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1. 发明申请

US20100317888A1 CARBONYLATION PROCESS WITH IN SITU REGENERATION OF MORDENITE CATALYST 有权
标题翻译：在原位催化剂再生过程中的碳化过程
公开(公告)号：US20100317888A1
公开(公告)日：2010-12-16
申请号：US12735123
申请日：2008-12-16
申请人： Evert Jan Ditzel , David John Law , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
发明人： Evert Jan Ditzel , David John Law , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
IPC分类号： C07C67/36 , C07C67/37 , C07C51/12
CPC分类号： B01J29/90 , B01J29/20 , B01J38/14 , C07C51/12 , C07C67/37 , Y02P20/584 , C07C53/08 , C07C69/14
摘要： A process for the carbonylation of dimethyl ether, dimethyl carbonate and/or methanol with carbon monoxide and hydrogen in the presence of a mordenite catalyst to produce at least one of acetic acid and methyl acetate in which process the mordenite catalyst is regenerated in-situ by contacting the catalyst with a regenerating gas comprising a molecular oxygen-containing gas and an inert diluent at a total pressure in the range 1 to 100 bar and wherein the partial pressure of the molecular oxygen-containing gas is such that the temperature of the catalyst is maintained within the range 225 to 325° C.
摘要翻译：一种在丝光沸石催化剂存在下用一氧化碳和氢气二甲醚，二甲基碳酸酯和/或甲醇羰基化的方法，以产生乙酸和乙酸甲酯中的至少一种，其中丝光沸石催化剂原位再生使催化剂与包含含分子氧的气体和惰性稀释剂的再生气体在1至100巴的总压力下接触，并且其中分子氧气体的分压使得催化剂的温度为维持在225至325℃的范围内

2. 发明授权

US08158815B2 Carbonylation process with in situ regeneration of mordenite catalyst 有权
标题翻译：羰基化过程与丝光沸石催化剂的原位再生
公开(公告)号：US08158815B2
公开(公告)日：2012-04-17
申请号：US12735123
申请日：2008-12-16
申请人： Evert Jan Ditzel , David John Law , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
发明人： Evert Jan Ditzel , David John Law , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
IPC分类号： C07C67/36 , C07C51/12 , C07C53/08
CPC分类号： B01J29/90 , B01J29/20 , B01J38/14 , C07C51/12 , C07C67/37 , Y02P20/584 , C07C53/08 , C07C69/14
摘要： A process for the carbonylation of dimethyl ether, dimethyl carbonate and/or methanol with carbon monoxide and hydrogen in the presence of a mordenite catalyst to produce at least one of acetic acid and methyl acetate in which process the mordenite catalyst is regenerated in-situ by contacting the catalyst with a regenerating gas comprising a molecular oxygen-containing gas and an inert diluent at a total pressure in the range 1 to 100 bar and wherein the partial pressure of the molecular oxygen-containing gas is such that the temperature of the catalyst is maintained within the range 225 to 325° C.
摘要翻译：一种在丝光沸石催化剂存在下用一氧化碳和氢气二甲醚，二甲基碳酸酯和/或甲醇羰基化的方法，以产生乙酸和乙酸甲酯中的至少一种，其中丝光沸石催化剂原位再生使催化剂与包含含分子氧的气体和惰性稀释剂的再生气体在1至100巴的总压下接触，并且其中分子氧气体的分压使得催化剂的温度为维持在225至325℃的范围内

