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1. 发明授权

US06193872B1 Process and plant for treating an aqueous waste stream containing at least one alkali metal carboxylate 有权
标题翻译：用于处理含有至少一种碱金属羧酸盐的废水流的方法和设备
公开(公告)号：US06193872B1
公开(公告)日：2001-02-27
申请号：US09297228
申请日：1999-06-22
申请人： Arthur James Reason , George Edwin Harrison , Richard Clive Spratt
发明人： Arthur James Reason , George Edwin Harrison , Richard Clive Spratt
IPC分类号： C25B116
CPC分类号： C02F1/46 , C02F1/048 , C02F1/4618 , C02F1/66 , C02F9/00 , C02F2103/36 , C07C29/38 , C07C45/74 , C07C31/20
摘要： The invention proposes a process and waste treatment plant for regenerating alkali metal hydroxide (3) from an alkaline aqueous waste stream (5) that contains alkali metal C3+ carboxylate byproduct. The waste stream (5) is acidified and the resulting liquour (9) is fed to a first distillation zone (12) to distil carboxylic acid and water. Alternatively, it is fed to a settling zone (14) from which an upper organic layer (16) is recovered as well as a lower aqueous phase (17; 104) which is fed to the first distillation zone. The overhead product (20) from the first distillation zone is condensed and separated into a carboxylic acid layer which is either purged (28) or fed (101) to the settling zone (25). The lower layer (32) of the condensate is redistilled and the water bottoms stream (47) is fed to the cathode compartment (60) of an electrolytic cell (58), while the bottoms stream (52) from the first distillation zone is supplied to the anode compartment (59). Inorganic acid (8) regenerated in the anode compartment is used to acidify the waste stream, while alkali metal hydroxide solution from the cathode compartment is recycled to the chemical production plant (1).
摘要翻译：本发明提出了一种用于从含有碱金属C 3+羧酸盐副产物的碱性废水（5）再生碱金属氢氧化物（3）的方法和废物处理设备。将废物流（5）酸化并将所得液体（9）进料至第一蒸馏区（12）以蒸馏羧酸和水。或者，将其进料到沉淀区（14），从中回收上部有机层（16）以及进料到第一蒸馏区的下部水相（17; 104）。来自第一蒸馏区的塔顶产物（20）被冷凝并分离成被清除（28）或进料（101）至沉降区（25）的羧酸层。将冷凝物的下层（32）重新蒸馏，并将水底部料流（47）送入电解池（58）的阴极室（60），同时从第一蒸馏区供给塔底物流（52）到阳极室（59）。在阳极室中再生的无机酸（8）用于酸化废物流，而来自阴极室的碱金属氢氧化物溶液被再循环到化学生产设备（1）。

2. 发明授权

US5841002A Process for the commercial production of polyhydroxy alcohols and glycols 失效
标题翻译：用于商业生产多羟基醇和二醇的方法
公开(公告)号：US5841002A
公开(公告)日：1998-11-24
申请号：US723186
申请日：1996-09-27
申请人： George Edwin Harrison , Arthur James Reason
发明人： George Edwin Harrison , Arthur James Reason
IPC分类号： C07C29/141 , C07C29/76 , C07C45/72 , C25B1/16 , C07C31/18
CPC分类号： C25B1/16 , C07C29/141 , C07C29/76 , C07C45/72 , Y02P20/584
摘要： An aldolisation process is disclosed for converting an aldehyde or mixture of aldehydes, such as iso-butyraldehyde and formaldehyde, to a desired polyhydroxy alcohol or glycol, such as neopentyl glycol. Aldolisation is effected in a stirred tank reactor using an alkali catalyst, such as sodium hydroxide. An aldolisation intermediate product is converted to the desired polyhydroxy alcohol or glycol by a hydrogenation or cross-Cannizzaro reaction step. The product is recovered and an aqueous catalyst-containing phase is recycled to the aldolisation zone. At least a portion of this catalyst recycle stream is purged to control the build up of cross-Cannizzaro products in the recycle stream. The purge stream is treated electrolytically to obtain an aqueous catalyst-containing solution for recycle to the aldolisation zone and an effluent stream comprising volatile organic materials and being substantially free from alkali catalyst.
摘要翻译：公开了醛醛化方法，用于将醛或其混合物如异丁醛和甲醛转化成所需的多羟基醇或二醇，例如新戊二醇。醛化在使用碱催化剂如氢氧化钠的搅拌釜反应器中进行。醛化中间体产物通过氢化或交叉坎尼扎罗反应步骤转化成所需的多羟基醇或二醇。回收产物并将含水催化剂的相循环到醛醇化区。将该催化剂再循环料流的至少一部分清除以控制在再循环流中交叉的Cannizzaro产品的积累。电解处理清洗流以获得用于循环到醛醇化区的含水催化剂的溶液和包含挥发性有机材料并基本上不含碱催化剂的流出物流。

