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1. 发明授权

US06410482B1 (Het) arylsulfonylureas having an amino function, their presentation and their use as herbicides and plant growth regulators 失效
标题翻译：（Het）芳基磺酰脲具有氨基功能，它们的表现及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06410482B1
公开(公告)日：2002-06-25
申请号：US08855251
申请日：1997-05-13
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D40112
CPC分类号： C07D521/00 , A01N47/36 , C07C311/46
摘要： (Het)Arylsulfonylureas having an imino function, their preparation, and their use as herbicides and plant growth regulators Compounds of the formula (I) and salts thereof in which A is a (hetero)aromatic or heterocyclic bridge linked to the group SO2 by a direct bond, or via O, S, NH, CH2 or via alkylated NH or alkylated methylene, B is a group having an imino-containing fragment N═C—N, N═C—S, N═C—O or N═C—C which is linked to A by one of the nitrogen atoms of the fragment, R═H or an aliphatic radical, W═O or S and X, Y and Z are as defined in claim 1 are suitable as herbicides and plant growth regulators. The preparation is carried out for example similarly to known processes via novel intermediates of the formula (XII) (cf. claims 6 and 10),
摘要翻译：（Het）具有亚氨基功能的芳基磺酰脲，它们的制备及其作为除草剂和植物生长调节剂的用途式（I）化合物及其盐，其中A是通过直接连接到基团SO 2上的（杂）芳族或杂环桥或通过O，S，NH，CH 2或通过烷基化NH或烷基化亚甲基，B是具有亚氨基的片段N = CN，N = CS，N = CO或N = CC的基团，其通过所述片段的氮原子之一R = H或脂族基，W = O或S和X，Y和Z如权利要求1中所定义，适合作为除草剂和植物生长调节剂。通过式（XII）的新型中间体（参见权利要求6和10）类似于已知方法进行制备，

2. 发明授权

US5861357A 5-acylamino-2-alkoxycarbonylphenylsulfonylureas as selective herbicides 失效
标题翻译：作为选择性除草剂的5-酰基氨基-2-烷氧基羰基苯基磺酰脲
公开(公告)号：US5861357A
公开(公告)日：1999-01-19
申请号：US757372
申请日：1996-11-27
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： A01N47/36 , C07D521/00 , A01N43/20 , A01N43/54 , A01N43/66
CPC分类号： C07D521/00 , A01N47/36
摘要： Compounds of the formula (I) ##STR1## in which R.sup.1 to R.sup.5, X, W, n and Z are defined as in claim 1 are particularly suitable for use as selective herbicides in crops of useful plants.
摘要翻译：其中R1至R5，X，W，n和Z如权利要求1中所定义的式（I）化合物（I）特别适合用作有用植物作物中的选择性除草剂。

3. 发明授权

US5658854A Acylated aminophenylsulfonylureas; preparation and use as herbicides and plant growth regulators 失效
标题翻译：酰化氨基苯基磺酰脲作为除草剂和植物生长调节剂的制备和使用
公开(公告)号：US5658854A
公开(公告)日：1997-08-19
申请号：US268274
申请日：1994-06-30
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D239/42 , A01N47/36 , A01N47/46 , A01P13/02 , C07C309/89 , C07C311/39 , C07C311/65 , C07D239/47 , C07D239/48 , C07D251/44 , C07D251/46 , C07D251/48 , C07D251/52 , C07D521/00 , C07D239/69 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36 , C07C309/89 , C07C311/39 , C07C311/65
摘要： Acylated aminophenylureas, preparation and use as herbicides and plant growth regulatorsThe compounds of the formula I or their salts ##STR1## in which G is a radical G1, G2 or G3 ##STR2## R.sup.1 is H or alkyl, R.sup.2 is COOH, CSOH or a derivative of the carboxyl or thiocarboxyl group, of 1 to 20 carbon atoms, or acyl of the type CO-R.degree. of 1-12 carbon atoms, or an imino, hydrazone or oxime derivative of the group CO-R.degree., and R.degree. , R.sup.3a, R.sup.4a, R.sup.3b, R.sup.4b, W, X, Y and Z are as defined in claim 1, are suitable as selective herbicides and plant growth regulators in crops.The preparation is carried out in analogy to known processes (see claim 5) by way of intermediates, some of which are new, from the group consisting of benzene-sulfonamides (II), benzenesulfonyl isocyanates (IV) and benzesulfonyl chlorides (VI) and heterocyclically substituted carbamates (III), amines (V) and/or (thio)-isocyanates (XIX).
摘要翻译：酰化氨基苯基脲，作为除草剂和植物生长调节剂的制备和用途式I化合物或其盐，其中G是基团G1，G2或G3（G1）（图像）（G2）（G3）R1为H或烷基，R2为COOH，CSOH或含1-20个碳原子的羧基或硫代羧基的衍生物，或碳原子数为1〜12的CO-R DEG型酰基，或CO-R DEG基团的亚氨基，腙或肟衍生物，R DEG，R3a，R4a，R3b，R4b，W，X，Y和Z如权利要求1所定义，适合作为选择性除草剂和植物生长农作物的监管者。类似于已知方法（参见权利要求5），通过中间体（其中一些是新的），由苯磺酰胺（II），苯磺酰基异氰酸酯（IV）和苯磺酰氯（VI）和苯磺酰基异氰酸酯杂环取代的氨基甲酸酯（III），胺（V）和/或（硫代） - 异氰酸酯（XIX）。

