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1. 发明授权

US5089661A New process for the preparation of 2-aryl-propionic acids 失效
标题翻译：制备2-芳基酸的新方法
公开(公告)号：US5089661A
公开(公告)日：1992-02-18
申请号：US580363
申请日：1990-09-10
申请人： Federico Maspero , Oreste Piccolo , Ugo Romano , Salvatore Gambino
发明人： Federico Maspero , Oreste Piccolo , Ugo Romano , Salvatore Gambino
IPC分类号： C07C51/02 , C25B3/04
CPC分类号： C25B3/04 , C07C51/02
摘要： A new process is described for the preparation of a 2-aryl-propionic acid, such as for instance 2-[4-(2-methyl-propyl)phenyl]propionic or 2-(6'-methoxy-2'-naphthyl)propionic acid, through hydrogenation of a complex salt which consists of the mono- and/or di-valent anion of the corresponding 2-hydroxy-2-aryl-propionic acid, a di- or tri-valent metal cation, such as for instance Al(+3), Fe(+3), Zn(+2), or Mg(+2), and optionally other anonic or neutral ligands.This new process is particularly advantageous in that the starting salt can be obtained directly via electrocarboxylation of the corresponding aryl methyl ketone, e.g. 4-(2-methyl-propyl)acetophenone or (6-methoxy-2-naphthyl) methyl ketone, with metal anodes which dissolve during the electrolysis.

2. 发明授权

US07048905B2 Process for the production of hydrogen peroxide 有权
标题翻译：过氧化氢生产工艺
公开(公告)号：US07048905B2
公开(公告)日：2006-05-23
申请号：US10343323
申请日：2001-08-03
申请人： Giuseppe Paparatto , Franco Rivetti , Pietro Andrigo , Giordano De Alberti , Ugo Romano
发明人： Giuseppe Paparatto , Franco Rivetti , Pietro Andrigo , Giordano De Alberti , Ugo Romano
IPC分类号： C01B15/029
CPC分类号： C01B15/013 , C01B15/029
摘要： Process for the production of concentrated aqueous solutions of hydrogen peroxide, comprising the following steps: (a) feeding to a reactor containing a catalyst based on palladium and platinum, heterogeneous and maintained in dispersion in a liquid reaction medium: (i) a liquid stream consisting of an alcohol or a mixture of C1–C3 alcohols or a mixture of said alcohols with water containing at least 50% by weight of alcohol, also containing an acid promoter and a halogenated promoter, the alcohol and optionally all or part of the water contained in the stream being recycled from the subsequent phase d); (ii) a gaseous stream containing hydrogen, oxygen and an inert gas, characterized in that the concentration of the hydrogen is less than 4.5% by volume and the concentration of the oxygen is less than 21% by volume, the complement to 100 being an inert gas; (b) removing from the reactor: (iii) a liquid stream consisting of stream (i) and also containing the hydrogen peroxide and water produced by the reaction, characterized in that the concentration of hydrogen peroxide ranges from 2% to 10% by weight; and (iv) a gaseous stream essentially consisting of non-reacted hydrogen and oxygen and the inert gas, (c) optionally adding to (iii) water in such a quantity so that its content is at least equal to that of the final aqueous solution of hydrogen peroxide; (d) sending the stream deriving from (c) to a system consisting of one or more evaporators or distillation columns from which the following are removed: (v) one or more streams containing all the alcohol and possibly water, which are recycled to (a); (vi) a concentrated aqueous solution of H2O2 at a concentration ranging from 15 to 60% by weight; (vii) optionally a stream containing the water fed in excess in (c).
摘要翻译：用于生产浓缩过氧化氢水溶液的方法，包括以下步骤：（a）向包含基于钯和铂的催化剂的反应器进料，在液体反应介质中分散均匀并保持分散体：（i）液体流由醇或C1-C3醇的混合物或所述醇与含有至少50重量％醇的水的混合物组成，还含有酸促进剂和卤化促进剂，醇和任选的全部或部分水包含在流中从后续阶段d）循环; （ii）含有氢气，氧气和惰性气体的气流，其特征在于氢气的浓度小于4.5体积％，氧气的浓度小于21体积％，补体为100为惰性气体（b）从反应器中除去：（iii）由流（i）组成并且还含有过氧化氢和通过反应产生的水组成的液体流，其特征在于，过氧化氢的浓度为2重量％至10重量％ ; 和（iv）基本上由未反应的氢气和氧气以及惰性气体组成的气流，（c）任选地加入（iii）水，使其含量至少等于最终水溶液的含量的过氧化氢; （d）将从（c）得到的物流送到一个由一个或多个蒸发器或蒸馏塔组成的系统，其中除去以下物质：（v）一个或多个含有所有醇和可能的水的物流，其被再循环到一个）; （vi）浓度为15至60重量％浓度的H 2 O 2的浓缩水溶液; （vii）任选地包含（c）中过量供给的水的流。