3. 发明授权

US5968347A Multi-step hydrodesulfurization process 失效
标题翻译：多步加氢脱硫工艺
公开(公告)号：US5968347A
公开(公告)日：1999-10-19
申请号：US849062
申请日：1997-05-23
申请人： Richard Joseph Kolodziej , George Edwin Harrison , Donald Hugh McKinley
发明人： Richard Joseph Kolodziej , George Edwin Harrison , Donald Hugh McKinley
IPC分类号： C10G49/00 , C10G65/04 , C10G17/02 , C10G45/04
CPC分类号： C10G65/04 , C10G49/007
摘要： A hydrotreatment process for effecting hydrotreatment of a liquid hydrocarbon feedstock containing a mixture of liquid hydrocarbons together with organic sulphurous impurities in which a desulphurised liquid first hydrocarbon fraction is contacted with a first stream of desulphurised recycle gas to produce (A) a vaporous mixture including unreacted hydrogen, hydrogen sulphide, and a second hydrocarbon fraction including relatively more volatile components of the mixture of hydrocarbons and (B) a third liquid hydrocarbon fraction including relatively less volatile components of the mixture of hydrocarbons as well as residual sulphurous impurities, the vaporous mixture and the third liquid hydrocarbon fraction being recovered as separate streams from the contact zone. The third liquid hydrocarbon fraction is contacted with a mixture of make-up hydrogen-containing gas and desulphurised recycle gas to cause hydrodesulphurisation of residual sulphurous impurities in the third liquid hydrocarbon fraction. Further processing is followed by recovering a hydrocarbon fraction as a final hydrotreated product material.
摘要翻译： PCT No.PCT / GB95 / 02731 Sec。 371日期1997年5月23日 102（e）日期1997年5月23日PCT提交1995年11月23日PCT公布。 WO96 / 17903 PCT出版物日期1996年6月13日一种用于对含有液体烃的混合物的液体烃原料与有机硫杂质进行加氢处理的加氢处理方法，其中脱硫的液体第一烃馏分与第一脱硫循环气体流接触以产生（A）包含未反应的氢，硫化氢和第二烃馏分的气态混合物，其包含烃混合物的相对更易挥发的组分的第二烃馏分和（B）包含烃混合物相对较少挥发性组分的第三液烃部分以及残留的含硫杂质，蒸气混合物和第三液体烃馏分作为与接触区分离的物流被回收。将第三液体烃馏分与补充含氢气体和脱硫循环气体的混合物接触，以引起第三液态烃馏分中剩余的含硫杂质的加氢脱硫。进一步处理之后是回收作为最终加氢处理的产物材料的烃馏分。

