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    • 1. 发明授权
    • Detergent formulations comprising at least one water soluble polymer, or salt thereof, bearing a phosphonate group
    • 包含至少一种带有膦酸酯基团的水溶性聚合物或其盐的洗涤剂制剂
    • US06489287B1
    • 2002-12-03
    • US09338304
    • 1999-06-22
    • Francois GauthierYves DucciniDavid WitiakBarry WeinsteinRaymond Porter
    • Francois GauthierYves DucciniDavid WitiakBarry WeinsteinRaymond Porter
    • C11D337
    • C11D3/3784C11D3/3749
    • The invention provides a detergent formulations comprising at least one water soluble polymer, or salt thereof, bearing at least one phosphonate group. Suitable polymers comprise: wherein X is H, Na, K or A; and A is a polymer, copolymer, or water soluble salt thereof, comprising, one or more of the following monomers in polymerized form: carboxylic acids of the formula wherein R1 is H, OH, C1-C9 alkyl or alkoxy or acetoxy or acetate R2 is H, C1-C3 alkyl or alkoxy, COOR3 R3 is H, Na, K or C1-C10 alkyl; hydroxypropyl acrylate, propyl methacrylate, 2-acrylamido-2-propane sulphonic acid, sodium styrene sulphonate, sodium allylsulphonate, sodium methyl sulphonate, vinyl sulphonic acid, and salts thereof; acrylamide, methacrylamide, tert-butylacrylamide, (meth)acrylonitrile, styrene, vinyl acetate allyloxy-2-hydroxypropyl sulphonate and dialkylacrylamide. Machine dish washing detergents and laundry detergents are also provided which comprise detergent formulations of the present invention.
    • 本发明提供了含有至少一种具有至少一个膦酸酯基团的水溶性聚合物或其盐的洗涤剂制剂。 合适的聚合物包括:其中X是H,Na,K或A; 并且A是其聚合物,共聚物或水溶性盐,其包含一种或多种聚合形式的以下单体:式I的羧酸是H,OH,C 1 -C 9烷基或烷氧基或乙酰氧基或乙酸酯,R 2是H, C 1 -C 3烷基或烷氧基,COOR 3 R 3为H,Na,K或C 1 -C 10烷基;丙烯酸羟丙酯,甲基丙烯酸丙酯,2-丙烯酰胺基-2-丙磺酸,苯乙烯磺酸钠,烯丙基磺酸钠,甲基磺酸钠,乙烯基磺酸 ,及其盐; 丙烯酰胺,甲基丙烯酰胺,叔丁基丙烯酰胺,(甲基)丙烯腈,苯乙烯,乙酸乙烯酯,烯丙氧基-2-羟丙基磺酸盐和二烷基丙烯酰胺。还提供了包含本发明洗涤剂配方的机洗餐具洗涤剂和衣物洗涤剂。
    • 2. 发明授权
    • Scale inhibitors
    • 阻垢剂
    • US06395185B1
    • 2002-05-28
    • US09612684
    • 2000-07-10
    • Francois GauthierJan ShulmanBarry WeinsteinAndrea KeenanYves Duccini
    • Francois GauthierJan ShulmanBarry WeinsteinAndrea KeenanYves Duccini
    • C02F100
    • C11D3/3757C02F5/10
    • The invention relates to the inhibition of tripolyphosphate and pyrophosphate scales in aqueous systems involving adding to said aqueous system at least one copolymer comprising the following monomers in polymerized form: (I) 50-80% by weight of one or more weak acids; (II) 2-50% by weight of one or more strong acids; (III) 0-30% by weight of one or more monoethylenically unsaturated C4-C8 dicarboxylic acids; and (IV) 0-30% by weight of one or more monomethylenically unsaturated monomers polymerizable with (I), (II) and (III); wherein the total of monomers (I), (II), (III), and (IV) equals 100% by weight of copolymer. The invention is particularly suited to the inhibition of tripolyphosphate and pyrophosphate scales which occur as a result of using low phosphate (STPP) containing detergent formulations.
    • 本发明涉及在含水体系中抑制三聚磷酸盐和焦磷酸盐垢,包括向所述水性体系中加入至少一种包含聚合形式的以下单体的共聚物:(I)50-80重量%的一种或多种弱酸;(II )2-50重量%的一种或多种强酸;(III)0-30重量%的一种或多种单烯属不饱和C4-C8二羧酸; 和(Ⅳ)0-30重量%的可与(I),(II)和(III)可聚合的一种或多种单甲基不饱和单体;其中单体(I),(II),(III)和( IV)等于100重量%的共聚物。本发明特别适用于由于使用含有低磷酸盐(STPP)的洗涤剂配方而发生的三聚磷酸盐和焦磷酸盐垢的抑制。