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1. 发明授权

US09174903B2 Reactive scrubbing for upgrading product value, simplifying process operation and product handling 有权
标题翻译：反应洗涤提升产品价值，简化工艺操作和产品处理
公开(公告)号：US09174903B2
公开(公告)日：2015-11-03
申请号：US13841975
申请日：2013-03-15
申请人： Gas Technologies LLC
发明人： Krishna K. Rao , Evan Michael Visser , Ian Lawrence Gaffney , Walter Breidenstein
IPC分类号： C07C45/33 , C07C45/35 , C07C29/86 , C07C29/80
CPC分类号： B01J19/245 , B01J12/00 , B01J2219/24 , C07C29/80 , C07C29/86 , C07C45/33 , C07C45/35 , C07C31/04 , C07C31/08 , C07C31/02
摘要： A method for removing formaldehyde from a blend of partially oxygenated hydrocarbons is provided. The method including a step of reacting a hydrocarbon-containing gas with an oxygen-containing gas in a reaction vessel to form first product blend. The first product blend includes a blend of partially oxygenated compounds that include formaldehyde. The blend of partially oxygenated compounds is provided to a reactive scrubbing station where it is contacted with a reactive scrubbing liquid to form a reactive liquid-formaldehyde compound. The reactive liquid-formaldehyde compound is then removed from the first blend of partially reactive compounds.
摘要翻译：提供了从部分含氧烃混合物中除去甲醛的方法。该方法包括使含烃气体与含氧气体在反应容器中反应以形成第一产物共混物的步骤。第一产品共混物包括部分含氧化合物（包括甲醛）的混合物。将部分含氧化合物的混合物提供给反应性洗涤站，其中其与反应性洗涤液体接触以形成反应性液体 - 甲醛化合物。然后从部分反应性化合物的第一共混物中除去反应性液体 - 甲醛化合物。

2. 发明申请

US20140275634A1 Ether Blends Via Reactive Distillation 审中-公开
标题翻译：醚通过反应蒸馏混合
公开(公告)号：US20140275634A1
公开(公告)日：2014-09-18
申请号：US13843471
申请日：2013-03-15
申请人： GAS TECHNOLOGIES LLC
发明人： Krishna K. Rao , Evan Michael Visser , Ian Lawrence Gaffney , Walter Breidenstein
IPC分类号： C07C41/01
CPC分类号： C07C41/42 , B01D3/009 , B01J8/02 , B01J12/00 , B01J2208/00805 , C07C29/50 , C07C31/04 , C07C31/08 , C07C41/09 , C07C43/04 , C07C43/043 , C07C43/06 , Y02P20/127
摘要： A method for forming a blend of ethers from a blend of alcohols includes a step of reacting a hydrocarbon-containing gas with an oxygen-containing gas to form first product blend. The first product blend includes a blend of partially oxygenated compounds. The blend of partially oxygenated compounds is provided to a reactive distillation station where it is converted a second product blend. The second product blend typically includes a mixture of ethers. An apparatus implementing the method is also provided.
摘要翻译：从醇的共混物形成醚共混物的方法包括使含烃气体与含氧气体反应以形成第一产物共混物的步骤。第一产品共混物包括部分含氧化合物的混合物。将部分氧化的化合物的混合物提供给反应性蒸馏站，其中转化第二产物共混物。第二产物混合物通常包括醚的混合物。还提供了实现该方法的装置。

3. 发明授权

US10995685B2 Tri-fuel electric power generator 有权
公开(公告)号：US10995685B2
公开(公告)日：2021-05-04
申请号：US16414322
申请日：2019-05-16
申请人： GAS TECHNOLOGIES LLC , FUEL INJECTION TECHNOLOGIES CO., LTD.
发明人： Walter Breidenstein , Harold Sun , Yi Wang , Zengyu Shan
IPC分类号： F02B13/00 , F02D41/00 , F02B63/04
摘要： An electricity generator includes a generator section which is a complete standalone electricity generator designed to operate on a hydrocarbon fuel and a fuel conversion section which adapts the generator section to operate on alternative fuels that are different than the designed fuel of generator section. The generator section includes a RPM control unit, an internal combustion engine which has a crankshaft, an electromagnetic conversion component which converts the rotational motion of the crankshaft into electricity and a crankshaft sensor which senses the rotational speed of the crankshaft thereby creating a RPM control signal. The control signal is provided to the RPM control unit which controls the rotational speed of the crankshaft. The fuel conversion section includes a first fuel source and a second fuel source. Characteristically, the first fuel source provides a methanol-containing fuel and the second fuel source provides LPG or flare gas.

