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    • 5. 发明授权
    • Process for recovering a polymer from a solution
    • 从溶液中回收聚合物的方法
    • US08530618B2
    • 2013-09-10
    • US12677906
    • 2008-09-18
    • Jean-Christophe LepersDenis GeetsJean-Raphael Caille
    • Jean-Christophe LepersDenis GeetsJean-Raphael Caille
    • C08F6/00
    • C08J11/08C08F6/12C08J2327/06Y02W30/701C08L27/06
    • Process for recovering a polymer by injection of steam, and optionally liquid water, into a solution of this polymer comprising a polar aprotic organic solvent (PAOS) that has an azeotrope with water and an apolar organic compound that is miscible with the PAOS and immiscible with water and that acts as a phase separation agent (PSA), the boiling point of which is below that of the water/PAOS azeotrope, the amount of steam injected being sufficient to give rise to the substantial removal of the PSA via stripping and that of the PAOS via azeotropic distillation, and the total amount of water being sufficient to give rise to the precipitation of the polymer, this process being characterized in that the polymer solution also comprises an alcohol, at least during the precipitation of the polymer.
    • 通过将蒸汽和任选的液态水注入到聚合物的溶液中来回收聚合物的方法,该聚合物包含与水共沸的极性非质子有机溶剂(PAOS)和与PAOS可混溶并与PAOS混溶的非极性有机化合物, 水,并且其作为相分离剂(PSA),其沸点低于水/ PAOS共沸物的沸点,注入的蒸汽量足以通过汽提产生基本上的PSA去除; PAOS通过共沸蒸馏,并且水的总量足以引起聚合物的沉淀,该方法的特征在于聚合物溶液还包含醇,至少在聚合物的沉淀期间。