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1. 发明授权

US3961023A Process for the production of cyanogen chloride and hydrogen chloride 失效
公开(公告)号：US3961023A
公开(公告)日：1976-06-01
申请号：US540706
申请日：1975-01-13
申请人： Friedhelm Geiger , Werner Heimberger , Gerd Schreyer , Wolfgang Weigert
发明人： Friedhelm Geiger , Werner Heimberger , Gerd Schreyer , Wolfgang Weigert
IPC分类号： B01D53/68 , B01D53/14 , B01D53/77 , C01B7/00 , C01B7/01 , C01C3/00 , C01C3/14 , C01B21/18
CPC分类号： C01C3/004 , B01D53/1493 , C01B7/01
摘要： Cyanogen chloride and hydrogen chloride are produced by reacting hydrogen cyanide and chlorine, separating from the gaseous mixture on the one hand hydrogen chloride and on the other hand cyanogen chloride which in a given case can also contain chlorine, by absorption in a halohydrocarbon which has a boiling point between that of cyanogen chloride and cyanuric chloride and after distillative separation of the dissolved cyanogen chloride-chlorine mixture returning the solvent to the absorption column, the process includesA. adding as the solvent for the absorption a trifluoromethyl substituted aromatic hydrocarbon or halohydrocarbon or a mixture of such trifluoromethyl substituted aromatic hydrocarbons or halohydrocarbons,B. subjecting the gas mixture consisting of cyanogen chloride, hydrogen chloride and in a given case chlorine after leaving the reactor for the chlorination of hydrogen cyanide and before entrance into the absorption column to a pretreatment with the solvents set forth under (a) at a temperature between 80.degree.C. and the boiling point of the solvent and/orC. either converting the N-chloro-chloroformimide chloride formed in small amounts from the chlorine and cyanogen chloride in the course of the absorption and distillation into the insoluble chloroformimide chloride hydrochloride by gassing the solvent with hydrogen chloride and separating the insoluble hydrochloride in conventional manner and/or withdrawing the N-chloro-chloroformimide together with some cyanogen chloride and solvent of the previously named distillation column for separation of the cyanogen chloride by means of a side outlet, and in a second subsequently provided distillation column separating into solvent and pure N-chloro-chloroformimide chloride, whereby then the latter can be conducted both into the cyanogen chloride reactor and also, if connected to a plant for the production of cyanuric chloride, into the trimerization reactor for cyanogen chloride and/orD. subjecting the solvent contaminated with byproducts by the suspension resulting from the pretreatment and/or accumulating in the sump of the distillation column for the separation of the cyanogen chloride completely or in a partial stream to an aqueous alkaline treatment or in combination with a cyanuric chloride condensation plant leading the suspension formed in the pretreatment to the cyanuric chloride condensation column.

2. 发明授权

US3947552A Process for the purification of cyanogen chloride 失效
标题翻译：氰化氯的净化方法
公开(公告)号：US3947552A
公开(公告)日：1976-03-30
申请号：US530611
申请日：1974-12-06
申请人： Friedhelm Geiger , Werner Heimberger , Gerd Schreyer
发明人： Friedhelm Geiger , Werner Heimberger , Gerd Schreyer
IPC分类号： C07D251/28 , B01D15/00 , B01D53/02 , B01D53/26 , B01J19/00 , B01J20/18 , C01C3/00 , C01B21/18
CPC分类号： C01C3/004 , B01D53/02
摘要： Cyanogen chloride is purified and the service life of activated carbon is increased in the subsequent trimerization of the cyanogen chloride to cyanuric chloride by process comprising reacting hydrogen cyanide with chlorine, in a given case in the presence of cyanogen chloride produced in the presence of water, which in a given case contains chlorine. The improvement comprises passing the cyanogen chloride over granular commercial sodium aluminum silicate or a molecular sieve of the mordenite type, at 20.degree.-100.degree.C., preferably 30.degree.-60.degree.C.
摘要翻译：纯化氰化氯，随后在氰化氢与氰尿酰氯的三聚反应中活性炭的使用寿命增加，包括使氰化氢与氯反应，在给定的情况下，在存在水的情况下生成的氯化氰，在给定的情况下，含氯。改进之处在于将氰化氯通过粒状商业硅酸铝钠或丝光沸石型分子筛在20℃-100℃，优选30℃-60℃下进行。

