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1. 发明授权

US07902535B2 Functional molecular element 有权
标题翻译：功能分子元素
公开(公告)号：US07902535B2
公开(公告)日：2011-03-08
申请号：US10597845
申请日：2005-02-02
申请人： Eriko Matsui , Haruo Watanabe , Oliver Harnack , Nobuyuki Matsuzawa , Akio Yasuda , Tadashi Mizutani , Takae Yamauchi , Susumu Kitagawa
发明人： Eriko Matsui , Haruo Watanabe , Oliver Harnack , Nobuyuki Matsuzawa , Akio Yasuda , Tadashi Mizutani , Takae Yamauchi , Susumu Kitagawa
IPC分类号： H01L47/00
CPC分类号： H01L51/0595 , B82Y10/00 , G02F1/061 , G02F1/167 , G11C11/5664 , G11C13/0014 , G11C13/0016 , G11C13/0069 , G11C2013/009 , G11C2213/14 , G11C2213/77 , H01L51/0076 , H01L51/0077 , H01L51/0508 , H01L51/0554 , H01L51/0591 , H01L51/428 , Y02E10/549
摘要： A functional molecular element is provided. The functional molecular element is adapted to change, by application of electric field, conformation of a disc shape like organic metallic complex molecule (1) which forms a columnar arrangement structure to exhibit function, wherein the structure of the organic metallic complex molecule is changed by application of electric field so that anisotropy of dielectric constant is changed. Accordingly, conductivity between measurement electrodes can be switched. As its stable value, there are three kinds of stable values or more. Thus, elements or devices to which such multi-value memory characteristic is applied can be constituted.
摘要翻译：提供功能性分子元件。功能分子元件适于通过施加电场来改变像圆形形状的有机金属络合物分子（1）的构型，其形成柱状排列结构以显示功能，其中有机金属络合物分子的结构由施加电场使介电常数各向异性发生变化。因此，可以切换测量电极之间的电导率。作为其稳定值，有三种稳定值或更多。因此，可以构成应用这种多值存储特性的元件或装置。

2. 发明授权

US07679080B2 Functional molecular device 失效
标题翻译：功能分子装置
公开(公告)号：US07679080B2
公开(公告)日：2010-03-16
申请号：US11571135
申请日：2005-06-23
申请人： Eriko Matsui , Nobuyuki Matsuzawa , Akio Yasuda , Oliver Harnack
发明人： Eriko Matsui , Nobuyuki Matsuzawa , Akio Yasuda , Oliver Harnack
IPC分类号： H01L51/30
CPC分类号： B82Y30/00 , B82Y10/00 , H01L27/283 , H01L51/005 , H01L51/0067 , H01L51/0512 , H01L51/0583 , H01L51/0595 , Y10S977/731 , Y10S977/791 , Y10S977/94 , Y10S977/943
摘要： A functional molecular device displaying its functions under the action of an electrical field is provided. A Louis base molecule, exhibiting positive dielectric constant anisotropy or exhibiting dipole moment along the long-axis direction of the Louis base molecule, is arrayed in the form of a pendant on an electrically conductive linear or film-shaped principal-axis molecule of a conjugated system, via a metal ion capable of acting as a Louis acid. The resulting structure is changed in conformation on application of an electrical field to exhibit its function. The electrically conductive linear or film-shaped principal-axis molecule and the Louis base molecule form a complex with the metal ion. On application of the electrical field, the Louis base molecule performs a swinging movement or a seesaw movement to switch the electrical conductivity of the principal-axis molecule. This molecule exhibits electrical characteristics which may be reversed depending on whether or not the molecule has been subjected to electrical field processing. A molecular device having a function equivalent to one of CMOS may be produced from one and the same material.
摘要翻译：提供了在电场作用下显示其功能的功能分子装置。在路易斯碱分子的长轴方向显示出正介电常数各向异性或显示偶极矩的路易斯碱基分子以共轭的导电线性或膜状主轴分子的侧基的形式排列系统，通过能够作为路易斯酸的金属离子。所产生的结构在施加电场以表现其功能的结构上改变。导电线性或膜状主轴分子和路易斯碱分子与金属离子形成络合物。在施加电场时，路易斯碱分子进行摆动运动或跷跷板运动以切换主轴分子的导电性。该分子表现出电特性，其可以根据分子是否经受电场加工而反转。具有与CMOS之一相当的功能的分子器件可以由同一材料制造。