3. 发明授权

US4835233A Liquid polymerizable compositions for the production of substitutes for optical glasses 失效
标题翻译：用于生产光学眼镜替代物的液体可聚合组合物
公开(公告)号：US4835233A
公开(公告)日：1989-05-30
申请号：US237664
申请日：1988-08-25
申请人： Fiorenzo Renzi , Franco Rivetti , Ugo Romano
发明人： Fiorenzo Renzi , Franco Rivetti , Ugo Romano
IPC分类号： C08F18/00 , C08F218/00 , C08F290/00 , C08F299/02 , G02B1/04
CPC分类号： C08F218/00 , G02B1/04
摘要： A liquid, fluid composition, comprising:(a) bis(allylcarbonate) of monomer diethylene glycol;(b) bis(allylcarbonate) of oligomer diethylene glycol;(c) tris(allylcarbonate) of monomer tris(hydroxyethyl)isocyanurate;(d) a monofunctional, unsaturated vinyl or methacryl ester monomer,is polymerized inside a mould (casting process), with fast polymerization cycle, to yield optical articles.
摘要翻译：一种液体流体组合物，其包含：（a）单体二甘醇的双（烯丙基碳酸酯）; （b）低聚物二甘醇二（烯丙基碳酸酯）; （c）单体三（羟乙基）异氰脲酸酯的三（碳酸烯丙酯）（d）单官能的，不饱和的乙烯基或甲基丙烯酸酯单体在模具（铸造工艺）内聚合，具有快速的聚合循环，以产生光学制品。

4. 发明授权

US4812545A Process for the preparation of substitutes for optical glasses and polymerizable liquid composition suitable to that purpose 失效
标题翻译：制备适用于该目的的光学玻璃和可聚合液体组合物的替代物的方法
公开(公告)号：US4812545A
公开(公告)日：1989-03-14
申请号：US863526
申请日：1986-05-15
申请人： Fiorenzo Renzi , Franco Rivetti , Ugo Romano , Claudio Gagliardi
发明人： Fiorenzo Renzi , Franco Rivetti , Ugo Romano , Claudio Gagliardi
IPC分类号： C08F18/00 , C08F218/00 , C08F283/02 , G02B1/04 , C08F26/06 , C08F18/24
CPC分类号： C08F218/00 , G02B1/04
摘要： Substitutes for optical glasses are obtained by submitting to polymerization, in the presence of a free-radical initiator and in bulk, a polymerizable liquid composition containing:a monomer of diethyleneglycol bis(allylcarbonate);oligomers of diethyleneglycol bis(alllycarbonate);a monomer of tris(hydroxyethyl)isocyanurate tris(allylcarbonate); andat least one free-radical initiator.
摘要翻译：用于光学眼镜的替代物是通过在自由基引发剂存在下并在本体上进行聚合而获得的，该可聚合液体组合物包含：二甘醇双（烯丙基碳酸酯）单体; 二甘醇双（全碳酸酯）的低聚物; 三（羟乙基）异氰脲酸酯三（碳酸烯丙酯）的单体; 和至少一种自由基引发剂。

