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    • 1. 发明授权
    • Method for reducing metal ores
    • 减少金属矿石的方法
    • US3904397A
    • 1975-09-09
    • US26882072
    • 1972-07-03
    • FIERRO ESPONJA
    • CELADA JUANMACKAY PATRICK WMARTINEZ ENRIQUE RAMONVILLASENOR ANTONIOVIRAMONTES RICARDO
    • C21B13/00C21B13/04C21B13/14
    • C21B13/04C21B13/0073C21B2100/22C21B2100/64Y02P10/136Y02P10/143
    • An improvement in a method for the batchwise gaseous reduction of metal oxides, e.g., iron ore, to metals, e.g., sponge iron, in a multiple unit reactor system of the type in which separate bodies of metal-bearing material are simultaneously treated in one or more reduction reactors and cooling reactors. Reduction is effected with a gas composed largely of carbon monoxide and hydrogen generated by the catalytic conversion of methane and steam at an elevated temperature. Improved cooling is obtained by first feeding the freshly prepared gas to a reduction reactor rather than a cooling reactor, thereby minimizing formation of methane in the cooling reactor. In a modified embodiment, methane is fed to the cooling reactor and at least a portion of the effluent gas is recycled through the catalytic reformer.
    • 在多单位反应器系统中将金属氧化物(例如铁矿石)分批气态还原成金属(例如海绵铁)的方法的改进,其中分离的含金属材料体同时在一个处理 或更多的还原反应器和冷却反应器。 通过在升高的温度下甲烷和蒸汽的催化转化产生的主要由一氧化碳和氢气组成的气体进行还原。 通过首先将新制备的气体供给到还原反应器而不是冷却反应器中,从而最小化冷却反应器中甲烷的形成,从而获得改进的冷却。 在一个改进的实施方案中,甲烷被供给到冷却反应器中,并且至少一部分废气通过催化重整器再循环。
    • 4. 发明授权
    • Method for gaseous reduction of metal ores
    • 金属矿石气态还原方法
    • US3890142A
    • 1975-06-17
    • US40680573
    • 1973-10-16
    • FIERRO ESPONJA
    • CELADA JUANMACKAY PATRICK W
    • C21B13/00C21B13/04C21B13/14C21B13/02
    • C21B13/0073C21B13/04C21B13/146C21B2100/64Y02P10/136Y02P10/212
    • An improvement in a method for the batchwise gaseous reduction of metal oxides, e.g., iron ore to metals, e.g., sponge iron, in a multiple unit reactor system of the type in which separate bodies of metal-bearing material are simultaneously treated in one or more charging reactors, reduction reactors and cooling reactors and a reducing gas is passed successively through the cooling and reduction reactors. The reducing gas is recirculated in both the cooling reactor and the reducing reactor to increase the mass flow rate of the gas. By recycling the gas to the reduction reactor acceptable reduction can be achieved in a shorter period of time and with a single reactor. Also the temperature gradient through the bed is reduced thus producing a higher average temperature in the bed for a given inlet temperature and more nearly uniform metallization is obtained.
    • 在多单元反应器系统中将金属氧化物,例如铁矿石,例如铁矿石,例如海绵铁分批气态还原的方法的改进,其中将单独的含金属材料体同时处理在一个或多个 更多的充电反应器,还原反应器和冷却反应器以及还原气体依次通过冷却和还原反应器。 还原气体在冷却反应器和还原反应器中再循环,以增加气体的质量流量。 通过将气体再循环到还原反应器中,可以在更短的时间内和单个反应器中实现可接受的还原。 此外,通过床的温度梯度减小,从而在给定入口温度下在床中产生较高的平均温度,并且获得更接近均匀的金属化。
    • 5. 发明授权
    • Method and apparatus for reducing particulate metal ores to sponge iron
    • 用于减少海绵铁颗粒金属矿石的方法和装置
    • US3889864A
    • 1975-06-17
    • US39484373
    • 1973-09-06
    • FIERRO ESPONJA
    • CELADA JUANMACKAY PATRICK WDE LA PENA RAMON
    • C21B13/00F27B1/00
    • C21B13/0073C21B13/029C21B2100/64Y02P10/136
    • A method and apparatus is disclosed for achieving improved reduction efficiency in the reduction of particulate metal ores, e.g., iron ore, in a vertical shaft, moving bed reactor having a reduction zone in which a hot reducing gas is caused to flow through a portion of the ore bed to reduce the metal ore thereof to metal, e.g., sponge iron. The improved efficiency is achieved by using a split-flow of reducing gas to the reduction zone of the reactor. In one embodiment of the invention separate reducing gas streams are supplied to the top and bottom of the reduction zone and combined near the center of the reduction zone and removed from the reactor. In another embodiment of the invention reducing gas is fed to a point near the center of the reduction zone, caused to flow both upwardly and downwardly through the ore in the reduction zone and removed at points near the top and bottom of the reduction zone. By using the disclosed split-flow systems, the residence time of the metal-bearing material within the reactor can be reduced and the productivity of the reactor thereby increased.
    • 公开了一种方法和装置,用于在垂直轴中减少微粒金属矿石(例如铁矿石)的降低效率,具有减少区域的移动床反应器,其中使热还原气体流过一部分 矿床将其金属矿石还原成金属,例如海绵铁。 通过使用还原气体向反应器的还原区域的分流来实现提高的效率。 在本发明的一个实施方案中,将分离的还原气流供应到还原区的顶部和底部并在还原区的中心附近组合并从反应器中除去。 在本发明的另一个实施方案中,还原气体被供给到还原区中心附近的点,使得还原区中的矿石向上和向下流动,并且在还原区的顶部和底部附近的点被去除。 通过使用公开的分流系统,可以减少含金属材料在反应器内的停留时间,从而提高反应器的生产率。