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1. 发明授权

US4609698A Oligoesters containing polyalkylpiperidine groups 失效
标题翻译：含聚烷基哌啶基团的低聚酯
公开(公告)号：US4609698A
公开(公告)日：1986-09-02
申请号：US728011
申请日：1985-04-26
申请人： Friedrich Karrer , Jean Rody
发明人： Friedrich Karrer , Jean Rody
IPC分类号： C07D211/46 , C07D211/58 , C07D401/14 , C08G18/00 , C08G63/00 , C08G63/68 , C08G63/685 , C08G73/02 , C08K5/3432 , C08K5/3435 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L75/00 , C08L75/04 , C08L77/00 , C08L101/00 , C08K5/34
CPC分类号： C08K5/3435 , C07D211/46 , C07D211/58
摘要： Oligomeric esters of the formula I or II ##STR1## in which n has a value from 1 to 3, R.sup.1 and R.sup.2 are divalent organic radicals, at least one of which contains a polyalkylpiperidine radical of the formula III ##STR2## in which R is hydrogen or C.sub.1 -C.sub.4 -alkyl and E and E' are end groups, are prepared by polycondensing a dicarboxylic acid ester with a diol, one of the two components being used in a molar excess of 33 to 100%. The end groups of these oligoesters can be modified by reaction with a monofunctional component. If two different dicarboxylic acid esters or diols are used, the corresponding co-oligoesters are obtained. All these oligoesters are valuable light stabilisers for light-sensitive organic material, especially for polymer.
摘要翻译：式I或II的低聚酯其中n具有1至3的值，R 1和R 2是二价有机基团，其中至少一个含有式III的聚烷基哌啶基团

2. 发明授权

US4256627A Novel light stabilizers for plastics 失效
标题翻译：用于塑料的新型光稳定剂
公开(公告)号：US4256627A
公开(公告)日：1981-03-17
申请号：US956716
申请日：1978-11-01
申请人： Paul Moser , Jean Rody , Friedrich Karrer
发明人： Paul Moser , Jean Rody , Friedrich Karrer
IPC分类号： C08L33/00 , C08L33/02 , C08L39/00 , C08L67/00 , C08L77/00 , C08L101/00 , C08K5/34 , C08K5/09 , C08K5/35
CPC分类号： C08L101/00 , C08L2201/08
摘要： Mixtures of a polymer which contains polyalkylpiperidines chemically bonded in any form and a metal compound MeL.sub.w, in which Me is a divalent or trivalent metal ion or a divalent oxo-metal ion or a divalent dialkyl-tin ion, L is the monovalent anion of a carboxylic acid, of a phosphinic acid or of a phosphonic acid monoester or of an enol and w is 2 or 3, are effective light stabilizers for plastics. The piperidine-containing polymers can be, for example, polyesters, polyamides, polyamines, polyaminotriazines or poly(meth)-acrylates. Examples of metal compounds MeL.sub.w are nickel oenanthate or nickel acetylacetonate. Plastics to be stabilized are in particular the polyolefins.
摘要翻译：含有以任何形式化学键合的聚烷基哌啶和金属化合物MeLw的聚合物的混合物，其中Me是二价或三价金属离子或二价氧代金属离子或二价二烷基锡离子，L是一价阴离子次膦酸或膦酸单酯或烯醇和w的羧酸为2或3，是塑料的有效光稳定剂。含哌啶的聚合物可以是例如聚酯，聚酰胺，聚胺，聚氨基三嗪或聚（甲基）丙烯酸酯。金属化合物MeLw的实例是乙酸鲸蜡酸镍或乙酰丙酮酸镍。待稳定的塑料尤其是聚烯烃。

3. 发明授权

US4237297A Piperidine containing malonic acid derivatives 失效
标题翻译：哌啶含有丙二酸衍生物
公开(公告)号：US4237297A
公开(公告)日：1980-12-02
申请号：US91630
申请日：1979-11-05
申请人： Jean Rody , Friedrich Karrer
发明人： Jean Rody , Friedrich Karrer
IPC分类号： C08K5/00 , C07D211/14 , C07D211/46 , C07D211/58 , C07D295/088 , C08K5/34 , C08K5/3412 , C08K5/3435 , C08L7/00 , C08L21/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L101/00 , C09D7/12 , C07D401/12
CPC分类号： C07D295/088 , C07D211/46 , C07D211/58 , C08K5/3435 , C09D7/1241
摘要： Malonic acid derivatives of the formula ##STR1## wherein Z contain sterically hindered piperidines as stabilizers against light-induced degradation for organic material.
摘要翻译：其中Z含有空间位阻哌啶作为稳定剂用于有机材料的光诱导降解的式“IMAGE”的丙二酸衍生物。

