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1. 发明授权

US5633415A Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers 失效
标题翻译：选择性氢化聚合物的分散剂和分散剂粘度指数改进剂
公开(公告)号：US5633415A
公开(公告)日：1997-05-27
申请号：US488046
申请日：1995-06-07
申请人： Ellen B. Brandes , Frederick C. Loveless
发明人： Ellen B. Brandes , Frederick C. Loveless
IPC分类号： B01F17/52 , C07C15/40 , C08F8/00 , C08F8/04 , C08F8/08 , C08F236/04 , C08F297/02 , C09K3/00 , C10L1/16 , C10L1/18 , C10L1/195 , C10L1/196 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/24 , C10L10/00 , C10L10/18 , C10M143/08 , C10M143/12 , C10M145/00 , C10M145/02 , C10M147/00 , C10M149/06 , C10M149/10 , C10M151/02 , C10N30/02 , C10N30/04 , C10N40/04 , C10N40/08 , C10M143/10 , C08F236/00
CPC分类号： C10L1/1955 , C07C15/40 , C08F236/04 , C08F297/02 , C08F8/00 , C08F8/04 , C08F8/08 , C10L1/1658 , C10L1/195 , C10L1/196 , C10L1/198 , C10L1/207 , C10L1/236 , C10L1/238 , C10L1/2468 , C10L1/2475 , C10L10/00 , C10M143/12 , C10M149/06 , C10M149/10 , C10L1/1963 , C10L1/1966 , C10L1/2364 , C10L1/2366 , C10L1/2368 , C10L1/2383 , C10L1/2387 , C10M2205/04 , C10M2205/06 , C10M2215/04 , C10M2215/26 , C10M2217/024 , C10M2217/028 , C10M2217/046 , C10M2217/06
摘要： The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated and functionalized. The dispersant substances include compositions including a copolymer of two different conjugated dienes, a copolymer of a p-alkylstyrene and a conjugated diene, or a homopolymer of a conjugated diene. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.
摘要翻译：本发明提供分散剂和分散剂粘度指数改进剂，其包括已被氢化和官能化的共轭二烯的聚合物。分散剂物质包括包含两种不同共轭二烯的共聚物，对烷基苯乙烯和共轭二烯的共聚物或共轭二烯的均聚物的组合物。聚合物被选择性氢化以产生具有高度受控量的不饱和度的聚合物，允许高选择性官能化。还提供了通过本发明的分散剂物质改性其分散性和/或粘度特性的润滑剂流体，例如矿物油和合成油。还提供了改变润滑流体如矿物和合成润滑油的分散性和/或粘度特性的方法。分散剂物质还可以包括提供分散剂浓缩物的载体流体。

2. 发明授权

US5637783A Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers 失效
标题翻译：选择性氢化聚合物的分散剂和分散剂粘度指数改进剂
公开(公告)号：US5637783A
公开(公告)日：1997-06-10
申请号：US476016
申请日：1995-06-07
申请人： Ellen B. Brandes , Frederick C. Loveless
发明人： Ellen B. Brandes , Frederick C. Loveless
IPC分类号： B01F17/52 , C07C15/40 , C08F8/00 , C08F8/04 , C08F8/08 , C08F236/04 , C08F236/10 , C08F297/02 , C10L1/16 , C10L1/18 , C10L1/195 , C10L1/196 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/24 , C10L10/00 , C10L10/18 , C10M143/12 , C10M147/02 , C10M149/02 , C10M149/06 , C10M149/10 , C10N30/02 , C10N30/04 , C10M143/10 , C08F236/00
CPC分类号： C10L1/195 , C07C15/40 , C08F236/04 , C08F297/02 , C08F8/00 , C08F8/04 , C08F8/08 , C10L1/1658 , C10L1/1955 , C10L1/196 , C10L1/198 , C10L1/207 , C10L1/236 , C10L1/238 , C10L1/2468 , C10L1/2475 , C10L10/18 , C10M143/12 , C10M149/06 , C10M149/10 , C10L1/1963 , C10L1/1966 , C10L1/2364 , C10L1/2366 , C10L1/2368 , C10L1/2383 , C10L1/2387 , C10M2205/04 , C10M2205/06 , C10M2215/04 , C10M2215/26 , C10M2217/024 , C10M2217/028 , C10M2217/046 , C10M2217/06
摘要： The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated and functionalized. The dispersant substances include compositions including a copolymer of a ring substituted styrene and a conjugated diene. The polymers are selectively hydrogenated to produce polymers which have highly controlled residual amounts of aromatic unsaturation, permitting highly selective functionalization. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.
摘要翻译：本发明提供分散剂和分散剂粘度指数改进剂，其包括已被氢化和官能化的共轭二烯的聚合物。分散剂物质包括包含环取代的苯乙烯和共轭二烯的共聚物的组合物。聚合物被选择性氢化以产生具有高度控制的芳族不饱和残余量的聚合物，允许高选择性官能化。还提供了通过本发明的分散剂物质改性其分散性和/或粘度特性的润滑剂流体，例如矿物油和合成油。还提供了改变润滑流体如矿物和合成润滑油的分散性和/或粘度特性的方法。分散剂物质还可以包括提供分散剂浓缩物的载体流体。

