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1. 发明申请

US20070260070A1 METHODS OF STABILIZING THIOPHENE DERIVATIVES 失效
标题翻译：稳定噻吩衍生物的方法
公开(公告)号：US20070260070A1
公开(公告)日：2007-11-08
申请号：US11744264
申请日：2007-05-04
申请人： Friedrich Jonas , Klaus Wussow , Knud Reuter
发明人： Friedrich Jonas , Klaus Wussow , Knud Reuter
IPC分类号： C07D495/02
CPC分类号： C07D495/04
摘要： Methods of stabilizing thiophene derivatives of the general formula (I) by treatment with basic compounds: wherein R1 and R2 each independently represents a moiety selected from the group consisting of hydrogen, optionally substituted C1-20 alkyl groups which can contain up to 5 heteroatoms selected from the group consisting of oxygen and sulfur, optionally substituted C1-20 oxyalkyl groups which can contain up to 5 heteroatoms selected from the group consisting of oxygen and sulfur, or wherein R1 and R2 together represent a fused cyclic moiety selected from the group consisting of optionally substituted C1-20 dioxyalkylene groups and C1-20 dioxyarylene groups; and stabilized thiophene derivatives that can be prepared by such methods.
摘要翻译：通过用碱性化合物处理来稳定通式（I）的噻吩衍生物的方法：其中R 1和R 2各自独立地表示选自氢，任选取代的C 1-20烷基，其可以含有至多5个选自氧和硫的杂原子，任选取代的C 1-20烷氧基，其可以含有多至5个选自氧和硫的杂原子，或其中R 1和R 2一起代表稠合的环状部分，其选自任选取代的 C 1-20二氧亚烷基和C 1-20二取代的亚芳基; 和可以通过这些方法制备的稳定的噻吩衍生物。

2. 发明授权

US07449588B2 Methods of stabilizing thiophene derivatives 失效
标题翻译：稳定噻吩衍生物的方法
公开(公告)号：US07449588B2
公开(公告)日：2008-11-11
申请号：US11744264
申请日：2007-05-04
申请人： Friedrich Jonas , Klaus Wussow , Knud Reuter
发明人： Friedrich Jonas , Klaus Wussow , Knud Reuter
IPC分类号： C07D333/16 , C07D495/06
CPC分类号： C07D495/04
摘要： Methods of stabilizing thiophene derivatives of the general formula (I) by treatment with basic compounds: wherein R1 and R2 each independently represents a moiety selected from the group consisting of hydrogen, optionally substituted C1-20 alkyl groups which can contain up to 5 heteroatoms selected from the group consisting of oxygen and sulfur, optionally substituted C1-20 oxyalkyl groups which can contain up to 5 heteroatoms selected from the group consisting of oxygen and sulfur, or wherein R1 and R2 together represent a fused cyclic moiety selected from the group consisting of optionally substituted C1-20 dioxyalkylene groups and C1-20 dioxyarylene groups; and stabilized thiophene derivatives that can be prepared by such methods.
摘要翻译：通过用碱性化合物处理来稳定通式（I）的噻吩衍生物的方法：其中R 1和R 2各自独立地表示选自氢，任选取代的C 1-20烷基，其可以含有至多5个选自氧和硫的杂原子，任选取代的C 1-20烷氧基，其可以含有多至5个选自氧和硫的杂原子，或其中R 1和R 2一起代表稠合的环状部分，其选自任选取代的 C 1-20二氧亚烷基和C 1-20二取代的亚芳基; 和可以通过这些方法制备的稳定的噻吩衍生物。

3. 发明授权

US08420671B2 Stabilised thiophene derivatives 失效
标题翻译：稳定的噻吩衍生物
公开(公告)号：US08420671B2
公开(公告)日：2013-04-16
申请号：US12894952
申请日：2010-09-30
申请人： Knud Reuter , Klaus Wussow , Udo Merker , Andreas Elschner
发明人： Knud Reuter , Klaus Wussow , Udo Merker , Andreas Elschner
IPC分类号： A61K31/4468
CPC分类号： C08K5/13 , C08G2261/3223 , C08K5/3435 , C08L65/00 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/43
摘要： The present invention relates to a stabilized monomer composition comprising at least 50 wt.-%, based on the total weight of the stabilized monomer composition, of a thiophene derivative monomer having the general formula (I) in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group, and 0.001 to 10 wt.-%, based on the total weight of the stabilized monomer composition, of a stabilizer. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method, the use of a stabilized monomer composition and to the use of a stabilizer.
摘要翻译：本发明涉及稳定的单体组合物，其包含基于稳定的单体组合物的总重量的至少50重量％的具有通式（I）的噻吩衍生物单体，其中R1和R2独立地为另一个，对于氢，对于任选被取代的C1-C20烷基或C1-C20-氧烷基，任选地被1至5个氧原子和/或硫原子间隔，或共同用于任选取代的C 1 -C 20 - 二氧亚烷基或C6-C20-二氧亚芳基，和基于稳定化单体组合物的总重量为0.001至10重量％的稳定剂。本发明还涉及一种用于制造电容器，通过该方法获得的电容器，使用稳定的单体组合物和使用稳定剂的方法。

