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1. 发明授权

US4954664A Process for the direct hydrogenation of butterfat 失效
标题翻译：乳脂直接氢化工艺
公开(公告)号：US4954664A
公开(公告)日：1990-09-04
申请号：US470428
申请日：1990-01-25
申请人： Franz-Josef Carduck , Juergen Falbe , Theo Fleckenstein , Gerd Goebel , Joachim Pohl
发明人： Franz-Josef Carduck , Juergen Falbe , Theo Fleckenstein , Gerd Goebel , Joachim Pohl
IPC分类号： C07C29/149 , C11C3/12
CPC分类号： C07C29/149 , C07C29/177 , C11C3/126
摘要： A process for the catalytic hydrogenation of butterfat where non-deacidified butterfat is continuously reacted with hydrogen under pressures of from 20 to 300 bar and at temperatures of from 180.degree. to 250.degree. C. with molar ratios of hydrogen to fatty acid residue in the butterfat of from 10:1 to 500:1. The reaction is carried out over catalysts which contain from 30 to 40% by weight copper, from 23 to 30% by weight chromium, from 1 to 10% by weight manganese, from 1 to 10% by weight silicon, and from 1 to 7% by weight barium. The percentages by weight in each case are based on the total oxidic mass of the catalyst. Other transition metals, especially zirconium and cerium, are additionally incorporated into the catalyst. The metals in the catalyst are converted to their oxides by calcination. The catalyst is converted into shaped particulate or granulated elements with from 1 to 10% by weight of at least one binder in addition to 1 to 10% by weight graphite. The catalyst is activated with hydrogen or a hydrogen-containing gas mixture.The reaction products include alcohols, oxo- and hydroxyfatty alcohols corresponding to the natural fatty acid composition of the butterfat and the desired, valuable product, propylene glycol. This process is advantageous since it eliminates the need for preseparation of the relatively short-chain fatty acids (or deacidification) of the butterfat prior to hydrogenation.
摘要翻译：一种用于催化加氢的方法，其中非脱酸乳脂在20-300巴的压力和180-250℃的温度下与氢气连续地与氢气与脂肪酸残余物的摩尔比连续地反应为10：1至500：1。反应在含有30-40重量％铜，23-30重量％铬，1-10重量％的锰，1-10重量％的硅和1至7的催化剂上进行重量％的钡。在每种情况下，重量百分比是基于催化剂的总氧化质量。其他过渡金属，特别是锆和铈也被并入催化剂中。通过煅烧将催化剂中的金属转化为它们的氧化物。除了1至10重量％的石墨之外，催化剂转化为具有1-10重量％的至少一种粘合剂的成型颗粒或颗粒状元素。催化剂用氢气或含氢气体混合物活化。反应产物包括对应于乳脂的天然脂肪酸组合物和所需有价值的产物丙二醇的醇，氧代和羟基脂肪醇。该方法是有利的，因为它消除了在氢化之前预先分离乳脂相对短链脂肪酸（或脱酸）的需要。

