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    • 2. 发明授权
    • Process for the production of coated substrates
    • 生产涂层基材的方法
    • US07399397B2
    • 2008-07-15
    • US10842312
    • 2004-05-10
    • Gabriele BuettnerHeinz-Peter KatzmannKlausjoerg Klein
    • Gabriele BuettnerHeinz-Peter KatzmannKlausjoerg Klein
    • C25D13/12
    • C25D13/20B05D1/007B05D5/12B05D7/14B05D7/546B05D2252/02B05D2252/10
    • A process for the production of coated substrates comprising the successive steps of: a) applying a coating composition A′ onto one side A″ of a metal sheet to form a coating layer A which is electrically insulating when cured and applying a coating composition B′ onto the opposite side of the metal sheet to form coating layer B which is electrically conductive when cured, wherein each of the coating compositions A′ and B′ are applied by coil coating, b) curing the two coating layers A and B, c) removing and shaping sheet metal parts provided with the cured coating layer A on one side A″ and with the cured coating layer B on the other side B″, d) optionally, assembling the coated shaped sheet metal parts to form a construction with outwardly directed sides A″ and e) electrodepositing an electrodeposition (ED) coating layer onto the electrically conductive surfaces and curing of the ED coating layer.
    • 一种用于生产涂覆基材的方法,包括以下连续步骤:a)将涂料组合物A'涂覆在金属板的一侧A“上以形成涂层A,其在固化时电绝缘并涂覆涂料组合物B 在金属片的相对侧上形成固化时导电的涂层B,其中涂覆组合物A'和B'各自通过卷材涂布施加,b)固化两个涂层A和B,c )在一侧A“上除去和成型设置有固化涂层A的金属片,并且在另一侧B”上固化涂层B,d)任选地,组装涂覆的成形金属片以形成结构 具有向外指向的侧面A“和e)将电沉积(ED)涂层电沉积到导电表面上并固化ED涂层。
    • 5. 发明授权
    • Process for producing coatings on electrically conductive substrates by cathodic electrodeposition coating
    • 通过阴极电沉积涂层在导电基材上生产涂层的方法
    • US07632386B2
    • 2009-12-15
    • US10650410
    • 2003-08-28
    • Klausjoerg KleinGabriele Buettner
    • Klausjoerg KleinGabriele Buettner
    • C25D13/13
    • C09D5/4496C25D13/22
    • A process for producing a CED coating by cathodic electrodeposition of a coating on an electrically conductive substrate in a CED coating bath and thermal cross-linking of the CED coating film obtained, wherein before thermal cross-linking outside of the CED coating bath, the CED coating film is brought into contact with an aqueous preparation of at least one metal compound, wherein the at least one metal compound is a compound of a metal with an oxidation number of +2 or higher and is selected from the group consisting of compounds containing cations of the metal, compounds forming cations of the metal in aqueous medium, compounds containing cations containing the metal, compounds forming cations containing the metal in aqueous medium, compounds comprising outwardly neutral complexes of the metal, colloidal oxide of the metal and colloidal hydroxide of the metal, wherein the metal itself is selected from the group consisting of metals having atomic numbers of 20 to 83 with the express exclusion of chromium, arsenic, cadmium, antimony, mercury, thallium and lead.
    • 在CED涂层浴中通过阴极电沉积导电基底上的涂层和所获得的CED涂膜的热交联来生产CED涂层的方法,其中在CED涂层浴外的热交联之前,CED 与至少一种金属化合物的水性制剂接触,其中所述至少一种金属化合物是氧化值为+2以上的金属的化合物,并且选自含有阳离子的化合物 的金属,在水性介质中形成金属阳离子的化合物,含有金属的阳离子的化合物,在水性介质中形成含金属的阳离子的化合物,金属的向外中性络合物,金属的胶体氧化物和 金属,其中金属本身选自具有原子序数为20至83的金属与快速 排除铬,砷,镉,锑,汞,铊和铅。
    • 6. 发明申请
    • Process for producing coatings on electrically conductive substrates by cathodic electrodeposition coating
    • 通过阴极电沉积涂层在导电基材上生产涂层的方法
    • US20050045490A1
    • 2005-03-03
    • US10650410
    • 2003-08-28
    • Klausjoerg KleinGabriele Buettner
    • Klausjoerg KleinGabriele Buettner
    • C09D5/44C25D13/22C25B1/00
    • C09D5/4496C25D13/22
    • A process for producing a CED coating by cathodic electrodeposition of a coating on an electrically conductive substrate in a CED coating bath and thermal cross-linking of the CED coating film obtained, wherein before thermal cross-linking outside of the CED coating bath, the CED coating film is brought into contact with an aqueous preparation of at least one metal compound, wherein the at least one metal compound is a compound of a metal with an oxidation number of +2 or higher and is selected from the group consisting of compounds containing cations of the metal, compounds forming cations of the metal in aqueous medium, compounds containing cations containing the metal, compounds forming cations containing the metal in aqueous medium, compounds comprising outwardly neutral complexes of the metal, colloidal oxide of the metal and colloidal hydroxide of the metal, wherein the metal itself is selected from the group consisting of metals having atomic numbers of 20 to 83 with the express exclusion of chromium, arsenic, cadmium, antimony, mercury, thallium and lead.
