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1. 发明申请

US20140080702A1 Copolymers of N-vinylcarboxamide and diallyldialkylammonium salt as dispersant for agrochemical formulations 审中-公开
标题翻译： N-乙烯基甲酰胺和二烯丙基二烷基铵盐的共聚物作为农业化学制剂的分散剂
公开(公告)号：US20140080702A1
公开(公告)日：2014-03-20
申请号：US14122469
申请日：2012-05-24
申请人： Gerhard Schnabel , Ruth Wirschem , Paul Klingelhoefer , Lucelena Patricio Cardoso
发明人： Gerhard Schnabel , Ruth Wirschem , Paul Klingelhoefer , Lucelena Patricio Cardoso
IPC分类号： A01N25/10 , C05G3/02 , A01N43/56
CPC分类号： A01N25/10 , A01N25/04 , A01N25/30 , A01N43/56 , A01N47/24 , C05G3/02 , A01N57/20 , A01N2300/00
摘要： The present invention relates to a composition comprising an agrochemical active substance and a copolymer which comprises an N-vinylcarboxamide and a diallyldialkylammonium salt incorporated into the polymer. The invention furthermore relates to a method of preparing this composition; to the use of this composition for dispersing agrochemical active substances; to a method of controlling phytopathogenic fungi and/or undesired plant growth and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or the crop plants to be protected from the respective pest, on the soil and/or on undesired plants and/or on the crop plants and/or on their environment; and furthermore to seed comprising the composition.
摘要翻译：本发明涉及包含农药活性物质和共聚物的组合物，其包含N-乙烯基甲酰胺和掺入聚合物中的二烯丙基二烷基铵盐。本发明还涉及一种制备该组合物的方法; 使用该组合物分散农药活性物质; 涉及一种控制植物病原真菌和/或不期望的植物生长和/或不期望的昆虫或螨攻击和/或调节植物生长的方法，其中允许组合物作用于相应的害虫，其环境或作物植物上在相应的有害生物，土壤和/或不需要的植物和/或作物植物和/或其环境上受到保护; 以及包含该组合物的种子。

2. 发明申请

US20140148337A1 Acrylate-acrylamide-AMPS terpolymer as dispersant for agrochemical formulations 审中-公开
标题翻译：丙烯酸酯 - 丙烯酰胺-AMPS三元共聚物作为农业化学制剂的分散剂
公开(公告)号：US20140148337A1
公开(公告)日：2014-05-29
申请号：US14117220
申请日：2012-05-10
申请人： Gerhard Schnabel , Ruth Wirschem , Paul Klingelhoefer , Lucelena Patricio Cardoso , Bolette Urtel
发明人： Gerhard Schnabel , Ruth Wirschem , Paul Klingelhoefer , Lucelena Patricio Cardoso , Bolette Urtel
IPC分类号： A01N25/04 , A01N47/20 , A01N57/20
CPC分类号： A01N25/04 , A01N25/00 , A01N25/10 , A01N47/20 , A01N47/24 , A01N57/20 , A01N2300/00
摘要： The present invention relates to a composition comprising an agrochemical active substance and a random terpolymer which comprises the monomers i), ii), iii) and optionally further monomers incorporated into the polymer, where monomer i) comprises an olefinically unsaturated monomer comprising a sulfonic acid group and/or a salt thereof, monomer ii) comprises (meth)acrylamide and/or an N-substituted derivative thereof, and monomer iii) comprises a monoethylenically unsaturated C3-C8-carboxylic acid, an anhydride and/or a salt thereof. The invention furthermore relates to a method of preparing this composition; to the use of this composition for dispersing agrochemical active substances; to a method of controlling phytopathogenic fungi and/or undesired plant growth and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or the crop plants to be protected from the respective pest, on the soil and/or on undesired plants and/or on the crop plants and/or on their environment; and furthermore to seed comprising the composition.
摘要翻译：本发明涉及包含农业化学活性物质和无规三元共聚物的组合物，其包含单体i），ii），iii）和任选地加入到聚合物中的其它单体，其中单体i）包含含有磺酸的烯属不饱和单体基团和/或其盐，单体ii）包含（甲基）丙烯酰胺和/或其N-取代的衍生物，并且单体iii）包含单烯属不饱和C 3 -C 8 - 羧酸，其酸酐和/或其盐。本发明还涉及一种制备该组合物的方法; 使用该组合物分散农药活性物质; 涉及控制植物病原性真菌和/或不期望的植物生长和/或不需要的昆虫或螨攻击和/或调节植物生长的方法，其中允许组合物作用于相应的害虫，其环境或作物植物，在相应的有害生物，土壤和/或不需要的植物和/或作物植物和/或其环境上受到保护; 以及包含该组合物的种子。