2. 发明授权

US4982020A Process for direct hydrogenation of glyceride oils 失效
标题翻译：甘油酯油的直接氢化方法
公开(公告)号：US4982020A
公开(公告)日：1991-01-01
申请号：US453021
申请日：1989-12-20
申请人： Franz-Josef Carduck , Jurgen Falbe , Theo Fleckenstein , Joachim Pohl
发明人： Franz-Josef Carduck , Jurgen Falbe , Theo Fleckenstein , Joachim Pohl
IPC分类号： B01J23/86 , C07B61/00 , C07C27/00 , C07C29/136 , C07C29/149 , C07C29/17 , C07C31/125 , C07C31/20 , C07C67/00 , C11C3/12
CPC分类号： C07C29/60 , B01J23/868 , C07C29/149 , C07C29/177 , C11C3/126 , Y02P20/52
摘要： In the direct catalytic hydrogenation of glyceride oils, the glyceride oils are continuously reacted with hydrogen under pressures of from 20 to 300 bar and at temperatures of from 160.degree. to 250.degree. C. with molar ratios of hydrogen to fatty acid residues in the glyceride oil substrate of from 10:1 to 500:1, the reaction being carried out over catalysts which contain from 30 to 40% by weight copper, from 23 to 30% by weight chromium, from 1 to 7% by weight barium (% by weight, based in each case on oxidic catalyst mass) and, if desired, other transition metals in the form of their oxides and which, after calcination of the components forming the catalyst mass, are converted into shaped particulate and/or granulated elements with from 1 to 10% by weight, based on oxidic catalyst, of at least one binder, and which have been activated with hydrogen or a hydrogen-containing gas mixture.
摘要翻译：在甘油酯油的直接催化氢化中，甘油酯油在20-300巴的压力和160-250℃的温度下与氢气连续反应，甘油酯油中的氢与脂肪酸残基的摩尔比底物为10：1至500：1，反应在含有30至40重量％铜，23至30重量％铬，1至7重量％钡（重量％基于每种情况下的氧化催化剂质量），并且如果需要，其氧化物形式的其它过渡金属，并且在形成催化剂物质的组分的煅烧之后，将其转化为成形颗粒和/或颗粒状元素，其中1 至少10重量％，基于氧化催化剂，至少一种粘合剂，并已经用氢气或含氢气体混合物活化。

3. 发明授权

US4855273A Acid-resistant catalysts for the direct hydrogenation of fatty acids to fatty alcohols 失效
标题翻译：用于脂肪酸直接氢化成脂肪醇的耐酸催化剂
公开(公告)号：US4855273A
公开(公告)日：1989-08-08
申请号：US162537
申请日：1988-03-01
申请人： Joachim Pohl , Franz-Josef Carduck , Gerd Goebel
发明人： Joachim Pohl , Franz-Josef Carduck , Gerd Goebel
IPC分类号： B01J23/86 , C07C27/00 , C07C29/149 , C07C31/125 , C07C67/00
CPC分类号： B01J23/868 , C07C29/149 , Y02P20/52 , Y02P20/582 , Y10S502/524
摘要： Process for the production of a new copper (II) chromite spinel catalyst using colloidal silica gel and to its use for the direct fixed-bed hydrogenation of fatty acids to fatty alcohols of corresponding chain length.
摘要翻译：用于生产使用胶体硅胶的新型（II）亚铬酸铁尖晶石催化剂的方法及其用于将脂肪酸直接固定床氢化成相应链长的脂肪醇的方法。

4. 发明授权

US4794098A Process for the stabilization of activated catalyst masses 失效
标题翻译：稳定活性催化剂物质的方法
公开(公告)号：US4794098A
公开(公告)日：1988-12-27
申请号：US62275
申请日：1987-06-15
申请人： Joachim Pohl , Franz-Josef Carduck , Gerd Goebel
发明人： Joachim Pohl , Franz-Josef Carduck , Gerd Goebel
IPC分类号： B01J23/80 , B01J23/86 , B01J23/94 , B01J33/00 , B01J37/00 , B01J31/26
CPC分类号： B01J33/00 , B01J37/00 , Y10S502/50
摘要： A process for the stabilization of particulate, activated catalyst masses after the activation of the starting catalyst masses in a gas stream, wherein the particulate, activated catalyst masses are removed from the activation reactor in an inert gas atmosphere into a liquid alcohol or a mixture of two or more alcohols which are straight-chain or branched-chain alcohols containing from 6 to 12 carbon atoms in the alkyl radical, stabilizing the catalyst masses by impregnation with the alcohol or the alcohol mixture, optionally storing and/or transporting the alcohol-impregnated catalyst masses, removing excess alcohol, sieving the alcohol-moist catalyst mass, and introducing the catalyst mass into a catalysis reactor to form a catalyst filling.
摘要翻译：一种在气流中活化起始催化剂物质之后稳定颗粒状活化催化剂块的方法，其中将颗粒活化的催化剂物质在惰性气体气氛中从活化反应器中除去至液态醇或混合物两个或多个醇，其是在烷基中含有6至12个碳原子的直链或支链醇，通过用醇或醇混合物浸渍来稳定催化剂质量，任选地存储和/或运输醇浸渍催化剂质量，去除过量的醇，筛分醇 - 湿催化剂物质，并将催化剂物质引入催化反应器中以形成催化剂填充物。