3. 发明授权

US4434148A Working up of the residual gases resulting from the production of cyanuric chloride 失效
标题翻译：处理由产生氰尿酰氯产生的残留气体
公开(公告)号：US4434148A
公开(公告)日：1984-02-28
申请号：US81555
申请日：1979-10-03
申请人： Gerhard Bach , Friedhelm Geiger , Werner Heimberger , Gerd Schreyer , Horst Hillenbrand
发明人： Gerhard Bach , Friedhelm Geiger , Werner Heimberger , Gerd Schreyer , Horst Hillenbrand
IPC分类号： B01D53/68 , C01C3/00 , C07D251/28 , C01B21/18
CPC分类号： C01C3/004 , C07D251/28
摘要： The residual gases obtained in the production of cyanuric chloride having a pressure of 1-5 bar (absolute) preferably 1-4 bar, are worked up by leading them into the lower portion of a column, reacted in the column with at least the equivalent amount of hydrogen cyanide to form cyanogen chloride and led in countercurrent flow to the water charged to the upper portion of the column whereupon the aqueous solution of cyanogen chloride formed is withdrawn from the lower portion of the column and preferably is returned into the production portion of the plant for recovery of the cyanogen chloride while the purified waste gas of the column leaves in the upper portion of the column.
摘要翻译：在生产具有1-5巴（绝对）压力优选1-4巴的压力的氰尿酰氯中获得的残余气体通过将它们引入塔的下部来处理，在塔中反应至少具有相当于氰化氢的量以形成氯化氰，并且逆流地流向加到塔上部的水，由此形成的氯化氢水溶液从柱的下部排出，优选返回到用于回收氯化氰的设备，而塔的净化废气在塔的上部离开。

4. 发明授权

US3949060A Process for the production of cyanogen chloride 失效
标题翻译：氯化氰生产工艺
公开(公告)号：US3949060A
公开(公告)日：1976-04-06
申请号：US530612
申请日：1974-12-06
申请人： Friedhelm Geiger , Werner Heimberger , Hermann Schmitt , Gerd Schreyer
发明人： Friedhelm Geiger , Werner Heimberger , Hermann Schmitt , Gerd Schreyer
IPC分类号： C07D251/28 , B01D15/00 , B01D53/02 , B01D53/28 , B01J19/00 , B01J20/08 , C01C3/00 , C01B21/18
CPC分类号： B01D53/02 , C01C3/004
摘要： Cyanogen chloride is purified and the service life of activated carbon is increased in the subsequent trimerization of the cyanogen chloride to cyanuric chloride by process comprising reacting hydrogen cyanide with chlorine, in a given case in the presence of cyanogen chloride produced in the presence of water, which in a given case contains chlorine. The improvement comprises passing the cyanogen chloride over granular gamma aluminum oxide with an alkali metal or in a given case an alkaline earth metal content of 0 to 3 weight % at 20.degree.-100.degree.C., preferably 30.degree.-60.degree.C.
摘要翻译：纯化氰化氯，随后在氰化氢与氰尿酰氯的三聚反应中活性炭的使用寿命增加，包括使氰化氢与氯反应，在给定的情况下，在存在水的情况下生成的氯化氰，在给定的情况下，含氯。改进之处在于使用氯化铵在含有碱金属的颗粒状γ氧化铝上，或者在给定的情况下，在20℃-100℃，优选30℃-60℃下使碱土金属含量为0-3％（重量）。

