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1. 发明授权

US4596878A Process for the production of maleic anhydride 失效
标题翻译：马来酸酐生产工艺
公开(公告)号：US4596878A
公开(公告)日：1986-06-24
申请号：US645329
申请日：1984-08-29
申请人： Gaylon T. Click , Bruno J. Barone
发明人： Gaylon T. Click , Bruno J. Barone
IPC分类号： B01J27/28 , C07C51/215 , C07C51/25 , C07D307/60
CPC分类号： C07C51/215 , B01J27/285 , C07C51/252 , Y02P20/584
摘要： The useful life of vanadium-phosphorus-oxygen (PVO) catalyst in fixed bed reactors can be substantially extended by treatment with a phosphorus compound followed by steam treatment. The PVO catalysts may be treated with steam after long periods (months) of only phosphorus compound treatment and the benefit of the present invention obtained or the phosphorus and steam treatments may be of only a few hours duration and sequential. In extending the useful life of the PVO catalyst according to the present invention, the temperature profile in the catalyst bed is restored to substantially the same profile as the fresh catalyst.
摘要翻译：固定床反应器中的钒 - 磷 - 氧（PVO）催化剂的使用寿命可以通过用磷化合物处理然后进行蒸汽处理而大大延长。 PVO催化剂可以在仅经过磷化合物处理的长时间（月）之后用蒸汽处理，并且所获得的本发明的益处或磷和蒸汽处理可能只有几个小时的持续时间和顺序。在延长根据本发明的PVO催化剂的使用寿命期间，催化剂床中的温度曲线恢复到与新鲜催化剂基本相同的轮廓。

2. 发明授权

US4283307A Catalyst structure for the partial oxidation of n-butane to produce maleic anhydride 失效
标题翻译：用于部分氧化正丁烷以生产马来酸酐的催化剂结构
公开(公告)号：US4283307A
公开(公告)日：1981-08-11
申请号：US155556
申请日：1980-06-02
申请人： Bruno J. Barone , Gaylon T. Click
发明人： Bruno J. Barone , Gaylon T. Click
IPC分类号： C07D307/60 , B01J23/22 , B01J27/18 , B01J27/198 , B01J35/02 , C01B25/45 , C07B61/00 , C07C51/215 , B01J35/00
CPC分类号： C07C51/215 , B01J23/002 , B01J23/22 , B01J27/198 , B01J35/026 , B01J2523/00
摘要： Phosphorus-Vanadium oxidation catalyst prepared as tablets with a hole in the center produce higher yields of maleic anhydride from C.sub.4 's, particularly n-butane than the same catalyst without the hole.
摘要翻译：由中心产生的具有孔的片剂制备的磷 - 钒氧化催化剂比没有孔的相同催化剂产生更高的C4，特别是正丁烷的马来酸酐产率。

3. 发明授权

US4515899A Steam regeneration of phosphorus treated vanadium-phosphorus-oxygen catalysts 失效
标题翻译：磷处理的钒 - 磷 - 氧催化剂的蒸汽再生
公开(公告)号：US4515899A
公开(公告)日：1985-05-07
申请号：US561320
申请日：1983-12-14
申请人： Gaylon T. Click , Bruno J. Barone
发明人： Gaylon T. Click , Bruno J. Barone
IPC分类号： C07D307/60 , B01J27/28 , B01J38/04 , B01J38/06 , B01J38/42 , C07B61/00 , C07C51/215 , C07C51/25
CPC分类号： C07C51/215 , B01J27/285 , C07C51/252 , Y02P20/584
摘要： The useful life of vanadium-phosphorus-oxygen (PVO) catalyst in fixed bed reactors can be substantially extended by treatment with a phosphorus compound followed by steam treatment. The PVO catalysts may be treated with steam after long periods (months) of only phosphorus compound treatment and the benefit of the present invention obtained or the phosphorus and steam treatments may be of only a few hours duration and sequential. In extending the useful life of the PVO catalyst according to the present invention, the temperature profile in the catalyst bed is restored to substantially the same profile as the fresh catalyst.
摘要翻译：固定床反应器中的钒 - 磷 - 氧（PVO）催化剂的使用寿命可以通过用磷化合物处理然后进行蒸汽处理而大大延长。 PVO催化剂可以在仅经过磷化合物处理的长时间（月）之后用蒸汽处理，并且所获得的本发明的益处或磷和蒸汽处理可能只有几个小时的持续时间和顺序。在延长根据本发明的PVO催化剂的使用寿命期间，催化剂床中的温度曲线恢复到与新鲜催化剂基本相同的轮廓。

4. 发明授权

US5360916A Two stage butane haleic anhydride process 失效
标题翻译：二级丁烷黑麦酸酐工艺
公开(公告)号：US5360916A
公开(公告)日：1994-11-01
申请号：US152088
申请日：1993-11-15
申请人： Ashok S. Padia , Gaylon T. Click
发明人： Ashok S. Padia , Gaylon T. Click
IPC分类号： B01J27/198 , C07B61/00 , C07C51/215 , C07D307/60
CPC分类号： C07C51/215
摘要： Butane is oxidized with molecular oxygen in a dilute state by bringing a mixture of vaporized butane and air of controlled butane content into the presence of a contact vanadium-phosphorus-oxygen catalyst in a first oxidation zone under controlled pressure and temperature conditions, cooling the gaseous effluent from the first oxidation zone to a temperature in the range of 50.degree. to 300.degree. C., introducing a controlled amount of butane into the cooled gaseous effluent from the first oxidation zone, introducing said cooled butane-enriched stream into the second oxidation zone, and bringing the thus butane-enriched mixture into contact with a vanadium-phosphorus-oxygen catalyst disposed in the second zone.
摘要翻译：在受控的压力和温度条件下，通过使第一氧化区中的受控丁烷含量的蒸发的丁烷和空气的混合物存在于第一氧化区中的接触的钒 - 磷 - 氧催化剂的存在下，丁烷被氧化，冷却气态从第一氧化区的流出物到50℃至300℃的温度，将受控量的丁烷引入来自第一氧化区的冷却的气态流出物中，将所述冷却的富含丁烷的物流引入第二氧化区并使如此的丁烷富集的混合物与设置在第二区域中的钒 - 磷 - 氧催化剂接触。

5. 发明授权

US4250083A Viscosity stabilized chloroprene-sulfur copolymers 失效
标题翻译：粘度稳定氯丁二烯 - 硫共聚物
公开(公告)号：US4250083A
公开(公告)日：1981-02-10
申请号：US009109
申请日：1979-02-05
申请人： Gaylon T. Click , Nathan L. Turner , Edwin F. Hoff, Jr.
发明人： Gaylon T. Click , Nathan L. Turner , Edwin F. Hoff, Jr.
IPC分类号： C08F36/00 , C08F36/18 , C08G75/00 , C08K5/18
CPC分类号： C08F36/18
摘要： Viscosity stable chloroprene-sulfur copolymers are prepared by polymerizing chloroprene and sulfur in the presence of styrenated diphenyl amine. The presence of this material in the polymerization causes no discernible detriment to or degradation in the other properties of the copolymers.
摘要翻译：粘度稳定的氯丁二烯 - 硫共聚物是通过在苯乙烯二苯胺存在下聚合氯丁二烯和硫来制备的。该聚合物中存在该物质对共聚物的其它性能没有明显的损害或降解。

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