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1. 发明授权

US5635567A Propylene polymer, process for obtaining it and use 失效
标题翻译：丙烯聚合物，获得和使用的过程
公开(公告)号：US5635567A
公开(公告)日：1997-06-03
申请号：US574185
申请日：1995-12-18
申请人： Fernand Gauthy , Eric Vandevijver , Martine Kaszacs
发明人： Fernand Gauthy , Eric Vandevijver , Martine Kaszacs
IPC分类号： C08J5/00 , C08F8/00 , C08F10/06 , C08F255/02 , C08J9/04 , C08K5/00 , C08K5/02 , C08K5/03 , C08L23/00 , C08L23/10 , C08L23/26
CPC分类号： C08F255/02 , C08L23/10 , C08L2205/02 , C08L2205/025
摘要： Propylene polymer containing monomer units derived from at least one functional compound (A) comprising at least two vinyl unsaturations and one or a number of aromatic rings which exhibits a structural stress-hardening.
摘要翻译：包含衍生自至少一种包含至少两个乙烯基不饱和官能化合物（A）的单体单元的丙烯聚合物和表现出结构应力硬化的一个或多个芳环。

2. 发明授权

US5656718A Process for the continuous manufacture of poly-.epsilon.-caprolactones 失效
标题翻译：连续制造聚ε-己内酯的方法
公开(公告)号：US5656718A
公开(公告)日：1997-08-12
申请号：US623815
申请日：1996-03-29
申请人： Henri Wautier , Lucienne Detournay , Martine Kaszacs
发明人： Henri Wautier , Lucienne Detournay , Martine Kaszacs
IPC分类号： C08G63/08 , C08G63/78 , C08G63/82 , C08G63/84
CPC分类号： C08G63/823
摘要： Poly-.epsilon.-caprolactones are produced by continuous polymerization of .epsilon.-caprolactone as a melt in an extruder (reactive extrusion) with the use, as polymerization initiator, of aluminium trialkoxides in which at least one alkoxy radical includes at least one other oxygen atom besides the oxygen atom constituting the aluminoxane (AI--O) bond. This oxygen atom is advantageously present in the form of an ester or ether functional group. These initiators are generally in the liquid state at ambient temperature and are furthermore miscible with .epsilon.-caprolactone, with the result that they can be used in the absence of solvent. The appropriate adjustment of the feed flow rates of .epsilon.-caprolactone and of initiator to the extruder permits the manufacture of custom-made poly-.epsilon.-caprolactones which have predesigned weight-average molecular masses.
摘要翻译：聚ε-己内酯通过在挤出机（反应性挤出）中作为熔体的ε-己内酯连续聚合而制备，其中使用三烷氧基铝作为聚合引发剂，其中至少一个烷氧基包括至少一个其它氧原子构成铝氧烷（AI-O）键的氧原子。该氧原子有利地以酯或醚官能团的形式存在。这些引发剂通常在环境温度下处于液态，并且还可与ε-己内酯混溶，结果可以在不存在溶剂的情况下使用它们。将ε-己内酯和引发剂的进料流速适当调整到挤出机允许制造具有预先设计的重均分子量的定制的聚ε-己内酯。

3. 发明授权

US07008577B2 Extrusion head for expanded plastic tubes 失效
标题翻译：膨胀塑料管挤出头
公开(公告)号：US07008577B2
公开(公告)日：2006-03-07
申请号：US10312038
申请日：2001-06-19
申请人： Claude Dehennau , Martine Kaszacs
发明人： Claude Dehennau , Martine Kaszacs
IPC分类号： B29C44/20 , B29C44/46
CPC分类号： B29C47/065 , B29C47/0023 , B29C47/0026 , B29C47/0852 , B29C47/26 , B29C47/261 , B29C47/28 , B29C47/86 , B29C47/862 , B29C47/864 , B29C47/92 , B29C47/94 , B29C2947/92209 , B29C2947/92314 , B29C2947/92409 , B29C2947/92704 , B29C2947/92809 , B29C2947/92904 , B29K2105/04
摘要： An extrusion head for the manufacture of tubes including at least one layer of expanded plastic by extruding a stream of molten plastic containing a blowing agent through an annular passage cross section made in the extrusion head. The stream of molten plastic containing the blowing agent spreads out circumferentially and welds itself to itself by the recombining of the two stream fronts. The extrusion head is equipped with a special-purpose thermal regulation device allowing the molten plastic containing the blowing agent to be heated or cooled after the stream fronts have recombined.
摘要翻译：一种用于制造包括至少一层膨胀塑料的管的挤出头，通过在挤出头中制造的环形通道横截面挤出含有发泡剂的熔融塑料流。包含发泡剂的熔融塑料流沿圆周扩展，并通过两条流前沿的重组将其自身焊接到自身。挤出头配备有专用热调节装置，其允许在流前端重新组合之后将含有发泡剂的熔融塑料加热或冷却。

4. 发明授权

US06013710A Process for the storage stabilization of poly-.epsilon.-caprolactones 失效
标题翻译：聚ε-己内酯的储存稳定化方法
公开(公告)号：US06013710A
公开(公告)日：2000-01-11
申请号：US928624
申请日：1997-09-12
申请人： Henri Wautier , Martine Kaszacs
发明人： Henri Wautier , Martine Kaszacs
IPC分类号： C08K3/34 , C08F6/00 , C08K5/5415 , C08K5/5419 , C08L67/00 , C08K5/24
CPC分类号： C08K5/5415
摘要： Poly-.epsilon.-caprolactones produced by continuous melt polymerization of .epsilon.-caprolactone with the use of aluminium alkoxides are stabilized for storage by incorporation of an effective quantity of silicon derivative such as, for example, a silicon oxide, an inorganic silicate or a silicon alkoxide, preference being given to silicon alkoxides. This process has the effect of greatly limiting the gradual reduction in the inherent viscosity of the poly-.epsilon.-caprolactones in the course of time. In accordance with a preferred embodiment the incorporation of the silicon derivative is preceded by the incorporation of an effective quantity of water, and this further improves the storage stability of the poly-.epsilon.-caprolactones produced with the use of aluminium alkoxides.
摘要翻译：通过使用烷氧基铝将ε-己内酯的连续熔融聚合生产的聚ε-己内酯通过加入有效量的硅衍生物例如氧化硅，无机硅酸盐或硅烷醇盐而被稳定以进行储存优选硅烷醇盐。该方法具有大大限制聚ε-己内酯在时间上的特性粘度的逐渐降低的作用。根据优选的实施方案，硅衍生物的引入之前是引入有效量的水，并且这进一步提高了使用烷氧化铝生产的聚ε-己内酯的储存稳定性。

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