5. 发明授权

US3957950A Process for preparing pure chlorine 失效
标题翻译：纯氯制备方法
公开(公告)号：US3957950A
公开(公告)日：1976-05-18
申请号：US346789
申请日：1973-04-02
申请人： Friedhelm Geiger , Werner Heimberger , Gerd Schreyer
发明人： Friedhelm Geiger , Werner Heimberger , Gerd Schreyer
IPC分类号： C01B7/00 , C01B7/01 , C01G49/10
CPC分类号： C01B7/01
摘要： Side reactions in the use of gaseous chlorine are avoided by leading the chlorine containing at least 0.0001% of non-volatile compounds such as ferric chloride over silica gel, glass wool, pumice or montmorillonite. Preferably the thus treated chlorine is passed through hexachlorobutadiene or perfluorokerosene in a second absorption step. Ferric chloride can also be removed from the chlorine gas by treating with sulfuric acid.
摘要翻译：通过在硅胶，玻璃棉，浮石或蒙脱石上引入含有至少0.0001％的非挥发性化合物如氯化铁的氯来避免使用气态氯的副反应。优选地，如此处理的氯在第二吸收步骤中通过六氯丁二烯或全氟代烯烃。氯化铁也可以通过用硫酸处理从氯气中除去。

6. 发明授权

US4239696A Process for the production of alkyl sulfonic acids 失效
标题翻译：制备烷基磺酸的方法
公开(公告)号：US4239696A
公开(公告)日：1980-12-16
申请号：US655017
申请日：1976-02-04
申请人： Gerd Schreyer , Friedhelm Geiger , Jorg Hensel
发明人： Gerd Schreyer , Friedhelm Geiger , Jorg Hensel
IPC分类号： C07C309/02 , C07C20060101 , C07C67/00 , C07C301/00 , C07C303/16 , C07C309/04 , C07C143/02
CPC分类号： C07C309/00
摘要： Alkylsulfonic acids are prepared by oxidation of an alkyl mercaptan or dialkyl disulfide with hydrogen peroxide in an alkylsulfonic acid in the absence of percarboxylic acids and preferably employing 1 to 35 mole % of alkylsulfonic acid based on the alkyl mercaptan or dialkyl disulfide employed.
摘要翻译：烷基磺酸通过在不存在过羧酸的情况下在烷基磺酸中用过氧化氢氧化烷基硫醇或二烷基二硫化物制备，优选使用基于所用烷基硫醇或二烷基二硫化物的1至35摩尔％的烷基磺酸。

7. 发明授权

US4052445A Process for the production of alkyl sulfonic acids 失效
标题翻译：生产亚磷酸的方法
公开(公告)号：US4052445A
公开(公告)日：1977-10-04
申请号：US655018
申请日：1976-02-04
申请人： Gerd Schreyer , Friedhelm Geiger , Jorg Hensel
发明人： Gerd Schreyer , Friedhelm Geiger , Jorg Hensel
IPC分类号： C07C143/02
CPC分类号： C07C309/00
摘要： Alkylsulfonic acids are prepared by oxidation of an alkyl mercaptan or dialkyl disulfide with hydrogen peroxide in an inert medium in the presence of ammonium or alkali molybdate or ammonium or alkali tungstate.

8. 发明授权

US4038276A Process for the production of finely divided solid cyanuric chloride 失效
标题翻译：生产精细分散固体氰基氯化物的方法
公开(公告)号：US4038276A
公开(公告)日：1977-07-26
申请号：US716353
申请日：1976-08-20
申请人： Friedhelm Geiger , Werner Heimberger , Theodor Lussling
发明人： Friedhelm Geiger , Werner Heimberger , Theodor Lussling
IPC分类号： C07D251/28
CPC分类号： C07D251/28
摘要： Finely divided solid cyanuric chloride is produced by feeding a jet of liquid cyanuric chloride into a separatory container, cooling the liquid cyanuric chloride with recycling inert gases to such an extent that the cyanuric chloride is separated in crystalline form, washing the thereby warmed cyanuric chloride vapor or dust containing gases free of cyanuric chloride in countercurrent flow with an inert liquid that is a good solvent for cyanuric chloride in a washing column connected to the outlet side of the separatory column, thus simultaneously cooling the gases, and subsequently again returning the gases to the separatory container, while the temperature of the cyanuric chloride containing washing liquid which has increased in the washing process is again brought to the original temperature by leading it in the cycle over a heat exchanger and spraying the inside of the pipe connected to the separatory container and leading to the washing column constantly with the washing liquid while dividing a partial stream of the cyanuric chloride containing washing liquid in a distillation column into pure liquid cyanuric chloride which is recycled into the separatory column and into pure washing liquid which is recycled into the washing column.

