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1. 发明授权

US5274010A Process for warp-free pigmenting of polyolefins 失效
标题翻译：聚烯烃无翘曲着色的方法
公开(公告)号：US5274010A
公开(公告)日：1993-12-28
申请号：US726055
申请日：1991-07-05
申请人： Philippe Bugnon , Fritz Herren
发明人： Philippe Bugnon , Fritz Herren
IPC分类号： C08J3/20 , C08K9/08 , C08K9/10 , C08L23/02 , C09B67/08 , C08L29/04 , C09B48/00
CPC分类号： C09B67/0013 , C08K9/08 , C08K9/10 , Y10T428/2998
摘要： A process for warp-free pigmenting of polyolefins comprising(A)(i) adsorbing a polyvinyl alcohol film onto the surface of an organic pigment particle,(ii) coating the surface of the polyvinyl alcohol coated organic pigment particle with one or more films of linear or branched homopolymers or copolymers selected from the group consisting of acrylic polymers based on acrylic acid, methacrylic acid, alkyl esters of acrylic or methacrylic acid and mixtures thereof, and(iii) admixing said pigment particles with a polyolefin; or(B)(i) adsorbing a film of hydrolysed zirconium acetylacetonate onto the surface of an organic ##STR1## in which R is methyl or ethyl and m is a number from 1 to 6, onto the surface of the hydrolysed zirconium acetylacetonate coated organic pigment particle, (ii) coating the surface of organic pigment particle coated in accordance with step (B)(i) with one or more films of linear or branched homopolymers or copolymers selected from the group consisting of acrylic polymers based on acrylic acid, methacrylic acid, alkyl esters of acrylic or methacrylic acid and mixtures thereof, and(iii) admixing said pigment particles with a polyolefin; or(C)(i) coating the surface of an organic pigment particle with one or more films or linear or branched homopolymers or copolymers of polyvinyl alcohols, and(ii) admixing said pigment particles with a polyolefin;said organic pigment particle being selected from the group consisting of azo, diketopyrrolopyrrole, perylene, quinacridone, phthalocyanine, perinone, quinophthalone, isoindolinone, isoindoline, benzimidazolone, dioxazine, anthraquinone, thioindigo, methine, azomethine and metal complex pigments.
摘要翻译：包括（A）（i）将聚乙烯醇膜吸附到有机颜料颗粒的表面上的方法，（ⅱ）将聚乙烯醇涂覆的有机颜料颗粒的表面用一种或多种选自基于丙烯酸，甲基丙烯酸，丙烯酸或甲基丙烯酸的烷基酯及其混合物的丙烯酸聚合物的线性或支化均聚物或共聚物，和（iii）将所述颜料颗粒与聚烯烃混合; 或（B）（i）将水解的乙酰丙酮酸锆的膜吸附到有机“IMAGE”的表面上，其中R是甲基或乙基，m是1至6的数，在水解的乙酰丙酮酸锆包被的有机颜料颗粒，（ii）将根据步骤（B）（i）涂布的有机颜料颗粒的表面用一种或多种线性或支化均聚物或共聚物涂布，所述共聚物或共聚物选自基于丙烯酸的丙烯酸聚合物，甲基丙烯酸酸，丙烯酸或甲基丙烯酸的烷基酯及其混合物，和（iii）将所述颜料颗粒与聚烯烃混合; 或（C）（i）用一种或多种膜或聚乙烯醇的直链或支链均聚物或共聚物涂覆有机颜料颗粒的表面，和（ii）将所述颜料颗粒与聚烯烃混合; 所述有机颜料颗粒选自偶氮，二酮吡咯并吡咯，苝，喹吖啶酮，酞菁，紫环酮，喹酞酮，异吲哚啉酮，异二氢吲哚，苯并咪唑酮，二恶嗪，蒽醌，硫靛，次甲基，偶氮甲碱和金属络合物颜料。