4. 发明授权

US5747421A Formylaminophenylsulfonylureas, preparation processes and use as herbicides and plant growth regulators 失效
标题翻译：甲酰氨基苯基磺酰脲，制备方法和用作除草剂和植物生长调节剂
公开(公告)号：US5747421A
公开(公告)日：1998-05-05
申请号：US453978
申请日：1995-05-30
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D251/16 , A01N47/36 , C07D239/42 , C07D251/46 , C07D251/50 , C07D405/12 , C07D521/00 , C07D239/69 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36
摘要： Formylaminophenylsulfonylureas; processes for their preparation, and their use as herbicides and plant growth regulators Compounds of the formula (I) ##STR1## in which R.sup.1 is H, a substituted or unsubstituted hydrocarbon radical or an unsubstituted or substituted heterocyclic radical, R.sup.2 is H, (C.sub.1 -C.sub.6)-alkyl or (C.sub.1 -C.sub.6)-alkoxy, R.sup.3 is halogen, (C.sub.1 -C.sub.6)-alkyl, (C.sub.1 -C.sub.6)-alkoxy, (C.sub.1 -C.sub.6)-haloalkyl, (C.sub.1 -C.sub.6)-haloalkoxy, NO.sub.2, CN, NH.sub.2, (C.sub.1 -C.sub.4) -mono- or dialkylamino, each independently of other radicals R.sup.3 if n is 2 or 3, n is 0, 1, 2 or 3, W is an oxygen atom or a sulfur atom, X and Y independently of one another are halogen, (C.sub.1 -C.sub.6)-alkyl, (C.sub.1 -C.sub.6)-alkoxy or (C.sub.1 -C.sub.6)-alkylthio, each of the three last-mentioned radicals being unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C.sub.1 -C.sub.4)-alkoxy and (C.sub.1 -C.sub.4)-alkylthio, or are (C.sub.3 -C.sub.6)-cycloalkyl, (C.sub.2 -C.sub.6)-alkenyl, (C.sub.2 -C.sub.6)-alkynyl, (C.sub.2 -C.sub.6)-alkenyloxy, (C.sub.2 -C.sub.6)-alkynyloxy, mono- or di�(C.sub.1 -C.sub.4 -alkyl)!amino, and Z is CH or N, are suitable as herbicides and plant growth regulators. The compounds (I) can be prepared by processes analogous to known processes whereby some novel intermediates of formula (II) are used.
摘要翻译：甲酰氨基苯基磺酰脲其制备方法及其作为除草剂和植物生长调节剂的用途式（I）取代烃基或未取代或取代的杂环基的化合物，R2是H，（C1-C6） - 烷基或（C1-C6） - 烷氧基，R 3为卤素，（C 1 -C 6） - 烷基，（C 1 -C 6） - 烷氧基，（C 1 -C 6） - 卤代烷基，（C 1 -C 6） - 卤代烷氧基，NO 2，CN，NH 2，（C 1 -C 4）单或二烷基氨基，如果n为2或3，各自独立地为其它基团，n为0,1,2或3，W为氧原子或硫原子，X和Y彼此独立地为卤素，（C1 （C 1 -C 6） - 烷基，（C 1 -C 6） - 烷氧基或（C 1 -C 6） - 烷硫基，三个最后提到的基团中的每一个是未取代的或被一个或多个选自卤素，（C1- 或（C 1 -C 6） - 烷硫基，或者是（C 3 -C 6） - 环烷基，（C 2 -C 6） - 烯基，（C 2 -C 6） - 炔基，（C 2 -C 6） - 炔基氧基，（C 2 -C 6） C6） - 炔氧基，单或二[（C1-C4烷基）]氨基，Z为CH或N，适合作为除草剂和植物生长调节剂。化合物（I）可以通过类似于已知方法的方法制备，由此使用一些新的式（II）中间体。

