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1. 发明授权

US4828032A Oil recovery process using alkyl hydroxyaromatic dianionic surfactants as mobility control agents 失效
标题翻译：使用烷基羟基芳族二阴离子表面活性剂作为迁移控制剂的油回收方法
公开(公告)号：US4828032A
公开(公告)日：1989-05-09
申请号：US282923
申请日：1988-12-07
申请人： Gary F. Teletzke , Thomas L. Ashcraft, Jr. , Ronald L. Reed
发明人： Gary F. Teletzke , Thomas L. Ashcraft, Jr. , Ronald L. Reed
IPC分类号： C09K8/584 , C09K8/592 , C09K8/594 , E21B43/24
CPC分类号： C09K8/592 , C09K8/584 , C09K8/594 , E21B43/24 , Y10S507/936
摘要： A method for recovering oil from a subterranean formation is disclosed wherein an aqueous surfactant solution is injected into the formation to reduce the mobility of gas in a gas-flooding process. The gas may include hydrocarbon gas, inert gas, carbon dioxide, and steam. The surfactant is represented by the general formula ##STR1## where R is a linear or branched chain alkyl group with n carbon atoms wherein n ranges from 0 to about 18, except that if the gas is steam n ranges from about 9 to about 30;x ranges from 0 to about 20 and y ranges from 0 to about 20, provided x+y does not exceed about 20;R' is a linear or branched chain alkyl group with m carbon atoms wherein m ranges from 0 to 4, except that if the gas is steam m ranges from 1 to 4, with the proviso that the sum of x+y+m is at least one; andeach M.sup.+ is a cation.
摘要翻译：公开了一种从地层中回收油的方法，其中将表面活性剂水溶液注入地层以降低气驱过程中气体的迁移率。气体可以包括烃气体，惰性气体，二氧化碳和蒸汽。表面活性剂由通式“IMAGE”表示，其中R是具有n个碳原子的直链或支链烷基，其中n为0至约18，不同之处在于，如果气体为蒸汽n的范围为约9至约30; x的范围为0至约20，y的范围为0至约20，条件是x + y不超过约20; R'是具有m个碳原子的直链或支链烷基，其中m为0至4，不同之处在于如果气体为蒸汽，m的范围为1至4，条件是x + y + m的和为至少有一个; 并且每个M +是阳离子。

2. 发明授权

US5046560A Oil recovery process using arkyl aryl polyalkoxyol sulfonate surfactants as mobility control agents 失效
标题翻译：使用烷基芳基聚烷氧基磺酸盐表面活性剂作为迁移控制剂的油回收方法
公开(公告)号：US5046560A
公开(公告)日：1991-09-10
申请号：US205715
申请日：1988-06-10
申请人： Gary F. Teletzke , Ronald L. Reed
发明人： Gary F. Teletzke , Ronald L. Reed
IPC分类号： C09K8/592 , C09K8/594 , E21B43/16 , E21B43/24
CPC分类号： C09K8/592 , C09K8/594 , E21B43/164 , E21B43/24 , Y02P90/70 , Y10S507/936
摘要： A method for recovering oil from a subterranean formation is disclosed wherein an aqueous surfactant solution is injected into the formation to reduce the mobility of gas in a gas-flooding process. The gas may include hydrocarbon gas, inert gas, carbon dioxide, and steam, or mixtures thereof. The surfactant is represented by the general formula ##STR1## where R is a linear or branched chain alkyl group with n carbon atoms wherein n ranges from about 6 to about 50, except that if the gas is steam n ranges from about 9 to about 50;Ar is a mononuclear or fused ring dinuclear aryl group;Z is an ionic group consisting of --SO.sub.3.sup.- M.sup.+ or --R'SO.sub.3.sup.- M.sup.+ wherein M.sup.+ is a cation and R' is a linear or branched chain alkyl group of from one to about six carbon atoms;x ranges from 0 to about 20; andy ranges from 3 to about 100.
摘要翻译：公开了一种从地层中回收油的方法，其中将表面活性剂水溶液注入地层以降低气驱过程中气体的迁移率。气体可以包括烃气体，惰性气体，二氧化碳和蒸汽，或其混合物。表面活性剂由通式“IMAGE”表示，其中R是具有n个碳原子的直链或支链烷基，其中n为约6至约50，不同之处在于如果气体为蒸汽n的范围为约9至约50 ; Ar是单核或稠环双核芳基; Z是由-SO 3 -M +或-R'SO 3 -M +组成的离子基团，其中M +是阳离子，R'是1至约6个碳原子的直链或支链烷基; x的范围为0至约20; y范围为3至约100。

