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    • 5. 发明授权
    • Polyene/polythiol paint vehicle
    • 聚烯/多硫醇漆车
    • US3898349A
    • 1975-08-05
    • US48453574
    • 1974-07-01
    • GRACE W R & CO
    • KEHR CLIFTON LWSZOLEK WALTER R
    • C08G75/04C08J3/28C09D181/02B44D1/50
    • C08J3/28C08G75/045C08G75/12C08J2381/02C09D181/02
    • A paint vehicle is prepared from a composition comprising (1) about 98 to 2% by weight of a liquid polyene containing at least terminal 2 reactive unsaturated carbon to carbon bonds per molecule and (2) about 2 to 98% by weight of a polythiol containing at least two thiol groups per molecule, the total combined functionality of (a) the reactive unsaturated carbon to carbon bonds per molecule in the polyene and (b) the thiol groups per molecule in the polythiol being greater than 4, which composition is curable, preferably under ambient conditions, in the presence of a free radical generator such as electromagnetic radiation of wave-length of about 2000-7000 A or high energy ionizing radiation. In instances where the free radical generator is electro-magnetic radiation, a curing rate accelerator in an amount ranging from 0.0005 to 50% by weight of said composition is added to the polyene/polythiol composition. The resultant vehicle, in pigmented form, can be used per se as a solventless paint or can be used with an inert organic solvent or as a watersoluble or water-dispersible paint.
    • 涂料载体由包含(1)约98至2重量%的每分子至少含有末端2个反应性不饱和碳与碳键的液体多烯的组合物制备,和(2)约2至98重量%的多硫醇 每分子含有至少两个硫醇基团,(a)多烯中每分子的反应性不饱和碳与碳键的总组合官能度和(b)多硫醇中每分子的硫醇基团大于4,该组成是可固化的 ,优选在环境条件下,在自由基发生剂的存在下,例如约2000-7000A的波长的电磁辐射或高能电离辐射。 在自由基发生剂是电磁辐射的情况下,加入到所述组合物的0.0005至50重量%的固化速率促进剂到多烯/多硫醇组合物中。 所得到的载色剂可以本身作为无溶剂涂料使用,或者可以与惰性有机溶剂或水溶性或水分散性涂料一起使用。
    • 7. 发明授权
    • Encapsulating and potting composition and process
    • 包埋和成型组合物和工艺
    • US3653959A
    • 1972-04-04
    • US3653959D
    • 1970-04-14
    • GRACE W R & CO
    • KEHR CLIFTON LWSZOLEK WALTER R
    • C08G18/67C08G18/83C08G75/04C08L81/00B29C6/00
    • C08G75/045C08G18/6715C08G18/835C08G75/12C08L81/00Y10T428/31533
    • This invention relates to encapsulating by, molding, embedding, casting, impregnating, potting and encasing various components, e.g., decorative, electric, electronic and microelectronic components using a composition which is preferably transparent comprising (1) a liquid polyene containing at least two reactive unsaturated carbon to carbon bonds per molecule and (2) a polythiol containing at least two thiol groups per molecule, the total combined functionality of (a) the reactive unsaturated carbon to carbon bonds per molecule in the polyene and (b) the thiol groups per molecule in the polythiol being greater than four, which composition, with the aforesaid components therein, can be cured under ambient conditions in the presence of a free radical generator to a solid, elastomeric or resinous product.
    • 本发明涉及通过使用优选透明的组合物来包封,模塑,包埋,铸造,浸渍,灌封和包装各种组分,例如装饰性,电学,电子和微电子组件,包括(1)含有至少两个反应性的液体多烯 每分子具有不饱和碳 - 碳键,和(2)每分子含有至少两个硫醇基的多硫醇,(a)多烯中每分子的反应性不饱和碳与碳键的总合并官能度,(b)每个硫醇基团 多硫醇中的分子大于四个,其中上述组分可以在环境条件下在自由基发生剂存在下固化成固体,弹性体或树脂产品。