2. 发明授权

US5646299A Two new crystal modifications of a diketopyrrolopyrrole pigment 失效
标题翻译：二酮吡咯并吡咯颜料的两种新的晶体改性
公开(公告)号：US5646299A
公开(公告)日：1997-07-08
申请号：US493776
申请日：1995-06-22
申请人： Zhimin Hao , Abul Iqbal , Fritz Herren
发明人： Zhimin Hao , Abul Iqbal , Fritz Herren
IPC分类号： C07D487/04 , C08K5/34 , C08K5/3415 , C08L101/00 , C09B57/00 , C09B67/10 , C09B67/48 , C09D7/12 , C09K11/06 , G03G9/09 , G03G9/097 , C07D487/06
CPC分类号： C07D487/04 , C08K5/3415 , C09B57/004 , C09B68/443 , C09K11/06 , G03G9/0906 , G03G9/0922 , G03G9/09758
摘要： Diketopyrrolopyrrole of the formula ##STR1## in its .beta.-modification and in its .gamma.-modification. Both the .beta.-modification and the .gamma.-modification are suitable as pigments for coloring high-molecular weight organic material. In comparison to the .alpha.-modification, the .beta.-modification shows a shift in shade towards yellowish-red. The .gamma.-modification gives brilliant orange colorations.
摘要翻译：式（Ⅰ）的二酮吡咯并吡咯在其β-改性及其γ改性中的作用。 β-改性和γ-改性均适用于着色高分子量有机材料的颜料。与α-修饰相比，β-修饰显示出阴影向黄红色的转变。伽马改性提供了辉煌的橙色着色。

3. 发明授权

US5591865A Crystal modification of a diketopyrrolopyrrole pigment 失效
标题翻译：二酮吡咯并吡咯颜料的水晶改性
公开(公告)号：US5591865A
公开(公告)日：1997-01-07
申请号：US493853
申请日：1995-06-22
申请人： Zhimin Hao , Abul Iqbal , Fritz Herren
发明人： Zhimin Hao , Abul Iqbal , Fritz Herren
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C09B57/00 , C09B67/10 , C09B67/48 , C09K11/06 , G03G9/09 , G03G9/097
CPC分类号： C07D487/04 , C08K5/3415 , C09B57/004 , C09B68/443 , C09K11/06 , G03G9/0906 , G03G9/0922 , G03G9/09758
摘要： Diketopyrrolopyrrole of the formula ##STR1## in its .beta.-modification. The new .beta.-modification is suitable as a pigment for coloring high-molecular weight organic material and shows, in comparison to the .alpha.-modification, a shift in shade towards yellowish-red.
摘要翻译：二酮吡咯并吡咯，其公式为：（I）的β-修饰。新的β-改性适合作为着色高分子量有机材料的颜料，并且与α-改性相比显示出阴影向黄红色的转变。

4. 发明授权

US4752460A Inorganic compounds based on bismuth vanadate 失效
标题翻译：基于钒酸铋的无机化合物
公开(公告)号：US4752460A
公开(公告)日：1988-06-21
申请号：US16045
申请日：1987-02-18
申请人： Fritz Herren
发明人： Fritz Herren
IPC分类号： C01G31/00 , C01G39/00 , C01G41/00 , C08K3/22 , C08K3/24 , C08L101/00 , C09C1/00 , D06P1/673 , D06P3/00
CPC分类号： C09C1/0006 , C01G31/006 , C01G39/006 , C01G41/006 , C08K3/24 , C01P2002/72 , C01P2006/60 , C01P2006/80
摘要： Process for mass coloring high molecular weight organic material, which comprises using a compound of the general formula (I)(Bi,A)(V,D)O.sub.4 (I)in a tetragonal, scheelitelike crystal structure, in which A is an alkaline earth metal, Zn or a mixture thereof, D is Mo, W or a mixture thereof, and the molar ratios A:Bi and D:V are between 0.1 and 0.4 and 0 and 0.4 respectively.Processes for preparing the compounds of the formula (I) are likewise described.
摘要翻译：用于大量着色高分子量有机材料的方法，其包括使用通式（I）（Bi，A）（V，D）O 4（I）的化合物为四方晶格状晶体结构，其中A为碱土壤金属，Zn或它们的混合物，D是Mo，W或它们的混合物，摩尔比A:Bi和D:V分别为0.1-0.4和0和0.4。同样地描述了制备式（I）化合物的方法。