5. 发明授权

US5294583A Use of colloidal silica sol as an auxiliary for catalysts 失效
标题翻译：使用胶体硅溶胶作为催化剂的辅助剂
公开(公告)号：US5294583A
公开(公告)日：1994-03-15
申请号：US890603
申请日：1992-09-14
申请人： Joachim Pohl , Gerd Goebel , Franz-Josef Carduck
发明人： Joachim Pohl , Gerd Goebel , Franz-Josef Carduck
IPC分类号： B01J21/12 , B01J37/00 , B01J21/08
CPC分类号： B01J21/12 , B01J37/0009
摘要： The invention relates to the use of colloidal, stabilized silica sol as an auxiliary for stabilizing and/or increasing the activity of catalysts which show a tendency towards activity-reducing sintering under high-temperature conditions.
摘要翻译： PCT No.PCT / EP90 / 02289 371日期：1992年9月14日 102（e）日期1992年9月14日PCT 1990年12月21日PCT PCT。 WO91 / 10509 PCT出版物日期：1991年7月25日。本发明涉及胶态稳定二氧化硅溶胶作为辅助剂用于稳定和/或提高催化剂活性的用途，其在高温条件下显示出降低活性的烧结趋势。

6. 发明授权

US4935556A Acid-resistant catalysts for the direct hydrogenation of fatty acids to fatty alcohols 失效
标题翻译：用于脂肪酸直接氢化成脂肪醇的耐酸催化剂
公开(公告)号：US4935556A
公开(公告)日：1990-06-19
申请号：US356476
申请日：1989-05-24
申请人： Joachim Pohl , Franz-Josef Carduck , Gerd Goebel
发明人： Joachim Pohl , Franz-Josef Carduck , Gerd Goebel
IPC分类号： B01J23/86 , C07C27/00 , C07C29/149 , C07C31/125 , C07C67/00
CPC分类号： B01J23/868 , C07C29/149 , Y02P20/52 , Y02P20/582 , Y10S502/524
摘要： Process for the production of a new copper (II) chromite spinel catalyst using colloidal silica gel and to its use for the direct fixed-bed hydrogenation of fatty acids to fatty alcohols of corresponding chain length.

7. 发明授权

US5124491A Process for the hydrogenation of fatty acid methyl esters 失效
标题翻译：脂肪酸甲酯氢化方法
公开(公告)号：US5124491A
公开(公告)日：1992-06-23
申请号：US504735
申请日：1990-04-03
申请人： Theo Fleckenstein , Joachim Pohl , Franz J. Carduck
发明人： Theo Fleckenstein , Joachim Pohl , Franz J. Carduck
IPC分类号： B01J35/02 , B01J23/86 , B01J37/00 , B01J37/03 , C07B61/00 , C07C27/00 , C07C29/145 , C07C29/149 , C07C31/125 , C07C33/025 , C07C67/00
CPC分类号： C07C29/149 , Y02P20/52
摘要： In the catalytic hydrogenation of fatty acid methyl esters, the fatty acid methyl esters are continuously reacted with hydrogen under pressures of from 20 to 100 bar and at temperatures of from 160.degree. to 270.degree. C. with molar ratios of hydrogen to fatty acid methyl ester substrate of from 10:1 to 500:1. The reaction is carried out over catalysts which contain from 30 to 40% by weight copper, from 23 to 30% by weight chromium, from 1 to 10% by weight manganese, from 1 to 10% by weight silicon and from 1 to 7% by weight barium (% by weight, based in each case on oxidic catalyst mass) and, if desired, other transition metals in the form of their oxides. After calcination of the components, the catalyst is converted into shaped particulate and/or granulated elements with from 1 to 10% by weight, based on oxidic catalyst, of at least one binder in addition to 1 to 10% by weight graphite. The catalyst is activated with hydrogen or a hydrogen-containing gas mixture. This process enables production of fatty alcohols in high yield from pre-separated distillation cuts of fatty acid methyl esters at low pressures and very low hydrocarbon formation.
摘要翻译：在脂肪酸甲酯的催化氢化中，脂肪酸甲酯在氢气压力为20〜100巴，温度为160〜270℃，氢气与脂肪酸甲酯的摩尔比例下与氢气连续反应底物为10：1至500：1。反应在含有30-40重量％铜，23-30重量％铬，1-10重量％锰，1-10重量％硅和1-7重量％的催化剂上进行，钡（按重量计，基于氧化催化剂的质量），以及如果需要，其氧化物形式的其它过渡金属。在组分煅烧之后，除了1-10重量％的石墨之外，催化剂还可以以至少一种粘合剂为基础，以氧化催化剂为1至10重量％转化为成型颗粒和/或造粒元件。催化剂用氢气或含氢气体混合物活化。该方法能够在低压下预先分离的脂肪酸甲酯蒸馏馏分和非常低的烃形成从高产率生产脂肪醇。