9. 发明申请

US20070109958A1 Network with redundancy properties, a branching unit for a user device in a network, redundancy manager for a network with redundancy properties and method for operating a network with redundancy properties 有权
标题翻译：具有冗余属性的网络，网络中的用户设备的分支单元，具有冗余属性的网络的冗余管理器和用于操作具有冗余性质的网络的方法
公开(公告)号：US20070109958A1
公开(公告)日：2007-05-17
申请号：US10561478
申请日：2004-11-26
申请人： Holger Fehrmann , Friedhelm Geiger , Gerhard Hammer , Klaus Rother
发明人： Holger Fehrmann , Friedhelm Geiger , Gerhard Hammer , Klaus Rother
IPC分类号： H04J3/14
CPC分类号： G05B19/048 , G05B2219/24182 , G05B2219/25021 , H04L69/40
摘要： The invention relates to a network, in particular a PA PROFIBUS network having redundant properties and a linear topology. Two line ends are connected to a redundancy manager which disconnects said line ends in error-free conditions and connects them in error conditions. Said redundancy manager supplies voltage to the first line end for operating customers' mobile telephones each of which is connected to the network by a branching unit. After receiving a supply voltage on one connection thereof, said branching units check the state of a cable which is connected to the other network connection and transmit the supply voltage in the faultless condition thereof only. When the redundancy manager does not detect the supply voltage on the other end of the line end at least during a predetermined space of time after voltage supply, said redundancy manager supplies the voltage thereto. A cable having a disturbance is then disconnected from the line by the adjacent branching units.
摘要翻译：本发明涉及一种网络，特别是具有冗余特性和线性拓扑的PA PROFIBUS网络。两个线路端连接到冗余管理器，该冗余管理器在无错误的条件下断开所有线路端，并在错误条件下连接它们。所述冗余管理器向第一线路端提供电压，以操作每个通过分支单元连接到网络的客户的移动电话。在其一个连接处接收到电源电压之后，所述分支单元检查连接到另一个网络连接的电缆的状态，并且仅在其无故障状态下传送电源电压。当冗余管理器至少在电压供给之后的预定时间内没有检测到线路端部的另一端的电源电压时，所述冗余管理器向其提供电压。然后由相邻的分支单元将具有干扰的电缆与线分离。

10. 发明授权

US4518801A Process for the hydrolysis of 5-(.beta.-methylmercaptoethyl)-hydantoin 失效
标题翻译：水解5-（β-甲基巯基乙基） - 乙内酰脲的方法
公开(公告)号：US4518801A
公开(公告)日：1985-05-21
申请号：US648136
申请日：1984-09-07
申请人： Rudolf Bolze , Friedhelm Geiger , Manfred Spindler , Herbert Tanner
发明人： Rudolf Bolze , Friedhelm Geiger , Manfred Spindler , Herbert Tanner
IPC分类号： C07C319/20 , C07C67/00 , C07C313/00 , C07C323/58 , C07K5/062 , C07C149/247
CPC分类号： C07C319/22
摘要： The invention is directed to a process for the hydrolysis of 5-(.beta.-methylmercaptoethyl)-hydantoin by reaction at elevated temperature and pressure in an aqueous alkaline medium. There are obtained alkali methioninate solutions from which there can be separated methionine.
摘要翻译：本发明涉及通过在碱性水溶液中升高温度和压力下的反应来水解5-（β-甲基巯基乙基） - 乙内酰脲的方法。得到可从其中分离甲硫氨酸的甲硫氨酸甲酯溶液。

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