5. 发明授权

US07740743B2 Fine particle size lime slurries and their production 失效
标题翻译：细粒度石灰浆及其生产
公开(公告)号：US07740743B2
公开(公告)日：2010-06-22
申请号：US11666871
申请日：2005-11-04
申请人： Michael Singh , Fritz Herren , Christina Northfleet , Robert Cockcroft , Kenneth Symes , Simon Donnelly , Andrew McCann , Valerie Reynolds
发明人： Michael Singh , Fritz Herren , Christina Northfleet , Robert Cockcroft , Kenneth Symes , Simon Donnelly , Andrew McCann , Valerie Reynolds
IPC分类号： D21H11/00 , D21H13/00 , D21H15/00 , D21H17/00 , D21H19/00 , D21H21/00 , D21H25/00 , D21H27/00 , C08F26/00 , C08F126/00 , C08F226/00
CPC分类号： C08F220/56 , D21H17/22 , D21H17/35 , D21H17/37 , D21H21/18 , D21H21/20
摘要： A polymer comprising i) a synthetic polymeric component that has been formed from an ethylenically unsaturated water-soluble or potentially water-soluble monomer and an ethylenically unsaturated monomer carrying a reactive group, wherein the reactive group is directly reactive with a cellulose binding domain protein; and ii) a protein component consisting of a cellulose binding domain protein, wherein the cellulose binding domain protein. The polymer is particularly suitable as a dry strength resin in a paper making process. It can also be used as a wet strength resin, internal sizing agent or surface sizing agent.
摘要翻译：一种聚合物，其包含i）由烯键式不饱和水溶性或潜在水溶性单体和携带反应性基团的烯属不饱和单体形成的合成聚合物组分，其中所述反应性基团与纤维素结合结构域蛋白直接反应; 和ii）由纤维素结合结构域蛋白组成的蛋白质组分，其中所述纤维素结合结构域蛋白。聚合物在造纸过程中特别适合作为干强度树脂。也可以用作湿强度树脂，内部施胶剂或表面施胶剂。

6. 发明申请

US20070265407A1 Fine Particle Size Lime Slurries and Their Production 失效
标题翻译：细粒度石灰浆及其生产
公开(公告)号：US20070265407A1
公开(公告)日：2007-11-15
申请号：US11666871
申请日：2005-11-04
申请人： Michael Singh , Fritz Herren , Christina Northfleet , Robert Cockcroft , Kenneth Symes , Simon Donnelly , Andrew McCann , Valerie Reynolds
发明人： Michael Singh , Fritz Herren , Christina Northfleet , Robert Cockcroft , Kenneth Symes , Simon Donnelly , Andrew McCann , Valerie Reynolds
IPC分类号： C08F2/00 , C08F16/36 , C08F26/00
CPC分类号： C08F220/56 , D21H17/22 , D21H17/35 , D21H17/37 , D21H21/18 , D21H21/20
摘要： A polymer comprising i) a synthetic polymeric component that has been formed from an ethylenically unsaturated water-soluble or potentially water-soluble monomer and an ethylenically unsaturated monomer carrying a reactive group, wherein the reactive group is directly reactive with a cellulose binding domain protein; and ii) a protein component consisting of a cellulose binding domain protein, wherein the cellulose binding domain protein. The polymer is particularly suitable as a dry strength resin in a paper making process. It can also be used as a wet strength resin, internal sizing agent or surface sizing agent.
摘要翻译：一种聚合物，其包含i）由烯键式不饱和水溶性或潜在水溶性单体和携带反应性基团的烯属不饱和单体形成的合成聚合物组分，其中所述反应性基团与纤维素结合结构域蛋白直接反应; 和ii）由纤维素结合结构域蛋白组成的蛋白质组分，其中所述纤维素结合结构域蛋白。聚合物在造纸过程中特别适合作为干强度树脂。也可以用作湿强度树脂，内部施胶剂或表面施胶剂。

