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1. 发明授权

US4533477A Organopolysiloxanes having SiC-bonded oxyalkylene units and a method for preparing the same 失效
标题翻译：具有SiC键合的氧化烯单元的有机聚硅氧烷及其制备方法
公开(公告)号：US4533477A
公开(公告)日：1985-08-06
申请号：US536476
申请日：1983-09-28
申请人： Gerhard Preiner , Karl Huhn , Johann Muller , Heinrich Marwitz , Kurt Ullrich
发明人： Gerhard Preiner , Karl Huhn , Johann Muller , Heinrich Marwitz , Kurt Ullrich
IPC分类号： C08G77/00 , C08G77/22 , C08G77/46 , D06M13/02 , D06M13/51 , D06M13/513 , D06M15/647 , B05D3/02
CPC分类号： C08G77/46 , D06M15/647
摘要： Organopolysiloxanes having SiC-bonded oxyalkylene units and Si-bonded hydroxyl groups, in which an average of at least 15 mol percent of the siloxane units contain only one SiC-bonded monovalent organic radical and the silicon valences which are not satisfied by the SiC-bonded monovalent organic radical are satisfied by siloxane oxygen atoms or oxygen atoms of hydroxyl groups. These organopolysiloxanes are preferably prepared by reacting triorganosiloxy end-blocked organopolysiloxanes consisting of diorganosiloxane units, in which at least part of these units contain SiC-bonded oxyalkylene units and, if appropriate, organohydrogensiloxane units or organohydroxyl siloxane units or organoalkoxysiloxane units of mixtures of at least two such monoorganosiloxy units with water in the presence of an acid or base or, and subsequently with a silane or simultaneously with water and a silane in which the silane contains one SiC-bonded monovalent organic radical, or partially hydrolyzed products of the silane. The new organopolysiloxanes are applied to textile fibers to impart hydrophilic properties thereto.
摘要翻译：具有SiC键合的氧化烯单元和Si键合的羟基的有机聚硅氧烷，其中平均至少15摩尔％的硅氧烷单元仅含有一个与SiC键合的一价有机基团和不符合SiC键合的硅价态硅氧烷氧原子或羟基氧原子满足一价有机基团。这些有机聚硅氧烷优选通过使由二有机硅氧烷单元组成的三有机甲硅烷氧基封端的有机聚硅氧烷反应制备，其中这些单元的至少一部分含有SiC键合氧化烯单元，以及如果合适的话，有机氢硅氧烷单元或有机羟基硅氧烷单元或有机烷氧基硅氧烷单元至少两个这样的单有机基甲硅烷氧基单元与酸在酸或碱的存在下反应，或随后与硅烷或水同时与硅烷混合，其中硅烷含有一个与SiC键合的一价有机基团或硅烷的部分水解产物。将新的有机聚硅氧烷应用于纺织纤维以赋予其亲水性。