    • 在CED涂层浴中通过阴极电沉积导电基底上的涂层和所获得的CED涂膜的热交联来生产CED涂层的方法,其中在CED涂层浴外的热交联之前,CED 与至少一种金属化合物的水性制剂接触,其中所述至少一种金属化合物是氧化值为+2以上的金属的化合物,并且选自含有阳离子的化合物 的金属,在水性介质中形成金属阳离子的化合物,含有金属的阳离子的化合物,在水性介质中形成含金属的阳离子的化合物,金属的向外中性络合物,金属的胶体氧化物和 金属,其中金属本身选自具有原子序数为20至83的金属与快速 排除铬,砷,镉,锑,汞,铊和铅。
    • 7. 发明授权
    • Process for electrocoating bulk articles
    • 电涂大批量物品的工艺
    • US06436260B1
    • 2002-08-20
    • US09715425
    • 2000-11-17
    • Klaus-Peter LorenzGabriele BuettnerKlausjoerg Klein
    • Klaus-Peter LorenzGabriele BuettnerKlausjoerg Klein
    • C25D1300
    • C09D5/44C09D5/448
    • This invention is directed to a process for electrocoating bulk articles to provide a corrosion protective coating and comprises the following steps: (1) the bulk articles to be coated are placed in an electrically conductive receiving container and the container and bulk articles are electrocoated with an aqueous electrocoating composition containing a film forming binder and electrically conductive components; (2) baking the coated bulk articles and the receiving container to form an electrically conductive coating on the bulk articles and the container and removing the coated bulk articles from the container; and (3) repeating steps (1) and (2) at least once without any intermediate cleaning of the receiving container having an electrically conductive coating. The advantage of the novel process of this invention is that the receiving container can be used at least twice and up to six times without any intermediate cleaning or removal of the applied electrocoating layer.
    • 本发明涉及一种电涂大批量制品以提供腐蚀保护涂层的方法,包括以下步骤:(1)待涂覆的散装物品放置在导电接收容器中,容器和散装物品用电镀 包含成膜粘合剂和导电组分的水性电涂组合物;(2)烘烤涂覆的散装物品和接收容器以在散装物品和容器上形成导电涂层并从容器中除去涂覆的散装物品; 并且(3)至少一次重复步骤(1)和(2),而没有对具有导电涂层的接收容器进行任何中间清洁。本发明的新方法的优点在于接收容器可以使用至少两次 并且最多六次,而不需要中间清洁或去除所施加的电涂层。
    • 9. 发明授权
    • Process for producing coatings on electrically conductive substrates by cathodic electrodeposition coating
    • 通过阴极电沉积涂层在导电基材上生产涂层的方法
    • US07211182B2
    • 2007-05-01
    • US10668956
    • 2003-09-23
    • Horst LehmannKlausjoerg KleinRudolf Schipfer
    • Horst LehmannKlausjoerg KleinRudolf Schipfer
    • C25D13/10C25D13/12
    • C09D5/4492C25D13/22
    • A process for the production of a CED (cathodic electrodeposition) coating with improved adhesion towards subsequent layers by cathodic electrodeposition of a coating layer of a CED coating composition onto an electrically conductive substrate and thermal curing by baking in an indirectly heated circulating air oven operated with a proportion of fresh air in the circulating air of the oven of 0 to 20 vol. %, wherein the CED coating composition used contains at least one water-soluble metal nitrate corresponding to a quantity of 1 to 10 mmol of nitrate per 100 g of resin solids content, wherein the metal is selected from the group consisting of metals of atomic numbers 20 to 83, with the exception of chromium, arsenic, rubidium, ruthenium, rhodium, palladium, cadmium, antimony, caesium, osmium, iridium, platinum, mercury, thallium and lead, and wherein at most 50 area-% of the CED-coated substrate surface are rinsed with water prior to thermal curing.
    • 一种用于生产CED(阴极电沉积)涂层的方法,其通过将CED涂层组合物的涂层阴极电沉积到导电基底上并且随后通过在间接加热的循环空气烘箱中进行热固化而对随后的层具有改进的粘附性, 一定比例的新鲜空气在烘箱的循环空气中为0〜20体积。 %,其中使用的CED涂料组合物含有至少一种对应于每100g树脂固体含量为1至10mmol硝酸盐的水溶性金属硝酸盐,其中金属选自原子序数金属 20至83,除了铬,砷,铷,钌,铑,钯,镉,锑,铯,锇,铱,铂,汞,铊和铅之外,其中至多50% 在热固化之前用水冲洗涂覆的基材表面。