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    • 1. 发明授权
    • Organic recycling with a pipe-cross or tubular reactor
    • 用管道交叉或管状反应器进行有机回收
    • US07128880B2
    • 2006-10-31
    • US10322802
    • 2002-12-19
    • Gary L. DahmsGary D. Greer
    • Gary L. DahmsGary D. Greer
    • B01J10/00C05F7/00C05F3/04
    • C05B7/00C05F7/00Y02A40/213C05B19/00C05C3/00C05G3/0058
    • The invention is directed to a process for enhancing the plant nutrient value of relatively low analysis organic waste material (e.g. sewage sludge) involves treating the waste material with an acid and base in a pipe-cross reactor or tubular to form a melt; spraying the melt onto a recycling bed of fines in a granulator and flashing off the water contained in the melt as steam; rolling the melt onto recycled fine particles in a granulator to form granulated particles; and drying these granulated particles to form an enhanced plant nutrient value composition (e.g. a fertilizer or soil conditioner having a greater NPK value than the original relatively low analysis organic waste material). The process further includes drawing off the fumes from the granulator, passing them through a dryer with the granulated particles, and subsequently oxidizing the fumes to eliminate volatile organic compounds and/or gaseous hydrocarbon pollutants be converting such into carbon dioxide and water vapor.
    • 本发明涉及一种用于增强相对低分析的有机废物(例如污水污泥)的植物营养价值的方法,其涉及在管交叉反应器或管中用酸和碱处理废料以形成熔体; 在造粒机中将熔体喷射到细粉的再循环床上,并将其作为蒸汽从包含在熔体中的水闪烁; 在造粒机中将熔体滚动到再循环的细颗粒上以形成造粒颗粒; 并干燥这些造粒颗粒以形成增强的植物营养价值组合物(例如具有比原始相对较低分析的有机废物材料更大的NPK值的肥料或土壤调理剂)。 该方法还包括从成粒机中除去烟雾,将其通过具有造粒颗粒的干燥器,随后氧化烟气以消除挥发性有机化合物和/或气态烃污染物转化为二氧化碳和水蒸气。
    • 2. 发明授权
    • Sewage sludge recycling with a pipe cross-reactor
    • 用管道交叉反应器进行污水污泥回收
    • US5984992A
    • 1999-11-16
    • US852663
    • 1997-05-07
    • Gary D. GreerGary L. Dahms
    • Gary D. GreerGary L. Dahms
    • B09B3/00B09B5/00C02F11/00C05D9/02C05F1/00C05F3/00C05F7/00C05F17/00C05G3/00C05G5/00C05F11/00
    • C05G3/0058C05D9/02C05F3/00C05F7/00Y02P20/136Y02P20/145Y02W30/43
    • An improved process for enhancing the plant nutrient value of relatively low analysis organic waste material (e.g. sewage sludge) involves treating the waste material with an acid and base in a pipe-cross reactor. The process more particularly involves mixing the waste material with water to form a slurry (or initially taking the waste material as a slurry); pumping the slurry to a pipe-cross reactor for reaction with a base, acid, and water to form a melt; spraying the melt onto a recycling bed of fines in a granulator, and flashing off the water contained in the melt as steam; rolling the melt onto recycled fine particles in a granulator to form granulated particles; and drying these granulated particles to form an enhanced plant nutrient value composition (e.g. a fertilizer or soil conditioner having a greater "NPK" value than the original relatively low analysis organic waste material). The invention also includes fertilizer produced according to the improved process, which fertilizers are of the same size and shape and density of commonly used fertilizers. The method advantageously utilizes the heat generated by the exothermic acid-base reaction in the pipe-cross reactor to remove the approximately 80% water from sludge, thus saving large amounts of energy normally used in conventional drying or burning methods, while, at the same time, conserving the intrinsic values of the nutrients and humates contained in the sludge. In one embodiment, the process includes a method of disposing of spent acid from a hot dip galvanizing process or a steel pickling process involving incorporating the spent acid to maintain the low pH of a venturi scrubber used in the improved process.