3. 发明申请

US20090224223A1 FUNCTIONAL MOLECULAR ELEMENT 有权
标题翻译：功能分子元素
公开(公告)号：US20090224223A1
公开(公告)日：2009-09-10
申请号：US10597845
申请日：2005-02-02
申请人： Eriko Matsui , Haruo Watanabe , Oliver Harnack , Nobuyuki Matsuzawa , Akio Yasuda , Tadashi Mizutani , Takae Yamauchi , Susumu Kitagawa
发明人： Eriko Matsui , Haruo Watanabe , Oliver Harnack , Nobuyuki Matsuzawa , Akio Yasuda , Tadashi Mizutani , Takae Yamauchi , Susumu Kitagawa
IPC分类号： H01L45/00
CPC分类号： H01L51/0595 , B82Y10/00 , G02F1/061 , G02F1/167 , G11C11/5664 , G11C13/0014 , G11C13/0016 , G11C13/0069 , G11C2013/009 , G11C2213/14 , G11C2213/77 , H01L51/0076 , H01L51/0077 , H01L51/0508 , H01L51/0554 , H01L51/0591 , H01L51/428 , Y02E10/549
摘要： A functional molecular element is provided. The functional molecular element is adapted to change, by application of electric field, conformation of a disc shape like organic metallic complex molecule (1) which forms a columnar arrangement structure to exhibit function, wherein the structure of the organic metallic complex molecule is changed by application of electric field so that anisotropy of dielectric constant is changed. Accordingly, conductivity between measurement electrodes can be switched. As its stable value, there are three kinds of stable values or more. Thus, elements or devices to which such multi-value memory characteristic is applied can be constituted.
摘要翻译：提供功能性分子元件。功能分子元件适于通过施加电场来改变像圆形形状的有机金属络合物分子（1）的构型，其形成柱状排列结构以显示功能，其中有机金属络合物分子的结构由施加电场使介电常数各向异性发生变化。因此，可以切换测量电极之间的电导率。作为其稳定值，有三种稳定值或更多。因此，可以构成应用这种多值存储特性的元件或装置。

4. 发明申请

US20090159873A1 FUNCTIONAL MOLECULAR DEVICE 失效
标题翻译：功能分子装置
公开(公告)号：US20090159873A1
公开(公告)日：2009-06-25
申请号：US11571135
申请日：2005-06-23
申请人： Eriko Matsui , Nobuyuki Matsuzawa , Akio Yasuda , Oliver Harnack
发明人： Eriko Matsui , Nobuyuki Matsuzawa , Akio Yasuda , Oliver Harnack
IPC分类号： H01L51/30
CPC分类号： B82Y30/00 , B82Y10/00 , H01L27/283 , H01L51/005 , H01L51/0067 , H01L51/0512 , H01L51/0583 , H01L51/0595 , Y10S977/731 , Y10S977/791 , Y10S977/94 , Y10S977/943
摘要： A functional molecular device displaying its functions under the action of an electrical field is provided. A Louis base molecule, exhibiting positive dielectric constant anisotropy or exhibiting dipole moment along the long-axis direction of the Louis base molecule, is arrayed in the form of a pendant on an electrically conductive linear or film-shaped principal-axis molecule of a conjugated system, via a metal ion capable of acting as a Louis acid. The resulting structure is changed in conformation on application of an electrical field to exhibit its function. The electrically conductive linear or film-shaped principal-axis molecule and the Louis base molecule form a complex with the metal ion. On application of the electrical field, the Louis base molecule performs a swinging movement or a seesaw movement to switch the electrical conductivity of the principal-axis molecule. This molecule exhibits electrical characteristics which may be reversed depending on whether or not the molecule has been subjected to electrical field processing. A molecular device having a function equivalent to one of CMOS may be produced from one and the same material.
摘要翻译：提供了在电场作用下显示其功能的功能分子装置。在路易斯碱分子的长轴方向显示出正介电常数各向异性或显示偶极矩的路易斯碱基分子以共轭的导电线性或膜状主轴分子的侧基的形式排列系统，通过能够作为路易斯酸的金属离子。所产生的结构在施加电场以表现其功能的结构上改变。导电线性或膜状主轴分子和路易斯碱分子与金属离子形成络合物。在施加电场时，路易斯碱分子进行摆动运动或跷跷板运动以切换主轴分子的导电性。该分子表现出电特性，其可以根据分子是否经受电场加工而反转。具有与CMOS之一相当的功能的分子器件可以由同一材料制造。

