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1. 发明申请

US20050203319A1 Process for the preparation of oligomers 审中-公开
标题翻译：制备低聚物的方法
公开(公告)号：US20050203319A1
公开(公告)日：2005-09-15
申请号：US11122470
申请日：2005-05-05
申请人： Eric De Boer , Hendrikus Deuling , Klaas Von Hebel , Bart Ruisch , Arie Van Zon
发明人： Eric De Boer , Hendrikus Deuling , Klaas Von Hebel , Bart Ruisch , Arie Van Zon
IPC分类号： C08F10/00 , C07C2/32 , C08F4/64 , C08F4/44 , C07C13/00
CPC分类号： C07C2/32 , C07C2531/02 , C07C2531/22
摘要： Process for the oligomerization of one or more olefinically unsaturated monomers comprising three or more carbon atoms, at least one of these monomers consisting of a C3 to C30 aliphatic mono-olefin, which process comprises reacting the olefinically unsaturated monomer(s) under oligomerization conditions in the presence of an effective amount of a catalyst system based on (a) a specific titanium bisamide compound or its dimer; (b) one or more activating cocatalysts comprising at least one boron atom; and optionally, but in any event if the titanium bisamide compound or its dimer comprise halogen: (c) one or more aluminium alkyls or alumoxanes. A mixture of homo-oligomers of propylene is provided by the above process, which mixture comprises oligomers of propylene based on up to 20 propylene molecules, wherein at least 50 mole % of the oligomer chains have a terminal vinyl group.
摘要翻译：一种或多种包含三个或更多个碳原子的烯属不饱和单体的低聚的方法，这些单体中的至少一种由C 3〜C 30脂族单烯烃该方法包括在有效量的催化剂体系存在下，在低聚条件下使烯属不饱和单体基于（a）特定的钛双酰胺化合物或其二聚体; （b）一种或多种包含至少一个硼原子的活化助催化剂; 并且任选地，但无论如何，如果钛二酰胺化合物或其二聚体包含卤素：（c）一种或多种烷基铝或铝氧烷。通过上述方法提供丙烯均聚物的混合物，该混合物包含基于至多20个丙烯分子的丙烯低聚物，其中至少50摩尔％的低聚物链具有末端乙烯基。

2. 发明申请

US20050059786A1 Process for the co-oligomerisation of ethylene and alpha olefins 失效
标题翻译：乙烯和α-烯烃的共低聚方法
公开(公告)号：US20050059786A1
公开(公告)日：2005-03-17
申请号：US10739715
申请日：2003-12-18
申请人： Eric De Boer , Hendrikus Deuling , Harry Van Der Heijden , Quoc On , Aart Van Oort , Arie Van Zon
发明人： Eric De Boer , Hendrikus Deuling , Harry Van Der Heijden , Quoc On , Aart Van Oort , Arie Van Zon
IPC分类号： C07D213/53 , C07B61/00 , C07C2/32 , C07C11/02 , C08F4/44
CPC分类号： C07C2/32 , C07C11/02 , C07C2531/22 , Y02P20/52 , Y02P20/582
摘要： A process for production of higher linear alpha olefins and/or alkyl-branched alpha olefins, which comprises the co-oligomerisation of one or more alpha olefins with ethylene in the presence of a metal catalyst system employing one or more bis-aryliminepyridine MXa complexes and/or one or more [bis-aryliminepyridine MYp.Lb+][NC−]q complexes; and said process is carried out at an ethylene pressure of less than 2.5 MPa.
摘要翻译：一种制备高级直链α-烯烃和/或烷基支链α-烯烃的方法，其包括在使用一种或多种双 - 芳基亚胺吡啶MXa络合物的金属催化剂体系存在下，一种或多种α-烯烃与乙烯的共低聚反应，以及 /或一种或多种[双芳基亚氨基吡啶MYp.Lb +] [NC“] q络合物; 所述方法在小于2.5MPa的乙烯压力下进行。