    • 用于提高相对低分析的有机废物(例如污水污泥)的植物营养价值的改进方法包括在管交叉反应器中用酸和碱处理废料。 该方法更具体地涉及将废料与水混合以形成浆料(或者最初以废料作为浆料); 将浆料泵送到管交叉反应器中以与碱,酸和水反应以形成熔体; 在造粒机中将熔体喷射到细粒的再循环床上,并将蒸汽中包含在熔体中的水闪烁; 在造粒机中将熔体滚动到再循环的细颗粒上以形成造粒颗粒; 并干燥这些造粒颗粒以形成增强的植物营养价值组合物(例如具有比原始相对较低分析的有机废物材料更大的“NPK”值的肥料或土壤调理剂)。 本发明还包括根据改进方法生产的肥料,其中肥料具有与常用肥料相同的尺寸,形状和密度。 该方法有利地利用了在交叉反应器中由放热酸碱反应产生的热量从污泥中除去约80%的水,从而节省了常规干燥或燃烧方法中通常使用的大量能量,同时 时间,保持污泥中所含营养物和腐殖酸的内在价值。 在一个实施方案中,该方法包括从热浸镀锌工艺或钢酸洗工艺处理废酸的方法,包括掺入废酸以维持改进方法中使用的文丘里洗涤器的低pH。
    • 3. 发明申请
    • Organic recycling with a pipe-cross or tubular reactor
    • 用管道交叉或管状反应器进行有机回收
    • US20100011823A1
    • 2010-01-21
    • US12454627
    • 2009-05-19
    • Gary L. DahmsGary D. Greer
    • Gary L. DahmsGary D. Greer
    • C05F3/04C05F3/06
    • C05B7/00C05F7/00Y02A40/213C05B19/00C05C3/00C05G3/0058
    • The invention is directed to a process for enhancing the plant nutrient value of relatively low analysis organic waste material (e.g. sewage sludge) involves treating the waste material with an acid and base in a pipe-cross,reactor or tubular to form a melt; spraying the melt onto a recycling bed of fines in a granulator and flashing off the water contained in the melt as steam; rolling the melt onto recycled fine particles in a granulator to form granulated particles; and drying these granulated particles in a to form an enhanced plant nutrient value composition (e.g. a fertilizer or soil conditioner having a greater NPK value than the original relatively low analysis organic waste material). The process further includes drawing off the fumes from the granulator, passing them through a dryer with the granulated particles, and subsequently oxidizing the fumes to eliminate volatile organic compounds and/or gaseous hydrocarbon pollutants be converting such into carbon dioxide and water vapor.
    • 本发明涉及一种用于提高相对低分析的有机废物(例如污水污泥)的植物营养价值的方法,包括用管道交叉,反应器或管状物中的酸和碱处理废物以形成熔体; 在造粒机中将熔体喷射到细粉的再循环床上,并将其作为蒸汽从包含在熔体中的水闪烁; 在造粒机中将熔体滚动到再循环的细颗粒上以形成造粒颗粒; 并且在a中干燥这些造粒颗粒以形成增强的植物营养价值组合物(例如具有比原始相对较低分析的有机废物材料更大的NPK值的肥料或土壤调理剂)。 该方法还包括从成粒机中除去烟雾,将其通过具有造粒颗粒的干燥器,随后氧化烟气以消除挥发性有机化合物和/或气态烃污染物转化为二氧化碳和水蒸气。
    • 4. 发明授权
    • Sewage sludge recycling with a pipe cross-reactor
    • US07169204B2
    • 2007-01-30
    • US10884856
    • 2004-07-06
    • Gary D. GreerGary L. Dahms
    • Gary D. GreerGary L. Dahms
    • C01B17/04
    • C05G3/0058C05D9/02C05F3/00C05F7/00Y02A40/205Y02A40/213Y02P20/136Y02P20/145Y02W30/43C05F5/00C05F7/02
    • An improved process for enhancing the plant nutrient value of relatively low analysis organic waste material (e.g., sewage sludge) involves treating the waste material with an acid and base in a pipe-cross reactor. The process more particularly involves mixing the waste material with water to form a slurry (or initially taking the waste material as a slurry); pumping the slurry to a pipe-cross reactor for reaction with a base, acid, and water to form a melt; spraying the melt onto a recycling bed of fines in a granulator, and flashing off the water contained in the melt as steam; rolling the melt onto recycled fine particles in a granulator to form granulated particles; and