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1. 发明申请

US20110258916A1 HYDROCARBON COMPOSITION USEFUL AS FUEL AND COMBUSTIBLE OBTAINED FROM OIL COMPONENTS AND A BIOLOGICAL COMPONENT 审中-公开
标题翻译：油料组合物作为燃料和从油组分和生物组分获得的燃烧有用
公开(公告)号：US20110258916A1
公开(公告)日：2011-10-27
申请号：US13125578
申请日：2009-10-16
申请人： Franco Baldiraghi , Silvia Guanziroli , Giovanni Faraci , Giacomo Rispoli
发明人： Franco Baldiraghi , Silvia Guanziroli , Giovanni Faraci , Giacomo Rispoli
IPC分类号： C10L1/19
CPC分类号： C10G45/00 , C10G3/46 , C10G3/47 , C10G3/49 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/104 , C10G2300/1044 , C10G2300/1059 , C10G2300/301 , C10G2300/304 , C10G2300/307 , C10G2300/308 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/80 , C10G2400/04 , Y02P30/20
摘要： The invention relates to a hydrocarbon composition which can be used as fuel and/or combustible, obtained by means of a process which comprises subjecting a gasoil component, a gasoline component and a component of biological origin to hydrotreatment.
摘要翻译：本发明涉及可用作燃料和/或可燃性的烃组合物，其通过包括使汽油组分，汽油组分和生物来源的组分经受加氢处理的方法获得。

2. 发明申请

US20110239532A1 HYDROCARBON COMPOSITION USEFUL AS A FUEL AND FUEL OIL CONTAINING A PETROLEUM COMPONENT AND A COMPONENT OF A BIOLOGICAL ORIGIN 审中-公开
标题翻译：作为含有石油成分和生物原料成分的燃料和燃油的烃油组合物
公开(公告)号：US20110239532A1
公开(公告)日：2011-10-06
申请号：US12531396
申请日：2008-03-05
申请人： Franco Baldiraghi , Silvia Guanziroli , Giovanni Faraci , Luigina Maria Flora Sabatino , Terry Louise Marker , John Anthony Petri
发明人： Franco Baldiraghi , Silvia Guanziroli , Giovanni Faraci , Luigina Maria Flora Sabatino , Terry Louise Marker , John Anthony Petri
IPC分类号： C10L1/02 , C10L1/04
CPC分类号： C10G65/02 , C10G67/02 , C10G67/14 , C10L1/08 , C10L1/1966 , C10L10/14 , C10L2200/0446 , C10L2200/0484 , C10L2270/026 , C10L2290/542 , Y02E50/13
摘要： The invention relates to a hydrocarbon composition, which can be used as a fuel and/or fuel oil, containing a petroleum component (A) and a component of a biological origin (B), wherein the component of a biological origin is present in a quantity of up to 75% by volume with respect to the total composition. Said component of a biological origin (B) is prepared starting from a mix of a biological origin (C) containing esters of fatty acids, with possible aliquots of free fatty acids, by means of a process which comprises the following steps: 1) hydrodeoxygenation of the mix of a biological origin; 2) hydroisomerization of the mix resulting from step (1), after possible water and gas flow separation, wherein said hydroisomerization is preferably carried out in the presence of a catalytic system comprising: a) a carrier of an acidic nature, comprising a completely amorphous micro-mesoporous silica-alumina, with a SiO2/Al2O3 molar ratio ranging from 30 to 500, a surface area larger than 500 m2/g, a pore volume ranging from 0.3 to 1.3 ml/g, an average pore diameter smaller than 40 A, b) a metal component containing one or more metals of group VIII, possibly mixed with one or more metals of group VIB.
摘要翻译：本发明涉及一种烃组合物，其可用作燃料和/或燃料油，其含有石油成分（A）和生物来源的组分（B），其中生物来源的组分存在于相对于组合物的总量可达75％。生物来源（B）的所述组分由含有脂肪酸酯的生物来源（C）与可能的游离脂肪酸等分试样的混合物通过包括以下步骤的方法制备：1）加氢脱氧的生物来源的组合; 2）在可能的水和气体流分离之后，由步骤（1）得到的混合物的加氢异构化，其中所述加氢异构化优选在催化体系存在下进行，所述催化体系包括：a）酸性载体，其包含完全无定形的微孔介孔二氧化硅 - 氧化铝，SiO 2 / Al 2 O 3摩尔比为30-500，表面积大于500m2 / g，孔体积为0.3-1.3ml / g，平均孔径小于40A ，b）含有一种或多种VIII族金属的金属组分，可能与VIB族的一种或多种金属混合。

