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    • 2. 发明授权
    • Method for determining oil and water saturation of core samples at
overburden pressure
    • 岩石样品在上覆压力下的油水饱和度测定方法
    • US5299453A
    • 1994-04-05
    • US10250
    • 1993-01-28
    • Eve S. SpruntNizar F. Djabbarah
    • Eve S. SpruntNizar F. Djabbarah
    • G01N15/08E21B49/00
    • G01N15/0893
    • A method and apparatus is provided to determine the amount of oil and water or brine in a representative core sample of reservoir rock at an overburden stress which approximates reservoir stress conditions. The core sample is initially saturated with reservoir hydrocarbon (crude oil) and aqueous fluids (water or brine). The core sample is surrounded with an elastic jacket, or sleeve, and placed in a confining pressure vessel that simulates reservoir overburden stress on the core sample. The hydrocarbon (oil) fluids and aqueous fluids (water or brine) are than extracted from the core sample with a solvent capable of dissolving both aqueous and hydrocarbon fluids. The solvent and aqueous fluids are separated from the hydrocarbon fluids by evaporation. Thereafter the aqueous fluids are separated from the solvent by extraction. The amounts of oil and aqueous fluids from the sample may be separately determined. The volume of the hydrocarbon fluids and aqueous fluids is determined from their weight and density or from direct volume measurement. For a rock sample fully saturated with a combination of oil and aqueous fluids, the total pore volume is the sum of the volumes of the two fluids and the fluid saturation is then the ratio of the fluid volume to the pore volume.
    • 提供了一种方法和装置,用于确定近似于储层应力条件的上覆层应力的储层岩石的代表性核心样品中的油和水或盐水的量。 核心样品最初饱和储层烃(原油)和含水流体(水或盐水)。 核心样品用弹性护套或套管包围,并放置在模拟压力容器中,该压力容器模拟核心样品上的储层覆盖层应力。 烃(油)流体和含水流体(水或盐水)不是用能够溶解水和烃流体的溶剂从芯样品中提取的。 通过蒸发将溶剂和含水流体与烃流体分离。 此后,通过萃取将含水流体与溶剂分离。 来自样品的油和水溶液的量可以单独测定。 烃流体和含水流体的体积由其重量和密度或直接体积测量确定。 对于完全饱和油和含水流体的岩石样品,总孔体积是两种流体体积的总和,而流体饱和度则是流体体积与孔体积之比。
    • 5. 发明授权
    • Foam mixture for steam and carbon dioxide drive oil recovery method
    • 蒸汽和二氧化碳的泡沫混合物驱油回收方法
    • US5295540A
    • 1994-03-22
    • US976638
    • 1992-11-16
    • Nizar F. DjabbarahRalph V. Garling
    • Nizar F. DjabbarahRalph V. Garling
    • C09K8/592C09K8/594E21B43/16E21B43/24E21B43/22
    • C09K8/594C09K8/592E21B43/164E21B43/24Y02P90/70
    • The invention is a foam method for improving conformance during a steam flood or carbon dioxide flood in a subterranean, oil-containing formation penetrated by at least one injection well and at least one production well. In a steam flood oil recovery process, sweep efficiency is improved by injecting steam until steam breakthrough occurs at the production well after which a mixture of steam, a noncondensible gas, and an aqueous surfactant-starch solution is injected into the formation. The aqueous surfactant-starch solution forms a stable foam with the formation oil at formation conditions that reduce the permeability of the highly permeable steam swept zones thereby diverting the steam to other portions of the formation containing unswept oil. The starch is used as a partial substitute for the surfactant to improve the cost of the foam-forming mixture without reducing its effectiveness in increasing sweep efficiency.