3. 发明授权

US08329606B2 Regeneration of zeolite carbonylation catalysts 有权
标题翻译：沸石羰基化催化剂的再生
公开(公告)号：US08329606B2
公开(公告)日：2012-12-11
申请号：US12735122
申请日：2008-12-16
申请人： Edo Johann Becker , Evert Jan Ditzel , Harry Kaiser , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
发明人： Edo Johann Becker , Evert Jan Ditzel , Harry Kaiser , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
IPC分类号： B01J38/10 , C07C51/12
CPC分类号： B01J29/06 , B01J29/20 , B01J29/50 , B01J29/65 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/90 , C07C51/12 , C07C67/37 , Y02P20/584 , C07C53/08 , C07C69/14
摘要： Process for the in-situ regeneration of a zeolite catalyst in a carbonylation process for the production of at least one of methyl acetate and acetic acid. The process is carried out by (a) contacting a carbonylatable reactant selected from methanol, dimethyl ether and dimethyl carbonate and carbon monoxide in a reactor with a zeolite catalyst and recovering a product stream containing at least one of methyl acetate and acetic acid from the reactor, (b) ceasing contact of the catalyst with the carbonylatable reactant, (c) regenerating the catalyst with a regenerating gas selected from hydrogen or a mixture of hydrogen and carbon monoxide at a temperature in the range 250 to 600 C, and (d) terminating the hydrogen regenerating step and resuming contact of the catalyst with the carbonylatable reactant and carbon monoxide.
摘要翻译：用于在羰基化方法中原位再生沸石催化剂以生产乙酸甲酯和乙酸中的至少一种的方法。该方法通过以下步骤进行：（a）在反应器中使沸石催化剂使选自甲醇，二甲醚和碳酸二甲酯的羰基化反应物与一氧化碳接触，并从反应器中回收含有至少一种乙酸甲酯和乙酸的产物流（b）停止催化剂与可羰基化反应物的接触，（c）在选自氢气或氢气和一氧化碳的混合物中的再生气体在250至600℃的温度范围内再生催化剂，和（d）终止氢再生步骤并恢复催化剂与可羰基化反应物和一氧化碳的接触。

4. 发明申请

US20100311567A1 REGENERATION OF ZEOLITE CARBONYLATION CATALYSTS 有权
标题翻译： ZEOLITE CARBONYLATION催化剂的再生
公开(公告)号：US20100311567A1
公开(公告)日：2010-12-09
申请号：US12735122
申请日：2008-12-16
申请人： Edo Johann Becker , Evert Jan Ditzel , Harry Kaiser , George Ernest Morris , Mark Stephen Roberts , Stephen Andreas Schunk , Martin Smit , John Glenn Sunley
发明人： Edo Johann Becker , Evert Jan Ditzel , Harry Kaiser , George Ernest Morris , Mark Stephen Roberts , Stephen Andreas Schunk , Martin Smit , John Glenn Sunley
IPC分类号： B01J38/10
CPC分类号： B01J29/06 , B01J29/20 , B01J29/50 , B01J29/65 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/90 , C07C51/12 , C07C67/37 , Y02P20/584 , C07C53/08 , C07C69/14
摘要： A process for the in-situ regeneration of a zeolite catalyst in a carbonylation process for the production of at least one of methyl acetate and acetic acid by contacting methanol, dimethyl ethyl or dimethyl carbonate with carbon monoxide in the presence of a zeolite catalyst, ceasing contact of the catalyst with the reactant, regenerating the catalyst with a regenerating gas selected from hydrogen or a mixture of hydrogen and carbon monoxide at a temperature in the range 250 to 600° C., terminating the hydrogen regenerating step and resuming contact of the catalyst with the reactant and carbon monoxide.
摘要翻译：一种用于在羰基化方法中原位再生沸石催化剂的方法，用于通过在沸石催化剂存在下使甲醇，二甲基乙基或碳酸二甲酯与一氧化碳接触来制备乙酸甲酯和乙酸中的至少一种，停止催化剂与反应物的接触，用选自氢或氢和一氧化碳的混合物的再生气体在250-600℃的温度下再生催化剂，终止氢再生步骤并恢复催化剂的接触与反应物和一氧化碳。