3. 发明申请

US20050014983A1 Process for producing linear alpha olefins 审中-公开
标题翻译：生产线性α-烯烃的方法
公开(公告)号：US20050014983A1
公开(公告)日：2005-01-20
申请号：US10883600
申请日：2004-07-01
申请人： Eric De Boer , Harry Van Der Heijden , Eric Kragtwijk , Quoc On , Johan Smit , Arie Van Zon
发明人： Eric De Boer , Harry Van Der Heijden , Eric Kragtwijk , Quoc On , Johan Smit , Arie Van Zon
IPC分类号： B01J31/12 , B01J31/14 , B01J31/18 , C07C2/32 , C08F4/70 , C08F10/00 , C07C2/26 , B01J31/00
CPC分类号： C07C2/32 , B01J31/143 , B01J31/1815 , B01J2231/20 , B01J2531/842 , B01J2531/845 , C07C2531/14 , C08F10/00 , C08F4/7042
摘要： A process for the production of alpha-olefins comprising reacting ethylene under oligomerization conditions in the presence of a mixture comprising: (a) a metal salt based on Fe(II), Fe(III), Co(II) or Co(III); (b) a pyridine bis-imine ligand; and (c) a co-catalyst which is the reaction product of water with one or more organometallic aluminium compounds, wherein the one or more organometallic aluminium compounds is selected from: (i) βδ-branched compounds of formula (I): Al(CH2—CR1R2—CH2—CR4R5R6)xR3yHz; (ii) βγ-branched compounds of formula (II) Al(CH2—CR1R2—CR4R5R6)xR3yHz and mixtures thereof; wherein when the metal salt and the bis-arylimine pyridine ligand are mixed together they are soluble in aliphatic or aromatic hydrocarbon solvent.
摘要翻译：一种制备α-烯烃的方法，包括在低聚条件下，在混合物存在下使乙烯反应，所述混合物包含：（a）基于Fe（II），Fe（III），Co（II）或Co（III）的金属盐， ; （b）吡啶双亚胺配体; 和（c）作为水与一种或多种有机金属铝化合物的反应产物的助催化剂，其中所述一种或多种有机金属铝化合物选自：（i）式（I）的betadelta支化化合物：Al CH2-CR 1 R 2 -CH2-CR 4 R 5 R 6）xR 3Hz; （ⅱ）式（Ⅱ）bet ma ma ma branched branched branched）Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz;;;;;;;;;;;;;; 其中当将金属盐和双芳基亚胺吡啶配体混合在一起时，它们可溶于脂族或芳族烃溶剂。

4. 发明申请

US20050159601A1 Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins 失效
标题翻译：用于乙烯低聚至直链α-烯烃的配体及其催化剂体系
公开(公告)号：US20050159601A1
公开(公告)日：2005-07-21
申请号：US11080170
申请日：2005-03-15
申请人： Eric De Boer , Harry Van Der Heijden , Wilhelmina Verhoef-Van Wijk , Arie Van Zon
发明人： Eric De Boer , Harry Van Der Heijden , Wilhelmina Verhoef-Van Wijk , Arie Van Zon
IPC分类号： C07D213/53 , C07D401/12 , C07D401/14 , C07F15/02 , C07F15/06 , C07F17/00 , C08F4/70 , C08F10/00 , C07F1/00 , C07C2/02 , C08F4/44
CPC分类号： C08F10/00 , C07F15/025 , C07F15/065 , C07F17/00 , Y02P20/582 , C08F4/7042
摘要： Mixed bis-imine pyridine ligands of formula (I), wherein Z1, which is different from Z2, is an optionally substituted aryl group; and Z2 comprises an optionally substituted heterohydrocarbyl moiety, or an optionally substituted aryl group in combination with a metal, said optionally substituted aryl group being π-co-ordinated to the metal; mixed bis-imine pyridine complexes comprising a ligand of formula (I); mixed ionic bis-imine pyridine complexes comprising a ligand of formula (I); and processes for the production of alpha olefins from ethylene, using said complexes.
摘要翻译：式（I）的混合双亚胺吡啶配体，其中Z 1不同于Z 2，是任选取代的芳基; 和Z 2包括任选取代的杂烃基部分或与金属组合的任选取代的芳基，所述任选取代的芳基与金属配位; 包含式（I）的配体的混合的双亚胺吡啶络合物; 包含式（I）的配体的混合离子双亚胺吡啶络合物; 以及使用所述复合物从乙烯生产α-烯烃的方法。