4. 发明申请

US20110102970A1 MONOMERS OF SELECTED COLOUR NUMBERS AND CAPACITORS PREPARED THEREFROM 失效
标题翻译：选择的颜色编号和电容器的单体
公开(公告)号：US20110102970A1
公开(公告)日：2011-05-05
申请号：US12894976
申请日：2010-09-30
申请人： Udo Merker , Klaus Wussow , Knud Reuter , Andreas Elschner
发明人： Udo Merker , Klaus Wussow , Knud Reuter , Andreas Elschner
IPC分类号： H01G4/06 , C07D333/10 , C07D333/18 , C07D333/16 , C07D495/04 , H01G7/00
CPC分类号： H01G4/18 , C07D495/04 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/435
摘要： The present invention relates to a monomer having the general formula (I) in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group, wherein the monomer has a colour in a range of a Hazen colour number determined according to test method described herein of at least 20, to a Gardner colour number determined according to test method described herein of not more than 5. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method and to the use of a monomer.
摘要翻译：本发明涉及具有通式（I）的单体，其中R 1和R 2彼此独立地为氢，任选取代的C 1 -C 20 - 烷基或C 1 -C 20 - 烷氧基，任选地被 1至5个氧原子和/或硫原子，或共同用于任选取代的C 1 -C 20 - 二氧亚烷基或C 6 -C 20 - 二亚甲基，其中单体具有根据测试方法确定的哈岑色数范围内的颜色根据本文所述的测试方法确定的加德纳颜色数不超过5个。本发明还涉及制造电容器，通过该方法获得的电容器和使用的方法的单体。

5. 发明申请

US20110102973A1 STABILISED THIOPHENE DERIVATIVES 失效
标题翻译：稳定的噻吩衍生物
公开(公告)号：US20110102973A1
公开(公告)日：2011-05-05
申请号：US12894952
申请日：2010-09-30
申请人： Knud Reuter , Klaus Wussow , Udo Merker , Andreas Elschner
发明人： Knud Reuter , Klaus Wussow , Udo Merker , Andreas Elschner
IPC分类号： H01G9/042 , C07D495/04 , H01G9/00 , H01G9/15
CPC分类号： C08K5/13 , C08G2261/3223 , C08K5/3435 , C08L65/00 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/43
摘要： The present invention relates to a stabilised monomer composition comprising at least 50 wt.-%, based on the total weight of the stabilised monomer composition, of a thiophene derivative monomer having the general formula (I) in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group, and 0.001 to 10 wt.-%, based on the total weight of the stabilised monomer composition, of a stabiliser. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method, the use of a stabilised monomer composition and to the use of a stabiliser.
摘要翻译：本发明涉及稳定的单体组合物，其包含基于稳定的单体组合物的总重量的至少50重量％的具有通式（I）的噻吩衍生物单体，其中R1和R2独立地为另一个，对于氢，对于任选被取代的C1-C20烷基或C1-C20-氧烷基，任选地被1至5个氧原子和/或硫原子间隔，或共同用于任选取代的C 1 -C 20 - 二氧亚烷基或C6-C20-二氧亚芳基，和基于稳定化单体组合物的总重量为0.001至10重量％的稳定剂。本发明还涉及一种用于制造电容器，通过该方法获得的电容器，使用稳定的单体组合物和使用稳定剂的方法。

6. 发明授权

US08390988B2 Monomers of selected colour numbers and capacitors prepared therefrom 失效
标题翻译：所选颜色数字和由其制备的电容器的单体
公开(公告)号：US08390988B2
公开(公告)日：2013-03-05
申请号：US12894976
申请日：2010-09-30
申请人： Udo Merker , Klaus Wussow , Knud Reuter , Andreas Elschner
发明人： Udo Merker , Klaus Wussow , Knud Reuter , Andreas Elschner
IPC分类号： H01G9/00
CPC分类号： H01G4/18 , C07D495/04 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/435
摘要： The disclosure describes a monomer having the general formula (I): in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group. The monomer has a color in a range of a Hazen color number determined according to test method described herein of at least 20 to a Gardner color number determined according to test method described herein of not more than 5. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method and to the use of a monomer.
摘要翻译：本公开描述了具有通式（I）的单体：其中R 1和R 2彼此独立地表示氢，对于任选取代的C 1 -C 20 - 烷基或C 1 -C 20 - 烷氧基，任选地被1 至5个氧原子和/或硫原子，或共同用于任选取代的C 1 -C 20 - 二氧亚烷基或C 6 -C 20 - 二亚甲基。该单体具有根据根据本文所述的测试方法确定的至少20至根据本文所述测试方法确定的加德纳颜色数不超过5的哈根色数的颜色。本发明还涉及一种方法用于制造电容器，通过该方法获得的电容器和单体的使用。

