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    • 1. 发明申请
    • Integrated Dimethyl Ether Recovery From An Oxygenate-To-Olefins Process And Production Of Polypropylene
    • 从氧化烯到烯烃方法的综合二甲醚回收和聚丙烯的生产
    • US20100317908A1
    • 2010-12-16
    • US12772276
    • 2010-05-03
    • Gerald G. McGlamery, JR.Lawrence C. SmithJennifer L. Bancroft
    • Gerald G. McGlamery, JR.Lawrence C. SmithJennifer L. Bancroft
    • C07C1/20
    • C08F110/06Y02P30/42
    • Provided is a method of producing polypropylene comprising contacting an oxygenate stream with a molecular sieve to form an olefin stream comprising propane, propylene and dimethylether; introducing the olefin stream into a propylene rectification tower possessing from less than 200 theoretical stages; withdrawing from the propylene rectification tower a bottom stream comprising dimethylether, a sidestream comprising propane, and an overhead stream comprising propane and propylene; introducing the overhead to a condenser to accumulate a propylene-rich stream; passing the propylene-rich stream to a splitter to produce (i) a first propylene stream that is introduced into a polypropylene reactor to contact a polyolefin catalyst, and (ii) a second propylene stream that is re-introduced into the rectification tower, the first and second propylene streams introduced at a desirable ratio; and recirculating the dimethylether stream to contact the molecular sieve.
    • 提供一种生产聚丙烯的方法,其包括使含氧化合物流与分子筛接触以形成包含丙烷,丙烯和二甲醚的烯烃流; 将烯烃流引入到具有小于200个理论级的丙烯精馏塔中; 从丙烯精馏塔中排出包含二甲醚的底部料流,包含丙烷的侧流和包含丙烷和丙烯的塔顶料流; 将塔顶馏出物引入冷凝器以积聚富含丙烯的料流; 将富丙烯流输送到分流器以产生(i)引入聚丙烯反应器中以接触聚烯烃催化剂的第一丙烯料流,和(ii)再次引入精馏塔中的第二丙烯料流, 以期望的比例引入第一和第二丙烯料流; 并使二甲醚流再循环以与分子筛接触。