3. 发明授权

US10159246B2 Copolymers of N-vinylcarboxamide and diallyldialkylammonium salt as dispersant for agrochemical formulations 有权
公开(公告)号：US10159246B2
公开(公告)日：2018-12-25
申请号：US14122469
申请日：2012-05-24
申请人： Gerhard Schnabel , Ruth Wirschem , Paul Klingelhoefer , Lucelena Patricio Cardoso
发明人： Gerhard Schnabel , Ruth Wirschem , Paul Klingelhoefer , Lucelena Patricio Cardoso
IPC分类号： A01N25/10 , A01N43/56 , C05G3/02 , A01N25/04 , A01N25/30 , A01N47/24
摘要： The present invention relates to a composition comprising an agrochemical active substance and a copolymer which comprises an N-vinylcarboxamide and a diallyldialkylammonium salt incorporated into the polymer. The invention furthermore relates to a method of preparing this composition; to the use of this composition for dispersing agrochemical active substances; to a method of controlling phytopathogenic fungi and/or undesired plant growth and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or the crop plants to be protected from the respective pest, on the soil and/or on undesired plants and/or on the crop plants and/or on their environment; and furthermore to seed comprising the composition.

4. 发明授权

US09056926B2 Process for preparing aqueous polyacrylic acid solutions 有权
标题翻译：制备水性聚丙烯酸溶液的方法
公开(公告)号：US09056926B2
公开(公告)日：2015-06-16
申请号：US13505907
申请日：2010-11-02
申请人： Matthias Kleiner , Wolfgang Loth , Markus Brym , Elke Gütlich-Hauk , Bolette Urtel , Ruth Wirschem , Jürgen Detering
发明人： Matthias Kleiner , Wolfgang Loth , Markus Brym , Elke Gütlich-Hauk , Bolette Urtel , Ruth Wirschem , Jürgen Detering
IPC分类号： C08L33/02 , C08F6/06 , B01J19/00 , C08F6/00 , C08F6/10 , C08F20/06
CPC分类号： C08F6/06 , B01J19/0093 , B01J2219/00006 , B01J2219/00033 , B01J2219/00783 , B01J2219/00858 , B01J2219/00873 , B01J2219/00889 , C08F2/01 , C08F2/10 , C08F6/003 , C08F6/10 , C08F20/06 , C08L33/02
摘要： A process for preparing aqueous solutions of homo- or copolymers of acrylic acid by means of free-radical polymerization of acrylic acid and optionally water-soluble, monoethylenically unsaturated comonomers in an aqueous medium in the presence of at least one water-soluble initiator and of at least one water-soluble regulator, wherein the polymerization is conducted by means of a continuous process, and wherein, after the polymerization, low molecular weight components are at least partly removed from the resulting aqueous polymer solution. For the polymerization, preference is given to using microstructured mixers and reactors. Preference is given to using at least one reactor and/or mixer with microstructures for the process.
摘要翻译：一种通过丙烯酸和任选的水溶性单烯属不饱和共聚单体在至少一种水溶性引发剂存在下在水性介质中的自由基聚合制备丙烯酸均聚物或共聚物的水溶液的方法，以及至少一种水溶性调节剂，其中通过连续方法进行聚合，并且其中在聚合之后，从所得聚合物水溶液中至少部分地除去低分子量组分。对于聚合，优选使用微结构混合器和反应器。优选使用至少一个具有该工艺的微结构的反应器和/或混合器。

