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1. 发明授权

US5100855A Mixed catalyst system for hyproconversion system 失效
标题翻译：低转化系统的混合催化剂体系
公开(公告)号：US5100855A
公开(公告)日：1992-03-31
申请号：US625092
申请日：1990-12-07
申请人： Frederick T. Clark , Albert L. Hensley, Jr. , David Lyzinski
发明人： Frederick T. Clark , Albert L. Hensley, Jr. , David Lyzinski
IPC分类号： B01J35/00 , B01J35/10 , B01J37/04 , C10G45/04
CPC分类号： C10G45/04 , B01J35/0006 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J35/109 , B01J37/04
摘要： Disclosed is an improved catalyst mixture suitable for use in the hydrodemetallization, hydrodesulfurization, hydrodenitrogenation, and hydroconversion of a hydrocarbon feedstock containing asphaltenes, metals and Shell hot filtration solids precursors. The catalyst mixture has one component of the mixture which is a relatively small pore catalyst and another component which is a catalyst that possesses a relatively large amount of macropore volume.
摘要翻译：公开了一种改进的催化剂混合物，其适用于含有沥青质，金属和壳热过滤固体前体的烃原料的加氢脱金属，加氢脱硫，加氢脱氮和加氢转化。催化剂混合物具有作为相对小的孔催化剂的混合物的一种组分和作为具有相对大量的大孔体积的催化剂的另一种组分。

2. 发明授权

US5009771A Hydroconversion process using mixed catalyst system 失效
标题翻译：加氢转化工艺采用混合催化剂体系
公开(公告)号：US5009771A
公开(公告)日：1991-04-23
申请号：US502297
申请日：1990-03-30
申请人： Frederick T. Clark , Albert L. Hensley, Jr. , David Lyzinski , Lawrence B. Peck
发明人： Frederick T. Clark , Albert L. Hensley, Jr. , David Lyzinski , Lawrence B. Peck
IPC分类号： B01J35/00 , B01J35/10 , B01J37/04 , C10G45/04
CPC分类号： C10G45/04 , B01J35/0006 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1066 , B01J35/109 , B01J37/04
摘要： Disclosed is an improved process for the hydrodemetallization, hydrodesulfurization, hydrodenitrogenation, and hydroconversion of a hydrocarbon feedstock containing asphaltenes, metals and Shell hot filtration solids precursors. The process utilizes a catalyst mixture wherein one component of the mixture is a relatively small pore catalyst and another component is a catalyst that possesses a relatively large amount of macropore volume.
摘要翻译：公开了一种用于含有沥青质，金属和壳热过滤固体前体的烃原料的加氢脱金属，加氢脱硫，加氢脱氮和加氢转化的改进方法。该方法使用催化剂混合物，其中混合物的一种组分是相对小的孔催化剂，另一种组分是具有相对大量的大孔体积的催化剂。

3. 发明授权

US5221656A Hydroprocessing catalyst 失效
标题翻译：加氢催化剂
公开(公告)号：US5221656A
公开(公告)日：1993-06-22
申请号：US857336
申请日：1992-03-25
申请人： Frederick T. Clark , Albert L. Hensley, Jr. , Simon G. Kukes , David C. Arters
发明人： Frederick T. Clark , Albert L. Hensley, Jr. , Simon G. Kukes , David C. Arters
IPC分类号： B01J23/85 , B01J35/10 , C10G49/04
CPC分类号： C10G49/04 , B01J23/85 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108
摘要： A hydroprocessing catalyst and process of using such catalyst wherein such catalyst has at least one hydrogenation metal deposited on an inorganic oxide support and is further characterized by a surface area of greater than about 220 m.sup.2 /g, a pore volume of about 0.23-0.30 cc/g in pores greater than about 600 Angstroms radius, an average pore radius of about 30-70 Angstroms in pores less than 600 Angstroms, and an incremental pore volume curve with a maximum at about 25-50 Angstroms radius.
摘要翻译：加氢处理催化剂和使用这种催化剂的方法，其中这种催化剂具有沉积在无机氧化物载体上的至少一种氢化金属，其进一步特征在于表面积大于约220m 2 / g，孔体积为约0.23-0.30cc / g在大于约600埃半径的孔中，平均孔半径在小于600埃的孔中约30-70埃，以及在约25-50埃半径处具有最大值的增量孔体积曲线。

