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    • 8. 发明申请
    • Process for the Manufacturing of an Optical Article and Optical Article
    • 光学制品和光学制品的制造工艺
    • US20160170095A1
    • 2016-06-16
    • US14906814
    • 2013-07-23
    • ESSILOR INTERNATIONAL (COMPAGNIE GÉNÉRALE D'OPTIQUE)
    • Haipeng ZHENG
    • G02B1/111B05D7/00
    • G02B1/111B05D7/50C08K3/22C08K3/34C09D5/006C09D7/61G02B27/0006
    • The invention relates to a process for the manufacturing of an optical article comprising forming a multilayered coating on at least one face of an uncoated or coated substrate,and forming on the outermost layer of said multilayered coating, a layer-by-layer (LbL) coating exposed to environment, said LbL coating comprising at least two bilayers, each bilayer being formed successively by: i) applying a first layer composition comprising at least one compound A having a first electrical charge; ii) applying, directly onto the first layer resulting from i),a second layer composition comprising at least one compound B having a second electrical charge, said second electrical charge being opposite to said first electrical charge; iii) repeating at least once steps i) and ii), with the provisos that: -each of compounds A and B is independently chosen from polysaccharide polymers and colloids of metal oxide such as TiO2 and ZrO2 or silicon oxide, with the proviso that at least one of the compounds A and B is a polysaccharide polymer,—each of said compounds A and B is positively or negatively charged respectively, and d) crosslinking the first and second layers of said bilayers of the LbL coating by treatment with an aqueous composition comprising at least tetrakis(2-hydroxyethyl) orthosilicate (THEOS) as crosslinking agent to induce chemical linkages between compounds A and B. The invention also relates to the optical substrate obtained according to this process.
    • 本发明涉及一种制造光学制品的方法,包括在未涂覆或涂覆的基材的至少一个表面上形成多层涂层,并在所述多层涂层的最外层上形成层叠(LbL) 所述LbL涂层包含至少两个双层,每个双层通过以下步骤形成:i)施加包含至少一种具有第一电荷的化合物A的第一层组合物; ii)直接施加到由i)产生的第一层上,第二层组合物包含至少一种具有第二电荷的化合物B,所述第二电荷与所述第一电荷相反; iii)重复至少一次步骤i)和ii),条件是: - 化合物A和B中的每一个独立地选自金属氧化物如TiO 2和ZrO 2或氧化硅的多糖聚合物和胶体,条件是在 化合物A和B中的至少一种是多糖聚合物,所述化合物A和B中的每一种分别是带正电荷或带负电荷的,以及d)通过用水性组合物处理来交联LbL涂层的所述双层的第一层和第二层 包括至少四(2-羟乙基)原硅酸盐(THEOS)作为交联剂以诱导化合物A和B之间的化学键。本发明还涉及根据该方法获得的光学基底。