5. 发明授权

US4623705A Process for synthesizing allyl carbonates by polyhydric alcohols and their derivatives 失效
标题翻译：通过多元醇及其衍生物合成碳酸烯丙酯的方法
公开(公告)号：US4623705A
公开(公告)日：1986-11-18
申请号：US694266
申请日：1985-01-24
申请人： Ugo Romano , Giuseppe Iori
发明人： Ugo Romano , Giuseppe Iori
IPC分类号： C07C69/96 , C07C68/06 , C08F18/00 , C08F18/24 , C08F2/00
CPC分类号： C07C68/06
摘要： The application relates to a process for synthesizing carbonic allyl esters from polyhydric alcohols, which are reacted with diallyl carbonate in the presence of a basic catalyst, which can be chosen from sodium hydroxide, sodium carbonate, sodium alcoholate, organic bases or basic ion exchange resins.The final products obtained differ according to the ratio of the components of the starting mixture. Thus, in the case of diols with a diallyl carbonate/diol ratio greater than or equal to 10, the resultant product is constituted by the bis allyl carbonate of the diol together with a quantity of less than or equal to 10% of oligomers represented mainly by dimers. If the ratio is less than 10, the percentage of oligomers rises until, in the case of an approximately stoichiometric ratio, it reaches a value close to 70% of the reaction product.

6. 发明授权

US4544725A Composition based on aliphatic polycarbonates which contain urethan groups and acrylic or metacrylic end groups, to be cross-linked in the presence of radicalic initiators 失效
标题翻译：基于含有氨基甲酸酯基团和丙烯酸或甲基丙烯酸端基的脂族聚碳酸酯的组合物，在自由基引发剂存在下进行交联
公开(公告)号：US4544725A
公开(公告)日：1985-10-01
申请号：US484954
申请日：1983-04-14
申请人： Aldo Priola , Ugo Romano , Fiorenzo Renzi
发明人： Aldo Priola , Ugo Romano , Fiorenzo Renzi
IPC分类号： C08G18/44 , C08G18/67 , C08G64/00 , C08G71/04 , C08F126/02 , C08F226/02
CPC分类号： C08G71/04 , C08G18/44 , C08G18/672 , C08G64/00
摘要： A composition based on aliphatic polycarbonates containing urethan groups and acrylic or metacrylic end groups, to be cross-linked in the presence of radicalic initiators for their functionalization with acrylic or metacrylic groups of a mixture composed of diols, polyols and their oligomeric derivatives terminated by OH groups and containing in their molecule carbonate groups and urethan groups.
摘要翻译：基于含有氨基甲酸酯基团和丙烯酸或甲基丙烯酸端基的脂肪族聚碳酸酯的组合物，在自由基引发剂的存在下进行交联，用于由二醇，多元醇及其低聚物衍生物的丙烯酸或甲基丙烯酸基组成的官能团并且在其分子中含有碳酸酯基团和氨基甲酸酯基团。

7. 发明授权

US4508656A Process for synthesizing allyl carbonates of polyhydric alcohols and their derivatives 失效
标题翻译：合成多元醇及其衍生物的碳酸烯丙酯的方法
公开(公告)号：US4508656A
公开(公告)日：1985-04-02
申请号：US374331
申请日：1982-05-03
申请人： Ugo Romano , Giuseppe Iori
发明人： Ugo Romano , Giuseppe Iori
IPC分类号： C07C69/96 , C07C68/06 , C08F18/00
CPC分类号： C07C68/06
摘要： The application relates to a process for synthesizing carbonic allyl esters from polyhydric alcohols, which are reacted with diallyl carbonate in the presence of a basic catalyst, which can be chosen from sodium hydroxide, sodium carbonate, sodium alcoholate, organic bases or basic ion exchange resins.The final products obtained differ according to the ratio of the components of the starting mixture. Thus, in the case of diols with a diallyl carbonate/diol ratio greater than or equal to 10, the resultant product is constituted by the bis allyl carbonate of the diol together with a quantity of less than or equal to 10% of oligomers represented mainly by dimers. If the ratio is less than 10, the percentage of oligomers rises until, in the case of an approximately stoichiometric ratio, it reaches a value close to 70% of the reaction product.
摘要翻译：本申请涉及在碱性催化剂存在下与多烯醇合成碳酸烯丙酯的方法，该碱性催化剂可以选自氢氧化钠，碳酸钠，醇钠，有机碱或碱式离子交换树脂。获得的最终产品根据起始混合物的组分的比例而不同。因此，在二烯丙基碳酸酯/二醇比大于或等于10的二醇的情况下，所得产物由二醇的双碳酸烯丙酯和少于或等于10％的主要代表的低聚物的量构成二聚体。如果该比例小于10，则低聚物的百分数上升直到在大约化学计量比的情况下达到接近70％反应产物的值。