4. 发明授权

US5071538A Process for regenerating spent heavy hydrocarbon hydroprocessing catalyst 失效
标题翻译：再生废重烃加氢催化剂的工艺
公开(公告)号：US5071538A
公开(公告)日：1991-12-10
申请号：US597012
申请日：1990-10-15
申请人： Frederick T. Clark , Albert L. Hensley, Jr.
发明人： Frederick T. Clark , Albert L. Hensley, Jr.
IPC分类号： B01J23/90 , B01J38/20 , B01J38/64 , C10G49/02
CPC分类号： B01J38/64 , B01J23/90 , B01J38/20 , C10G49/02
摘要： The present invention relates to a spent hydroprocessing catalyst regeneration process wherein the catalyst is subjected to an initial partial decoking step, followed by the addition of at least one rare earth metal, and then subjected to a final decoking step.
摘要翻译：本发明涉及一种废加氢处理催化剂再生方法，其中催化剂经受初始部分脱焦步骤，然后加入至少一种稀土金属，然后进行最终脱焦步骤。

5. 发明授权

US4997799A Process for regenerating spent heavy hydrocarbon hydroprocessing catalyst 失效
标题翻译：再生废重烃加氢催化剂的工艺
公开(公告)号：US4997799A
公开(公告)日：1991-03-05
申请号：US541069
申请日：1990-06-20
申请人： Frederick T. Clark , Albert L. Hensley, Jr.
发明人： Frederick T. Clark , Albert L. Hensley, Jr.
IPC分类号： B01J23/90 , B01J38/20 , B01J38/64 , C10G49/02
CPC分类号： C10G49/02 , B01J23/90 , B01J38/20 , B01J38/64 , Y10S502/517 , Y10S502/521
摘要： The present invention relates to a spent hydroprocessing catalyst regeneration process wherein the catalyst is subjected to an initial partial decoking step, followed by the addition of at least one rare earth metal, and then subjected to a final decoking step.
摘要翻译：本发明涉及一种废加氢处理催化剂再生方法，其中催化剂进行初始部分除焦步骤，然后加入至少一种稀土金属，然后进行最终脱焦步骤。

6. 发明授权

US5154819A Hydroprocessing using regenerated spent heavy hydrocarbon catalyst 失效
标题翻译：使用再生废重烃催化剂进行加氢处理
公开(公告)号：US5154819A
公开(公告)日：1992-10-13
申请号：US597005
申请日：1990-10-15
申请人： Frederick T. Clark , Albert L. Hensley, Jr.
发明人： Frederick T. Clark , Albert L. Hensley, Jr.
IPC分类号： B01J23/90 , B01J38/20 , B01J38/64 , C10G49/02
CPC分类号： C10G49/02 , B01J23/90 , B01J38/20 , B01J38/64 , Y10S502/517 , Y10S502/521
摘要： The present invention relates to a hydroprocessing process that employs a catalyst that has been regenerated by subjecting the catalyst to an initial partial decoking step, followed by impregnation with a Group IIA metal-containing component and then subjected to a final decoking step.
摘要翻译：本发明涉及一种加氢处理方法，其采用通过使催化剂进行初始部分脱焦步骤而再生的催化剂，然后用含IIA族金属的组分浸渍，然后进行最终的脱焦步骤。

7. 发明授权

US5087596A Process for regenerating spent heavy hydrocarbon hydroprocessing catalyst 失效
标题翻译：再生废重烃加氢催化剂的工艺
公开(公告)号：US5087596A
公开(公告)日：1992-02-11
申请号：US541616
申请日：1990-06-21
申请人： Frederick T. Clark , Albert L. Hensley, Jr.
发明人： Frederick T. Clark , Albert L. Hensley, Jr.
IPC分类号： B01J23/92 , B01J23/94 , B01J38/20 , B01J38/68 , C10G49/04
CPC分类号： C10G49/04 , B01J23/92 , B01J23/94 , B01J38/20 , B01J38/68
摘要： The present invention relates to a spent hydroprocessing catalyst regeneration process wherein the catalyst is subjected to an initial partial decoking step, followed by impregnation with a Group VIB metal-containing component, and then subjected to a final decoking step.
摘要翻译：本发明涉及一种废加氢处理催化剂再生方法，其中催化剂进行初始部分脱焦步骤，随后用含VIB族金属组分浸渍，然后进行最终脱焦步骤。

8. 发明授权

US4994423A Process for regenerating spent heavy hydrocarbon hydroprocessing catalyst 失效
标题翻译：再生废重烃加氢催化剂的工艺
公开(公告)号：US4994423A
公开(公告)日：1991-02-19
申请号：US529192
申请日：1990-05-25
申请人： Frederick T. Clark , Albert L. Hensley, Jr.
发明人： Frederick T. Clark , Albert L. Hensley, Jr.
IPC分类号： B01J23/90 , B01J38/20 , B01J38/64 , C10G49/02
CPC分类号： B01J23/90 , B01J38/20 , B01J38/64 , C10G49/02 , Y10S502/517 , Y10S502/521
摘要： The present invention relates to a spent hydroprocessing catalyst regeneration process wherein the catalyst is subjected to an initial partial decoking step, followed by impregnation with a Group IIA metal-containing component, and then subjected to a final decoking step.
摘要翻译：本发明涉及一种废加氢处理催化剂再生方法，其中催化剂进行初始部分脱焦步骤，然后用含IIA族金属的组分浸渍，然后进行最终脱焦步骤。