    • 本发明是一种用于在由至少一个注入井和至少一个生产井穿透的地下含油地层中的蒸汽洪水或二氧化碳洪水期间改善一致性的泡沫方法。 在蒸汽洪水回收过程中,通过注入蒸汽直至在生产井发生蒸汽渗透之前提高了扫描效率,之后将蒸汽,不可冷凝气体和表面活性剂 - 水性水溶液的混合物注入到地层中。 水性表面活性剂 - 淀粉溶液在形成条件下形成稳定的泡沫,其中地层油降低了高度可渗透的蒸汽扫过区的渗透性,从而将蒸汽转移到含有未除油的地层的其它部分。 淀粉用作表面活性剂的部分替代物以改善泡沫形成混合物的成本,而不降低其提高扫掠效率的有效性。
    • 6. 发明授权
    • Oil recovery method employing carbon dioxide flooding with improved
sweep efficiency
    • 采用二氧化碳驱油的油回收方法具有改进的吹扫效率
    • US4605066A
    • 1986-08-12
    • US593465
    • 1984-03-26
    • Nizar F. Djabbarah
    • Nizar F. Djabbarah
    • E21B43/16E21B43/18E21B43/22
    • E21B43/18E21B43/164Y02P90/70
    • Oil is recovered from oil-containing formations employing alternate injection of carbon dioxide and a mixture of carbon dioxide and an additive comprising an intermediate hydrocarbon or tall oil to improve sweep efficiency. First, carbon dioxide is injected and fluid including oil is recovered from the formation until CO.sub.2 breakthrough occurs at the production well. Next, a mixture of carbon dioxide and an intermediate hydrocarbon or carbon dioxide and tall oil is injected and fluids produced until the injection pressure increases to a value about 10% above the injection pressure when injection of the mixture is initiated. Thereafter, carbon dioxide is injected and fluids including oil are recovered until carbon dioxide breakthrough occurs at the production well. The sequence of injection of carbon dioxide followed by injection of a mixture of carbon dioxide and an intermediate hydrocarbon or carbon dioxide and tall oil is repeated for a plurality of cycles to more completely sweep the full volume of the formation defined by the injection and production well. The process should be applied to a formation in which adequate communication exists.
    • 使用替代注射二氧化碳和二氧化碳和包含中间烃或妥尔油的添加剂的混合物从含油地层中回收油,以提高扫描效率。 首先,注入二氧化碳,并从地层回收包括油的流体,直到在生产井发生CO2突破。 接下来,注入二氧化碳和中间体烃或二氧化碳和妥尔油的混合物,并且产生流体,直到注射压力升高到开始注射混合物时高于注射压力的约10%的值。 此后,注入二氧化碳,并回收包括油在内的液体,直到生产井发生二氧化碳突破。 重复注入二氧化碳的顺序,然后注入二氧化碳和中间体烃或二氧化碳和妥尔油的混合物进行多个循环,以更完全地扫描由注入和生产井定义的地层的全部体积 。 该过程应适用于存在充分沟通的形式。
    • 7. 发明授权
    • Foam mixture for carbon dioxide drive oil recovery method
    • 泡沫混合二氧化碳驱油回收方法
    • US5542474A
    • 1996-08-06
    • US566636
    • 1995-12-04
    • Nizar F. DjabbarahRalph V. GarlingDavid T. HandJennifer Macfadyen
    • Nizar F. DjabbarahRalph V. GarlingDavid T. HandJennifer Macfadyen
    • C09K8/58C09K8/592C09K8/594E21B33/138E21B43/16E21B43/24E21B43/22
    • E21B43/164C09K8/58C09K8/592C09K8/594E21B33/138E21B43/24Y02P90/70
    • The invention is a foam method for improving conformance during a steam flood or carbon dioxide flood in a subterranean, oil-containing formation penetrated by at least one injection well and at least one production well. In a steam flood oil recovery process, sweep efficiency is improved by injecting steam until steam breakthrough occurs at the production well after which a mixture of steam, a noncondensible gas, and an aqueous surfactant-polypeptide solution is injected into the formation. The aqueous surfactant-polypeptide solution forms a stable foam with the formation oil at formation conditions that reduce the permeability of the highly permeable steam swept zones thereby diverting the steam to other portions of the formation containing unswept oil. The polypeptide is used as a partial substitute for the surfactant to improve the cost of the foam-forming mixture without reducing its effectiveness in increasing sweep efficiency. In another embodiment of the invention, the mixture of steam, surfactant-polypeptide solution and noncondensible gas may be injected into the formation surrounding a production well that has previously experienced severe steam breakthrough to significantly decrease the permeability of steam-swept zone surrounding the production well.