5. 发明申请

US20060081838A1 Functional molecular element and functional molecular device 失效
标题翻译：功能分子元素和功能分子装置
公开(公告)号：US20060081838A1
公开(公告)日：2006-04-20
申请号：US10540237
申请日：2003-12-25
申请人： Eriko Matsui , Oliver Harnack , Nobuyuki Matsuzawa , Akio Yasuda
发明人： Eriko Matsui , Oliver Harnack , Nobuyuki Matsuzawa , Akio Yasuda
IPC分类号： H01L29/08 , H01L35/24 , H01L51/00
CPC分类号： H01L51/0595 , B82Y10/00 , Y10S977/731 , Y10S977/791 , Y10S977/94 , Y10S977/943
摘要： A functional molecular element whose functions can be controlled by an electric field based on a new principle. A Lewis base molecule (14) with positive permittivity anisotropy or a dipole moment in the major axis direction of the molecule is disposed, via a metal ion (3) that can act as a Lewis acid, in a pendant-like form on a key molecule (2) in the form of a line or film that has a conjugated system and exhibits conductivity, thereby forming a functional molecular element 1 that can realize a function where the conformation changes due to the application of an electric field. The conductive key molecule (2) and the Lewis base molecule (14) form a complex with the metal ion (3). When an electric field is applied in a direction perpendicular to the plane of the paper in FIG. 1(b), for example, the Lewis base molecule (14) performs a 90° “neck twisting” movement with the up-down direction in the drawing as the axis. Also, when an electric field is applied in the up-down direction in the drawing as shown in FIG. 1(c), the Lewis base molecule (14) performs a “see-saw” movement with the direction perpendicular to the plane of the paper as the axis, thereby switching the conductivity of the conductive key molecule (2).
摘要翻译：功能分子元素，其功能可以通过电场控制，基于新的原理。通过可以作为路易斯酸的金属离子（3）以键状形式在键上设置在分子的长轴方向上具有正介电常数各向异性或偶极矩的路易斯碱分子（14）分子（2）以具有共轭体系的线或膜的形式表现出导电性，从而形成能够实现构象由于施加电场而变化的功能的功能分子元件1。导电键分子（2）和路易斯碱分子（14）与金属离子（3）形成络合物。当在垂直于图1中纸面的方向上施加电场时，如图1（b）所示，例如，路易斯碱分子（14）以图中的上下方向为轴进行90°的“颈部扭转”运动。此外，如图所示，当在图中的上下方向上施加电场时，如图1（c）所示，路易斯碱分子（14）以垂直于纸面的方向作为轴进行“跷跷板”运动，从而切换导电键分子（2）的导电性。

6. 发明授权

US08692231B2 Functional molecular element and functional molecular device 失效
标题翻译：功能分子元素和功能分子装置
公开(公告)号：US08692231B2
公开(公告)日：2014-04-08
申请号：US11571136
申请日：2005-06-24
申请人： Eriko Matsui , Nobuyuki Matsuzawa , Akio Yasuda , Oliver Harnack
发明人： Eriko Matsui , Nobuyuki Matsuzawa , Akio Yasuda , Oliver Harnack
IPC分类号： H01L35/24 , H01L29/08
CPC分类号： G11C13/0014 , B82Y10/00 , B82Y30/00 , G11C2213/14 , H01L51/0036 , H01L51/0039 , H01L51/0068 , H01L51/0512 , H01L51/0545 , H01L51/0583 , H01L51/0595
摘要： A functional molecular element exhibiting its function under the operation of an electrical field is provided. A compound is used in which a pendant molecule, formed by 4-pentyl-4′-cyanobiphenyl, exhibiting positive dielectric constant anisotropy or a dipole moment along the direction of the long axis of the molecule, is covalently bonded to an electrically conductive linear or film-shaped principal-axis molecule having a conjugated system. The pendant molecule is changed in its orientation on application of an electrical field to change the conformation to switch the electrical conductivity of the electrically conductive principal-axis molecule.
摘要翻译：提供了在电场操作下表现出其功能的功能分子元件。使用化合物，其中由4-戊基-4'-氰基联苯形成的侧分子沿着分子的长轴方向显示出正介电常数各向异性或偶极矩，共价键合到导电线性或具有共轭体系的膜状主轴分子。在施加电场以改变构象以改变导电主轴分子的导电性的情况下，侧分子的取向发生变化。