5. 发明授权

US5723409A Intermediates for the preparation of phenylsulfonylurea herbicides and plant growth regulators 失效
公开(公告)号：US5723409A
公开(公告)日：1998-03-03
申请号：US430343
申请日：1995-04-28
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N47/36 , C07C311/47 , C07C311/65 , C07C335/28 , C07D521/00 , C07D239/64 , A01N43/54 , C07D401/12
CPC分类号： C07D521/00 , A01N47/36 , C07C311/47 , C07C311/65 , C07C335/28
摘要： The compounds of the formula (I) ##STR1## in which R.sup.1 -R.sup.4, W, X, Y and Z are as defined in claim 1 are suitable for controlling harmful plants in crops. Their preparation may employ the intermediates of the formulae II and III: ##STR2##

6. 发明授权

US06498253B1 Acylated aminophenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators 有权
标题翻译：酰化氨基苯基磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06498253B1
公开(公告)日：2002-12-24
申请号：US09257669
申请日：1999-02-25
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D23969
CPC分类号： C07D521/00 , A01N47/36 , C07C311/16 , C07C311/39 , C07C311/46 , C07C311/47 , C07D239/42 , C07D239/46 , C07D239/47 , C07D251/16 , C07D251/42 , C07D251/46 , C07D251/52 , C07D405/12 , C07D409/12
摘要： Compounds of the formula (I) and salts thereof in which W1, W2, R, n, R1, R2, R4, X, Y and Z are as defined in claim 1 and R3 is an acyl radical, are suitable as herbicides and plant growth regulators. The herbicides can be prepared by the process variants from claim 5, the novel intermediate products (II), (IV), (VI) and (VIII)* of claims 9 and 10 being employed.
摘要翻译： W1，W2，R，n，R1，R2，R4，X，Y和Z如权利要求1所定义的式（I）化合物及其盐，其中R 3为酰基，适用作除草剂和植物生长监管者。除草剂可以通过权利要求5的方法变体制备，使用权利要求9和10的新型中间产物（II），（IV），（VI）和（VIII）*。

7. 发明授权

US5854179A Sulfur-substituted phenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators 失效
标题翻译：硫取代的苯基磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US5854179A
公开(公告)日：1998-12-29
申请号：US552670
申请日：1995-11-03
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D239/42 , A01N47/36 , C07D239/46 , C07D239/47 , C07D521/00 , C07D403/12 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36
摘要： Sulfur-substituted phenylsulfonylureas; processes for their preparation and their use as herbicides and plant growth regulators Compounds of the formula (I) and salts thereof ##STR1## in which R*, R.sup.1, R.sup.2, R.sup.3, X, Y, Z, W, n and m are defined as in claim 1, and specifically R* is a formyl equivalent of the formula CHO, --CH.dbd.NR or CH(X.sup.1 R')(X.sup.2 R"), are suitable as herbicides and plant growth regulators. They are prepared analogously to known methods, in some cases using novel intermediate products of the formula (XVII) ##STR2## in which U*.dbd.NH.sub.2, Cl or (substituted) amino.
摘要翻译：硫取代苯磺酰脲; 其制备方法及其作为除草剂和植物生长调节剂的用途式（I）化合物及其盐其中R *，R 1，R 2，R 3，X，Y，Z，W，n和 m定义为权利要求1，特别地，R *为式CHO，-CH = NR或CH（X1R'）（X2R“）的甲酰当量，适用作除草剂和植物生长调节剂。它们是类似于已知方法制备的，在某些情况下，使用其中U * = NH 2，Cl或（取代的）氨基的式（XVII）的新型中间产物。