drying these granulated particles to form an enhanced plant nutrient value composition (e.g., a fertilizer or soil conditioner having a greater “NPK” value than the original relatively low analysis organic waste material). The invention also includes fertilizers produced according to the improved process, which fertilizers are of the same size and shape and density of commonly used fertilizers. The method advantageously utilizes the heat generated by the exothermic acid-base reaction in the pipe-cross reactor to remove the approximately 80% water from sludge, thus saving large amounts of energy normally used in conventional drying or burning methods, while, at the same time, conserving the intrinsic values of the nutrients and humates contained in the sludge. In one embodiment, the process includes a method of disposing of spent acid from a hot dip galvanizing process or a steel pickling process involving incorporating the spent acid to maintain the low pH of a venturi scrubber used in the improved process.
    • 5. 发明申请
    • Sewage Sludge Recycling With A Pipe Cross-Reactor
    • 污水污泥回收利用管道交叉反应堆
    • US20100064747A1
    • 2010-03-18
    • US12625210
    • 2009-11-24
    • Gary D. GreerGary L. Dahms
    • Gary D. GreerGary L. Dahms
    • C05F7/00
    • C05G3/0058C05D9/02C05F3/00C05F7/00Y02A40/205Y02A40/213Y02P20/136Y02P20/145Y02W30/43C05F5/00C05F7/02
    • An improved process for enhancing the plant nutrient value of relatively low analysis organic waste material (e.g., sewage sludge) involves treating the waste material with an acid and base in a pipe-cross reactor. The process more particularly involves mixing the waste material with water to form a slurry (or initially taking the waste material as a slurry); pumping the slurry to a pipe-cross reactor for reaction with a base, acid, and water to form a melt: spraying the melt onto a recycling bed of fines in a granulator and flashing off the water contained in the melt as steam; rolling the melt onto recycled fine particles in a granulator to form granulated particles; and drying these granulated particles to form an enhanced plant nutrient value composition (e.g., a fertilizer or soil conditioner having a greater “NPK” value than the original relatively low analysis organic waste material). The invention also includes fertilizers produced according to the improved process, which fertilizers are of the same size and shape and density of commonly used fertilizers. The method advantageously utilizes the heat generated by the exothermic acid-base reaction in the pipe-cross reactor to remove the approximately 80% water from sludge, thus saving large amounts of energy normally used in conventional drying or burning methods, while, at the same time, conserving the intrinsic values of the nutrients and humates contained in the sludge. In one embodiment, the process includes a method of disposing of spent acid from a hot dip galvanizing process or a steel pickling process involving incorporating the spent acid to maintain the low pH of a venturi scrubber used in the improved process.