4. 发明授权

US4429077A Process for curing stoving lacquers 失效
标题翻译：烘烤漆的工艺
公开(公告)号：US4429077A
公开(公告)日：1984-01-31
申请号：US328885
申请日：1981-12-09
申请人： Friedrich Karrer , Godwin Berner , Jean Rody
发明人： Friedrich Karrer , Godwin Berner , Jean Rody
IPC分类号： C09D7/00 , C07D211/46 , C07D211/58 , C07D249/20 , C07D295/088 , C07D471/10 , C07F9/38 , C07F9/40 , C08K5/3435 , C09D7/12 , B01J31/02 , C08L33/00 , C08L61/06 , C08L61/28
CPC分类号： C07D295/088 , C07D211/46 , C07D211/58 , C07D249/20 , C07D471/10 , C07F9/3808 , C07F9/4006 , C08K5/3435 , C09D7/1233
摘要： Acid addition salts of basic polyalkylpiperidine derivatives, which contain a group of the formula I ##STR1## in which R is H or CH.sub.3, and an inorganic or organic acid, and also inner salts of sulfonic acids which contain a group of the formula I, are suitable as curing catalysts for acid-curable stoving lacquers. Their advantage is a long pot life and also an additional light stabilizing action.
摘要翻译：碱式聚烷基哌啶衍生物的酸加成盐，其含有其中R为H或CH 3的式I（I）基团和无机或有机酸，以及含有一组式I，适用于酸固化烘烤漆的固化催化剂。它们的优点是使用寿命长，并且还具有额外的光稳定作用。

5. 发明申请

US20090173176A1 MECHANICAL ADJUSTING DEVICE FOR ADJUSTING AN ADJUSTING ELEMENT 审中-公开
标题翻译：用于调整调节元件的机械调节装置
公开(公告)号：US20090173176A1
公开(公告)日：2009-07-09
申请号：US12061101
申请日：2008-04-02
申请人： Friedrich Karrer , Gundolf Kaupp , Marco Thurau
发明人： Friedrich Karrer , Gundolf Kaupp , Marco Thurau
IPC分类号： F16H1/06
CPC分类号： F16K31/535 , B60H1/00857 , Y10T74/19651
摘要： The invention relates to a mechanical adjusting device for an adjusting element, for example an air flap (2) in an air channel (1) of a ventilation system in the passenger compartment of a motor vehicle. The mechanical adjusting device comprises two toothed wheels (5, 6) that mesh with one another, one of which wheels (6) comprises an operating wheel (17) and the other of which toothed wheels (5) is connected to an air flap so as to rotate therewith. By the overcoming of a pressure point created by a raised base (13) between two teeth, the air flap (2) is held in a closed position. The invention provides a stiffening element (15), for example in the form of a spoke, which braces the toothing (7) of one of the toothed wheels (5) in a chordal direction and thereby increases the bias with which the air flap (2) rests in position.
摘要翻译：本发明涉及一种用于调节元件的机械调节装置，例如在机动车辆的乘客舱中的通风系统的空气通道（1）中的空气挡板（2）。机械调节装置包括彼此啮合的两个齿轮（5,6），其中一个轮（6）包括操作轮（17），另一个齿轮（5）连接到空气挡片，因此以便随之旋转。通过克服由两个齿之间的升高的基座（13）产生的压力点，空气挡板（2）保持在关闭位置。本发明提供一种加强元件（15），例如以辐条的形式，其以弦向方向支撑一个齿轮（5）的齿部（7），从而增加了气翼（ 2）休息。

6. 发明授权

US06186379B1 Device for securing pieces of luggage in car luggage compartment 失效
标题翻译：用于将行李固定在汽车行李箱中的装置
公开(公告)号：US06186379B1
公开(公告)日：2001-02-13
申请号：US08961471
申请日：1997-10-31
申请人： Manfred Haage , Bernd Schoch , Wilhelm Schoch , Andrè Hein , Michael Braun , Dietmar Renner , Stefan Kühn , Friedrich Karrer
发明人： Manfred Haage , Bernd Schoch , Wilhelm Schoch , Andrè Hein , Michael Braun , Dietmar Renner , Stefan Kühn , Friedrich Karrer
IPC分类号： B60R700
CPC分类号： B60R7/02
摘要： A device for securing pieces of luggage in a luggage compartment of a car has a frame having an adjustable size and placeable on a luggage compartment floor, and a floor mat which is impermeable to liquid and is mounted on the frame.
摘要翻译：用于将行李箱固定在汽车行李箱中的装置具有可调整尺寸的框架，并可放置在行李箱底板上，并且地板垫不透液体并安装在框架上。