5. 发明申请

US20070299290A1 CATALYTIC TRIMERIZATION AND TETRAMERIZATION OF OLEFINIC MONOMERS 失效
标题翻译：烯烃单体的催化三聚和四聚体
公开(公告)号：US20070299290A1
公开(公告)日：2007-12-27
申请号：US11770520
申请日：2007-06-28
申请人： Eric De Boer , Harry Van Der Heijden , Quoc On , Johan Smit , Arie Van Zon
发明人： Eric De Boer , Harry Van Der Heijden , Quoc On , Johan Smit , Arie Van Zon
IPC分类号： C07C2/08 , B01J31/00
CPC分类号： B01J31/188 , B01J31/143 , B01J31/2409 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2540/10 , C07C2/36 , C07C2531/24 , C07C11/02 , C07C11/107
摘要： A catalyst precursor composition comprising a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I): (R1)(R2)P—X—P(R3)(R4) (I) where X is a bivalent organic bridging group, R1 and R3 are hydrocarbyl groups, and R2 and R4 are aromatic groups; and c) a second ligand having the general formula (II): (R1′)(R2′)P—X′—P(R3′)(R4′) (II) where X′ is a bridging group containing nitrogen and R1′, R2″, R3′ and R4′ are hydrocarbyl groups. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and a cocatalyst.
摘要翻译：一种催化剂前体组合物，其包含a）铬，钼或钨的源; b）具有通式（I）的第一配体：<？in-line-formula description =“In-line formula”end =“lead”？>（R 1 SUP）（2）PXP（R 3）（R 4）（I）<βin-line-formula description =“In-line Formulas”end = “尾”→>其中X是二价有机桥基，R 1和R 3是烃基，R 2和R 2， SUP> 4是芳基; 和（c）具有通式（II）的第二配位体：<？in-line-formula description =“In-line formula”end =“lead”→（R 1> （二）'P-X'-P（R 3'）（R 4'）（II）<β在线式描述=“在线公式”end =“tail”？>其中X'是含有氮和R 1'的桥连基团，R 2“，R” SUP 3'和R 4'是烃基。本发明还涉及包含本发明的催化剂前体组合物和助催化剂的催化剂体系。

6. 发明申请

US20070185357A1 CATALYTIC PROCESS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体低级化的催化方法
公开(公告)号：US20070185357A1
公开(公告)日：2007-08-09
申请号：US11561816
申请日：2006-11-20
申请人： Eric De Boer , Harry Van Der Heijden , Quoc On , Johan Smit , Arie Van Zon
发明人： Eric De Boer , Harry Van Der Heijden , Quoc On , Johan Smit , Arie Van Zon
IPC分类号： C07C2/34 , C07C2/26
CPC分类号： B01J31/188 , B01J31/143 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07C2/36 , C07C2531/24 , C07F9/46
摘要： A process for the simultaneous trimerization and tetramerization of olefinic monomers, wherein the process comprises contacting at least one olefinic monomer with a catalyst system comprising: a) a source of chromium, molybdenum or tungsten; b) a ligand having the general formula (I); (R1)2P-X-P(R1)m(R2)n (I) wherein: X is a bridging group of the formula —N(R3)—; the R1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; and c) a cocatalyst.
摘要翻译：烯烃单体的同时三聚和四聚的方法，其中所述方法包括使至少一种烯属单体与催化剂体系接触，所述催化剂体系包括：a）铬，钼或钨的来源; b）具有通式（I）的配体; <？in-line-formula description =“In-line Formulas”end =“lead”？>（R＆lt; 1＆gt;）2 PXP（R＆lt; 1＆（I）（I）<？in-line-formula description =“In-line Formulas”end = “尾”→其中：X是式-N（R 3 O 3） - 的桥基; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; 并且R“2”独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当基团是芳族的时，它在任何邻位不含极性取代基; 和c）助催化剂。

7. 发明申请

US20070129583A1 CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 有权
公开(公告)号：US20070129583A1
公开(公告)日：2007-06-07
申请号：US11561812
申请日：2006-11-20
申请人： Eric De Boer , Harry Der Heijden , Quoc An On , Johan Smit , Arie Zon
发明人： Eric De Boer , Harry Der Heijden , Quoc An On , Johan Smit , Arie Zon
IPC分类号： C07C13/00 , C07C2/34 , B01J31/00 , C07C2/24
CPC分类号： C07C2/36 , B01J31/188 , B01J31/34 , B01J2231/20 , B01J2531/62 , C07C2531/14 , C07C2531/24 , C07F9/46
摘要： A catalyst precursor composition comprising: a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I); (R1)(R2)P—X—P(R3)(R4) (I) wherein: X is a bridging group of the formula —N(R5)—, wherein R5 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; at least three of R1 to R4 are independently selected from optionally substituted aromatic groups, each bearing a polar substituent on at least one of the ortho-positions; and optionally one of R1 to R4 is independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; c) a second ligand having the general formula (II); (R1′)(R2′)P—X′—P(R3′)(R4′) (II) wherein: X′ is a bridging group as defined for X of the first ligand, component (b), of general formula (I); at least R1′ and R2′ of R1′ to R4′ are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; and optionally none, one or both of R3′ and R4′ are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and additional component; d) a cocatalyst. The present invention further relates to a process for the trimerization and tetramerization of olefinic monomers, particularly the trimerization and tetramerization of ethylene to 1-hexene and 1-octene, wherein the process comprises contacting at least one olefinic monomer with the catalyst system of the present invention.