    • 用于提高相对低分析的有机废物(例如,污水污泥)的植物营养价值的改进方法包括在管交叉反应器中用酸和碱处理废料。 该方法更具体地涉及将废料与水混合以形成浆料(或者最初以废料作为浆料); 将浆料泵送到管交叉反应器以与基底,酸和水反应以形成熔体:将熔体喷雾到造粒机的细粒再循环床上,并将其作为蒸汽从包含在熔体中的水闪烁; 在造粒机中将熔体滚动到再循环的细颗粒上以形成造粒颗粒; 并干燥这些造粒颗粒以形成增强的植物营养价值组合物(例如,具有比原始相对较低分析的有机废物材料更大的“NPK”值的肥料或土壤调理剂)。 本发明还包括根据改进方法生产的肥料,其中肥料具有与常用肥料相同的尺寸,形状和密度。 该方法有利地利用了在交叉反应器中由放热酸碱反应产生的热量从污泥中除去约80%的水,从而节省了常规干燥或燃烧方法中通常使用的大量能量,同时 时间,保持污泥中所含营养物和腐殖酸的内在价值。 在一个实施方案中,该方法包括从热浸镀锌工艺或钢酸洗工艺处理废酸的方法,包括掺入废酸以维持改进方法中使用的文丘里洗涤器的低pH。
    • 6. 发明授权
    • Organic recycling with a pipe-cross or tubular reactor
    • 用管道交叉或管状反应器进行有机回收
    • US07534281B2
    • 2009-05-19
    • US11522083
    • 2006-09-15
    • Gary L. DahmsGary D. Greer
    • Gary L. DahmsGary D. Greer
    • C05C9/00
    • C05B7/00C05F7/00Y02A40/213C05B19/00C05C3/00C05G3/0058
    • The invention is directed to a process for enhancing the plant nutrient value of relatively low analysis organic waste material (e.g. sewage sludge) involves treating the waste material with an acid and base in a pipe-cross reactor or tubular to form a melt; spraying the melt onto a recycling bed of fines in a granulator and flashing off the water contained in the melt as steam; rolling the melt onto recycled fine particles in a granulator to form granulated particles; and drying these granulated particles in a to form an enhanced plant nutrient value composition (e.g. a fertilizer or soil conditioner having a greater NPK value than the original relatively low analysis organic waste material). The process further includes drawing off the fumes from the granulator, passing them through a dryer with the granulated particles, and subsequently oxidizing the fumes to eliminate volatile organic compounds and/or gaseous hydrocarbon pollutants be converting such into carbon dioxide and water vapor.
    • 本发明涉及一种用于增强相对低分析的有机废物(例如污水污泥)的植物营养价值的方法,其涉及在管交叉反应器或管中用酸和碱处理废料以形成熔体; 在造粒机中将熔体喷射到细粉的再循环床上,并将其作为蒸汽从包含在熔体中的水闪烁; 在造粒机中将熔体滚动到再循环的细颗粒上以形成造粒颗粒; 并且在a中干燥这些造粒颗粒以形成增强的植物营养价值组合物(例如具有比原始相对较低分析的有机废物材料更大的NPK值的肥料或土壤调理剂)。 该方法还包括从成粒机中除去烟雾,将其通过具有造粒颗粒的干燥器,随后氧化烟气以消除挥发性有机化合物和/或气态烃污染物转化为二氧化碳和水蒸气。
    • 7. 发明授权
    • Sewage sludge recycling with a pipe cross-reactor
    • 用管道交叉反应器进行污水回用污泥
    • US06758879B2
    • 2004-07-06
    • US09735768
    • 2000-12-12
    • Gary D. GreerGary L. Dahms
    • Gary D. GreerGary L. Dahms
    • C01B1704
    • C05G3/0058C05D9/02C05F3/00C05F7/00Y02A40/205Y02A40/213Y02P20/136Y02P20/145Y02W30/43C05F5/00C05F7/02
    • An improved process for enhancing the plant nutrient value of relatively low analysis organic waste material (e.g., sewage sludge) involves treating the waste material with an acid and base in a pipe-cross reactor. The process more particularly involves mixing the waste material with water to form a slurry (or initially taking the waste material as a slurry); pumping the slurry to a pipe-cross reactor for reaction with a base, acid, and water to form a melt; spraying the melt onto a recycling bed of fines in a granulator, and flashing off the water contained in the melt as steam; rolling the melt onto recycled fine particles in a granulator to form granulated particles; and drying these granulated particles to form an enhanced plant nutrient value composition (e.g., a fertilizer or soil conditioner having a greater “NPK” value than the original relatively low analysis organic waste material). The invention also includes fertilizers produced according to the improved process, which fertilizers are of the same size and shape and density of commonly used fertilizers. The method advantageously utilizes the heat generated by the exothermic acid-base reaction in the pipe-cross reactor to remove the approximately 80% water from sludge, thus saving large amounts of energy normally used in conventional drying or burning methods, while, at the same time, conserving the intrinsic values of the nutrients and humates contained in the sludge. In one embodiment, the process includes a method of disposing of spent acid from a hot dip galvanizing process or a steel pickling process involving incorporating the spent acid to maintain the low pH of a venturi scrubber used in the improved process.
