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1. 发明授权

US6080830A Products of the reaction between isocyanates and hydroxyl compounds for textile finishing 失效
标题翻译：异氰酸酯和羟基化合物之间的反应的产物用于织物整理
公开(公告)号：US6080830A
公开(公告)日：2000-06-27
申请号：US60689
申请日：1998-04-15
申请人： Franz Dirschl , Franz Mosch , Theodor Angele , Wilhelm Artner , Edeltraud Schidek , Erich Rossler
发明人： Franz Dirschl , Franz Mosch , Theodor Angele , Wilhelm Artner , Edeltraud Schidek , Erich Rossler
IPC分类号： C08L75/04 , C08G18/08 , C08G18/10 , C08G18/32 , C08G18/80 , D06M15/277 , D06M15/564 , D06M15/568 , D06M15/576 , D06M101/00 , D06M101/02 , D06M101/12 , D06M101/16
CPC分类号： D06M15/576 , C08G18/0814 , C08G18/0866 , C08G18/10 , C08G18/3275 , C08G18/8035 , D06M15/277 , D06M15/564 , D06M15/568
摘要： Products which are produced by reaction of diisocyanates with di- or polyhydric alcohols and/or with one or more mono- and/or diethers of such alcohols and subsequent reaction with organic amines containing two or more alcoholic hydroxyl groups and subsequent blocking of free isocyanate groups are suitable for the finishing of fiber materials, in particular in the form of aqueous dispersions as extenders for use in combination with polymers containing perfluoroalkyl groups for the oil-, water- and soil-repellent finishing of fiber materials.
摘要翻译：通过二异氰酸酯与二元醇或多元醇和/或与这些醇的一个或多个单醚和/或二醚反应制备的产物，随后与含有两个或多个醇羟基的有机胺反应并随后封闭游离异氰酸酯基适用于纤维材料的整理，特别是水性分散体的形式，作为用于与含有全氟烷基的聚合物组合的增量剂的形式用于纤维材料的油，水和污垢排斥整理。

2. 发明授权

US06306958B1 Aqueous dispersions for textile finishing 有权
标题翻译：用于纺织品整理的水性分散体
公开(公告)号：US06306958B1
公开(公告)日：2001-10-23
申请号：US09465867
申请日：1999-12-16
申请人： Franz Dirschl , Franz Mosch , Wilhelm Artner , Edeltraud Schidek , Heinz Gaugenrieder , Simpert Lüdemann , Erich Rössler
发明人： Franz Dirschl , Franz Mosch , Wilhelm Artner , Edeltraud Schidek , Heinz Gaugenrieder , Simpert Lüdemann , Erich Rössler
IPC分类号： C08G1880
CPC分类号： C08G18/6279 , C08G18/6423 , C08G18/8029 , C08G18/8077 , D06M13/432 , D06M15/277 , D06M15/423 , D06M15/55 , D06M15/564 , D06M2200/11 , D06M2200/12
摘要： Aqueous dispersions comprising as component A) a compound containing two or more blocked isocyanate groups in the molecule and as component B) a compound obtainable by reacting a diepoxy compound with a diamine or polyamine and subsequently reacting the resulting reaction product with an acid and possibly as component C) a dispersant are suited together with fluorine containing oligomers or polymers for the oil-, water- and soil-repellent finishing of fiber materials.
摘要翻译：包含作为组分A）的水分散体在分子中含有两个或多个封端异氰酸酯基团的化合物和作为组分B）通过使二环氧化合物与二胺或多胺反应得到的化合物，随后使所得反应产物与酸反应，并且可能为组分C）分散剂与含氟低聚物或聚合物一起适用于纤维材料的油，水和拒污整理。

3. 发明授权

US06387999B1 Compositions for the oil and water repellent finishing of fiber materials 有权
标题翻译：纤维材料防油整理的组合物
公开(公告)号：US06387999B1
公开(公告)日：2002-05-14
申请号：US09669466
申请日：2000-09-25
申请人： Franz Dirschl , Simpert Lüdemann , Edeltraud Schidek , Heinz Gaugenrieder , Wilhelm Artner
发明人： Franz Dirschl , Simpert Lüdemann , Edeltraud Schidek , Heinz Gaugenrieder , Wilhelm Artner
IPC分类号： C08L5100
CPC分类号： D06M15/653 , C08G18/10 , C08G18/46 , C08L33/06 , C08L67/00 , C08L75/04 , D06M13/148 , D06M13/224 , D06M13/236 , D06M13/425 , D06M15/277 , D06M15/564 , D06M15/568 , D06M15/576 , D06M2200/11 , D06M2200/12 , C08G18/8077 , C08L2666/02
摘要： Compositions comprising an ester with perfluoroalkyl groups and an oligo- or polyurethane which may likewise contain perfluoroalkyl groups are useful for the oil and water repellant finishing of sheetlike textile materials. The compositions may additionally include acrylic polymers having perfluoroalkyl groups and extenders. Especially the use of nonionic aqueous dispersions of the compositions makes it possible to obtain textiles with little if any effect losses after mechanical abrasion and good LAD effects.
摘要翻译：包含具有全氟烷基的酯和同样含有全氟烷基的低聚物或聚氨酯的组合物可用于片状纺织材料的防水和防水处理。组合物还可以包括具有全氟烷基和增量剂的丙烯酸聚合物。特别是使用组合物的非离子水性分散体使得可以获得在机械磨损和良好的LAD效应后几乎没有效果损失的纺织品。