5. 发明授权

US07915446B2 Catalyst and process for the production of acetic acid 有权
标题翻译：用于生产乙酸的催化剂和方法
公开(公告)号：US07915446B2
公开(公告)日：2011-03-29
申请号：US10563920
申请日：2004-06-23
申请人： Anthony Haynes , David John Law , Andrew Miller , George Ernest Morris , Marc John Payne , John Glenn Sunley
发明人： Anthony Haynes , David John Law , Andrew Miller , George Ernest Morris , Marc John Payne , John Glenn Sunley
IPC分类号： C07C51/16
CPC分类号： B01J23/468 , C07C51/12 , C07C53/08
摘要： A catalyst and process for the production of acetic acid by the carbonylation of methanol and/or a reactive derivative thereof. The catalyst system comprises an iridium carbonylation catalyst, methyl iodide co-catalyst, optionally at least one of ruthenium, osmium, rhenium, zinc, gallium, tungsten, cadmium, mercury and indium and at least one non-hydrohalogenoic acid promoter. The non-hydrohalogenoic acid may be an oxoacid, a superacid and/or a heteropolyacid.
摘要翻译：用于通过甲醇和/或其反应性衍生物的羰基化生产乙酸的催化剂和方法。催化剂体系包括铱羰基化催化剂，甲基碘助催化剂，钌，锇，铼，锌，镓，钨，镉，汞和铟中的至少一种和至少一种非氢卤酸促进剂。非氢卤酸可以是含氧酸，超酸和/或杂多酸。

6. 发明授权

US5932764A Iridium-catalyzed carbonylation process for the production of a carboxylic acid 失效
标题翻译：用于制备羧酸的铱催化羰基化方法
公开(公告)号：US5932764A
公开(公告)日：1999-08-03
申请号：US984996
申请日：1997-12-04
申请人： George Ernest Morris , John Glenn Sunley
发明人： George Ernest Morris , John Glenn Sunley
IPC分类号： B01J23/46 , C07B61/00 , C07C51/12 , C07C53/08 , C07C53/126 , C07C51/14
CPC分类号： C07C51/12
摘要： A process for the production of a carboxylic acid having n+1 carbon atoms comprises (a) carbonylating with carbon monoxide in a first reaction zone at elevated temperature and pressure an alkyl alcohol having n carbon atoms and/or a reactive derivative thereof to produce a carboxylic acid having n+1 carbon atoms in a liquid reaction composition comprising carboxylic acid product, an iridium catalyst, an alkyl halide co-catalyst, water, an ester of the carboxylic acid product and the alkyl alcohol, and optionally one or more promoters, (b) withdrawing from the first reaction zone at least a portion of the liquid reaction composition together with dissolved and/or entrained carbon monoxide, and passing at least a portion of the withdrawn liquid reaction composition and carbon monoxide to a second reaction zone, ((c)reacting at least 1% of the dissolved and/or entrained carbon monoxide in the withdrawn reaction composition by further carbonylation at elevated temperature and pressure in the second reaction zone to produce further carboxylic acid product.
摘要翻译：制备具有n + 1个碳原子的羧酸的方法包括（a）在高温和高压下在第一反应区中用一氧化碳羰基化具有n个碳原子的烷基醇和/或其反应性衍生物以产生在包含羧酸产物，铱催化剂，烷基卤助催化剂，水，羧酸产物的酯和烷基醇的液体反应组合物中具有n + 1个碳原子的羧酸，以及任选的一种或多种助催化剂，（b）将液体反应组合物的至少一部分与溶解和/或夹带的一氧化碳一起排出第一反应区，并将至少一部分抽出的液体反应组合物和一氧化碳通入第二反应区（（c）通过在升高的温度和压力下进一步羰基化使至少1％的溶解和/或夹带的一氧化碳在撤回的反应组合物中反应他的第二反应区产生更多的羧酸产物。

7. 发明授权

US07642392B2 Process for preparing branched chain hydrocarbons 失效
标题翻译：制备支链烃的方法
公开(公告)号：US07642392B2
公开(公告)日：2010-01-05
申请号：US10569441
申请日：2004-08-19
申请人： Richard Daniel Kay , George Ernest Morris , John Glenn Sunley
发明人： Richard Daniel Kay , George Ernest Morris , John Glenn Sunley
IPC分类号： C07C1/00
CPC分类号： C07C1/20 , C07C2527/125 , C07C2527/138 , C10G3/44 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2400/02 , Y02P30/20
摘要： The present invention relates to a process for the production of branched chain hydrocarbons from methanol and/or dimethyl ether, which process comprises contacting, in a reactor, methanol and/or dimethyl ether with a catalyst comprising indium halide.
摘要翻译：本发明涉及从甲醇和/或二甲醚生产支链烃的方法，该方法包括在反应器中使甲醇和/或二甲醚与包含卤化铟的催化剂接触。