    • 用于提高相对低分析的有机废物(例如,污水污泥)的植物营养价值的改进方法包括在管交叉反应器中用酸和碱处理废料。 该方法更具体地涉及将废料与水混合以形成浆料(或者最初以废料作为浆料); 将浆料泵送到管交叉反应器中以与碱,酸和水反应以形成熔体; 在造粒机中将熔体喷射到细粒的再循环床上,并将蒸汽中包含在熔体中的水闪烁; 在造粒机中将熔体滚动到再循环的细颗粒上以形成造粒颗粒; 并干燥这些造粒颗粒以形成增强的植物营养价值组合物(例如,具有比原始相对较低分析的有机废物材料更大的“NPK”值的肥料或土壤调理剂)。 本发明还包括根据改进方法生产的肥料,其中肥料具有与常用肥料相同的尺寸,形状和密度。 该方法有利地利用了在交叉反应器中由放热酸碱反应产生的热量从污泥中除去约80%的水,从而节省了常规干燥或燃烧方法中通常使用的大量能量,同时 时间,保持污泥中所含营养物和腐殖酸的内在价值。 在一个实施方案中,该方法包括从热浸镀锌工艺或钢酸洗工艺处理废酸的方法,包括掺入废酸以维持改进方法中使用的文丘里洗涤器的低pH。
    • 8. 发明授权
    • Sewage sludge recycling with a pipe cross-reactor
    • 用管道交叉反应器进行污水回用污泥
    • US6159263A
    • 2000-12-12
    • US416370
    • 1999-10-12
    • Gary D. GreerGary L. Dahms
    • Gary D. GreerGary L. Dahms
    • B09B3/00B09B5/00C02F11/00C05D9/02C05F1/00C05F3/00C05F7/00C05F17/00C05G3/00C05G5/00C05F11/00
    • C05G3/0058C05D9/02C05F3/00C05F7/00Y02P20/136Y02P20/145Y02W30/43
    • An improved process for enhancing the plant nutrient value of relatively low analysis organic waste material (e.g., sewage sludge) involves treating the waste material with an acid and base in a pipe-cross reactor. The process more particularly involves mixing the waste material with water to form a slurry (or initially taking the waste material as a slurry); pumping the slurry to a pipe-cross reactor for reaction with a base, acid, and water to form a melt; spraying the melt onto a recycling bed of fines in a granulator, and flashing off the water contained in the melt as steam; rolling the melt onto recycled fine particles in a granulator to form granulated particles; and drying these granulated particles to form an enhanced plant nutrient value composition (e.g., a fertilizer or soil conditioner having a greater "NPK" value than the original relatively low analysis organic waste material). The invention also includes fertilizers produced according to the improved process, which fertilizers are of the same size and shape and density of commonly used fertilizers. The method advantageously utilizes the heat generated by the exothermic acid-base reaction in the pipe-cross reactor to remove the approximately 80% water from sludge, thus saving large amounts of energy normally used in conventional drying or burning methods, while, at the same time, conserving the intrinsic values of the nutrients and humates contained in the sludge. In one embodiment, the process includes a method of disposing of spent acid from a hot dip galvanizing process or a steel pickling process involving incorporating the spent acid to maintain the low pH of a venturi scrubber used in the improved process.