4. 发明申请

US20160045890A1 Reactive Scrubbing for Upgrading Product Value, Simplifying Process Operation and Product Handling 审中-公开
标题翻译：升级产品价值的反应洗涤，简化过程操作和产品处理
公开(公告)号：US20160045890A1
公开(公告)日：2016-02-18
申请号：US14922623
申请日：2015-10-26
申请人： Gas Technologies LLC
发明人： Krishna K. Rao , Evan Michael Visser , Ian Lawrence Gaffney , Walter Breidenstein
IPC分类号： B01J19/24 , B01J12/00
CPC分类号： B01J19/245 , B01J12/00 , B01J2219/24 , C07C29/80 , C07C29/86 , C07C45/33 , C07C45/35 , C07C31/04 , C07C31/08 , C07C31/02
摘要： A method for removing formaldehyde from a blend of partially oxygenated hydrocarbons is provided. The method including a step of reacting a hydrocarbon-containing gas with an oxygen-containing gas in a reaction vessel to form first product blend. The first product blend includes a blend of partially oxygenated compounds that include formaldehyde. The blend of partially oxygenated compounds is provided to a reactive scrubbing station where it is contacted with a reactive scrubbing liquid to form a reactive liquid-formaldehyde compound. The reactive liquid-formaldehyde compound is then removed from the first blend of partially reactive compounds.
摘要翻译：提供了从部分含氧烃混合物中除去甲醛的方法。该方法包括使含烃气体与含氧气体在反应容器中反应以形成第一产物共混物的步骤。第一产品共混物包括部分含氧化合物（包括甲醛）的混合物。将部分含氧化合物的混合物提供给反应性洗涤站，其中其与反应性洗涤液体接触以形成反应性液体 - 甲醛化合物。然后从部分反应性化合物的第一共混物中除去反应性液体 - 甲醛化合物。

5. 发明授权

US09255051B2 Efficiency, flexibility, and product value of a direct alkanes to oxygenates process 有权
标题翻译：直接烷烃对含氧化合物工艺的效率，灵活性和产品价值
公开(公告)号：US09255051B2
公开(公告)日：2016-02-09
申请号：US13844217
申请日：2013-03-15
申请人： Gas Technologies LLC
发明人： Ian Lawrence Gaffney , Evan Michael Visser , Walter Breidenstein
IPC分类号： C07C29/50 , C07C27/00 , C07C41/09 , C01B3/26
CPC分类号： C07C29/50 , C01B3/26 , C01B2203/0277 , C07C41/09 , Y02P20/127 , C07C31/04 , C07C31/08 , C07C43/043 , C07C43/06 , C07C43/04
摘要： A method for preparing oxygenated hydrocarbons includes steps of: reacting a first heated hydrocarbon-containing gas stream with an oxygen-containing gas stream in a reactor for form a first product blend, recovering the energy generated in the reactor in order to preheat incoming hydrocarbon feed to the reactor and/or to drive endothermic reactions that generate synthesis gas, separating and condensing one or more liquid oxygenated hydrocarbons from the product stream, separating a reject stream from a recycle stream, mixing remaining gaseous hydrocarbon product from the recycle stream with the first hydrocarbon-containing gas stream after one reaction cycle, converting the first reject stream to a synthesis gas mixture, and converting the synthesis gas mixture to light alkanes to be blended with one or with oxygenates in an output stream to optionally form higher molecular weight oxygenates.
摘要翻译：一种制备含氧烃的方法包括以下步骤：使第一加热含烃气流与含氧气流在反应器中反应形成第一产物共混物，回收在反应器中产生的能量，以预热进入的烃进料向反应器和/或驱动产生合成气的吸热反应，从产物流中分离和冷凝一种或多种液态含氧烃，从再循环流中分离出废品流，将来自再循环料流的剩余气态烃产物与第一在一个反应循环之后的含烃气流，将第一废料流转化为合成气混合物，并将合成气混合物转化成轻质烷烃，以与输出物流中的一种或多种含氧化合物共混，以任选地形成较高分子量的含氧化合物。

6. 发明申请

US20140275643A1 Reactive Scrubbing for Upgrading Product Value, Simplifying Process Operation and Product Handling 有权
标题翻译：升级产品价值的反应洗涤，简化过程操作和产品处理
公开(公告)号：US20140275643A1
公开(公告)日：2014-09-18
申请号：US13841975
申请日：2013-03-15
申请人： GAS TECHNOLOGIES LLC
发明人： Krishna K. Rao , Evan Michael Visser , Ian Lawrence Gaffney , Walter Breidenstein
IPC分类号： C07C29/88 , C07C29/48
CPC分类号： B01J19/245 , B01J12/00 , B01J2219/24 , C07C29/80 , C07C29/86 , C07C45/33 , C07C45/35 , C07C31/04 , C07C31/08 , C07C31/02
摘要： A method for removing formaldehyde from a blend of partially oxygenated hydrocarbons is provided. The method including a step of reacting a hydrocarbon-containing gas with an oxygen-containing gas in a reaction vessel to form first product blend. The first product blend includes a blend of partially oxygenated compounds that include formaldehyde. The blend of partially oxygenated compounds is provided to a reactive scrubbing station where it is contacted with a reactive scrubbing liquid to form a reactive liquid-formaldehyde compound. The reactive liquid-formaldehyde compound is then removed from the first blend of partially reactive compounds.
摘要翻译：提供了从部分含氧烃混合物中除去甲醛的方法。该方法包括使含烃气体与含氧气体在反应容器中反应以形成第一产物共混物的步骤。第一产品共混物包括部分含氧化合物（包括甲醛）的混合物。将部分含氧化合物的混合物提供给反应性洗涤站，其中其与反应性洗涤液体接触以形成反应性液体 - 甲醛化合物。然后从部分反应性化合物的第一共混物中除去反应性液体 - 甲醛化合物。