7. 发明授权

US07408184B2 Functional molecular element and functional molecular device 失效
标题翻译：功能分子元素和功能分子装置
公开(公告)号：US07408184B2
公开(公告)日：2008-08-05
申请号：US10540237
申请日：2003-12-25
申请人： Eriko Matsui , Oliver Harnack , Nobuyuki Matsuzawa , Akio Yasuda
发明人： Eriko Matsui , Oliver Harnack , Nobuyuki Matsuzawa , Akio Yasuda
IPC分类号： H01L51/30
CPC分类号： H01L51/0595 , B82Y10/00 , Y10S977/731 , Y10S977/791 , Y10S977/94 , Y10S977/943
摘要： A functional molecular element whose functions can be controlled by an electric field based on a new principle. A Lewis base molecule (14) with positive permittivity anisotropy or a dipole moment in the major axis direction of the molecule is disposed, via a metal ion (3) that can act as a Lewis acid, in a pendant-like form on a key molecule (2) in the form of a line or film that has a conjugated system and exhibits conductivity, thereby forming a functional molecular element 1 that can realize a function where the conformation changes due to the application of an electric field. The conductive key molecule (2) and the Lewis base molecule (14) form a complex with the metal ion (3). When an electric field is applied in a direction perpendicular to the plane of the paper in FIG. 1(b), for example, the Lewis base molecule (14) performs a 90° “neck twisting” movement with the up-down direction in the drawing as the axis. Also, when an electric field is applied in the up-down direction in the drawing as shown in FIG. 1(c), the Lewis base molecule (14) performs a “see-saw” movement with the direction perpendicular to the plane of the paper as the axis, thereby switching the conductivity of the conductive key molecule (2).
摘要翻译：功能分子元素，其功能可以通过电场控制，基于新的原理。通过可以作为路易斯酸的金属离子（3）以键状形式在键上设置在分子的长轴方向上具有正介电常数各向异性或偶极矩的路易斯碱分子（14）分子（2）以具有共轭体系的线或膜的形式表现出导电性，从而形成能够实现构象由于施加电场而变化的功能的功能分子元件1。导电键分子（2）和路易斯碱分子（14）与金属离子（3）形成络合物。当在垂直于图1中的纸平面的方向上施加电场时，如图1（b）所示，例如，路易斯碱分子（14）以图中的上下方向为轴进行90°的“颈部扭转”运动。此外，如图所示，当在图中的上下方向上施加电场时，如图1（c）所示，路易斯碱分子（14）以垂直于纸面的方向作为轴进行“跷跷板”运动，从而切换导电键分子（2）的导电性。