3. 发明授权

US5552492A Solid elastomeric block copolymers 失效
公开(公告)号：US5552492A
公开(公告)日：1996-09-03
申请号：US443742
申请日：1995-05-18
申请人： Ellen B. Brandes , Frederick C. Loveless
发明人： Ellen B. Brandes , Frederick C. Loveless
IPC分类号： C08F297/02 , C08F297/04 , C08L51/00 , C08L53/00 , C08L53/02
CPC分类号： C08L51/006 , C08F297/02 , C08F297/046 , C08L53/005 , C08L53/025 , Y10S525/94
摘要： There are disclosed novel, solid, elastomeric block copolymers having excellent oxidative and thermal stability, wherein the terminal blocks are each a polymer (D polymer) of at least one conjugated diene D, which is a hydrocarbon containing a 1,3-conjugated diene structure wherein the 2 and 3 carbon atoms are each additionally bonded to a hydrocarbyl side group, e.g., 2,3-dimethyl-1,3-butadiene, with a preponderance of polymerized D units being 1,4 units; and at least one interior block is a hydrogenated polymer (I polymer) of at least one conjugated diene I which is a hydrocarbon containing a 1,3-conjugated diene structure wherein one of the 2- and 3-carbon atoms is additionally bonded to a hydrocarbyl side group and the other is additionally bonded to a hydrogen atom, e.g. isoprene. The block copolymers may be prepared by selectively hydrogenating substantially all the I polymer units of a precursor block copolymer with a sufficient number of D units in the D polymer blocks retaining their unsaturation on selective hydrogenation to enable the vulcanization of the block copolymer.

4. 发明授权

US5438102A Solid elastomeric block copolymers 失效
标题翻译：固体弹性体嵌段共聚物
公开(公告)号：US5438102A
公开(公告)日：1995-08-01
申请号：US80638
申请日：1993-06-24
申请人： Ellen B. Brandes , Frederick C. Loveless
发明人： Ellen B. Brandes , Frederick C. Loveless
IPC分类号： C08F297/02 , C08F297/04 , C08L51/00 , C08L53/00 , C08L53/02
CPC分类号： C08L51/006 , C08F297/02 , C08F297/046 , C08L53/005 , C08L53/025 , Y10S525/94
摘要： There are disclosed novel, solid, elastomeric block copolymers having excellent oxidative and thermal stability, wherein the terminal blocks are each a polymer (D polymer) of at least one conjugated diene D, which is a hydrocarbon containing a 1,3-conjugated diene structure wherein the 2 and 3 carbon atoms are each additionally bonded to a hydrocarbyl side group, e.g., 2,3-dimethyl-1,3-butadiene, with a preponderance of polymerized D units being 1,4 units; and at least one interior block is a hydrogenated polymer (I polymer) of at least one conjugated diene I which is a hydrocarbon containing a 1,3-conjugated diene structure wherein one of the 2- and 3-carbon atoms is additionally bonded to a hydrocarbyl side group and the other is additionally bonded to a hydrogen atom, e.g. isoprene. The block copolymers may be prepared by selectively hydrogenating substantially all the I polymer units of a precursor block copolymer with a sufficient number of D units in the D polymer blocks retaining their unsaturation on selective hydrogenation to enable the vulcanization of the block copolymer.
摘要翻译：公开了具有优异的氧化和热稳定性的新型，固体，弹性体嵌段共聚物，其中端嵌段各自是至少一种共轭二烯D的聚合物（D聚合物），其是含有1,3-共轭二烯结构的烃其中2和3个碳原子另外与烃基侧基键合，例如2,3-二甲基-1,3-丁二烯，聚合的D单元的优势为1,4单元; 并且至少一个内部嵌段是至少一种共轭二烯I的氢化聚合物（I聚合物），其是含有1,3-共轭二烯结构的烃，其中2-和3-碳原子中的一个另外键合到烃基侧基和另一个另外键合到氢原子，例如异戊二烯嵌段共聚物可以通过选择性氢化前体嵌段共聚物的基本上所有的I聚合物单元来制备，所述前体嵌段共聚物在D聚合物嵌段中具有足够数量的D单元，其在选择性氢化时保持其不饱和键以使嵌段共聚物硫化。