4. 发明授权

US06197271B1 Catalytic reactor and process for exothermic gas phase reactions 有权
标题翻译：催化反应器和放热气相反应过程
公开(公告)号：US06197271B1
公开(公告)日：2001-03-06
申请号：US09101047
申请日：1998-12-10
申请人： Simon Robert Early , George Edwin Harrison , John Wilson Kippax
发明人： Simon Robert Early , George Edwin Harrison , John Wilson Kippax
IPC分类号： C01C104
CPC分类号： C07C29/152 , B01J8/0005 , B01J8/0492 , B01J2208/00884 , C01C1/0417 , Y02P20/52 , C07C31/04
摘要： Disclosed is a reactor and process for exothermic vapour phase reaction, wherein the reactor (1; 101) comprises a pressure vessel (2; 102) having an inlet (3;103) for reactant(s) and an outlet (4; 104) for products; a plurality of beds (5; 105) with heterogeneous catalyst, each bed supported by a catalyst support grating (6; 106); a vapour collection chamber (9; 109) and a vapour redistribution chamber (10; 110) between successive pair(s) of beds for redistribution of vapourous reaction mixture over the inlet of the next bed; a diaphragm (11; 111) separating the vapour collection chamber (9; 109) from the vapour redistribution chamber; at least one pair of nested trough members extending at least partially across the diaphragm, each comprising an inner trough member (14; 114) having one or more apertures (18; 118), an outer trough (20; 120) having one or more apertures (21; 121) and a quench gas conduit (15; 115) provided with apertures (17; 117); the apertures (18; 118; 21; 121; 17; 117) arranged to provide a tortuous pathway for the flow of vapour and quench gas.
摘要翻译：公开了一种用于放热气相反应的反应器和方法，其中反应器（1; 101）包括具有用于反应物的入口（3; 103）和出口（4; 104）的压力容器（2; 102）产品; 具有多相催化剂的多个床（5; 105），每个床由催化剂支撑光栅（6; 106）支撑; 蒸气收集室（9; 109）和连续的一对床之间的蒸气再分配室（10; 110），用于将蒸气反应混合物重新分配在下一个床的入口上; 将蒸气收集室（9; 109）与蒸气再分配室分离的隔膜（11; 111）至少一对嵌套槽构件至少部分延伸穿过隔膜，每对包括具有一个或多个孔（18; 118）的内槽构件（14; 114），具有一个或多个孔的外槽（20; 120）孔（21; 121）和设有孔（17; 117）的骤冷气体导管（15; 115）所述孔（18; 118; 21; 121; 17; 117）被布置成为蒸气和骤冷气体的流动提供曲折的通路。

5. 发明授权

US06946580B2 Hydroformylation process with recycle of active rhodium catalyst 有权
标题翻译：加氢甲酰化工艺与活性铑催化剂循环
公开(公告)号：US06946580B2
公开(公告)日：2005-09-20
申请号：US10479309
申请日：2002-05-29
申请人： James Andrew Banister , George Edwin Harrison
发明人： James Andrew Banister , George Edwin Harrison
IPC分类号： B01J31/24 , B01J31/40 , B01J38/00 , B01J38/04 , B01J38/12 , C07B61/00 , C07C45/50 , C07C47/02
CPC分类号： C07C45/50 , Y02P20/584 , C07C47/02
摘要： The present invention relates to a continuous hydroformylation process for the production of an aldehyde by hydroformylation of an olefin which comprises: providing a hydroformylation zone containing a charge of a liquid reaction medium having dissolved therein a rhodium hydroformylation catalyst comprising rhodium in combination with carbon monoxide and a ligand; supplying the olefin to the hydroformylation zone; maintaining temperature and pressure conditions in the hydroformylation zone conducive to hydroformylation of the olefin; recovering from the liquid hydroformylation medium a hydroformylation product comprising aldehyde; recovering from the hydroformylation zone a stream comprising the rhodium catalyst; contacting at least a portion of the stream with a solid acidic absorbent under process conditions which allow at least some of the rhodium to become bound to the absorbent; subjecting the rhodium bound to the absorbent, under process conditions which allow desorption of the metal, to a fluid stripping medium comprising hydrogen and solvent; recovering the rhodium hydride catalyst; and recycling the rhodium hydride catalyst to the hydroformylation zone.
摘要翻译：本发明涉及通过烯烃的加氢甲酰化生产醛的连续加氢甲酰化方法，该方法包括：提供含有液体反应介质的加氢甲酰化区，该液体反应介质溶解有铑加氢甲酰化催化剂，该催化剂包含铑与一氧化碳和配体; 将烯烃供应到加氢甲酰化区; 维持加氢甲酰化区中有利于烯烃加氢甲酰化的温度和压力条件; 从液体加氢甲酰化介质中回收含有醛的加氢甲酰化产物; 从加氢甲酰化区回收包含铑催化剂的物流; 在工艺条件下使至少一部分流与固体酸性吸收剂接触，使得至少一些铑与吸收剂结合; 在允许金属解吸的工艺条件下将结合到吸收剂上的铑经受包含氢和溶剂的流体汽提介质; 回收氢化铑催化剂; 并将氢化铑催化剂再循环到加氢甲酰化区。

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