3. 发明授权

US08608812B2 Process for producing hydrocarbon fractions from mixtures of a biological origin 有权
$Process for producing hydrocarbon fractions from mixtures of a biological origin$
标题翻译：从生物来源的混合物生产烃馏分的方法
公开(公告)号：US08608812B2
公开(公告)日：2013-12-17
申请号：US12515086
申请日：2007-11-07
申请人： Carlo Perego , Luigina Maria Flora Sabatino , Franco Baldiraghi , Giovanni Faraci
发明人： Carlo Perego , Luigina Maria Flora Sabatino , Franco Baldiraghi , Giovanni Faraci
IPC分类号： C10L1/00
CPC分类号： C10G3/50 , C10G3/46 , C10G3/47 , C10G3/48 , C10G3/49 , C10G3/54 , C10G3/56 , C10G45/60 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/1059 , C10G2300/202 , C10G2300/4018 , C10G2300/4081 , C10G2400/04 , C10L1/08 , C10L2200/0446 , C10L2200/0469 , Y02E50/13 , Y02P30/20
摘要： A process is described for producing hydrocarbon fractions which can be used as diesel fuel or as components of diesel fuel, starting from a mixture of a biological origin containing esters of fatty acids possibly with amounts of free fatty acids, which comprises the following steps: 1) hydrodeoxygenation of the mixture of a biological origin; 2) hydroisomerization of the mixture resulting from step (1), after possible purification treatment, said hydroisomerization being effected in the presence of a catalytic system which comprises: a) a carrier of acid nature comprising a completely amorphous micro-mesoporous silico-alumina having a SiO2/Al2O3 molar ratio ranging from 30 to 500, a surface area greater than 500 m2/g, a pore volume ranging from 0.3 to 1.3 ml/g, an average pore diameter lower than 40 Å, b) a metallic component containing one or more metals of group VIII, possibly mixed with one or more metals of group VIB.
摘要翻译：描述了一种用于生产可用作柴油燃料或作为柴油燃料成分的烃馏分的方法，其起始于含有可能含有游离脂肪酸的脂肪酸酯的生物来源的混合物，其包括以下步骤：1 ）生物来源的混合物的加氢脱氧; 2）由步骤（1）得到的混合物的加氢异构化，在可能的纯化处理之后，所述加氢异构化在催化体系存在下进行，所述催化体系包括：a）酸性载体，其包含完全无定形的微介孔硅 - 氧化铝，其具有 SiO 2 / Al 2 O 3摩尔比为30-500，表面积大于500m2 / g，孔体积为0.3-1.3ml / g，平均孔径低于40，b）含有一个或更多的VIII族金属，可能与VIB族的一种或多种金属混合。

4. 发明申请

US20090077867A1 Production of Diesel Fuel from Renewable Feedstocks with Reduced Hydrogen Consumption 有权
标题翻译：从可再生原料生产柴油，减少氢消耗
公开(公告)号：US20090077867A1
公开(公告)日：2009-03-26
申请号：US12193161
申请日：2008-08-18
申请人： Terry L. Marker , Peter Kokayeff , Giovanni Faraci , Franco Baldiraghi
发明人： Terry L. Marker , Peter Kokayeff , Giovanni Faraci , Franco Baldiraghi
IPC分类号： C10L1/18
CPC分类号： C10L1/08 , C01B3/16 , C01B3/50 , C01B2203/0415 , C01B2203/043 , C01B2203/0455 , C01B2203/0475 , C01B2203/0485 , C01B2203/148 , C10G3/46 , C10G3/52 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/28 , Y02E50/13 , Y02P30/20
摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant and animal fats and oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. Water is added to the deoxygenation reaction to drive carbon monoxide and water to react to form hydrogen and carbon dioxide. The hydrogen is then consumed by the reactions. If desired, the hydrocarbon fraction can be isomerized to improve cold flow properties.
摘要翻译：已经开发了用于从可再生原料如植物和动物脂肪和油生产柴油沸点燃料的方法。该方法包括通过氢化和脱氧处理可再生原料以提供可用作柴油沸程燃料的烃馏分。将水加入脱氧反应中以驱使一氧化碳和水反应形成氢气和二氧化碳。然后氢被反应消耗。如果需要，烃馏分可以被异构化以改善冷流动性能。