7. 发明授权

US5166153A Bisacylethylamines 失效
标题翻译：二甲基乙烯胺
公开(公告)号：US5166153A
公开(公告)日：1992-11-24
申请号：US515001
申请日：1990-04-24
申请人： Friedrich Karrer
发明人： Friedrich Karrer
IPC分类号： C07D295/18 , A01N47/12 , A01N47/28 , A01N47/34 , A01N47/38 , C07C271/64 , C07C271/66 , C07D295/185 , C07D295/20
CPC分类号： C07D295/185 , A01N47/12 , A01N47/34 , A01N47/38 , C07C271/64 , C07C271/66
摘要： Novel N-acylated 2-[4-(halophenoxy)-phenoxy]-ethylcarbamic acid esters of formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.8 alkyl or C.sub.3 -C.sub.5 alkenyl,R.sub.2 is C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkoxy, --CO--R.sub.7 or --NR.sub.8 R.sub.9,R.sub.3 and R.sub.4 independently of one another are hydrogen or methyl,R.sub.5 is chlorine or fluorine,R.sub.6 is either the same substituent as R.sub.5 or is hydrogen,R.sub.7 is C.sub.1 -C.sub.8 alkoxy or --NR.sub.10 R.sub.11,R.sub.8 is C.sub.1 -C.sub.4 alkyl,R.sub.9 is C.sub.1 -C.sub.4 alkyl orR.sub.8 and R.sub.9 together form a C.sub.4 -C.sub.6 alkylene chain which may be interrupted by oxygen, sulfur or --NCH.sub.3 --,R.sub.10 is hydrogen or C.sub.1 -C.sub.4 alkyl andR.sub.11 is hydrogen or C.sub.1 -C.sub.4 alkyl, benzyl, phenyl, or phenyl substituted by halogen or by methyl, orR.sub.10 and R.sub.11 together form a C.sub.4 -C.sub.6 alkylene chain which may be interrupted by oxygen, sulfur or --NCH.sub.3 --;their preparation, their use in pest control, and pesticidal compositions that contain those carbamic acid esters as active ingredient are disclosed.
摘要翻译：式I的新型N-酰化2-酰氯化2- [4-（卤代苯氧基） - 苯氧基] - 乙基氨基甲酸酯其中R 1是C 1 -C 8烷基或C 3 -C 5烯基，R 2是C 1 -C 8烷基，C 1 -C 8烷氧基， CO-R7或-NR8R9，R3和R4彼此独立地是氢或甲基，R5是氯或氟，R6是与R5相同的取代基或是氢，R7是C1-C8烷氧基或-NR10R11，R8是C1- C 4烷基，R 9为C 1 -C 4烷基或R 8和R 9一起形成可被氧，硫或-NCH 3 - ，R 10为氢或C 1 -C 4烷基，R 11为氢或C 1 -C 4烷基，苄基，苯基或被卤素或甲基取代的苯基，或R 10和R 11一起形成可被氧，硫或-NCH 3 - 间隔的C 4 -C 6亚烷基链; 公开了它们的制备，其在病虫害防治中的用途和含有这些氨基甲酸酯作为活性成分的农药组合物。

8. 发明授权

US5114977A Ethers 失效
标题翻译：其他人
公开(公告)号：US5114977A
公开(公告)日：1992-05-19
申请号：US740657
申请日：1991-08-02
申请人： Friedrich Karrer , Alfred Rindlisbacher
发明人： Friedrich Karrer , Alfred Rindlisbacher
IPC分类号： C07C41/01 , A01N31/16 , C07C41/16 , C07C43/29 , C07C43/295 , C07C67/00
CPC分类号： C07C43/295 , A01N31/16 , C07C43/29
摘要： There are disclosed 1-[4-(halophenoxy)phenoxy]-4-pentines of formula ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other chloro or fluoro and one of R.sub.1 and R.sub.2 is also hydrogen, a process for their preparation and intermediates for their preparation, the use of these compounds in pest control, and pesticidal compositions which contains a compound of formula I as active component. The preferred field of use is ovicidal control of pests.
摘要翻译：公开了式（I）的1- [4-（卤代苯氧基）苯氧基] -4-戊烯基，其中R 1和R 2各自独立地为另一个氯或氟并且R 1和R 2之一也是氢，其制备方法及其制备中间体，这些化合物在害虫防治中的应用，以及含有式I化合物作为活性组分的杀虫组合物。优选的使用领域是对害虫的杀卵控制。