8. 发明授权

US5922646A Acylated aminophenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators 失效
标题翻译：酰化氨基苯基磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US5922646A
公开(公告)日：1999-07-13
申请号：US906238
申请日：1997-08-04
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D251/16 , A01N47/36 , A01P13/00 , C07C311/16 , C07C311/37 , C07C311/38 , C07C311/39 , C07C327/40 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D251/42 , C07D251/44 , C07D251/46 , C07D251/48 , C07D251/52 , C07D521/00 , C07D239/69 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36
摘要： Acylated aminophenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators. Compounds of the formula (I) and salts thereof ##STR1## in which W.sup.1, W.sup.2, R, n, R.sup.1, R.sup.2, R.sup.4, X, Y and Z are as defined in claim 1 and R.sup.3 is an acyl radical, are suitable as herbicides and plant growth regulators. The herbicides can be prepared by the process variants from claim 5, the novel intermediate products (II), (IV), (VI) and (VIII)* of claims 9 and 10 being employed.
摘要翻译：酰化氨基苯基磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途。其中W 1，W 2，R，n，R 1，R 2，R 4，X，Y和Z如权利要求1中所定义，式（I）的化合物及其盐为R 3为酰基，适用作除草剂和植物生长调节剂除草剂可以通过权利要求5的方法变体制备，使用权利要求9和10的新型中间产物（II），（IV），（VI）和（VIII）*。

9. 发明授权

US5696053A Nitrogen-substituted phenylsulfonylureas; processes for their preparation, and their use as herbicides and plant growth regulators 失效
标题翻译：氮取代苯磺酰脲; 其制备方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US5696053A
公开(公告)日：1997-12-09
申请号：US453967
申请日：1995-05-30
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D251/16 , A01N47/36 , C07D239/42 , C07D251/46 , C07D251/50 , C07D405/12 , C07D521/00 , C07D239/69 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36
摘要： Salts of the formula (I) ##STR1## in which n is 0, 1, 2 or 3, R is halogen, alkyl or alkoxy, mainly in each case independently of other substituents R in the event that n is greater than 1, R.sup.1 is a substituted or unsubstituted hydrocarbon radical or a substituted or unsubstituted heterocyclic radical, R.sup.2 is an acyl radical, R.sup.3 is hydrogen or C.sub.1 -C.sub.5 -alkyl, M.sym. is a metal or ammonium ion, X and Y independently of one another are halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkylthio, each of the three last-mentioned radicals being unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, C.sub.1 -C.sub.4 -alkoxy and C.sub.1 -C.sub.4 -alkylthio, or are C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.2 -C.sub.6 -alkynyloxy, mono- or di(C.sub.1 -C.sub.4 -alkyl)amino, and Z is CH or N, are suitable as herbicides and plant growth regulators, The compounds (I) can be prepared by processes of claims 5 to 7, for example by hydrogenating 2-alkoxycarbonyl-5-nitrophenylsulfonylureas in the presence of anhydrides.
摘要翻译：式（I）的盐，其中n是0,1,2或3，R是卤素，烷基或烷氧基，在n大于1的情况下，主要在每种情况下独立于其它取代基R，R 1 是取代或未取代的烃基或取代或未取代的杂环基，R 2是酰基，R 3是氢或C 1 -C 5 - 烷基，M（+）是金属或铵离子，X和Y彼此独立地是卤素，C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基或C 1 -C 6 - 烷硫基，三个最后提及的基团中的每一个是未取代的或被一个或多个选自卤素，C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷硫基，或者是C 3 -C 6 - 环烷基，C 2 -C 6 - 烯基，C 2 -C 6炔基，C 3 -C 6 - 烯氧基，C 2 -C 6 - 炔氧基，一或二（C 1 -C 4 - 烷基）氨基和Z是CH或N，适合作为除草剂和植物生长调节剂。化合物（I）可以通过权利要求5至7的方法制备，例如通过氢化2-烷氧基羰基-5-硝基苯基磺酰脲在酸酐的存在下。

10. 发明授权

US5449812A Intermediates for the preparation of phenylsulfonylurea herbicides and plant growth regulators 失效
标题翻译：用于制备苯基磺酰脲除草剂和植物生长调节剂的中间体
公开(公告)号：US5449812A
公开(公告)日：1995-09-12
申请号：US144895
申请日：1993-10-28
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D239/42 , A01N47/36 , C07C311/47 , C07C311/65 , C07C335/28 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/58 , C07D251/16 , C07D251/22 , C07D251/52 , C07D521/00 , C07C311/38
CPC分类号： C07D521/00 , A01N47/36 , C07C311/47 , C07C311/65 , C07C335/28
摘要： The compounds of the formula (I) ##STR1## in which R.sup.1 -R.sup.4, W, X, Y and Z are as defined in claim 1 are suitable for controlling harmful plants in crops. Their preparation may employ the intermediates of the formulae II and III: ##STR2##
摘要翻译：其中R 1 -R 4，W，X，Y和Z如权利要求1中所定义的式（I）化合物（I）适用于防治作物中的有害植物。它们的制备可以使用式II和III的中间体：其中（II）

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