5. 发明授权

US6139721A Fluid bed catalytic cracking process characterized by a high selectivity to olefins 失效
标题翻译：流化床催化裂化方法，其特征在于对烯烃的高选择性
公开(公告)号：US6139721A
公开(公告)日：2000-10-31
申请号：US42734
申请日：1998-03-17
申请人： Franco Baldiraghi , Paolo Ferrarini , Giovanni Faraci , Mario Lorenzo Occelli , Sergio Leoncini
发明人： Franco Baldiraghi , Paolo Ferrarini , Giovanni Faraci , Mario Lorenzo Occelli , Sergio Leoncini
IPC分类号： B01J29/06 , B01J29/80 , B01J29/89 , C10G11/05 , C10G11/18 , C10G11/02
CPC分类号： C10G11/05 , B01J29/80 , B01J29/89
摘要： The invention relates to a fluid catalytic cracking process for the preparation of good quality hydrocarbon fractions with a high octane number starting from heavy hydrocarbon fractions of a poorer quality characterized in that the heavy hydrocarbon fraction is put in contact, under cracking conditions, with a catalytic composition comprising a conventional FCC catalyst and a quantity of between 3-60% of a hydrothermally stable microporous material containing titanium.
摘要翻译：本发明涉及一种用于制备具有高辛烷值的优质烃馏分的流化催化裂化方法，其起始于质量较差的重质烃馏分，其特征在于重质烃馏分在裂化条件下与催化剂接触包含常规FCC催化剂的组合物和含有3-60％含钛的水热稳定的微孔材料的量。

6. 发明授权

US07999143B2 Production of diesel fuel from renewable feedstocks with reduced hydrogen consumption 有权
标题翻译：从可再生原料生产柴油，减少氢消耗
公开(公告)号：US07999143B2
公开(公告)日：2011-08-16
申请号：US12193161
申请日：2008-08-18
申请人： Terry L. Marker , Peter Kokayeff , Giovanni Faraci , Franco Baldiraghi
发明人： Terry L. Marker , Peter Kokayeff , Giovanni Faraci , Franco Baldiraghi
IPC分类号： C07C4/00 , C07C5/13
CPC分类号： C10L1/08 , C01B3/16 , C01B3/50 , C01B2203/0415 , C01B2203/043 , C01B2203/0455 , C01B2203/0475 , C01B2203/0485 , C01B2203/148 , C10G3/46 , C10G3/52 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/28 , Y02E50/13 , Y02P30/20
摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant and animal fats and oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. Water is added to the deoxygenation reaction to drive carbon monoxide and water to react to form hydrogen and carbon dioxide. The hydrogen is then consumed by the reactions. If desired, the hydrocarbon fraction can be isomerized to improve cold flow properties.
摘要翻译：已经开发了用于从可再生原料如植物和动物脂肪和油生产柴油沸点燃料的方法。该方法包括通过氢化和脱氧处理可再生原料以提供可用作柴油沸程燃料的烃馏分。将水加入脱氧反应中以驱使一氧化碳和水反应形成氢气和二氧化碳。然后氢被反应消耗。如果需要，烃馏分可以被异构化以改善冷流动性能。

7. 发明申请

US20090300970A1 PROCESS FOR PRODUCING HYDROCARBON FRACTIONS FROM MIXTURES OF A BIOLOGICAL ORIGIN 有权
标题翻译：从生物原料混合物生产烃类的方法
公开(公告)号：US20090300970A1
公开(公告)日：2009-12-10
申请号：US12515086
申请日：2007-11-07
申请人： Carlo Perego , Luigina Maria Flora Sabatino , Franco Baldiraghi , Giovanni Faraci
发明人： Carlo Perego , Luigina Maria Flora Sabatino , Franco Baldiraghi , Giovanni Faraci
IPC分类号： C10L1/00
CPC分类号： C10G3/50 , C10G3/46 , C10G3/47 , C10G3/48 , C10G3/49 , C10G3/54 , C10G3/56 , C10G45/60 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/1059 , C10G2300/202 , C10G2300/4018 , C10G2300/4081 , C10G2400/04 , C10L1/08 , C10L2200/0446 , C10L2200/0469 , Y02E50/13 , Y02P30/20
摘要： A process is described for producing hydrocarbon fractions which can be used as diesel fuel or as components of diesel fuel, starting from a mixture of a biological origin containing esters of fatty acids possibly with amounts of free fatty acids, which comprises the following steps: 1) hydrodeoxygenation of the mixture of a biological origin; 2) hydroisomerization of the mixture resulting from step (1), after possible purification treatment, said hydroisomerization being effected in the presence of a catalytic system which comprises: a) a carrier of acid nature comprising a completely amorphous micro-mesoporous silico-alumina having a SiO2/Al2O3 molar ratio ranging from 30 to 500, a surface area greater than 500 m2/g, a pore volume ranging from 0.3 to 1.3 ml/g, an average pore diameter lower than 40 Å, b) a metallic component containing one or more metals of group VIII, possibly mixed with one or more metals of group VIB.
摘要翻译：描述了一种用于生产可用作柴油燃料或作为柴油燃料成分的烃馏分的方法，其起始于含有可能含有游离脂肪酸的脂肪酸酯的生物来源的混合物，其包括以下步骤：1 ）生物来源的混合物的加氢脱氧; 2）由步骤（1）得到的混合物的加氢异构化，在可能的纯化处理之后，所述加氢异构化在催化体系存在下进行，所述催化体系包括：a）酸性载体，其包含完全无定形的微介孔硅 - 氧化铝，其具有 SiO 2 / Al 2 O 3摩尔比为30-500，表面积大于500m2 / g，孔体积为0.3-1.3ml / g，平均孔径低于40，b）含有一个或更多的VIII族金属，可能与VIB族的一种或多种金属混合。