9. 发明授权

US4444928A Polymeric malonic acid derivatives 失效
标题翻译：聚合丙二酸衍生物
公开(公告)号：US4444928A
公开(公告)日：1984-04-24
申请号：US405114
申请日：1982-08-04
申请人： Friedrich Karrer
发明人： Friedrich Karrer
IPC分类号： C08K5/00 , C07D211/14 , C07D211/46 , C07D211/58 , C07D491/113 , C07D519/00 , C08G61/00 , C08G61/02 , C08G61/10 , C08G61/12 , C08K5/34 , C08K5/3412 , C08K5/3435 , C08L23/00 , C08L65/00 , C08L101/00 , C07D211/30 , C07D211/36 , C07D401/00
CPC分类号： C08G61/02 , C08G61/12 , C08K5/3435
摘要： Polymers or oligometic compounds of the general formula ##STR1## in which X, X.sup.a and X.sup.b are an ester, amide or cyano group, Y, Y.sup.a and Y.sup.b are --O-- or --NR.sup.10 --, R.sup.1, R.sup.1a and R.sup.1b are a group which contains a polyalkylpiperidine radical, and R.sup.1a can also be alkyl, and R.sup.3, R.sup.3a and R.sup.3b are alkylene, alkenylene, arylene-dialkylene, cycloalkylene-dialkylene or monooxa-alkylene or polyoxa-alkylene, can be prepared by the polycondensation of malonic acid esters or amides or cyanoacetic acid esters or amides with difunctional compounds, preferably dihalogen compounds, in the presence of bases. The products obtained have a molecular weight of 800 to 20,000 and are outstanding light stabilizers for organic polymers.
摘要翻译： X，Xa和Xb为酯，酰胺或氰基，Y，Ya和Yb的通式为“IMAGE”的聚合物或低聚物为-O-或-NR10-，R1，R1a和R1b为含有多烷基哌啶基团，R 1a，R 3a和R 3b可以是亚烷基，亚烯基，亚芳基亚烷基，亚环亚烷基 - 亚烷基或单亚烷基亚烷基或聚氧亚烷基，可以通过丙二酸酯缩聚或酰胺或氰基乙酸酯或酰胺与二官能化合物，优选二卤化合物在碱的存在下反应。所得产物的分子量为800至20,000，并且是有机聚合物的突出的光稳定剂。

10. 发明授权

US4309546A Piperidino pyrrolidinones 失效
标题翻译：哌啶子基吡咯烷酮
公开(公告)号：US4309546A
公开(公告)日：1982-01-05
申请号：US143387
申请日：1980-04-24
申请人： Friedrich Karrer
发明人： Friedrich Karrer
IPC分类号： C08K5/00 , C07D401/04 , C07D401/06 , C08G69/24 , C08K5/34 , C08K5/3412 , C08K5/3415 , C08L101/00 , C07D401/12 , C07D401/14
CPC分类号： C08K5/3415 , C08G69/24 , C08L101/00
摘要： Pyrrolidiones of the formula I ##STR1## wherein n is 1, 2, 3 or 4, R.sub.1 is free or esterified hydroxyl or hydroxyl which has been converted to a salt or is substituted or unsubstituted amino, X is a direct bond or a linking member and Pip is a substituted or unsubstituted 2,2,6,6-tetraalkylpiperidin-4-yl or a 2,2,6,6-tetraalkylpiperidin-4-ylidene, which pyrrolidones can be oligomerized or polymerized by linking R.sub.1 with X or by linking R.sub.1 with Pip. These compounds are used as light stabilizers for polymers.
摘要翻译：式I的吡咯烷（I）其中n为1,2,3或4，R1为已转化为盐或被取代或未取代的氨基的游离或酯化的羟基或羟基，X为直接键或连接构件和Pip是取代或未取代的2,2,6,6-四烷基哌啶-4-基或2,2,6,6-四烷基哌啶-4-亚基，该吡咯烷酮可以通过将R 1与 X或通过将R1与Pip连接。这些化合物用作聚合物的光稳定剂。

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