4. 发明授权

US07053148B2 Compositions of polysiloxanes, fluoropolymers extenders 有权
标题翻译：聚硅氧烷，含氟聚合物增强剂的组合物
公开(公告)号：US07053148B2
公开(公告)日：2006-05-30
申请号：US10479946
申请日：2002-08-03
申请人： Franz Dirschl , Edeltraud Schidek , Thu Thao Reimann-Dang , Rolf Moors , Simpert Lüdemann , Wilhelm Artner , Heinz Gaugenrieder
发明人： Franz Dirschl , Edeltraud Schidek , Thu Thao Reimann-Dang , Rolf Moors , Simpert Lüdemann , Wilhelm Artner , Heinz Gaugenrieder
IPC分类号： C08L83/04
CPC分类号： C08G18/8077 , C08G18/61 , C08G18/6279
摘要： Fiber materials in the form of fabrics receive, as a result of treatment with compositions according to the invention, a pleasant soft hand and excellent oil-and water-repelling properties with good permanence. The compositions can be obtained by a) preparing a solution of a polysiloxane and an extender with blocked isocyanate groups in an organic solvent, b) dispersing this solution in water, c) removing the organic solvent and d) combining the aqueous dispersion obtained with a second aqueous dispersion which comprises a polymer with perfluoroalkyl groups. One variant of this preparation process consists in cousing a polymer with perfluoroalkyl groups as early as in step a). In this case, step d) can be omitted.
摘要翻译：织物形式的纤维材料作为根据本发明的组合物处理的结果，可以获得令人愉悦的柔软手感和优异的耐油和防水性能，具有良好的持久性。组合物可以通过以下方法获得：a）在有机溶剂中制备聚硅氧烷和具有封端异氰酸酯基团的增量剂的溶液，b）将该溶液分散在水中，c）除去有机溶剂，d）将得到的水分散体第二水分散体，其包含具有全氟烷基的聚合物。该制备方法的一个变体是早在步骤a）中将聚合物与全氟烷基基团共聚。在这种情况下，步骤d）可以省略。

5. 发明授权

US5562761A Compositions, containing organic silicon compounds, for the treatment of fibre materials 失效
标题翻译：含有机硅化合物的组合物，用于处理纤维材料
公开(公告)号：US5562761A
公开(公告)日：1996-10-08
申请号：US579640
申请日：1995-12-27
申请人： Franz Dirschl , Harald Chrobaczek , Rainer Augart , Hans-Ludwig Kienle , Jurgen Uhl
发明人： Franz Dirschl , Harald Chrobaczek , Rainer Augart , Hans-Ludwig Kienle , Jurgen Uhl
IPC分类号： D06M13/02 , C08J3/03 , C08K5/544 , C08K5/549 , C08L83/04 , D06M13/51 , D06M13/513 , D06M15/643 , D06M15/647 , D06N3/12 , C08G77/04 , C09K3/18 , D06M13/50
CPC分类号： C08J3/03 , D06M15/6436 , D06M15/647 , D06N3/128 , C08J2383/04
摘要： Compositions in the form of aqueous dispersions which contain dihydroxypolyorganosiloxanes, amino-functional silanes and cyclic oligosiloxanes and/or reaction products of these components, are suitable for coating sheet materials made of fiber materials. This confers, to the sheet materials, good waterproofness properties with good permanency of the waterproofness, good low-temperature flexibility and springiness.
摘要翻译：含有二羟基聚有机硅氧烷，氨基官能硅烷和环状低聚硅氧烷的水性分散体和/或这些组分的反应产物的组合物适用于涂覆由纤维材料制成的片材。这对于片材材料具有良好的防水性能，具有良好的耐久性，防水性，良好的低温柔韧性和弹性。

