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    • 7. 发明授权
    • Process for recovering high boiling solvents from a photolithographic waste stream comprising at least 10 percent by weight of monomeric units
    • 从包含至少10重量%单体单元的光刻废料流中回收高沸点溶剂的方法
    • US06187965B1
    • 2001-02-13
    • US09188007
    • 1998-11-06
    • Anilkumar C. BhattJerome J. Wagner
    • Anilkumar C. BhattJerome J. Wagner
    • C07C2980
    • C07D307/33C07C29/80C07C33/20C07C33/22C07C33/24
    • A method of recovering benzyl alcohol, gamma butyrolactone, or propylene carbonate from an impure effluent stream of an industrial process is provided. The effluent waste stream contains greater than about 10 percent by weight of monomeric units that are reacted to form larger oligomers and polymers. The first step in the recovery process involves polymerizing the monomeric units present in the effluent waste stream under conditions effective to reduce the concentration of monomeric units in the waste stream to less than about 10 weight percent. The waste stream then is fed to a first separation stage where it is separated into (i) a gaseous stream of water, soluble gases, and volatile contaminants and (ii) a suspension comprising the high boiling solvent, semi-volatile materials, and non-volatile contaminants and materials. Then the dewatered, low vapor pressure, high boiling solvent-containing suspension is either distilled or evaporated to separate the high boiling solvent from non-volatile materials. In this second separation stage, the solvent-containing suspension is separated into (i) a solvent-containing fraction, and (ii) a sludge fraction. The sludge fraction contains non-volatile materials in the high boiling solvent.
    • 提供了从工业过程不纯的流出物流中回收苄醇,γ-丁内酯或碳酸亚丙酯的方法。 流出物废物流含有大于约10重量%的单体单元,其被反应以形成较大的低聚物和聚合物。 回收过程中的第一步包括在有效降低废物流中的单体单元浓度至小于约10重量%的条件下聚合存在于流出物废物流中的单体单元。 然后将废物流送入第一分离阶段,在该分离阶段将其分离为(i)气态的水流,可溶性气体和挥发性污染物,和(ii)包含高沸点溶剂,半挥发性物质和非挥发性物质的悬浮液 挥发性污染物和材料。 然后将脱水,低蒸气压,高沸点溶剂的悬浮液蒸馏或蒸发,以将高沸点溶剂与非挥发性物质分离。 在该第二分离阶段,将含溶剂的悬浮液分离成(i)含溶剂的级分,和(ii)污泥馏分。 污泥级分在高沸点溶剂中含有非挥发性物质。