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    • 3. 发明授权
    • Polylactic acid resin composition and molded article thereof, and process of producing the molded article
    • 聚乳酸树脂组合物及其成型体,以及该成型品的制造方法
    • US07034102B2
    • 2006-04-25
    • US10831124
    • 2004-04-26
    • Etsuo TobitaNaoshi KawamotoTsuyoshi UrushiharaHisashi OkuyamaTakeshi Kanamori
    • Etsuo TobitaNaoshi KawamotoTsuyoshi UrushiharaHisashi OkuyamaTakeshi Kanamori
    • C08G63/08
    • C08K5/20C08K5/13C08K5/25C08L67/04
    • A polylactic acid resin composition comprising 100 parts by weight of a polylactic acid, (A) 0 to 10 parts by weight of a phenol antioxidant, and (B) 0.01 to 10 parts by weight of at least one amide compound selected from the group consisting of (b-1) an acyclic amide, (b-2) a cyclic amide, (b-3) an acyclic hydrazide, and (b-4) a cyclic hydrazide or (b-5) a compound represented by formula (P): wherein Ra and Rb each represent a hydrogen atom, a hydroxyl group, an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms or an aryl group having 6 to 18 carbon atoms, or they are connected to each other to form a ring to make a condensed ring having a total carbon-atom number of 10 to 18; R represents a single bond, an n-valent hydrocarbon group having 2 to 30 carbon atoms, an n-valent heterocyclic group or a group of formula: wherein R′ represents an n-valent hydrocarbon group having 1 to 30 carbon atoms or an n-valent heterocyclic group; X represents a single bond or an alkylene group having 1 to 20 carbon atoms; and n represents 1, 2 or 3, and n represents 1, 2 or 3.
    • 一种聚乳酸树脂组合物,其包含100重量份的聚乳酸,(A)0至10重量份的酚抗氧化剂,和(B)0.01至10重量份的至少一种选自以下的酰胺化合物 的(b-1)无环酰胺,(b-2)环酰胺,(b-3)无环酰肼和(b-4)环状酰肼或(b-5) ):其中R a a和R b各自表示氢原子,羟基,具有1至8个碳原子的烷基,具有1至8个碳原子的烷氧基 原子或具有6至18个碳原子的芳基,或它们彼此连接形成环,以形成总碳原子数为10至18的稠环; R表示单键,碳原子数2〜30的n价烃基,n价的杂环基或式的基团,式中,R'表示碳原子数1〜30的n价的烃基或n 杂环基; X表示单键或碳原子数1〜20的亚烷基。 n表示1,2或3,n表示1,2或3。
    • 7. 发明申请
    • PROCESS OF PRODUCING LAMINATE FILM AND RESIN COMPOSITION FOR COATING MEMBERS
    • 生产层压膜的方法和涂料成员的树脂组合物
    • US20130331515A1
    • 2013-12-12
    • US14002525
    • 2012-02-08
    • Naoshi KawamotoTsuyoshi UrushiharaKohei OkamotoTetsuya Seguchi
    • Naoshi KawamotoTsuyoshi UrushiharaKohei OkamotoTetsuya Seguchi
    • C08K5/20
    • C08K5/20B32B7/12B32B27/08B32B27/32B32B27/36C08F2/44
    • Provided is a method of producing a laminate film by which a laminate film having excellent adhesion with a laminate base material, in which laminate film the amount of elution of an additive into a solvent is small, can be produced.The method of producing a laminate film is characterized by comprising the step of adding, before or during polymerization of a monomer having an ethylenically unsaturated bond, a phenolic antioxidant represented by the following Formula (1), which is masked with an organoaluminum compound, to at least one of a catalyst system, a polymerization system and a piping, such that the phenolic antioxidant is incorporated in an amount of 0.001 to 0.5 parts by mass with respect to 100 parts by mass of a polymer obtained by the polymerization: (wherein, R1 and R2 each independently represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms which is optionally branched, or the like; and R represents an alkyl group having 1 to 30 carbon atoms which is optionally branched, an alkenyl group having 2 to 30 carbon atoms which is optionally branched, or the like).
    • 提供一种层压膜的制造方法,通过该层叠膜,可以制造与叠层基材具有优异粘附性的层压膜,其中层压膜的添加剂溶解到溶剂中的量少。 制造层压膜的方法的特征在于包括在具有烯键式不饱和键的单体聚合之前或期间,将由有机铝化合物掩蔽的由下式(1)表示的酚类抗氧化剂加入到 催化剂体系,聚合体系和管道中的至少一种,相对于100质量份通过聚合得到的聚合物,酚类抗氧化剂的配合量为0.001〜0.5质量份(式中, R 1和R 2各自独立地表示氢原子,可以具有支链的碳原子数1〜5的烷基等,R表示任意支链的碳原子数为1〜30的烷基,具有2个 至30个碳原子,其任选是支链的等)。
    • 9. 发明申请
    • POLYOLEFIN RESIN COMPOSITION
    • 聚烯烃树脂组合物
    • US20100240815A1
    • 2010-09-23
    • US12680398
    • 2008-08-29
    • Tsuyoshi UrushiharaNaoto UedaNaoshi Kawamoto
    • Tsuyoshi UrushiharaNaoto UedaNaoshi Kawamoto
    • C08K5/20
    • C08K5/0083C08K5/20C08L23/02
    • A polyolefin resin composition having a high crystallization temperature and excellent transparency is provided.Disclosed is a polyolefin resin composition comprising 0.01 to 10 parts by mass of a methylenebisanilide compound with respect to 100 parts by mass of a polyolefin resin, which methylenebisanilide compound is represented by the following General Formula (1): (wherein each of X1, X2, X3, X4, X5, X6, X7 and X8 independently represents a hydrogen atom or C1-C10 alkyl which is optionally substituted or branched; and each of R1 and R2 independently represents a hydrogen atom, C1-C21 alkyl which is optionally substituted or branched, C3-C12 cycloalkyl which is optionally substituted, or C6-C20 aryl which is optionally substituted).
    • 提供了具有高结晶温度和优异透明度的聚烯烃树脂组合物。 公开了一种聚烯烃树脂组合物,其相对于100质量份的聚烯烃树脂含有0.01〜10质量份的亚甲基双酰苯胺化合物,该亚甲基双苯赖德化合物由以下通式(1)表示:(其中X1,X2 X3,X4,X5,X6,X7和X8独立地表示氢原子或任选取代或支链的C 1 -C 10烷基; R 1和R 2各自独立地表示氢原子,任选取代的C 1 -C 21烷基或 支链的,任选取代的C 3 -C 12环烷基或任选被取代的C 6 -C 20芳基)。