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    • 1. 发明授权
    • Metal oxide oil slurries
    • 金属氧化物油浆
    • US4354872A
    • 1982-10-19
    • US226302
    • 1981-01-19
    • George T. KekishMei-Jan L. LinJohn H. Collins
    • George T. KekishMei-Jan L. LinJohn H. Collins
    • F28F19/00F28G9/00C04B9/00C04B9/02C04B9/04C23F11/00
    • F28G9/00F28F19/00
    • A highly stable metal oxide oil slurry useful in reducing slag, facilitating removal of deposits from boiler tubes, and reducing corrosion on the heating surfaces of boilers has been developed. Such a slurry consists essentially of about 50% by weight magnesium oxide or the entity of magnesium oxide and alumina oxide, together with an oil-soluble emulsifier such as alkanolamide and preferably ethanolamide, or an alkanol with a carbon chain greater than a C.sub.3 alcohol, an oil-soluble dispersant such as a C.sub.12 -C.sub.22 entity selected from an unsaturated or saturated fatty acid; e.g., oleic acid. Also, as a constituent is an anionic surfactant such as magnesium lauryl sulfate in an oil base such as No. 2 fuel oil. The alkanolamide is fashioned from heating alkanolamines and fatty acids either in a 1:1 ratio or 2:1 ratio. The reactant amino alcohol is in the range C.sub.10 -C.sub.24. The alcohol itself is greater than C.sub.3 and up to C.sub.16, with a preferred range C.sub.12 -C.sub.16.
    • 已经开发了用于还原炉渣的高度稳定的金属氧化物油浆料,有助于从锅炉管道中去除沉积物并减少锅炉的加热表面的腐蚀。 这种浆料基本上由约50重量%的氧化镁或氧化镁和氧化铝的实体,以及油溶性乳化剂如链烷醇酰胺,优选乙醇酰胺或具有大于C 3醇的碳链的链烷醇组成, 油溶性分散剂,例如选自不饱和或饱和脂肪酸的C12-C22实体; 例如油酸。 此外,作为组分是在诸如2号燃料油的油基中的阴离子表面活性剂如月桂基硫酸镁。 链烷醇酰胺是以1:1比例或2:1的比例加热链烷醇胺和脂肪酸而制成的。 反应物氨基醇在C10-C24的范围内。 醇本身大于C3且高达C16,优选范围为C12-C16。
    • 4. 发明授权
    • Copper chelants/dispersants and their applications for boiler internal
treatment
    • 铜螯合剂/分散剂及其在锅炉内部处理中的应用
    • US4734203A
    • 1988-03-29
    • US21076
    • 1987-03-03
    • Mei-Jan L. LinFrederick J. Sibert
    • Mei-Jan L. LinFrederick J. Sibert
    • C02F5/12
    • C02F5/12
    • This invention discloses a method of improving the constitution of boiler water by adding thereto an effective amount of a copper transport agent which is either rubeanic acid or a low molecular weight polymer of polypiperazine methyl-para-hydroxysulfonic acid or polypiperazine methyl-para-hydroxybenzoic acid. The copper transport agent satisfactorily separates the copper from iron, calcium, magnesium and other heavy metals with a high degree of selectivity. The chelant may be added in a ratio of 100/1 to 10/1 chelant/copper and an advantageous ratio in the case of the polymer is 50/1 ppm active polymer to 1 ppm Cu. The chelants, which form a soluble chelate with Cu, is capable of removing Cu through boiler blowdown in an operating, layup or cleanup boiler. This adds an anti-corrosion factor to the galvanized boiler corrosion.
    • 本发明公开了一种通过添加有效量的铜运输剂来提高锅炉水的构成的方法,铜运输剂是无机硼酸或聚哌嗪甲基对羟基磺酸或聚哌嗪甲基对羟基苯甲酸的低分子量聚合物 。 铜输送剂以高选择性令人满意地将铜与铁,钙,镁和其他重金属分离。 螯合剂可以以100/1至10/1的螯合剂/铜的比例加入,并且在聚合物的情况下的有效比例为50/1ppm的活性聚合物与1ppm的Cu。 与Cu形成可溶性螯合物的螯合剂能够通过锅炉排放在操作,上铺或清理锅炉中除去Cu。 这为镀锌锅炉腐蚀增加了防腐蚀因素。