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    • 1. 发明申请
    • PROCESS FOR THE PREPARATION OF A DIARYL CARBONATE
    • 制备二氧化碳的方法
    • US20090131706A1
    • 2009-05-21
    • US12194422
    • 2008-08-19
    • Garo Garbis VAPORCIYAN
    • Garo Garbis VAPORCIYAN
    • C07C68/06
    • C07C68/06C07C67/02C07C67/055C07C69/14C07C69/017C07C69/96C07C69/157
    • The invention relates to a process for the preparation of a diaryl carbonate, which comprises: (i) contacting an aromatic non-hydroxy compound with a carboxylic acid of formula HOC(═O)R1 (I), wherein R1 is a hydrocarbyl group, and with an oxygen containing gas in the presence of a catalyst, resulting in water and an aromatic carboxylic acid ester of formula R2OC(═O)R1 (II), wherein R2 is an aryl group originating from the aromatic non-hydroxy compound; and (ii) contacting the aromatic carboxylic acid ester of formula (II) from step (i) with a dialkyl carbonate of formula R3OC(═O)OR4 (III), wherein R3 and R4 are the same or different and are alkyl groups, in the presence of a catalyst, resulting in a diaryl carbonate of formula R2OC(═O)OR2 (IV) and an alkyl carboxylic acid ester of formula R5OC(═O)R1 (V), wherein R5 is R3 or R4.
    • 本发明涉及一种制备碳酸二芳基酯的方法,其包括:(i)使芳族非羟基化合物与式HOC(-O)R 1(I)的羧酸接触,其中R1是烃基, 并在催化剂存在下与含氧气体反应,得到水和式R 2 OC(-O)R 1(II)的芳族羧酸酯,其中R 2是源自芳族非羟基化合物的芳基; 和(ii)使来自步骤(i)的式(II)的芳族羧酸酯与式R 3 OC(-O)OR 4(III)的碳酸二烷基酯接触,其中R 3和R 4相同或不同,并且是烷基, 在存在催化剂的情况下,得到式R 2 OC(-O)OR 2(IV)的碳酸二芳基酯和式R 5 OC(-O)R 1(V)的烷基羧酸酯,其中R 5是R 3或R 4。