5. 发明授权

US06319881B1 Haze free oil additive compositions containing dispersants from selectively hydrogenated diene copolymers 失效
标题翻译：含有选自氢化二烯共聚物的分散剂的无色油添加剂组合物
公开(公告)号：US06319881B1
公开(公告)日：2001-11-20
申请号：US09351709
申请日：1999-07-12
申请人： Thomas S. Coolbaugh , Frederick C. Loveless , John E. Marlin, II , Demetreos N. Matthews
发明人： Thomas S. Coolbaugh , Frederick C. Loveless , John E. Marlin, II , Demetreos N. Matthews
IPC分类号： C10M16100
CPC分类号： C08F279/02 , C10L1/143 , C10L1/1641 , C10L1/1658 , C10L1/1883 , C10L1/1905 , C10L1/195 , C10L1/1966 , C10L1/198 , C10L1/206 , C10L1/232 , C10L1/236 , C10L1/2368 , C10L1/238 , C10L1/2383 , C10L1/2475 , C10L1/303 , C10L10/04 , C10M129/90 , C10M129/92 , C10M129/95 , C10M133/52 , C10M133/54 , C10M133/58 , C10M143/12 , C10M2205/026 , C10M2205/06 , C10M2207/02 , C10M2207/129 , C10M2207/289 , C10M2207/34 , C10M2209/00 , C10M2209/02 , C10M2209/10 , C10M2215/04 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/24 , C10M2215/26 , C10M2215/28 , C10M2215/30 , C10M2217/00 , C10M2217/02 , C10M2217/04 , C10M2217/046 , C10M2217/06 , C10M2227/061 , C10N2230/02 , C10N2230/04 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2260/14 , C10N2270/02
摘要： The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated, functionalized, optionally modified, and post treated. The dispersant substances include a copolymer of two different conjugated dienes. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. The polymers may be blended with lower molecular weight components. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. The addition of minor amounts of lower molecular weight components improves compatibility and reduces haze. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.
摘要翻译：本发明提供分散剂和分散剂粘度指数改进剂，其包括已被氢化，官能化，任选改性和后处理的共轭二烯的聚合物。分散剂物质包括两种不同共轭二烯的共聚物。聚合物被选择性氢化以产生具有高度受控量的不饱和度的聚合物，允许高选择性官能化。聚合物可以与较低分子量的组分共混。还提供了通过本发明的分散剂物质改性其分散性和/或粘度特性的润滑剂流体，例如矿物油和合成油。少量较低分子量组分的添加可提高相容性并降低雾度。还提供了改变润滑流体如矿物和合成润滑油的分散性和/或粘度特性的方法。分散剂物质还可以包括提供分散剂浓缩物的载体流体。

6. 发明授权

US5717035A Solid block and random elastomeric copolymers 失效
标题翻译：固体块和无规弹性共聚物
公开(公告)号：US5717035A
公开(公告)日：1998-02-10
申请号：US740116
申请日：1996-10-22
申请人： Thomas S. Coolbaugh , Frederick C. Loveless , Demetreos N. Matthews
发明人： Thomas S. Coolbaugh , Frederick C. Loveless , Demetreos N. Matthews
IPC分类号： C08F8/00 , C08F8/04 , C08F236/04 , C08F297/02 , C08F297/04 , C08L53/00 , C08L53/02 , C08F8/20 , C08F8/36 , C08F8/46
CPC分类号： C08L53/025 , C08F236/04 , C08F297/02 , C08F297/04 , C08F297/046 , C08F8/00 , C08F8/04 , C08L53/00 , Y10S525/94
摘要： There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of a polymerized conjugated diene of at least 5 carbon atoms, such as isoprene, and B is a block of a polymer of a conjugated diene, different from that of formula (1), of at least 4 carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from an aryl-substituted olefin, such as styrene, and the conjugated diene used to polymerize the block I, the second middle polymer block of the diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of double bonds to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random and star-branched block and random copolymers made from the same monomers as the linear block copolymers. Also disclosed are methods of producing and selectively hydrogenating the polymers.
摘要翻译：公开了包含至少一个三嵌段IBI的线性嵌段共聚物，其中I是至少5个碳原子的聚合共轭二烯的嵌段，例如异戊二烯，B是共轭二烯的聚合物的嵌段，不同于具有至少4个碳原子的式（1）的化合物，例如1,3-丁二烯。 B嵌段被选择性地氢化，而每个I嵌段保留足够量的其原始不饱和度以硫化共聚物。还公开了一种替代的线性嵌段共聚物，其含有由芳基取代的烯烃如苯乙烯制成的第一聚合物嵌段的至少一个三嵌段，和用于聚合嵌段I的共轭二烯，二烯的第二中间聚合物嵌段用于聚合嵌段B和与第一聚合物嵌段相同的第三聚合物嵌段。在该替代共聚物中，中间嵌段也被选择性氢化，从而使末端聚合物嵌段具有足够量的双键硫化共聚物。聚合物可以通过含有乙烯基不饱和键的末端嵌段交联或官能化。还公开了由与线性嵌段共聚物相同的单体制备的无规和星形支链嵌段和无规共聚物。还公开了制备和选择性氢化聚合物的方法。