8. 发明申请

US20070156704A1 METHOD FOR ACCESS TO SUBSCRIPTION DATA STORED IN A DATABASE ENTITY IN A MOBILE COMMUNICATION NETWORK 有权
标题翻译：用于访问移动通信网络中数据库实体中存储的订阅数据的方法
公开(公告)号：US20070156704A1
公开(公告)日：2007-07-05
申请号：US11610998
申请日：2006-12-14
申请人： Eric De Boer , Alain Bultinck
发明人： Eric De Boer , Alain Bultinck
IPC分类号： G06F17/30
CPC分类号： H04W8/18 , G06F17/30864 , H04W8/20
摘要： One object of the present invention is a method for access to subscription data stored in a database entity of a mobile communication network referred to as first database entity, storing subscription data referred to as first subscription data for support to network entities of said mobile communication network entities referred to as first network entities, said method comprising: a step wherein a database entity of said mobile communication network referred to as second database entity, storing subscription data referred to as second subscription data for support to network entities of said mobile communication network referred to as second network entities, communicates with said first database entity to have access to at least part of said first subscription data, a step wherein an Application Server communicates with said second database entity, to have access to said at least part of first subscription data via said second database entity.
摘要翻译：本发明的一个目的是访问存储在被称为第一数据库实体的移动通信网络的数据库实体中的订阅数据的方法，存储被称为第一订阅数据的订阅数据以用于支持所述移动通信网络的网络实体被称为第一网络实体的实体，所述方法包括：步骤，其中被称为第二数据库实体的所述移动通信网络的数据库实体存储被称为第二订阅数据的订阅数据，用于支持所述移动通信网络的网络实体作为第二网络实体，与所述第一数据库实体通信以访问所述第一订阅数据的至少一部分;步骤，其中应用服务器与所述第二数据库实体通信以访问所述至少部分第一订阅数据通过所述第二数据库实体。

9. 发明授权

US09037619B2 Method for access to subscription data stored in a database entity in a mobile communication network 有权
标题翻译：用于访问存储在移动通信网络中的数据库实体中的订阅数据的方法
公开(公告)号：US09037619B2
公开(公告)日：2015-05-19
申请号：US11610998
申请日：2006-12-14
申请人： Eric De Boer , Alain Bultinck
发明人： Eric De Boer , Alain Bultinck
IPC分类号： G06F12/00 , G06F17/30 , H04M11/00 , H04W4/00 , H04W8/18 , H04W24/00 , H04W8/20
CPC分类号： H04W8/18 , G06F17/30864 , H04W8/20
摘要： One object of the present invention is a method for access to subscription data stored in a database entity of a mobile communication network referred to as first database entity, storing subscription data referred to as first subscription data for support to network entities of the mobile communication network entities referred to as first network entities, the method comprising a step wherein a database entity of the mobile communication network referred to as second database entity, storing subscription data referred to as second subscription data for support to network entities of the mobile communication network referred to as second network entities, communicates with the first database entity to have access to at least part of the first subscription data, a step wherein an Application Server communicates with the second database entity, to have access to the at least part of first subscription data via the second database entity.
摘要翻译：本发明的一个目的是访问存储在被称为第一数据库实体的移动通信网络的数据库实体中的订阅数据的方法，存储被称为第一订阅数据的订阅数据，以支持移动通信网络的网络实体被称为第一网络实体的实体，所述方法包括以下步骤：将所述移动通信网络的数据库实体称为第二数据库实体，存储被称为第二订阅数据的订阅数据，以支持所述移动通信网络的网络实体作为第二网络实体，与第一数据库实体通信以访问至少部分第一订阅数据;步骤，其中应用服务器与第二数据库实体进行通信，以便通过以下方式访问第一订阅数据的至少部分：第二个数据库实体。

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