9. 发明授权

US5275990A Process for regenerating a spent resid hydroprocessing catalyst using a group IIA metal 失效
标题翻译：使用IIA族金属再生废渣加氢处理催化剂的方法
公开(公告)号：US5275990A
公开(公告)日：1994-01-04
申请号：US955496
申请日：1992-10-02
申请人： Frederick T. Clark , Albert L. Hensley, Jr.
发明人： Frederick T. Clark , Albert L. Hensley, Jr.
IPC分类号： B01J23/94 , B01J38/20 , C10G49/12 , B01J20/20 , B01J38/34 , C10G45/16
CPC分类号： B01J23/94 , B01J38/20 , C10G49/12 , Y10S502/521
摘要： A method is provided for regenerating a molecular sieve-free resid hydroprocessing catalyst for use with an ebullated bed reaction process comprising at least one hydrogenation metal and at least one Group IIA metal deposited on an inorganic oxide support wherein the catalyst contains a pore volume of pores having a diameter greater than 1200 Angstroms of at least 0.05 cc/gm. The method comprises the steps of contacting the molecular sieve-free resid hydroprocessing catalyst with a contaminant metal-containing hydrocarbon feedstream in a first contacting step at conditions sufficient to deposit contaminant metals and coke onto the catalyst; and contacting the coke-deactivated, contaminant metal-containing, molecular sieve-free catalyst with an oxygen-containing gas in a second contacting step at oxidation conditions sufficient to remove a substantial amount of the coke from the coke-deactivated, contaminant metal-containing, molecular sieve-free catalyst. The loss on attrition of the regenerated molecular sieve-free resid hydroprocessing catalyst after the second contacting step is less than 10 weight percent fines per day calculated based on a regeneration temperature of about 900.degree. F.
摘要翻译：提供了一种用于再生无分子筛余渣加氢催化剂的方法，该催化剂与沸腾床反应方法一起使用，该方法包括至少一种氢化金属和沉积在无机氧化物载体上的至少一种IIA族金属，其中催化剂含有孔体积的孔直径大于1200埃至少为0.05cc / gm。该方法包括以下步骤：在足以将污染金属和焦炭沉积到催化剂上的条件下，在第一接触步骤中使无分子筛的残渣加氢处理催化剂与含污染金属的烃进料流接触; 并在第二接触步骤中使氧化条件下使含焦炭失活的含金属的不含分子筛的催化剂与含氧气体接触，所述氧化条件足以从焦炭失活的含杂质金属中除去大量的焦炭，无分子筛的催化剂。基于再生温度约900华氏度，在第二次接触步骤之后再生的不含分子筛的残渣加氢处理催化剂的磨损损失小于每天10重量％的细粉。

10. 发明授权

US5338878A Alkyl carbonate extraction process 失效
标题翻译：烷基碳酸酯萃取工艺
公开(公告)号：US5338878A
公开(公告)日：1994-08-16
申请号：US11246
申请日：1993-01-29
申请人： Michael A. Pacheco , Franklin D. Darrington , Albert L. Hensley, Jr.
发明人： Michael A. Pacheco , Franklin D. Darrington , Albert L. Hensley, Jr.
IPC分类号： C07C68/08 , C07C69/96
CPC分类号： C07C68/005 , C07C68/08
摘要： A process is provided for separating alkyl carbonate from a feedstock comprising at least one alkyl carbonate and at least one alkanol comprising extracting the alkyl carbonate from the feedstock in a liquid-liquid extraction step comprising a first extraction solvent comprising hydrocarbon selective for extracting alkyl carbonates relative to alkanol in an amount sufficient to extract a substantial portion of the alkyl carbonate from the feedstock and a second solvent comprising water in an amount sufficient to extract a substantial portion of the alkanol from the feedstock.
摘要翻译：提供了一种从包含至少一种碳酸烷基酯和至少一种链烷醇的原料分离碳酸酯的方法，其包括在液 - 液萃取步骤中从原料中提取碳酸烷基酯，所述液 - 液萃取步骤包括第一提取溶剂，所述第一萃取溶剂包含选择性烃，用于提取相对于以足以从原料中提取大部分碳酸烷基酯的量的链烷醇和含有足以从原料中提取大部分烷醇的量的水的第二溶剂。

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