7. 发明授权

US5625100A Vulcanizable liquid compositions 失效
标题翻译：可硫化液体组合物
公开(公告)号：US5625100A
公开(公告)日：1997-04-29
申请号：US578407
申请日：1995-12-26
申请人： Thomas S. Coolbaugh , Frederick C. Loveless , Demetreos N. Matthews , Leslie R. Rudnick
发明人： Thomas S. Coolbaugh , Frederick C. Loveless , Demetreos N. Matthews , Leslie R. Rudnick
IPC分类号： C07C15/40 , C08F8/00 , C08F8/04 , C08F8/08 , C08F236/04 , C08F297/02 , C10L1/16 , C10L1/18 , C10L1/195 , C10L1/196 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/24 , C10L10/00 , C10M143/12 , C10M149/06 , C10M149/10
CPC分类号： C08F297/02 , C07C15/40 , C08F236/04 , C08F8/00 , C08F8/04 , C08F8/08 , C10L1/1658 , C10L1/195 , C10L1/1955 , C10L1/196 , C10L1/198 , C10L1/207 , C10L1/236 , C10L1/238 , C10L1/2468 , C10L1/2475 , C10L10/00 , C10M143/12 , C10M149/06 , C10M149/10 , C10L1/1963 , C10L1/1966 , C10L1/2364 , C10L1/2366 , C10L1/2368 , C10L1/2383 , C10L1/2387 , C10M2205/04 , C10M2205/06 , C10M2215/04 , C10M2215/26 , C10M2217/024 , C10M2217/028 , C10M2217/046 , C10M2217/06
摘要： There is disclosed a linear block copolymer comprising at least one triblock I--B--I, wherein I is a block of at least one polymerized conjugated diene of at least five (5) carbon atoms, such as isoprene, and B is a block of a polymer of at least one conjugated diene, different from that used to polymerize the block I, of at least four (4) carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks is unhydrogenated and therefore retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from a minor proportion of at least one aryl-substituted olefin, such as styrene, and a major proportion of at least one conjugated diene used to polymerize the block I, the second middle polymer block of at least one diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of their original unsaturation to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random linear and star-branched block and random copolymers made from the same monomers as the linear block copolymers. Also disclosed are methods of producing the polymers and selectively hydrogenating the aforementioned polymerized dienes.
摘要翻译：公开了包含至少一个三嵌段IBI的线性嵌段共聚物，其中I是至少一种具有至少五（5）个碳原子的聚合的共轭二烯的嵌段，例如异戊二烯，B是在与用于聚合嵌段I的至少一种与至少四（4）个碳原子如1,3-丁二烯聚合的共轭二烯的至少一种共轭二烯。 B嵌段被选择性氢化，而每个I嵌段是未氢化的，因此保留足够量的其原始不饱和度以硫化共聚物。还公开了另一种线性嵌段共聚物，该线性嵌段共聚物含有至少一个由少部分至少一种芳基取代的烯烃如苯乙烯制成的第一聚合物嵌段的三嵌段，以及用于聚合的至少一种共轭二烯的主要比例嵌段I，用于聚合嵌段B的至少一种二烯的第二中间聚合物嵌段和与第一聚合物嵌段相同的第三聚合物嵌段。在该替代共聚物中，中间嵌段也被选择性氢化，从而使末端聚合物嵌段具有足够量的其初始不饱和度以硫化共聚物。聚合物可以通过含有乙烯基不饱和键的末端嵌段交联或官能化。还公开了由与线性嵌段共聚物相同的单体制备的随机线性和星形支链嵌段和无规共聚物。还公开了制备聚合物和选择性氢化上述聚合二烯的方法。