3. 发明授权

US4452708A Oil recovery method using sulfonate surfactants derived from extracted aromatic feedstocks 失效
标题翻译：使用从提取的芳香原料衍生的磺酸盐表面活性剂的油回收方法
公开(公告)号：US4452708A
公开(公告)日：1984-06-05
申请号：US349952
申请日：1982-02-18
申请人： Haven S. Aldrich , Thomas L. Ashcraft, Jr. , Maura C. Puerto , Ronald L. Reed
发明人： Haven S. Aldrich , Thomas L. Ashcraft, Jr. , Maura C. Puerto , Ronald L. Reed
IPC分类号： C09K8/584 , E21B43/22
CPC分类号： C09K8/584 , Y10S507/938
摘要： An oil recovery method is disclosed which uses a particular class of alkylaryl sulfonate surfactants. The surfactants are derived from an extracted aromatic feedstock consisting essentially of benzene, toluene, xylenes, and lesser amounts of ethylbenzene, trimethylbenzenes, and tetramethylbenzenes. The aromatic feedstock is then alkylated with linear .alpha.-olefins to favor second-carbon attachment, and sulfonated to result in surfactants having high oil solubilization parameters and whose phase behavior is substantially independent of temperature over 120.degree.-250.degree. Fahrenheit.
摘要翻译：公开了使用特定类型的烷基芳基磺酸盐表面活性剂的油回收方法。表面活性剂衍生自基本上由苯，甲苯，二甲苯和较少量的乙苯，三甲基苯和四甲基苯组成的提取的芳族原料。然后将芳族原料用直链α-烯烃烷基化以有利于第二碳连接，并磺化以产生具有高油溶性参数的表面活性剂，其相位行为基本上与120-250华氏度的温度无关。

4. 发明授权

US4240504A Simultaneous microemulsion-aqueous phase flooding process 失效
标题翻译：同时微乳液 - 水相淹没过程
公开(公告)号：US4240504A
公开(公告)日：1980-12-23
申请号：US972118
申请日：1978-12-21
申请人： Ronald L. Reed
发明人： Ronald L. Reed
IPC分类号： C09K8/58 , C09K8/90 , E21B43/20 , E21B43/22
CPC分类号： C09K8/905 , C09K8/58 , E21B43/20
摘要： A method of enhanced oil recovery is disclosed wherein an upper-phase or a middle-phase microemulsion and an immiscible aqueous phase are simultaneously injected into a subterranean formation. The viscosities of the injected phases are adjusted so that the aqueous phase/microemulsion viscosity ratio approximates the reservoir brine/oil viscosity ratio. The injection rates of the injected phases are such that similar oil, microemulsion and aqueous phase velocities are achieved in the reservoir. Oil is displaced to a production well and recovered.
摘要翻译：公开了一种提高油回收率的方法，其中将上相或中相微乳液和不混溶的水相同时注入地下地层。调节注入相的粘度，使得水相/微乳液粘度比接近储层盐水/油粘度比。注入相的注射速率使得在储层中实现相似的油，微乳液和水相速度。石油被转移到生产井并恢复。

5. 发明授权

US4337159A Shear-stabilized emulsion flooding process 失效
标题翻译：剪切稳定的乳液浸渍工艺
公开(公告)号：US4337159A
公开(公告)日：1982-06-29
申请号：US161195
申请日：1980-06-19
申请人： Ronald L. Reed , Clarence W. Carpenter, Jr.
发明人： Ronald L. Reed , Clarence W. Carpenter, Jr.
IPC分类号： E21B43/22 , C09K8/584
CPC分类号： C09K8/584 , Y10S507/938
摘要： Additional amounts of crude oil are recovered from a subterranean formation by flooding with a translucent emulsion comprising an upper- or middle-phase microemulsion as an external phase and a polymer-containing brine solution as an internal phase. The translucent emulsion tends to coalesce into its component phases under conditions of no shear, but is stabilized by low shears such as those imposed on fluids flowing through a subterranean formation.
摘要翻译：通过用包含上相或中间相微乳作为外相的半透明乳液和含内含盐的聚合物溶液浸渍从地层中回收额外量的原油。半透明乳液趋向于在没有剪切的条件下聚结成其组分相，但是通过低剪切剂稳定，例如施加在流经地层的流体上的剪切。

6. 发明授权

US4293428A Propoxylated ethoxylated surfactants and method of recovering oil therewith 失效
标题翻译：丙氧基化乙氧基化表面活性剂及其回收方法
公开(公告)号：US4293428A
公开(公告)日：1981-10-06
申请号：US870313
申请日：1978-01-18
申请人： Walter W. Gale , Maura C. Puerto , Thomas L. Ashcraft , Rhoderick K. Saunders , Ronald L. Reed
发明人： Walter W. Gale , Maura C. Puerto , Thomas L. Ashcraft , Rhoderick K. Saunders , Ronald L. Reed
IPC分类号： C09K8/584 , C09K3/00
CPC分类号： C09K8/584 , Y10S516/02 , Y10S516/03 , Y10S516/04
摘要： A method for recovering oil from a subterranean formation is disclosed wherein a novel solution is injected into and driven through the formation. The solution contains an effective amount of surface-active agent having the general formulaR.sub.1 O(C.sub.3 H.sub.6 O,.sub.m (C.sub.2 H.sub.4 O).sub.n YXwhereinR.sub.1 is a linear or branched alkyl radical, an alkenyl radical, or an alkyl or alkenyl substituted benzene radical, the non-aromatic portion of the radical containing from about 6 to about 24 carbon atoms;m has an average value of between about 1 and about 10;n has an average value of between about 1 and about 10;Y is a hydrophilic group; andX is a cation, preferably monovalent.
摘要翻译：公开了一种从地层中回收油的方法，其中将新的溶液注入和驱动通过地层。该溶液含有有效量的具有通式R 1 O（C 3 H 6 O，m（C 2 H 4 O）n Y X）的表面活性剂，其中R 1是直链或支链烷基，烯基或烷基或烯基取代的苯基，含有约6至约24个碳原子的基团的芳族部分; m具有约1至约10的平均值; n具有约1至约10的平均值; Y是亲水基团; X是阳离子，优选一价。

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