    • 用于提高相对低分析的有机废物(例如,污水污泥)的植物营养价值的改进方法包括在管交叉反应器中用酸和碱处理废料。 该方法更具体地涉及将废料与水混合以形成浆料(或者最初以废料作为浆料); 将浆料泵送到管交叉反应器中以与碱,酸和水反应以形成熔体; 在造粒机中将熔体喷射到细粒的再循环床上,并将蒸汽中包含在熔体中的水闪烁; 在造粒机中将熔体滚动到再循环的细颗粒上以形成造粒颗粒; 并干燥这些造粒颗粒以形成增强的植物营养价值组合物(例如,具有比原始相对较低分析的有机废物材料更大的“NPK”值的肥料或土壤调理剂)。 本发明还包括根据改进方法生产的肥料,其中肥料具有与常用肥料相同的尺寸,形状和密度。 该方法有利地利用了在交叉反应器中由放热酸碱反应产生的热量从污泥中除去约80%的水,从而节省了常规干燥或燃烧方法中通常使用的大量能量,同时 时间,保持污泥中所含营养物和腐殖酸的内在价值。 在一个实施方案中,该方法包括从热浸镀锌工艺或钢酸洗工艺处理废酸的方法,包括掺入废酸以维持改进方法中使用的文丘里洗涤器的低pH。
    • 9. 发明申请
    • Process for Treating Sludge and Manufacturing Bioorganically-Augmented High Nitrogen-Containing Inorganic Fertilizer
    • 污泥处理工艺及生物有机增强高含氮无机肥料
    • US20110265532A1
    • 2011-11-03
    • US13104127
    • 2011-05-10
    • Jeffrey C. BurnhamJames P. CarrGary L. Dahms
    • Jeffrey C. BurnhamJames P. CarrGary L. Dahms
    • C05F3/00C05F9/00C05F11/08C05F7/00
    • C05C3/005C05B7/00C05C3/00C05C9/00C05D9/02C05F7/00C05G3/0041Y02A40/213C05D3/02C05F3/00
    • The invention describes a new method for treating sludge, which can result in the production of high nitrogen organically-augmented inorganic fertilizer that incorporates municipal sludges or biosolids or organic sludges that can compete with traditional fertilizers such as ammonium phosphate, ammonium sulfate and urea on the commodity fertilizer marketplace. The method takes advantage of the thixotropic property of dewatered biosolids or organic sludge to create a pumpable paste-like material from the biosolids or organic sludge that is then treated with an oxidizer to reduce odorant effects and an acid. This mix is then interacted with concentrated sulfuric and or phosphoric acids and an ammonia source or alternatively a hot or molten melt or salt of ammonium sulfate/phosphate to form a fertilizer mix. The present invention controls the heat, atmospheric pressure and retention time of the fertilizer mix in the reaction vessel. When a fertilizer melt is formed ammoniation is subsequently completed by the specific use of vaporized ammonia. The invention can also be an add-on to commercial production of ammonium salts. The fertilizer produced by the present invention contains more than 8 wt. % nitrogen and preferably 15 wt. % nitrogen. The invention is oriented to be tailored to the biosolids production for individual municipal waste treatment plants in order to keep the fertilizer manufacturing plants of the present invention small with a minimization of logistics and liability.
    • 本发明描述了一种用于处理污泥的新方法,其可以产生高氮有机增强的无机肥料,其包含可与传统肥料如磷酸铵,硫酸铵和尿素竞争的市政污泥或生物固体或有机污泥 商品化肥市场。 该方法利用脱水生物固体或有机污泥的触变性质,从生物固体或有机污泥中产生可抽出的糊状材料,然后用氧化剂处理以减少气味效应和酸。 然后将该混合物与浓硫酸和/或磷酸和氨源或热或熔融的熔融物或硫酸铵/磷酸盐形成一种肥料混合物相互作用。 本发明控制肥料混合物在反应容器中的热,大气压力和保留时间。 当形成化肥熔体时,氨化随后通过具体使用蒸发的氨完成。 本发明也可以是商业生产铵盐的附加物。 本发明生产的肥料含有超过8wt。 %氮,优选15wt。 % 氮。 本发明的目标是针对各个城市废物处理厂的生物固体生产进行定制,以便使物流和责任最小化来保持本发明的肥料制造工厂的效果。