5. 发明授权

US08735516B2 Low molecular weight phosphorus-containing polyacrylic acids and use thereof as dispersants 有权
标题翻译：低分子量含磷聚丙烯酸及其作为分散剂的用途
公开(公告)号：US08735516B2
公开(公告)日：2014-05-27
申请号：US13364877
申请日：2012-02-02
申请人： Howard Roger Dungworth , David Petty , Bolette Urtel , Ruth Wirschem
发明人： Howard Roger Dungworth , David Petty , Bolette Urtel , Ruth Wirschem
IPC分类号： C08F2/10 , C08L33/02
CPC分类号： C08L33/02 , C08F8/06 , C08F8/40 , C08F220/06 , C08F230/02 , C08K3/26 , C08F8/44
摘要： Aqueous solutions of acrylic acid polymers are prepared by polymerization of acrylic acid in a feed operation with a free-radical initiator in the presence of hypophosphite in water as solvent, by a process comprising (i) initially charging water and optionally one or more ethylenically unsaturated comonomers, (ii) continuously adding acrylic acid in acidic, unneutralized form, optionally one or more ethylenically unsaturated comonomers, aqueous free-radical initiator solution and aqueous hypophosphite solution, and (iii) adding a base to the aqueous solution on completion of the acrylic acid feed, wherein a comonomer content does not exceed 30% by weight and the aqueous hypophosphite solution is added during a total feed time made up of three consecutive feed time spans ΔtI, ΔtII, and ΔtIII, wherein the average feed rate in the second feed time span ΔtII is greater than the average feed rates in the first and third feed time spans ΔtI and ΔtIII.
摘要翻译：通过以下方法制备丙烯酸聚合物的水溶液，该方法包括：（i）初始加入水和任选的一种或多种烯属不饱和的，由丙烯酸在进料操作中与自由基引发剂在次亚磷酸盐存在下，在水中作为溶剂，共聚单体，（ii）以酸性，未中和形式连续加入丙烯酸，任选地一种或多种烯属不饱和共聚单体，自由基引发剂水溶液和次磷酸钠水溶液，和（iii）在丙烯酸完成时向水溶液中加入碱酸进料，其中共聚单体含量不超过30重量％，并且在由三个连续进料时间跨度＆Dgr; tI，＆Dgr; tII和＆Dgr; tIII组成的总进料时间内加入次磷酸钠溶液，其中平均第二进料时间跨度和Dgr; tII的进料速率大于第一和第三进料时间跨度＆Dgr; tI和＆Dgr; tIII中的平均进料速率。