2. 发明授权

US4433007A Process for coating substrates with aqueous emulsions containing organopolysiloxanes 失效
标题翻译：用含有机聚硅氧烷的水性乳液涂布基材的方法
公开(公告)号：US4433007A
公开(公告)日：1984-02-21
申请号：US345880
申请日：1982-02-04
申请人： Heinrich Marwitz , Kurt Ullrich , Karl Huhn
发明人： Heinrich Marwitz , Kurt Ullrich , Karl Huhn
IPC分类号： B05D7/00 , B05D7/24 , B32B27/00 , C08L83/04 , C09D183/04 , D06M13/02 , D06M13/51 , D06M13/513 , D06M15/356 , D06M15/643 , D06M15/65 , D21H19/14 , D21H19/32 , B05D3/14 , B05D3/02
CPC分类号： D06M15/65 , C08L83/04 , C09D183/04 , D06M15/3568 , D06M15/643 , C08G77/12 , C08G77/20 , Y10T428/31663
摘要： A process for coating a substrate which comprises applying to the substrate an aqueous emulsion containing:(1) A diorganopolysiloxane having terminal SiC-bonded vinyl groups;(2) An organopolysiloxane containing at least three Si-bonded hydrogen atoms per molecule;(3) A catalyst which promotes the addition of Si-bonded hydrogen to an aliphatic multiple bond; and if desired,(4) An agent which delays or retards the addition at room temperature; and(5) A thickening agent, which may be mixed with or added separately to the emulsion, and prior to cross-linking the organopolysiloxane, applying separately or together with one or more of the constituents (1) through (5);(6) A vinyl-containing trimethylsiloxy end-blocked diorganopolysiloxane in which the vinyl group is bonded to from 10 to 50 percent of the number of the silicon atoms of the diorganopolysiloxane units, and the other organic radicals are free of aliphatic multiple bonds;(7) An organosilicon adhesive compound; and(8) At least one aqueous dispersion of a polymer selected from the group consisting of ethylene, vinyl acetate, acrylic acid esters, and copolymers containing at least two of these monomers and thereafter crosslinking the coating.
摘要翻译：一种涂布基材的方法，其包括向所述基材施加水性乳液，所述水性乳液含有：（1）具有末端与SiC键合的乙烯基的二有机聚硅氧烷; （2）每分子含有至少三个与Si键合的氢原子的有机聚硅氧烷; （3）促进将Si键合的氢加成脂肪族多键的催化剂; 如果需要，（4）在室温下延迟或延迟添加的试剂; 和（5）增稠剂，其可以与乳液混合或分开加入，并且在交联有机聚硅氧烷之前，单独或与一种或多种组分（1）至（5）一起使用; （6）一种含乙烯基的三甲基甲硅烷氧基封端的二有机聚硅氧烷，其中乙烯基与二有机聚硅氧烷单元的硅原子数的10〜50％键合，其它有机基团不含脂族多键; （7）有机硅粘合剂; 和（8）至少一种选自乙烯，乙酸乙烯酯，丙烯酸酯的聚合物的水性分散体和含有这些单体中的至少两种的共聚物，然后交联涂层。

3. 发明授权

US4421783A Process for coating substrates 失效
标题翻译：涂布基材的工艺
公开(公告)号：US4421783A
公开(公告)日：1983-12-20
申请号：US345853
申请日：1982-02-04
申请人： Heinrich Marwitz , Kurt Ullrich , Karl Huhn
发明人： Heinrich Marwitz , Kurt Ullrich , Karl Huhn
IPC分类号： D06M15/263 , B05D7/00 , B32B27/00 , B32B27/12 , C08L83/04 , C09D183/04 , C09D191/00 , D06M13/02 , D06M13/51 , D06M13/513 , D06M15/643 , D06M15/65 , D21H19/14 , D21H19/32 , B05D3/06 , B05D3/02
CPC分类号： D06M15/643 , C08L83/04 , C09D183/04 , C08G77/12 , C08G77/20
摘要： A process for coating a substrate which comprises coating the substrate with a solution containing an organic solvent and(1) a diorganopolysiloxane having terminal SiC-bonded vinyl groups,(2) an organopolysiloxane having at least 3 Si-bonded hydrogen atoms per molecule,(3) a catalyst which promotes the addition of Si-bonded hydrogen to an aliphatic multiple bond; and optionally(4) an agent which delays or retards the addition of Si-bonded hydrogen to an aliphatic multiple bond at room temperature,(5) a diorganopolysiloxane having a viscosity of at least 10.sup.6 mPa.s at 25.degree. C. in which a vinyl group is bonded to a silicon atom in 0.033 to 3.33 percent of the diorganosiloxane units, while the other organic radicals in the diorganosiloxane units of the diorganopolysiloxane are free of aliphatic multiple bonds, and(6) an organosilicon adhesive compound.An acrylic acid ester polymer or copolymer (7) may be applied to the substrate simultaneously with or prior to the application of the solution containing components (1) through (6) above.
摘要翻译：一种涂布基材的方法，该方法包括用含有机溶剂的溶液涂布基材，和（1）具有末端键合有碳原子的乙烯基的二有机聚硅氧烷，（2）每分子具有至少3个Si键合氢原子的有机聚硅氧烷（ 3）促进将Si键合的氢加成脂肪族多键的催化剂; 和任选地（4）在室温下延迟或延迟Si键合的氢加成到脂族多重键的试剂，（5）在25℃下粘度至少为106mPa.s的二有机聚硅氧烷，其中a 乙烯基与二原子硅氧烷单元的0.033〜3.33％的硅原子键合，二有机聚硅氧烷的二有机硅氧烷单元中的其他有机基团不含脂肪族多键，（6）有机硅粘合剂。