    • 本发明是一种用于在由至少一个注入井和至少一个生产井穿透的地下含油地层中的蒸汽洪水或二氧化碳洪水期间改善一致性的泡沫方法。 在蒸汽泛油回收过程中,通过注入蒸汽来提高吹扫效率,直到在生产井发生蒸汽渗透,然后将蒸汽,不可冷凝气体和表面活性剂 - 多水溶液的混合物注入到地层中。 水性表面活性剂 - 多肽溶液在形成条件下形成稳定的泡沫,其中地层油降低了高渗透性蒸汽扫过区的渗透性,从而将蒸汽转移到含有未除油的地层的其它部分。 多肽用作表面活性剂的部分替代物以改善泡沫形成混合物的成本,而不降低其提高扫描效率的有效性。 在本发明的另一个实施方案中,可以将蒸汽,表面活性剂 - 多肽溶液和不可冷凝气体的混合物注入到先前经历过严重蒸汽渗透的生产井周围的地层中,以显着降低围绕生产井的蒸汽扫过区的渗透性 。
    • 10. 发明授权
    • Foam mixture for steam and carbon dioxide drive oil recovery method
    • 蒸汽和二氧化碳的泡沫混合物驱油回收方法
    • US5513705A
    • 1996-05-07
    • US438584
    • 1995-05-10
    • Nizar F. DjabbarahRalph V. GarlingDavid T. HandJennifer Macfadyen
    • Nizar F. DjabbarahRalph V. GarlingDavid T. HandJennifer Macfadyen
    • C09K8/58C09K8/592C09K8/594E21B33/138E21B43/16E21B43/24E21B43/22
    • E21B43/164C09K8/58C09K8/592C09K8/594E21B33/138E21B43/24Y02P90/70
    • The invention is a foam method for improving conformance during a steam flood or carbon dioxide flood in a subterranean, oil-containing formation penetrated by at least one injection well and at least one production well. In a steam flood oil recovery process, sweep efficiency is improved by injecting steam until steam breakthrough occurs at the production well after which a mixture of steam, a noncondensible gas, and an aqueous surfactant-polypeptide solution is injected into the formation. The aqueous surfactant-polypeptide solution forms a stable foam with the formation oil at formation conditions that reduce the permeability of the highly permeable steam swept zones thereby diverting the steam to other portions of the formation containing unswept oil. The polypeptide is used as a partial substitute for the surfactant to improve the cost of the foam-forming mixture without reducing its effectiveness in increasing sweep efficiency. In another embodiment of the invention, the mixture of steam, surfactant-polypeptide solution and noncondensible gas may be injected into the formation surrounding a production well that has previously experienced severe steam breakthrough to significantly decrease the permeability of steam-swept zone surrounding the production well.
    • 本发明是一种用于在由至少一个注入井和至少一个生产井穿透的地下含油地层中的蒸汽洪水或二氧化碳洪水期间改善一致性的泡沫方法。 在蒸汽泛油回收过程中,通过注入蒸汽来提高吹扫效率,直到在生产井发生蒸汽渗透,然后将蒸汽,不可冷凝气体和表面活性剂 - 多水溶液的混合物注入到地层中。 水性表面活性剂 - 多肽溶液在形成条件下形成稳定的泡沫,其中地层油降低了高渗透性蒸汽扫过区的渗透性,从而将蒸汽转移到含有未除油的地层的其它部分。 多肽用作表面活性剂的部分替代物以改善泡沫形成混合物的成本,而不降低其提高扫描效率的有效性。 在本发明的另一个实施方案中,可以将蒸汽,表面活性剂 - 多肽溶液和不可冷凝气体的混合物注入到先前经历过严重蒸汽渗透的生产井周围的地层中,以显着降低围绕生产井的蒸汽扫过区的渗透性 。