically insulated from the positive and the negative electrode, the reference electrode having layer or sheet form comprising at least one non-metallic lithium compound, and an electrically conducting structure in layer or sheet form being in electrical contact with the said reference electrode, the electrically conducting structure extending through a wall of the casing for further electrical connection. The invention is further directed to a method for the preparation of this electrochemical cell, to a method for measuring the voltage or the impedance of a cathode and/or of an anode of such an electrochemical cell based on lithium technology, and to driving methods of said cell, decreasing aging phenomena and improving its life duration.
    • 本发明涉及一种基于锂技术的电化学电池,其包括以下组分:包含阴极材料的正电极,由电绝缘材料制成的隔膜,负极包含阳极材料的电极,电极和隔板 具有层或片形式,用于在正电极和负电极之间输送锂离子的液体和/或固体离子导体材料,所述部件被密封在壳体内,其中正极和负极各自包括导电结构 延伸穿过所述壳体的壁以进一步电连接,其特征在于,其还包括:所述壳体内的参考电极,其与所述正极和所述负极电绝缘,所述参考电极具有层或片形式,包括至少一个 非金属锂化合物和电导管 层或片形式的电阻结构与所述参考电极电接触,所述导电结构延伸穿过所述壳体的壁以进一步电连接。 本发明还涉及一种用于制备该电化学电池的方法,一种用于测量基于锂技术的这种电化学电池的阴极和/或阳极的电压或阻抗的方法以及驱动方法 说细胞,减少衰老现象,提高其寿命。