4. 发明授权

US4436856A Aqueous organopolysiloxane emulsiers and a process for treating organic fibers therewith 失效
标题翻译：水性有机聚硅氧烷乳化剂及其有机纤维的处理方法
公开(公告)号：US4436856A
公开(公告)日：1984-03-13
申请号：US346457
申请日：1982-02-08
申请人： Karl Huhn , Heinrich Marwitz
发明人： Karl Huhn , Heinrich Marwitz
IPC分类号： D06M15/423 , C08L83/04 , D06M15/643 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06M101/10 , D06M101/16
CPC分类号： D06M15/6436 , C08L83/04 , C08G77/12 , C08G77/16 , C08G77/26 , Y10T428/2962 , Y10T428/31663
摘要： Organic fibers are impregnated with an aqueous emulsion comprising (1) an organopolysiloxane containing diorganosiloxane units in which both organic radicals are monovalent hydrocarbon radicals, and further contains at least two monovalent SiC-bonded organic radicals with a basic nitrogen atom per molecule in which the SiC-bonded organic radicals with a basic nitrogen are present in monoorganosiloxane units, (2) an organopolysiloxane having at least 3 Si-bonded hydrogen atoms per molecule, (3) a catalyst for the condensation of Si-bonded condensable groups (4) emulsifiers, and (5) a diorganopolysiloxane containing an Si-bonded hydroxyl group in each of its terminal units and whose radicals are free of the basic nitrogen atom. If it is desired to impart hydrophobic properties to the impregnated organic fibers, then it is essential that (6) a trimethylsiloxy end-blocked diorganopolysiloxane be added to the aqueous emulsion. Moreover, as the amount of trimethylsiloxy end-blocked diorganopolysiloxane (6) is increased in the emulsion, the hydrophobic properties of the impregnated fibers increases.
摘要翻译：有机纤维用水性乳液浸渍，包括（1）含有二有机硅氧烷单元的有机聚硅氧烷单元，其中有机基团均为一价烃基，并且还含有至少两个每分子具有碱性氮原子的一价SiC键合的有机基团，其中SiC 具有碱性氮的键合有机基团存在于单有机硅氧烷单元中，（2）每分子具有至少3个Si键合氢原子的有机聚硅氧烷，（3）用于缩合Si键合的可缩合基团（4）乳化剂，和（5）在其每个末端单元中含有与Si键合的羟基并且其自由基不含碱性氮原子的二有机聚硅氧烷。如果希望对浸渍的有机纤维赋予疏水性，则必须将（6）三甲基甲硅烷氧基封端的二有机聚硅氧烷加入到水性乳液中。此外，随着乳液中三甲基甲硅烷氧基封端的二有机基聚硅氧烷（6）的量增加，浸渍纤维的疏水性增加。