8. 发明授权

US5043485A Process for the hydrogenation of fatty acid methyl ester mixtures 失效
标题翻译：脂肪酸甲酯混合物氢化方法
公开(公告)号：US5043485A
公开(公告)日：1991-08-27
申请号：US464606
申请日：1990-01-11
申请人： Theo Fleckenstein , Joachim Pohl , Franz J. Carduck
发明人： Theo Fleckenstein , Joachim Pohl , Franz J. Carduck
IPC分类号： B01J37/00 , B01J23/86 , B01J35/02 , B01J37/03 , C07B61/00 , C07C27/00 , C07C29/145 , C07C29/149 , C07C31/125 , C07C33/025 , C07C67/00
CPC分类号： C07C29/149 , Y02P20/52
摘要： In the catalytic hydrogenation of fatty acid methyl ester mixtures, the mixtures are continuously reacted with hydrogen under pressures of from 100 to 300 bar and at temperatures of from 160.degree. to 270.degree. C. with molar ratios or hydrogen to fatty acid methyl ester mixture of from 10:1 to 500:1. The reaction is carried out over catalysts which contain from 30 to 40% by weight copper, from 23 to 30% by weight chromium, from 1 to 10% by weight manganese, from 1 to 10% by weight silicon and from 1 to 7% by weight barium (% by weight, based in each case on total weight of the oxidic catalyst) and, if desired, other transition metals in the form of their oxides. After calcination of the components, the catalyst is converted into shaped particulate and/or granulated elements with from 1 to 10% by weight, based on oxidic catalyst, of at least one binder in addition to 1 to 10% by weight graphite. The catalyst is activated with hydrogen or a hydrogen-containing gas mixture. This process enables production of fatty alcohols in high yield from fatty acid methyl ester mixtures containing fatty acid residues in the C.sub.8 to C.sub.22 carbon chain range without prior separation of the mixtures into individual boiling fractions.
摘要翻译：在脂肪酸甲酯混合物的催化氢化中，将混合物在100-300巴的压力和160-270℃的温度下与摩尔比或氢气与氢气的脂肪酸甲酯混合物连续地与氢气反应，从10：1到500：1。反应在含有30至40重量％的铜，23至30重量％的铬，1至10重量％的锰，1至10重量％的硅和1至7重量％的催化剂上进行，钡（以每种情况为基础，基于氧化催化剂的总重量）和如果需要，其氧化物形式的其它过渡金属。在组分煅烧之后，除了1-10重量％的石墨之外，催化剂还可以以至少一种粘合剂为基础，以氧化催化剂为1至10重量％转化为成型颗粒和/或造粒元件。催化剂用氢气或含氢气体混合物活化。该方法可以从C8-C22碳链范围内含有脂肪酸残基的脂肪酸甲酯混合物高产率生产脂肪醇，而无需将混合物预先分离成单独的沸腾馏分。