7. 发明授权

US06706330B2 Process for coating a surface 失效
标题翻译：涂布表面的方法
公开(公告)号：US06706330B2
公开(公告)日：2004-03-16
申请号：US10150796
申请日：2002-05-17
申请人： Ryuichi Takahashi , Adrian Schulthess , Kimiya Takeshita , Fritz Herren , Patrice Bujard
发明人： Ryuichi Takahashi , Adrian Schulthess , Kimiya Takeshita , Fritz Herren , Patrice Bujard
IPC分类号： B05D310
CPC分类号： C09C1/0021 , C01P2004/20 , C01P2004/84 , C08F292/00 , C09B67/0004 , C09B67/0098 , C09C1/0015 , C09C2200/1004 , C09C2200/102 , C09C2200/1054 , C09C2200/1062 , C09C2200/1087 , C09C2200/406 , C09C2220/10 , Y10T428/2991 , Y10T428/2998
摘要： The invention relates to a process for coating a surface through graft polymerization, characterized in that before graft polymerization, the surface is modified, in the presence of an amine of formula: wherein R1 is hydrogen or a group R4, R2 and R3 are each independently a group R4, and R4 is [-1,2-C2-C3alkylen-T-]n-H wherein T is O or NH and n is a number from 1 to 3, by a compound having a functional group: wherein R5 to R7 are each C1-C4alkyl. The amount of amine is preferably from 5 to 500 g/m2 of surface of the substrate particle. The amount of the trialkoxysilane compound is preferably from 0.1 to 2 g/m2 of surface of the substrate particle. The process for coating a surface is particularly useful for effect pigments.
摘要翻译：本发明涉及通过接枝聚合涂覆表面的方法，其特征在于在接枝聚合之前，在下式胺的存在下改性表面：其中R 1是氢或基团R 4，R 2和R 3各自独立地是 R4和R4是具有官能团的化合物，其中T是O或NH，n是1至3的数[1,2-C2-C3烷基-T-] nH，其中R5至R7是每个C 1 -C 4烷基。胺的量优选为基材颗粒表面的5至500g / m 2。三烷氧基硅烷化合物的量优选为基板颗粒表面的0.1〜2g / m 2。涂覆表面的方法对于效果颜料特别有用。

8. 发明授权

US6143067A Isoindoline pigment having improved low shear dispersibility 有权
标题翻译：具有改进的低剪切分散性的异吲哚啉颜料
公开(公告)号：US6143067A
公开(公告)日：2000-11-07
申请号：US229875
申请日：1999-01-13
申请人： Philippe Bugnon , Fritz Herren , Michel Fran.cedilla.ois , Alastair McAlpine Marr
发明人： Philippe Bugnon , Fritz Herren , Michel Fran.cedilla.ois , Alastair McAlpine Marr
IPC分类号： C08J5/00 , C08K5/103 , C08K5/3462 , C08L23/10 , C08L27/06 , C08L101/00 , C09B67/10 , C09B67/20 , C09D17/00 , D01F1/04 , D06P1/00 , D06P1/44 , D06P1/651 , C09B57/04
CPC分类号： C09B67/0065 , C09B67/0014
摘要： A pigment composition, which comprises70-95% by weight of a pigment of formula ##STR1## 5-15% by weight of at least one C.sub.2 -C.sub.16 alkylenedicarboxylic acid-di-C.sub.1 -C.sub.12 alkyl ester; and0-15% by weight of at least one C.sub.12 -C.sub.24 fatty acid ester of polyhydroxy-C.sub.2 -C.sub.12 alkane;each based on the total weight of the pigment composition.Also claimed is a process for the preparation of this pigment composition and its use for mass-colouring in particular high molecular weight organic materials which can be moulded as plastics or melts.The products obtained are distinguished by an improved low shear dispersibility effect at high tinctorial strength.
摘要翻译：一种颜料组合物，其包含70-95重量％的至少一种C 2 -C 16亚烷基二羧酸 - 二-C 1 -C 12烷基酯的式5-15重量％的颜料; 和0-15重量％的至少一种多羟基-C 2 -C 12烷烃的C 12 -C 24脂肪酸酯; 各自基于颜料组合物的总重量。还要求的是制备该颜料组合物的方法及其用于大量着色的用途，特别是可以模塑成塑料或熔融的高分子量有机材料。所得产物的特征在于高着色强度下的低剪切分散效果。