5. 发明授权

US4559385A Method for preparing aqueous emulsions 失效
标题翻译：水乳液的制备方法
公开(公告)号：US4559385A
公开(公告)日：1985-12-17
申请号：US648416
申请日：1984-09-10
申请人： Karl Huhn , Kurt Ullrich
发明人： Karl Huhn , Kurt Ullrich
IPC分类号： D06M13/50 , C08J3/03 , C08L83/04 , D06M13/02 , D06M13/51 , D06M15/643 , C08L83/00
CPC分类号： C08J3/03 , C08L83/04 , D06M15/6436 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/26 , C08G77/70 , C08J2383/04 , Y10T428/31663
摘要： Aqueous emulsions for impregnating organic fibers, comprising, in addition to water and dispersants, (1) a diorganopolysiloxane having a Si-bonded hydroxyl group in each terminal unit and whose organic radicals are free of basic nitrogen atoms; (2) an organopolysiloxane containing diorganosiloxane units in which the two organic radicals are monovalent hydrocarbon radicals and also contains at least two monovalent SiC-bonded organic radicals per molecule having a basic nitrogen atom in which the organopolysiloxane is present in the emulsion in an amount of from 5 to 50 weight percent based on the weight of the diorganopolysiloxane (1); (3) an organosilicon compound selected from an organosilane containing at least two SiOC-bonded monovalent organic radicals consisting of carbon, hydrogen and possibly oxygen and/or partial hydrolyzates thereof, in which the organosilicon compound is present in the emulsion in an amount of from 2 to 6 weight percent based on the total weight of the diorganopolysiloxane (1) and organopolysiloxane (2); and (4) a condensation catalyst, which is present in an amount of from 0.2 to 1 weight percent based on the total weight of the diorganopolysiloxane (1) and organopolysiloxane (2).These aqueous emulsions are prepared by mixing the organosilicon compound (3) with an emulsion of diorganopolysiloxane (1) and organopolysiloxane (2) and thereafter mixing the resultant mixture with the condensation catalyst (4).
摘要翻译：用于浸渍有机纤维的水乳液，除了水和分散剂之外，还包含（1）在每个末端单元中具有与Si键合的羟基的二有机聚硅氧烷，其有机基团不含碱性氮原子; （2）含有二有机硅氧烷单元的有机聚硅氧烷单元，其中两个有机基团是单价烃基，并且每分子含有至少两个具有碱性氮原子的单价SiC键合的有机基团，其中有机聚硅氧烷以乳液中的量存在于乳液中基于二有机基聚硅氧烷（1）的重量为5至50重量％; （3）选自含有由碳，氢和可能的氧和/或部分水解产物组成的至少两个SiOC键合的一价有机基团的有机硅烷的有机硅化合物，其中有机硅化合物以乳液的量存在于乳液中基于二有机聚硅氧烷（1）和有机基聚硅氧烷（2）的总重量计，2至6重量％; 和（4）缩合催化剂，其以基于二有机聚硅氧烷（1）和有机聚硅氧烷（2）的总重量的0.2至1重量％的量存在。通过将有机硅化合物（3）与二有机聚硅氧烷（1）和有机聚硅氧烷（2）的乳液混合，然后将所得混合物与缩合催化剂（4）混合来制备这些水性乳液。

6. 发明授权

US5302657A Highly dispersed organopolysiloxane emulsions 失效
标题翻译：高度分散的有机聚硅氧烷乳液
公开(公告)号：US5302657A
公开(公告)日：1994-04-12
申请号：US891901
申请日：1992-06-01
申请人： Karl Huhn , Christine Seidl , Kurt Ullrich
发明人： Karl Huhn , Christine Seidl , Kurt Ullrich
IPC分类号： A61K8/72 , A61K8/89 , A61K8/891 , C08J3/03 , C08L83/02 , C08L83/04 , C08L83/08 , D06M15/643 , D06M101/00 , C08L83/00
CPC分类号： C08J3/03 , B01D19/0409 , D06M15/643 , D06M15/6436 , C08J2383/04 , Y10T428/2962
摘要： The invention relates to a process for preparing polyorganosiloxane-containing emulsions having a mean particle size of less than 0.3 .mu.m in which, in a first step,(A) a concentrate is prepared by mixing a polyorganosiloxane with water and an emulsifier which is soluble in the polyorganosiloxane.and, in a second step,(B) the concentrate thus obtained is diluted with water to the desired polyorganosiloxane concentration.These emulsions can be used for impregnating fibres and fabrics.
摘要翻译：本发明涉及一种制备平均粒径小于0.3（my）m的含聚有机硅氧烷的乳液的方法，其中在第一步中，（A）通过将聚有机硅氧烷与水和乳化剂混合制备浓缩物，可溶于聚有机硅氧烷。在第二步中，（B）将由此获得的浓缩物用水稀释至所需的聚有机硅氧烷浓度。这些乳液可用于浸渍纤维和织物。