7. 发明授权

US10227538B2 Facilitated oxygenate separations and synthetic fuel production via reactive distillation 有权
公开(公告)号：US10227538B2
公开(公告)日：2019-03-12
申请号：US15126432
申请日：2015-03-16
申请人： GAS TECHNOLOGIES LLC
发明人： Ian Lawrence Gaffney , Walter Breidenstein , Evan Michael Visser
IPC分类号： C10L1/02 , C07C51/00 , C07C29/00 , C07C67/00 , C07C45/28 , C07C41/50
摘要： A method includes a step of reacting a hydrocarbon-containing gas with an oxygen-containing gas to form a first product blend in a reactor. The first product blend includes a blend of partially oxygenated compounds. The blend of partially oxygenated compounds is provided to one or more reactive distillation stations; and The blend of partially oxygenated compounds is converted to a second product blend at one or more reactive distillation stations. Characteristically, the second product blend includes a mixture comprising a at least two of components selected from acetals, ethers, alcohols, esters, and alkenes.

8. 发明申请

US20190071378A1 UPGRADING OF A RAW BLEND INTO A DIESEL FUEL SUBSTITUTE: POLY(DIMETHOXYMETHANE) 审中-公开
公开(公告)号：US20190071378A1
公开(公告)日：2019-03-07
申请号：US15693991
申请日：2017-09-01
申请人： GAS TECHNOLOGIES LLC
发明人： Evan Visser , Walter Breidenstein
IPC分类号： C07C41/56 , C10L1/02 , C07C41/58 , B01D3/00 , B01D3/14
摘要： A method for forming poly(dimethoxymethane) includes a step of separating a formaldehyde-containing blend into a first bottom stream and a first top stream. The first formaldehyde-containing blend includes methanol, formaldehyde, and water while the first bottom stream includes water. The first top stream includes dimethoxymethane that is produced from the reaction between methanol and formaldehyde. The first top stream is separated into a second bottom stream and a second top stream. The second bottom stream includes poly(dimethoxymethane) while the second top stream includes dimethoxymethane, methanol, and ethanol. The second top stream is separated into a third bottom stream and a third top stream. Third bottom stream includes methanol and ethanol while the third top stream includes dimethoxymethane. The third top steam can be recycled to form additional poly(dimethoxymethane). A system that implements the method is also provided.

9. 发明授权

US10099199B2 Reactive scrubbing for upgrading product value, simplifying process operation and product handling 有权
公开(公告)号：US10099199B2
公开(公告)日：2018-10-16
申请号：US14922623
申请日：2015-10-26
申请人： Gas Technologies LLC
发明人： Krishna K. Rao , Evan Michael Visser , Ian Lawrence Gaffney , Walter Breidenstein
IPC分类号： B01J19/24 , C07C29/80 , C07C29/86 , B01J12/00 , C07C45/35 , C07C45/33
摘要： An apparatus for removing formaldehyde from a blend of partially oxygenated hydrocarbons includes a reactor for reacting a hydrocarbon-containing gas with an oxygen-containing gas in a reactor vessel to form first product blend. The first product blend includes a blend of partially oxygenated compounds that include formaldehyde. The apparatus also includes a reactive scrubbing station in fluid communication with the reactor where the blend of partially oxygenated compounds that include formaldehyde is contacted with a reactive scrubbing liquid at the reactive scrubbing station to form a reactive liquid-formaldehyde compound.

10. 发明授权

US11103849B2 Upgrading of a raw blend into a diesel fuel substitute: poly(dimethoxymethane) 有权
公开(公告)号：US11103849B2
公开(公告)日：2021-08-31
申请号：US16434318
申请日：2019-06-07
申请人： GAS TECHNOLOGIES LLC
发明人： Evan Visser , Walter Breidenstein
IPC分类号： C07C41/56 , C07C41/58 , B01J19/24 , C10G5/06 , B01D3/00 , B01D3/14 , C10L1/02
摘要： A method for forming poly(dimethoxymethane) includes a step of separating a formaldehyde-containing blend into a first bottom stream and a first top stream. The first formaldehyde-containing blend includes methanol, formaldehyde, and water while the first bottom stream includes water. The first top stream includes dimethoxymethane that is produced from the reaction between methanol and formaldehyde. The first top stream is separated into a second bottom stream and a second top stream. The second bottom stream includes poly(dimethoxymethane) while the second top stream includes dimethoxymethane, methanol, and ethanol. The second top stream is separated into a third bottom stream and a third top stream. Third bottom stream includes methanol and ethanol while the third top stream includes dimethoxymethane. The third top steam can be recycled to form additional poly(dimethoxymethane). A system that implements the method is also provided.

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