8. 发明申请

US20070241324A1 Functional Molecular Element and Functional Molecular Device 失效
标题翻译：功能分子元件和功能分子装置
公开(公告)号：US20070241324A1
公开(公告)日：2007-10-18
申请号：US11571136
申请日：2005-06-24
申请人： Eriko Matsui , Nobuyuki Matsuzawa , Akio Yasuda , Oliver Harnack
发明人： Eriko Matsui , Nobuyuki Matsuzawa , Akio Yasuda , Oliver Harnack
IPC分类号： H01L51/00
CPC分类号： G11C13/0014 , B82Y10/00 , B82Y30/00 , G11C2213/14 , H01L51/0036 , H01L51/0039 , H01L51/0068 , H01L51/0512 , H01L51/0545 , H01L51/0583 , H01L51/0595
摘要： A functional molecular element exhibiting its function under the operation of an electrical field is provided. A compound is used in which a pendant molecule, formed by 4-pentyl-4′-cyanobiphenyl, exhibiting positive dielectric constant anisotropy or a dipole moment along the direction of the long axis of the molecule, is covalently bonded to an electrically conductive linear or film-shaped principal-axis molecule having a conjugated system. The pendant molecule is changed in its orientation on application of an electrical field to change the conformation to switch the electrical conductivity of the electrically conductive principal-axis molecule.
摘要翻译：提供了在电场操作下表现出其功能的功能分子元件。使用化合物，其中由4-戊基-4'-氰基联苯形成的侧分子沿着分子的长轴方向显示出正介电常数各向异性或偶极矩，共价键合到导电线性或具有共轭体系的膜状主轴分子。在施加电场以改变构象以改变导电主轴分子的导电性的情况下，侧分子的取向发生变化。

9. 发明申请

US20070159572A1 Element for modulating area 失效
标题翻译：用于调制区域的元件
公开(公告)号：US20070159572A1
公开(公告)日：2007-07-12
申请号：US10598774
申请日：2005-03-08
申请人： Eriko Matsui , Haruo Watanabe , Nobuyuki Matsuzawa , Akio Yasuda , Tadashi Mizutani , Takae Yamauchi , Susumu Kitagawa
发明人： Eriko Matsui , Haruo Watanabe , Nobuyuki Matsuzawa , Akio Yasuda , Tadashi Mizutani , Takae Yamauchi , Susumu Kitagawa
IPC分类号： G02F1/1333
CPC分类号： G02F1/01 , C09K19/40
摘要： The present invention is directed to an element for modulating area, in which there is used a functional molecular element adapted to change, by application of electric field, conformation of disc-shape like organic metallic complex molecule to exhibit function so that the structure of the organic metallic complex molecule is changed by application of electric field and the occupation area thereof is thus changed. The area modulating element is adapted to variously change molecular structure in accordance with control of applied electric field to change occupation area of molecule to thereby constitute a functional device such as optical filter and/or optical screen, etc.
摘要翻译：本发明涉及一种用于调制区域的元件，其中使用适于通过施加电场来改变圆盘形状的有机金属络合物分子的构象以展现功能的功能性分子元件，以使得其结构有机金属络合物分子通过施加电场而改变，因此其占用面积发生变化。面积调制元件适于根据施加的电场的控制来不同地改变分子结构，以改变分子的占有面积，从而构成诸如光学滤波器和/或光学屏幕等功能器件。

10. 发明授权

US07518783B2 Element for modulating area 失效
标题翻译：用于调制区域的元件
公开(公告)号：US07518783B2
公开(公告)日：2009-04-14
申请号：US10598774
申请日：2005-03-08
申请人： Eriko Matsui , Haruo Watanabe , Nobuyuki Matsuzawa , Akio Yasuda , Tadashi Mizutani , Takae Yamauchi , Susumu Kitagawa
发明人： Eriko Matsui , Haruo Watanabe , Nobuyuki Matsuzawa , Akio Yasuda , Tadashi Mizutani , Takae Yamauchi , Susumu Kitagawa
IPC分类号： G02F1/00 , G02F1/061 , C09K19/02
CPC分类号： G02F1/01 , C09K19/40
摘要： An element for modu1ating an area is provided. The element for modulating area, in which there is used a functional molecular element adapted to change, by application of electric field, conformation of disc-shape like organic metallic complex molecule to exhibit function so that the structure of the organic metallic complex molecule is changed by application of electric field and the occupation area thereof is thus changed. The area modulating element is adapted to variously change molecular structure in accordance with control of applied electric field to change occupation area of molecule to thereby constitute a functional device such as optical filter and/or optical screen, etc.
摘要翻译：提供了一个用于修改区域的元素。用于调制区域的元件，其中使用适于通过施加电场改变的功能分子元件，像有机金属络合物分子那样的盘状构象以显示有机金属络合物分子的结构变化因此通过施加电场而改变其占用面积。面积调制元件适于根据施加的电场的控制来不同地改变分子结构，以改变分子的占有面积，从而构成诸如光学滤波器和/或光学屏幕等功能器件。

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