9. 发明申请

US20100144519A1 METHOD FOR PRODUCING STABLE, HIGH-PURITY MOLDED BODIES FROM PYROGENIC METAL OXIDES WITHOUT THE ADDITION OF BINDERS 有权
标题翻译：在不添加粘合剂的情况下，从含磷金属氧化物生产稳定的高纯度模塑体的方法
公开(公告)号：US20100144519A1
公开(公告)日：2010-06-10
申请号：US12518522
申请日：2007-12-06
申请人： Roland Heidenreich , Hans-Jurgen Eberle , Torsten Gottschalk-Gaudig , Johann Weis , Joachim Pohl
发明人： Roland Heidenreich , Hans-Jurgen Eberle , Torsten Gottschalk-Gaudig , Johann Weis , Joachim Pohl
IPC分类号： B01J21/08 , B01J27/24 , B01J21/04 , B01J23/10 , B01J21/06
CPC分类号： B01J23/44 , B01J21/04 , B01J21/08 , B01J23/52 , B01J23/58 , B01J23/60 , B01J23/66 , B01J35/1019 , B01J35/1047 , B01J37/0009 , B01J37/0036 , C04B35/14 , C04B35/16 , C04B35/18 , C04B35/481 , C04B35/62615 , C04B35/6263 , C04B2235/3217 , C04B2235/3232 , C04B2235/3244 , C04B2235/3418 , C04B2235/5409 , C04B2235/6021 , C04B2235/604 , C04B2235/606 , C04B2235/95
摘要： Shaped bodies with good strength properties are prepared from pyrogenic metal oxide(s) by suspending the metal oxide(s) in a liquid, milling to activate the metal oxide particles, forming an activated homogenous suspension, coagulating the suspension, and forming shaped bodies therefrom.
摘要翻译：通过将金属氧化物悬浮在液体中，研磨以激活金属氧化物颗粒，形成活化的均匀悬浮液，使悬浮液凝结并形成成形体，从热原金属氧化物制备具有良好强度特性的成型体。

10. 发明申请

US20070012796A1 Humidifying device for a humidor 审中-公开
标题翻译：加湿器加湿装置
公开(公告)号：US20070012796A1
公开(公告)日：2007-01-18
申请号：US10572494
申请日：2004-09-17
申请人： Joachim Pohl
发明人： Joachim Pohl
IPC分类号： A24F25/00 , A61L9/04
CPC分类号： A24F25/02
摘要： The invention relates to a humidifying device for a humidor, comprising a humidity reservoir (9) from which the humidity that is discharged from the same can be directed within the interior of the humidor by means of evaporation ports (8a -8d) of the humidifying device (1). Said humidifying device (1) further comprises a fan (7), with the aid of which an air flow can be generated that allows the humidity to be conveyed into the interior of the humidor. A housing (2) of the humidifying device (1) is provided with a suction port (6) for the fan (7). According to the invention, the evaporation ports (8a-8d) are located in a lid (3) of the housing (2) of the humidifying device (1), the humidity reservoir (9) is disposed below the evaporation ports (8a-8d), and the air flow generated by the impeller (7a) of the fan (7) runs towards at least one of the evaporation ports (8a-8d) within the housing (2) of the humidifying device (1) such that the air flow is directed to the humidity reservoir (9) essentially parallel to the bottom side of the lid (3) of the housing (2) of the humidifying device (1), sweeps across the surface (9) of the humidity reservoir (9) while entraining the humidity discharged from the same, and flows out of the housing (2) through at least one of the evaporation ports (8a-8d).
摘要翻译：本发明涉及一种用于加湿器的加湿装置，包括一个湿度贮存器（9），从该湿度贮存器（9）可以通过蒸发端口（8a--8d）将从其中排出的湿度引导到加湿器内部，加湿装置（1）。所述加湿装置（1）还包括风扇（7），借助于该风扇可以产生允许湿气被输送到加湿器内部的气流。加湿装置（1）的壳体（2）设置有用于风扇（7）的吸入口（6）。根据本发明，蒸发端口（8a-8d）位于加湿装置（1）的壳体（2）的盖（3）中，湿气储存器（9）设置在蒸发端口并且由风扇（7）的叶轮（7a）产生的空气流朝向加湿器的壳体（2）内的至少一个蒸发端口（8a--8d）延伸装置（1），使得空气流被引导到基本平行于加湿装置（1）的壳体（2）的盖子（3）的底侧的湿气储存器（9），扫过表面（9）），同时夹带从其中排出的湿气，并通过至少一个蒸发端口（8a-8d）从壳体（2）流出。

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