8. 发明申请

US20100160698A1 PROCESS FOR THE PRODUCTION OF HYDROCARBONS, USEFUL FOR MOTOR VEHICLES, FROM MIXTURES OF A BIOLOGICAL ORIGIN 有权
标题翻译：从生物原料混合物生产汽油车用烃的方法
公开(公告)号：US20100160698A1
公开(公告)日：2010-06-24
申请号：US12637232
申请日：2009-12-14
申请人： Carlo PEREGO , Franco Baldiraghi , Suheil Fares Abdo , Terry Louise Marker , Luigina Maria Flora Sabatino
发明人： Carlo PEREGO , Franco Baldiraghi , Suheil Fares Abdo , Terry Louise Marker , Luigina Maria Flora Sabatino
IPC分类号： C07C1/00 , B01J31/02
CPC分类号： B01J21/12 , B01J23/42 , B01J23/60 , B01J23/62 , B01J23/6482 , B01J23/652 , B01J23/85 , B01J23/883 , B01J27/185 , B01J27/1856 , B01J27/188 , B01J27/198 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0018 , B01J37/036 , B01J37/084 , C10G2300/1011 , C10G2400/04 , C10L1/08 , Y02E50/13 , Y02P30/20
摘要： The present invention describes a process for producing, in a single step, hydrocarbon fractions useful as diesel fuel or as a component of diesel fuel, from a mixture of a biological origin containing esters of fatty acids, and possibly also containing aliquots of free fatty acids. The process comprises the contemporaneous hydrodeoxygenation and hydroisomerization of the mixture of a biological origin, with the formation of linear and branched paraffins. The process is carried out in the presence of a catalytic composition comprising: A) an amorphous carrier of an acidic nature, selected from: (1) an amorphous silica-alumina having a SiO2/Al2O3 molar ratio higher than or equal to 5, (2) a porous solid comprising silicon, aluminium, phosphorus and oxygen bonded together so as to form an amorphous mixed oxide forming a single phase, characterized by a Si/Al atomic ratio ranging from 15 to 250, a P/Al ratio of at least 0.1, but lower than 5, preferably ranging from 0.3 to 3.5, a total pore volume of between 0.5 and 2.0 ml/g, an average pore diameter of between 3 nm and 40 nm and a specific surface area ranging from 200 to 1,000 m2/g, preferably from 300 to 900; B) a metallic component containing one or more metals of group VIII, possibly in a mixture with one or more metals of group VIB. If a catalytic composition consisting of a silica-alumina of type (1) and Pt, is used, the composition is pretreated by means of a hydrocarbon containing 7 to 16 carbon atoms, when the silica-alumina is a completely amorphous, micro-mesoporous silica-allumina (1a) having a SiO2/Al2O3 molar ratio comprised between 30 and 500, a surface area greater than 500 m2/g, a pore volume comprised between 0.3 and 1.3 ml/g, an average pore diameter smaller than 40 Å.
摘要翻译：本发明描述了在一个步骤中，从含有脂肪酸酯的生物来源的混合物中制备可用作柴油燃料或作为柴油燃料成分的烃馏分的方法，并且还可以含有游离脂肪酸等分试样。该方法包括生物来源的混合物的同时加氢脱氧和加氢异构化，形成直链和支链烷烃。该方法在催化组合物的存在下进行，所述催化剂组合物包含：A）酸性的无定形载体，其选自：（1）SiO 2 / Al 2 O 3摩尔比高于或等于5的无定形二氧化硅 - 氧化铝（ 2）包含结合在一起的硅，铝，磷和氧的多孔固体，以形成形成单相的无定形混合氧化物，其特征在于Si / Al原子比为15-250，P / Al比至少 0.1，但小于5，优选为0.3至3.5，总孔体积为0.5至2.0ml / g，平均孔径为3nm至40nm，比表面积为200至1,000m 2 / g，优选为300〜900; B）含有一种或多种第VIII族金属的金属组分，可能与VIB族的一种或多种金属的混合物。如果使用由（1）型的二氧化硅 - 氧化铝和Pt组成的催化剂组合物，则当二氧化硅 - 氧化铝是完全无定形的，微中孔的时，组合物通过含有7至16个碳原子的烃进行预处理 SiO 2 / Al 2 O 3摩尔比在30-500之间的二氧化硅 - 氧化铝（1a），表面积大于500m 2 / g，孔体积在0.3-1.3ml / g之间，平均孔径小于40。