8. 发明授权

US07553473B2 Process for the removal of hydrogen sulfide, by means of its oxidation in the presence of hetero polyacids 有权
标题翻译：通过在杂多酸存在下氧化除去硫化氢的方法
公开(公告)号：US07553473B2
公开(公告)日：2009-06-30
申请号：US10588215
申请日：2005-01-20
申请人： Alberto De Angelis , Giuseppe Bellussi , Paolo Pollesel , Ugo Romano , Carlo Perego
发明人： Alberto De Angelis , Giuseppe Bellussi , Paolo Pollesel , Ugo Romano , Carlo Perego
IPC分类号： C01B17/04 , C01B17/05 , C10L3/10
CPC分类号： B01D53/52 , B01D2257/304 , C01B17/05
摘要： Hydrogen sulfide is oxidized to sulfur by means of treatment with an aqueous acid solution containing trivalent iron and a hetero polyacid having formula (I): HnXVyM(12-y)O40; or a sole hetero polyacid having formula (II): HnMeM12O40; wherein the symbols X, M Me n and y are specified in the text. At the end of the oxidation, the solution is treated with gas containing oxygen to re-oxidize the reduced metal.
摘要翻译：通过用含有三价铁的含水酸溶液和式（I）的杂多酸（HnXVyM（12-y）O40）处理将硫化氢氧化成硫。或具有式（II）的唯一的杂多酸：HnMeM12O40; 其中符号X，M Me n和y在文中指定。在氧化结束时，用含氧的气体处理溶液以再还原还原的金属。

9. 发明授权

US5527943A Method for removing acid and saline contaminants from a gaseous stream leaving a dimethylcarbonate synthesis reactor 失效
标题翻译：从离开二甲基碳酸酯合成反应器的气流中除去酸和盐污染物的方法
公开(公告)号：US5527943A
公开(公告)日：1996-06-18
申请号：US272229
申请日：1994-07-08
申请人： Franco Rivetti , Ugo Romano , Guido Garone , Maurizio Ghirardini
发明人： Franco Rivetti , Ugo Romano , Guido Garone , Maurizio Ghirardini
IPC分类号： C07C68/00 , C07C68/08 , C07C69/96
CPC分类号： C07C68/08 , C07C68/005
摘要： A method is described enabling HCl and possible entrained CuCl particulate to be removed from a gas-vapor stream leaving a dimethylcarbonate synthesis reactor. The contaminant removal is effected by one of the process fluids used in a small quantity.
摘要翻译：描述了一种方法，其使HCl和可能夹带的CuCl颗粒从气 - 气流中除去，留下碳酸二甲酯合成反应器。污染物去除是通过少量使用的工艺流体之一来实现的。

10. 发明授权

US5395949A Process and catalyst for preparing organic carbonates 失效
标题翻译：制备有机碳酸酯的工艺和催化剂
公开(公告)号：US5395949A
公开(公告)日：1995-03-07
申请号：US1801
申请日：1993-01-08
申请人： Daniele Delledonne , Franco Rivetti , Ugo Romano
发明人： Daniele Delledonne , Franco Rivetti , Ugo Romano
IPC分类号： B01J27/128 , B01J31/04 , B01J31/22 , C07B61/00 , C07C68/00 , C07C69/96 , C07D317/36 , C07D317/38 , C07D321/00 , C07D317/08
CPC分类号： C07D317/38 , C07C68/005
摘要： Organic carbonates and cyclic organic carbonates are prepared by reacting an aliphatic or cycloaliphatic alcohol, or, respectively, an aliphatic diol, with carbon monoxide and oxygen, by operating in the presence of a complex catalyst of cobalt with organic ligands bearing one or more oxygen functional groups, as electron donors.
摘要翻译：有机碳酸酯和环状有机碳酸酯是通过使一种具有一个或多个氧官能团的有机配体的钴复合催化剂存在下使脂族或脂环族醇，或分别是脂族二醇与一氧化碳和氧反应来制备的作为电子给体。

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