7. 发明授权

US07951901B2 Process for the production of polyethylene dioxythiophenes 失效
标题翻译：生产聚乙烯二氧噻吩的方法
公开(公告)号：US07951901B2
公开(公告)日：2011-05-31
申请号：US11477873
申请日：2006-06-29
申请人： Knud Reuter , Stephan Kirchmeyer , Friedrich Jonas
发明人： Knud Reuter , Stephan Kirchmeyer , Friedrich Jonas
IPC分类号： C08G75/00
CPC分类号： C08G61/126 , C08L65/00
摘要： The production of electrically conductive polythiophenes by reaction of 2,5-dihalogen-3,4-ethylene dioxythiophenes with 3,4-ethylene dioxythiophenes in a solvent or liquid phase is provided. These polythiophenes can be used as a plastic or lacquer additive to provide antistatic properties.
摘要翻译：提供了在溶剂或液相中通过2,5-二卤代-3,4-亚乙基二氧噻吩与3,4-亚乙基二氧噻吩的反应制备导电聚噻吩。这些聚噻吩可用作塑料或漆添加剂以提供抗静电性能。

8. 发明授权

US07341801B2 Polythiophenes having alkyleneoxythia thiophene units in electrolyte capacitors 失效
标题翻译：在电解质电容器中具有亚烷氧基硫噻吩单元的聚噻吩
公开(公告)号：US07341801B2
公开(公告)日：2008-03-11
申请号：US10889491
申请日：2004-07-12
申请人： Knud Reuter , Udo Merker , Friedrich Jonas
发明人： Knud Reuter , Udo Merker , Friedrich Jonas
IPC分类号： H01M4/00
CPC分类号： H01B1/127 , H01G9/025 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： Electrolyte capacitors containing certain polythiophenes are described. More particularly, the polythiophenes have backbones containing repeating units of the following general formula (I) and/or repeating units of the following general formula (II), wherein A is, for example, a C1-C5-alkylene radical, R is, for example, a C1-C18-alkyl radical, and x is an integer from 0 to 8. Also described are dispersions comprising such polythiophenes, and the use of such polythiophenes or dispersions thereof for producing conductive layers.
摘要翻译：描述了含有某些聚噻吩的电解电容器。更具体地说，聚噻吩具有含有以下通式（I）的重复单元和/或下列通式（II）的重复单元的骨架，其中A是例如C 1〜 C 5 - 亚烷基，R是例如C 1 -C 18 - 烷基，x是0的整数还描述了包含这种聚噻吩的分散体，以及这种聚噻吩或其分散体在制备导电层中的用途。

9. 发明申请

US20070010653A1 Process for the production of polyethylene dioxythiophenes 失效
标题翻译：生产聚乙烯二氧噻吩的方法
公开(公告)号：US20070010653A1
公开(公告)日：2007-01-11
申请号：US11477873
申请日：2006-06-29
申请人： Knud Reuter , Stephan Kirchmeyer , Friedrich Jonas
发明人： Knud Reuter , Stephan Kirchmeyer , Friedrich Jonas
IPC分类号： C08G61/12 , H01B1/12
CPC分类号： C08G61/126 , C08L65/00
摘要： The production of electrically conductive polythiophenes by reaction of 2,5-dihalogen-3,4-ethylene dioxythiophenes with 3,4-ethylene dioxythiophenes in a solvent or liquid phase is provided. These polythiophenes can be used as a plastic or lacquer additive to provide antistatic properties.
摘要翻译：提供了在溶剂或液相中通过2,5-二卤代-3,4-亚乙基二氧噻吩与3,4-亚乙基二氧噻吩的反应制备导电聚噻吩。这些聚噻吩可用作塑料或漆添加剂以提供抗静电性能。

10. 发明申请

US20050175861A1 Polythiophene compositions for improving organic light-emitting diodes 审中-公开
标题翻译：用于改善有机发光二极管的聚噻吩组合物
公开(公告)号：US20050175861A1
公开(公告)日：2005-08-11
申请号：US11044908
申请日：2005-01-27
申请人： Andreas Elschner , Friedrich Jonas , Knud Reuter , Peter Lovenich
发明人： Andreas Elschner , Friedrich Jonas , Knud Reuter , Peter Lovenich
IPC分类号： H01L51/50 , C08L25/18 , C08L27/12 , C08L65/00 , C08L101/06 , H01L51/30 , H01B1/12 , H05B33/12
CPC分类号： C08L65/00 , C08L25/18 , C08L27/12 , H01L51/0037 , H01L51/5088 , Y02E10/549 , Y02P70/521 , C08L2666/06 , C08L2666/04
摘要： Disclosed are compositions/formulations that include: polythiophenes (A) containing recurring units represented by the following general formula (I), in which is, for example, —CH2—CH2—; and two additional polymers (B) and (C), each having SO3−M+ or COO−M+ functional groups. Also disclosed are electroluminescent arrangements having hole-injecting layers containing the disclosed compositions.
摘要翻译：公开的组合物/制剂包括：含有由以下通式（I）表示的重复单元的聚噻吩（A），其中例如是-CH 2 -CH 2， SUB> - ; 和另外两种另外的聚合物（B）和（C），它们各自具有SO 3 - ， - ，SO 2 - M + + / SO 2官能团。还公开了具有包含所公开组合物的空穴注入层的电致发光装置。

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