7. 发明授权

US4720520A Method for impregnating organic fibers 失效
标题翻译：浸渍有机纤维的方法
公开(公告)号：US4720520A
公开(公告)日：1988-01-19
申请号：US039811
申请日：1987-04-09
申请人： Karl Huhn , Ingomar Kovar
发明人： Karl Huhn , Ingomar Kovar
IPC分类号： C08L83/04 , D06M15/643 , D06M101/00 , D06M101/16 , C08L83/08
CPC分类号： D06M15/6436
摘要： A method for impregnating organic fibers which comprises applying a composition containing (1) an organopolysiloxane having silicon-bonded condensable groups and containing diorganosiloxane units in which the two SiC-bonded organic radicals are monovalent hydrocarbon radicals and also contains two monovalent SiC-bonded radicals having a basic nitrogen group; (2) an organopolysiloxane having at least 3 Si-bonded hydrogen atoms per molecule; and (3) a catalyst which promotes the condensation of the silicon-bonded condensable groups, in which the SiC-bonded radicals having a basic nitrogen group are present in the organopolysiloxane (1) as monoorganosiloxane units and as diorganosiloxane units.
摘要翻译：一种浸渍有机纤维的方法，其包括将含有（1）具有硅键合的可缩合基团并且含有二有机硅氧烷单元的有机聚硅氧烷的组合物，其中两个SiC键合的有机基团是一价烃基，并且还含有两个一价SiC键合基团，碱性氮基; （2）每分子具有至少3个Si键合氢原子的有机聚硅氧烷; 和（3）促进硅键合的可缩合基团的缩合的催化剂，其中具有碱性氮基团的SiC键合基团作为单有机硅氧烷单元存在于有机聚硅氧烷单元中，并作为二有机硅氧烷单元存在。

8. 发明授权

US4625010A Organopolysiloxanes having Si-bonded hydrogen and SiC-bonded epoxy groups and a process for preparing the same 失效
公开(公告)号：US4625010A
公开(公告)日：1986-11-25
申请号：US763865
申请日：1985-08-09
申请人： Karl Huhn , Rudolf Kaufmann
发明人： Karl Huhn , Rudolf Kaufmann
IPC分类号： C08G77/00 , C08G77/06 , C08G77/14 , C08G77/22 , C08G77/38 , C08L83/12 , D06M13/02 , D06M13/51 , D06M13/513 , D06M15/65 , C08G77/12
CPC分类号： D06M15/65 , C08G77/38
摘要： Novel organopolysiloxanes are described in which the organopolysiloxanes are terminated by units of the formula R.sub.3 SiO.sub.1/2 and comprise units of the formulas RR.sup.1 SiO, RR.sup.2 SiO, RR.sup.3 SiO, RHSiO and R.sub.2 SiO, where R represents the same or different alkyl radicals having from 1 to 4 carbon atoms per radical, or phenyl radicals, R.sup.1 represents the same or different alkyl radicals having at least 6 carbon atoms per radical, R.sup.2 represents the same or different aralkyl radicals and R.sup.3 represents the same or different, SiC-bonded, monovalent organic radicals having at least one vicinal epoxy group per radical. These organopolysiloxanes are preferably prepared by reacting organopolysiloxanes which contain units of the formulas R.sub.3 SiO.sub.1/2 and RHSiO and optionally units of the formula R.sub.2 SiO, wherein R is the same as above, with an organic compound that has a terminal C.dbd.C-bond and at least one vicinal epoxy group per molecule, at least one alkene having at least 6 carbon atoms per molecule, and at least one aralkene in the presence of a catalyst which promotes the addition of Si-bonded hydrogen to the aliphatic C.dbd.C bond. These organopolysiloxanes may be applied simultaneously with a polymer having perfluoroalkyl groups with at least 3 carbon atoms per alkyl group to fibers to render them oil and water repellent.