9. 发明授权

US5123965A Process for stabilizing bismuth vanadate pigments against attack by hydrochloric acid 失效
标题翻译：通过氢氯酸对双歧杆菌色素进行稳定化处理的方法
公开(公告)号：US5123965A
公开(公告)日：1992-06-23
申请号：US616556
申请日：1990-11-21
申请人： Fritz Herren , Leonardus J. H. Erkens
发明人： Fritz Herren , Leonardus J. H. Erkens
IPC分类号： C08K3/00 , C09C1/00 , C09D7/12 , C09D11/03
CPC分类号： C09D11/03 , C09C1/0006 , C09D7/1225 , C01P2006/60 , C01P2006/80 , C08K3/0033 , C08K9/02
摘要： A process for stabilizing bismuth vanadate pigments against attack by hydrochloric acid by treating said pigments with a metal phosphate, which process comprises treating an aqueous suspension of a bismuth vanadate pigment with 2-20% by weight, based on said pigment, of an orthophosphate selected from the group consisting of calcium, magnesium, aluminium, zirconium and titanium orthophosphate, of a mixture of such orthophosphates with one another or of such orthophosphates with zinc orthophosphate, with stirring, in the temperature range from 20.degree. to 100.degree. C. and in the pH range from 2 to 8, which orthophosphate is precipitated in situ from the appropriate metal salt of a strong mineral acid and orthophosphoric acid or from an alkali metal salt thereof, and isolating the resultant product by conventional methods.The pigments so obtained have excellent resistance to hydrochloric acid.
摘要翻译：一种通过用金属磷酸盐处理所述颜料来稳定钒酸铋颜料以防止盐酸侵蚀的方法，该方法包括用选自正磷酸盐的2-20重量％的基于所述颜料的2-20重量％的钒酸铋颜料颜料的水性悬浮液由正磷酸钙，镁，铝，锆和钛组成的组，这些正磷酸盐彼此或这些正磷酸盐与正磷酸锌的混合物在搅拌下在20℃至100℃的温度范围内 pH范围为2至8，其中正磷酸盐由强无机酸和正磷酸的合适金属盐或其碱金属盐原位沉淀，并通过常规方法分离得到的产物。如此获得的颜料具有优异的耐盐酸性。

10. 发明授权

US06180694B2 Process for warp-free pigmenting of polyolefins 失效
标题翻译：聚烯烃无翘曲着色的方法
公开(公告)号：US06180694B2
公开(公告)日：2001-01-30
申请号：US08359710
申请日：1994-12-20
申请人： Philippe Bugnon , Fritz Herren
发明人： Philippe Bugnon , Fritz Herren
IPC分类号： C08J320
CPC分类号： C09B67/0013 , C08K9/08 , C08K9/10 , Y10T428/2998 , C08L23/02
摘要： The instant invention relates to a process for the warp-free pigmenting of polyolefins, which process comprises admixing coated pigment particles with a polyolefin, wherein said coated pigment particles are prepared by coating organic pigment particles with one or more films of a preformed polymer by adsorption thereon of from 1 to 10% by weight of the polymer, based on the pigment particles, at room temperature, the polymer being selected from the group consisting of polyvinylpyrrolidone homopolymers and copolymers.
摘要翻译：本发明涉及一种聚烯烃无翘曲着色的方法，该方法包括将涂覆的颜料颗粒与聚烯烃混合，其中所述涂覆颜料颗粒通过用一种或多种预成型聚合物膜通过吸附涂布有机颜料颗粒来制备其中基于颜料颗粒的聚合物的1-10重量％，在室温下，该聚合物选自聚乙烯吡咯烷酮均聚物和共聚物。

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