6. 发明授权

US5196260A Process for the treatment of fibrous materials with modified organopolysiloxanes and the materials 失效
标题翻译：用改性有机聚硅氧烷和材料处理纤维材料的方法
公开(公告)号：US5196260A
公开(公告)日：1993-03-23
申请号：US892387
申请日：1992-05-27
申请人： Franz Dirschl , Jurgen Uhl , Michael Bernheim
发明人： Franz Dirschl , Jurgen Uhl , Michael Bernheim
IPC分类号： D06M15/356 , D06N3/12
CPC分类号： D06N3/128 , D06M15/3568 , Y10T428/31663 , Y10T442/218 , Y10T442/223 , Y10T442/2352
摘要： The present invention relates to a process for the treatment of fibrous materials with modified organopolysiloxanes, wherein, in an aqueous medium, an organopolysiloxane copolymer prepared in a first stage from customary cyclic siloxanes (A) and unsaturated silanes (B) in the presence of a crosslinking agent and emulsifier (1) is copolymerized in a second stage with at least one vinyl monomer in the presence of emulsifiers (2), and the resulting dispersion of the modified organopolysiloxane copolymer is applied to the material in the customary manner and the material is dried and subjected to condensation.The process has the advantage that the materials, in particular textiles, treated by the process, above all coated by the process, have very good waterproof properties and at the same time good to very good water repellency. However, the materials are simultaneously distinguished by a pleasant soft handle, without the degree of whiteness thereof being noticeably impaired.
摘要翻译：本发明涉及一种用改性有机聚硅氧烷处理纤维材料的方法，其中在水性介质中，在常规环状硅氧烷（A）和不饱和硅烷（B）的第一阶段中制备的有机聚硅氧烷共聚物在交联剂和乳化剂（1）在乳化剂（2）的存在下在第二阶段与至少一种乙烯基单体共聚，并且将所得改性的有机聚硅氧烷共聚物的分散体以常规方式施加到材料上，并且材料是干燥并冷凝。该方法的优点是，通过该方法处理的材料，特别是纺织品，首先通过该方法涂覆，具有非常好的防水性能，同时具有非常好的防水性。然而，这些材料同时通过舒适的柔软手柄来区分，而白度却明显受损。

7. 发明授权

US06803407B2 Polyorganosiloxanes having alkoxylated side chains 失效
标题翻译：具有烷氧基化侧链的聚有机硅氧烷
公开(公告)号：US06803407B2
公开(公告)日：2004-10-12
申请号：US10221614
申请日：2002-09-13
申请人： Harald Chrobaczek , Franz Dirschl , Ralf Goretzki , Günther Tschida
发明人： Harald Chrobaczek , Franz Dirschl , Ralf Goretzki , Günther Tschida
IPC分类号： C08L8310
CPC分类号： D06M13/144 , C08G77/46 , D06M11/38 , D06M15/6436 , D06M15/647
摘要： Described are polysiloxane compositions that are obtainable in 2 steps. The first step comprises reacting a linear organopolysiloxane which contains Si—H bonds with a compound that has a terminal C═C double bond and a polyoxyalkylene chain. This reaction is carried out in such a way that Si—H bonds are still present in the resultant product. The second step comprises adding a base or water and an acid to the resultant product. The hydrophilic properties of the resultant polysiloxane compositions can be influenced in a specific manner. The compositions are useful for treating fiber materials, especially textile fabrics. The effects obtained are notable for good durability. Further groups may be incorporated into the polysiloxanes to open up further applications.
摘要翻译：描述的是可以2个步骤获得的聚硅氧烷组合物。第一步包括使含有Si-H键的直链有机聚硅氧烷与具有C = C末端的化合物和聚氧化烯链反应。该反应以所得产物中仍然存在Si-H键的方式进行。第二步包括向所得产物中加入碱或水和酸。所得聚硅氧烷组合物的亲水性能可以以特定方式影响。该组合物可用于处理纤维材料，特别是纺织织物。获得的效果值得注意，以获得良好的耐久性。可以将其它基团并入聚硅氧烷中以开发进一步的应用。

8. 发明授权

US06566470B2 Fluorinated polymeric paper sizes and soil-release agents 失效
公开(公告)号：US06566470B2
公开(公告)日：2003-05-20
申请号：US09834773
申请日：2001-04-12
申请人： Shobha Kantamneni , Franz Dirschl
发明人： Shobha Kantamneni , Franz Dirschl
IPC分类号： C08F11800
CPC分类号： C08F220/56 , C08F220/24 , Y10T428/253 , Y10T428/31544 , Y10T428/3188 , Y10T428/31891 , Y10T442/2779 , Y10T442/2787 , Y10T442/2893 , Y10T442/291
摘要： Novel fluorine-containing paper sizes which impart oil and grease resistance to paper and soil-release properties to textile products are described which are the copolymerization products of (a) a perfluoroalkyl-substituted (meth)acrylate or (meth)acrylamide, (b) a secondary- or tertiary-amino or quaternary ammonium group-containing (meth)acrylate or (meth)acrylamide, (c) vinylidene chloride and, optionally, d) other copolymerizable nonfluorinated vinyl monomers.

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