9. 发明授权

US4652662A Process for preparing organofunctional organopolysiloxanes 失效
标题翻译：制备有机官能有机聚硅氧烷的方法
公开(公告)号：US4652662A
公开(公告)日：1987-03-24
申请号：US733562
申请日：1985-05-14
申请人： Gunther von Au , Karl Braunsperger , Karl Huhn , Ingomar Kovar
发明人： Gunther von Au , Karl Braunsperger , Karl Huhn , Ingomar Kovar
IPC分类号： C08G77/00 , C08G77/06 , C08G77/08 , C08G77/28 , C08G77/38 , C07F7/08 , C07D303/02 , C07F7/10
CPC分类号： C08G77/08 , C08G77/06
摘要： A process for preparing organofunctional organopolysiloxanes which comprises reacting a cyclic diorganopolysiloxane with a silane having a SiC-bonded monovalent organic radical with at least one functional group and at least one SiOC-bonded monovalent hydrocarbon radical which can be substituted by an ether oxygen atom, or with an oligomer of such a silane having a maximum of 10 silicon atoms per molecule, in the presence of a quaternary ammonium hydroxide.
摘要翻译：一种制备有机官能有机聚硅氧烷的方法，其包括使环状二有机聚硅氧烷与具有与SiC键合的一价有机基团的硅烷与至少一个官能团和至少一个可被醚氧原子取代的SiOC键合的一价烃基反应，或在季铵氢氧化物的存在下，每分子具有最多10个硅原子的硅烷的低聚物。

10. 发明授权

US4555419A Method of impregnating textile materials made from organic fibers 失效
标题翻译：浸渍由有机纤维制成的纺织材料的方法
公开(公告)号：US4555419A
公开(公告)日：1985-11-26
申请号：US627125
申请日：1984-07-02
申请人： Karl Huhn , Gunter von Au
发明人： Karl Huhn , Gunter von Au
IPC分类号： D06M13/02 , D06M13/51 , D06M13/513 , D06M15/643 , B05D3/02
CPC分类号： D06M15/6436
摘要： A method for impregnating textile materials made from organic fibers which comprises impregnating the textile materials with a composition containing a crosslinkable diorganopolysiloxane, an organopolysiloxane containing at least 3 Si-bonded hydrogen atoms per molecule, a crosslinking catalyst, and an organo(poly)siloxane containing 1 or 2 Si-bonded hydrogen atoms and 2 to 8 silicon atoms per molecule, in which the composition is free of a filler having a surface area greater than 50 g/m.sup.2 in an amount greater than 1 weight percent based on the weight of the organosilicon compounds and thereafter crosslinking the crosslinkable diorganopolysiloxane to form a coating thereon.
摘要翻译：一种用于浸渍由有机纤维制成的纺织材料的方法，其包括用含有可交联的二有机聚硅氧烷，每分子含有至少3个Si键合氢原子的有机聚硅氧烷，含有有机聚硅氧烷的有机聚硅氧烷 1或2个Si键合的氢原子和每个分子2至8个硅原子，其中组合物不含表面积大于50g / m 2的填料，其量大于1重量％，基于有机硅化合物，然后交联可交联的二有机基聚硅氧烷以在其上形成涂层。

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