9. 发明申请

US20090193709A1 Production of Diesel Fuel from Biorenewable Feedstocks with Lower Hydrogen Consumption 有权
标题翻译：生产可燃低原料的生物可利用原料柴油
公开(公告)号：US20090193709A1
公开(公告)日：2009-08-06
申请号：US12193120
申请日：2008-08-18
申请人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Franco Baldiraghi , Luigina M.F. Sabatino
发明人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Franco Baldiraghi , Luigina M.F. Sabatino
IPC分类号： C10L1/18
CPC分类号： C10L1/08 , C01B3/16 , C01B3/50 , C01B2203/0415 , C01B2203/043 , C01B2203/0455 , C01B2203/0475 , C01B2203/0485 , C01B2203/148 , C10G3/46 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/202 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/28 , Y02E50/13 , Y02P30/20
摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant and animal fats and oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating i.e. decarboxylating, decarbonylating, and hydrodeoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. A sulfur containing component is added to drive the conversion preferentially through carbonylation and carbonylation with reduced hydrodeoxygenation. If desired, the hydrocarbon fraction can be isomerized to improve cold flow properties.
摘要翻译：已经开发了用于从可再生原料如植物和动物脂肪和油生产柴油沸点燃料的方法。该方法包括通过氢化和脱氧处理可再生原料，即脱羧，脱羰和加氢脱氧以提供可用作柴油沸程燃料的烃馏分。加入含硫组分以优先通过羰基化和羰基化优化以减少加氢脱氧。如果需要，烃馏分可以被异构化以改善冷流动性能。

10. 发明授权

US08581014B2 Process for the production of hydrocarbons, useful for motor vehicles, from mixtures of a biological origin 有权
标题翻译：从生物来源的混合物生产用于机动车辆的碳氢化合物的方法
公开(公告)号：US08581014B2
公开(公告)日：2013-11-12
申请号：US12637232
申请日：2009-12-14
申请人： Carlo Perego , Franco Baldiraghi , Suheil Fares Abdo , Terry Louise Marker , Luigina Maria Flora Sabatino
发明人： Carlo Perego , Franco Baldiraghi , Suheil Fares Abdo , Terry Louise Marker , Luigina Maria Flora Sabatino
IPC分类号： C07C1/00 , C10G1/10
CPC分类号： B01J21/12 , B01J23/42 , B01J23/60 , B01J23/62 , B01J23/6482 , B01J23/652 , B01J23/85 , B01J23/883 , B01J27/185 , B01J27/1856 , B01J27/188 , B01J27/198 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0018 , B01J37/036 , B01J37/084 , C10G2300/1011 , C10G2400/04 , C10L1/08 , Y02E50/13 , Y02P30/20
摘要： Provided is a process for producing, in a single step, hydrocarbon fractions useful as diesel fuel or as a component of diesel fuel, from a mixture of a biological origin containing esters of fatty acids and, optionally, aliquots of free fatty acids. The process comprises the contemporaneous hydrodeoxygenation and hydroisomerization of the mixture of a biological origin, with the formation of linear and branched paraffins. The process is carried out in the presence of a catalytic composition comprising an amorphous carrier of an acidic nature and a metallic component containing one or more metals of group VIII.
摘要翻译：本发明提供了一种从含有脂肪酸酯和任选地等分游离脂肪酸的生物来源的混合物中单独制备可用作柴油燃料或作为柴油燃料组分的烃馏分的方法。该方法包括生物来源的混合物的同时加氢脱氧和加氢异构化，形成直链和支链烷烃。该方法在包含酸性的无定形载体和含有一种或多种VIII族金属的金属组分的催化组合物存在下进行。

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