8. 发明授权

US5663430A Process for purifying a carboxylic acid 失效
标题翻译：纯化羧酸的方法
公开(公告)号：US5663430A
公开(公告)日：1997-09-02
申请号：US460537
申请日：1995-06-02
申请人： George Ernest Morris , Stephen James Smith , John Glenn Sunley , Robert John Watt , Bruce Leo Williams
发明人： George Ernest Morris , Stephen James Smith , John Glenn Sunley , Robert John Watt , Bruce Leo Williams
IPC分类号： B01J23/46 , C07C51/10 , C07C51/12 , C07C51/44 , C07C53/08 , C07C51/42 , C07C53/10
CPC分类号： C07C51/12 , C07C51/44
摘要： In a process for purifying a carboxylic acid fraction obtained by liquid phase carbonylation of an alkyl alcohol and/or its reactive derivative in which volatile iridium- and/or volatile co-promoter contaminants are converted to involatile forms by contacting with an iodide in the absence of carbon monoxide or at a partial pressure less than that of the carbonylation reaction. The involatile contaminants are then separated from the carboxylic acid.
摘要翻译：在通过烷基醇和/或其反应性衍生物的液相羰基化获得的羧酸级分的纯化方法中，其中挥发性铱和/或挥发性共助催化剂污染物通过在不存在下与碘化物接触而转化为非挥发性形式的一氧化碳或分压低于羰基化反应的分压。然后将非挥发性污染物与羧酸分离。

9. 发明授权

US07977272B2 Process and catalyst for the manufacture of acetic acid 失效
标题翻译：用于制造乙酸的方法和催化剂
公开(公告)号：US07977272B2
公开(公告)日：2011-07-12
申请号：US11793237
申请日：2005-11-17
申请人： Andrew John Miller , George Ernest Morris
发明人： Andrew John Miller , George Ernest Morris
IPC分类号： B01J27/185 , B01J27/053 , B01J27/13
CPC分类号： B01J31/0227 , B01J27/188 , B01J31/0224 , B01J31/0231 , B01J31/20 , B01J2231/34 , B01J2531/822 , C07C51/12 , C07C53/08
摘要： Catalyst system for the production of acetic acid comprising a rhodium carbonylation catalyst, methyl iodide and at least one heteropolyacid promoter.
摘要翻译：用于生产包含铑羰基化催化剂，甲基碘和至少一种杂多酸促进剂的乙酸的催化剂体系。

10. 发明申请

US20080269519A1 Process and Catalyst for the Manufacture of Acetic Acid 失效
标题翻译：用于制造乙酸的方法和催化剂
公开(公告)号：US20080269519A1
公开(公告)日：2008-10-30
申请号：US11793237
申请日：2005-11-17
申请人： Andrew John Miller , George Ernest Morris
发明人： Andrew John Miller , George Ernest Morris
IPC分类号： C07C51/12 , B01J31/02
CPC分类号： B01J31/0227 , B01J27/188 , B01J31/0224 , B01J31/0231 , B01J31/20 , B01J2231/34 , B01J2531/822 , C07C51/12 , C07C53/08
摘要： A process and catalyst for the production of acetic acid by the carbonylation of methanol and/or a reactive derivative thereof wherein the catalyst system comprises a rhodium carbonylation catalyst, methyl iodide, a non-hydrohalogenoic acid promoter and optionally a co-promoter capable of generating ionic iodide.
摘要翻译：用于通过甲醇和/或其反应性衍生物的羰基化生产乙酸的方法和催化剂，其中催化剂体系包含铑羰基化催化剂，甲基碘，非氢卤酸启动子和任选的能够产生离子碘化物。

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