6. 发明申请

US20120214941A1 PROCESS FOR PREPARING AQUEOUS POLYACRYLIC ACID SOLUTIONS 有权
标题翻译：制备水性聚丙烯酸溶液的方法
公开(公告)号：US20120214941A1
公开(公告)日：2012-08-23
申请号：US13505907
申请日：2010-11-02
申请人： Matthias Kleiner , Wolfgang Loth , Markus Brym , Elke Gütlich-Hauk , Bolette Urtel , Ruth Wirschem , Jürgen Detering
发明人： Matthias Kleiner , Wolfgang Loth , Markus Brym , Elke Gütlich-Hauk , Bolette Urtel , Ruth Wirschem , Jürgen Detering
IPC分类号： C08L33/02 , C08F2/16
CPC分类号： C08F6/06 , B01J19/0093 , B01J2219/00006 , B01J2219/00033 , B01J2219/00783 , B01J2219/00858 , B01J2219/00873 , B01J2219/00889 , C08F2/01 , C08F2/10 , C08F6/003 , C08F6/10 , C08F20/06 , C08L33/02
摘要： A process for preparing aqueous solutions of homo- or copolymers of acrylic acid by means of free-radical polymerization of acrylic acid and optionally water-soluble, monoethylenically unsaturated comonomers in an aqueous medium in the presence of at least one water-soluble initiator and of at least one water-soluble regulator, wherein the polymerization is conducted by means of a continuous process, and wherein, after the polymerization, low molecular weight components are at least partly removed from the resulting aqueous polymer solution. For the polymerization, preference is given to using microstructured mixers and reactors. Preference is given to using at least one reactor and/or mixer with microstructures for the process.
摘要翻译：一种通过丙烯酸和任选的水溶性单烯属不饱和共聚单体在至少一种水溶性引发剂存在下在水性介质中的自由基聚合制备丙烯酸均聚物或共聚物的水溶液的方法，以及至少一种水溶性调节剂，其中通过连续方法进行聚合，并且其中在聚合之后，从所得聚合物水溶液中至少部分地除去低分子量组分。对于聚合，优选使用微结构混合器和反应器。优选使用至少一个具有该工艺的微结构的反应器和/或混合器。

7. 发明申请

US20120220707A1 LOW MOLECULAR WEIGHT PHOSPHORUS-CONTAINING POLYACRYLIC ACIDS AND USE THEREOF AS DISPERSANTS 有权
标题翻译：低分子量含磷酸的聚丙烯酸及其作为分散剂的用途
公开(公告)号：US20120220707A1
公开(公告)日：2012-08-30
申请号：US13364877
申请日：2012-02-02
申请人： Howard Roger DUNGWORTH , David Petty , Bolette Urtel , Ruth Wirschem
发明人： Howard Roger DUNGWORTH , David Petty , Bolette Urtel , Ruth Wirschem
IPC分类号： C08K3/26 , C08K3/22 , C08K3/34 , C08L33/02 , C08L33/26
CPC分类号： C08L33/02 , C08F8/06 , C08F8/40 , C08F220/06 , C08F230/02 , C08K3/26 , C08F8/44
摘要： Aqueous solutions of acrylic acid polymers are prepared by polymerization of acrylic acid in a feed operation with a free-radical initiator in the presence of hypophosphite in water as solvent, by a process comprising (i) initially charging water and optionally one or more ethylenically unsaturated comonomers, (ii) continuously adding acrylic acid in acidic, unneutralized form, optionally one or more ethylenically unsaturated comonomers, aqueous free-radical initiator solution and aqueous hypophosphite solution, and (iii) adding a base to the aqueous solution on completion of the acrylic acid feed, wherein a comonomer content does not exceed 30% by weight and the aqueous hypophosphite solution is added during a total feed time made up of three consecutive feed time spans ΔtI, ΔtII, and ΔtIII, wherein the average feed rate in the second feed time span ΔtII is greater than the average feed rates in the first and third feed time spans ΔtI and ΔtIII.
摘要翻译：通过以下方法制备丙烯酸聚合物的水溶液，该方法包括：（i）初始加入水和任选的一种或多种烯属不饱和的，由丙烯酸在进料操作中与自由基引发剂在次亚磷酸盐存在下，在水中作为溶剂，共聚单体，（ii）以酸性，未中和形式连续加入丙烯酸，任选地一种或多种烯属不饱和共聚单体，自由基引发剂水溶液和次磷酸钠水溶液，和（iii）在丙烯酸完成时向水溶液中加入碱酸进料，其中共聚单体含量不超过30重量％，并且在由三个连续进料时间跨度＆Dgr; tI，＆Dgr; tII和＆Dgr; tIII组成的总进料时间内加入次磷酸钠溶液，其中平均第二进料时间跨度和Dgr; tII的进料速率大于第一和第三进料时间跨度＆Dgr; tI和＆Dgr; tIII中的平均进料速率。

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