8. 发明授权

US5268427A Solid block and random elastomeric copolymers 失效
标题翻译：固体块和无规弹性共聚物
公开(公告)号：US5268427A
公开(公告)日：1993-12-07
申请号：US952127
申请日：1992-09-28
申请人： Thomas S. Coolbaugh , Frederick C. Loveless , Demetreos N. Matthews
发明人： Thomas S. Coolbaugh , Frederick C. Loveless , Demetreos N. Matthews
IPC分类号： C08F8/00 , C08F8/04 , C08F236/04 , C08F297/02 , C08F297/04 , C08L53/00 , C08L53/02
CPC分类号： C08L53/025 , C08F236/04 , C08F297/02 , C08F297/04 , C08F297/046 , C08F8/00 , C08F8/04 , C08L53/00 , Y10S525/94
摘要： There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of a polymerized conjugated diene of at least 5 carbon atoms, such as isoprene, and B is a block of a polymer of a conjugated diene, different from that of formula (1), of at least 4 carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from an aryl-substituted olefin, such as styrene, and the conjugated diene used to polymerize the block I, the second middle polymer block of the diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of double bonds to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random and star-branched block and random copolymers made from the same monomers as the linear block copolymers.Also disclosed are methods of producing and selectively hydrogenating the polymers.
摘要翻译：公开了包含至少一个三嵌段IBI的线性嵌段共聚物，其中I是至少5个碳原子的聚合共轭二烯的嵌段，例如异戊二烯，B是共轭二烯的聚合物的嵌段，不同于具有至少4个碳原子的式（1）的化合物，例如1,3-丁二烯。 B嵌段被选择性地氢化，而每个I嵌段保留足够量的其原始不饱和度以硫化共聚物。还公开了一种替代的线性嵌段共聚物，其含有由芳基取代的烯烃如苯乙烯制成的第一聚合物嵌段的至少一个三嵌段，和用于聚合嵌段I的共轭二烯，二烯的第二中间聚合物嵌段用于聚合嵌段B和与第一聚合物嵌段相同的第三聚合物嵌段。在该替代共聚物中，中间嵌段也被选择性氢化，从而使末端聚合物嵌段具有足够量的双键来硫化共聚物。聚合物可以通过含有乙烯基不饱和键的末端嵌段交联或官能化。还公开了由与线性嵌段共聚物相同的单体制备的无规和星形支链嵌段和无规共聚物。还公开了制备和选择性氢化聚合物的方法。

9. 发明授权

US5149895A Vulcanizable liquid compositions 失效
标题翻译： VULCANIZABLE液体组合物
公开(公告)号：US5149895A
公开(公告)日：1992-09-22
申请号：US466135
申请日：1990-01-16
申请人： Thomas S. Coolbaugh , Frederick C. Loveless , Demetreos N. Matthews , Leslie R. Rudnick
发明人： Thomas S. Coolbaugh , Frederick C. Loveless , Demetreos N. Matthews , Leslie R. Rudnick
IPC分类号： C08F8/00 , C08F8/04 , C08F8/08 , C08F236/04 , C08F297/02
CPC分类号： C08F297/02 , C08F236/04 , C08F8/00 , C08F8/04 , C08F8/08
摘要： There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of at least one polymerized conjugated diene of at least five (5) carbon atoms, such as isoprene, and B is a block of a polymer of at least one conjugated diene, different from that used to polymerize the block I, of at least four (4) carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks is unhydrogenated and therefore retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from a minor proportion of at least one aryl-substituted olefin, such as styrene, and a major proportion of at least one conjugated diene used to polymerize the block I, the second middle polymer block of at least one diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of their original unsaturation to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random linear and star-branched block and random copolymers made from the same monomers at the linear block copolymers.Also disclosed are methods of producing the polymers and selectively hydrogenating the aforementioned polymerized dienes.

10. 发明授权

US4866120A Elastomeric end difunctional polymers 失效
标题翻译：弹性末端双官能聚合物
公开(公告)号：US4866120A
公开(公告)日：1989-09-12
申请号：US205126
申请日：1988-06-09
申请人： Leslie R. Rudnick , Frederick C. Loveless
发明人： Leslie R. Rudnick , Frederick C. Loveless
IPC分类号： C08C19/02 , C08C19/44 , C08G18/62
CPC分类号： C08G18/6208 , C08C19/02 , C08C19/44
摘要： Directed to functionalized saturated polymers having elastomeric characteristics and to compositions containing minor amounts thereof and to the process of making them.
摘要翻译：导向具有弹性体特征的官能化饱和聚合物和包含少量的组合物及其制备方法。

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