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1. 发明授权

US5750817A Process for producing .alpha.-olefin oligomers and .alpha.-olefin oligomer compositions 失效
标题翻译：制备α-烯烃低聚物和α-烯烃低聚物组合物的方法
公开(公告)号：US5750817A
公开(公告)日：1998-05-12
申请号：US614905
申请日：1996-03-13
申请人： Eiji Tanaka , Hisao Urata , Toshiyuki Oshiki , Takayuki Aoshima , Riichirou Kawashima , Shinji Iwade , Hirofumi Nakamura , Syunji Katsuki , Takeshi Okano
发明人： Eiji Tanaka , Hisao Urata , Toshiyuki Oshiki , Takayuki Aoshima , Riichirou Kawashima , Shinji Iwade , Hirofumi Nakamura , Syunji Katsuki , Takeshi Okano
IPC分类号： B01J31/02 , B01J31/12 , B01J31/14 , B01J31/18 , B01J31/22 , C07C2/30 , C07C11/02 , C07C2/02
CPC分类号： C07C11/02 , B01J31/0212 , B01J31/0237 , B01J31/143 , C07C2/30 , B01J2231/20 , B01J2531/62 , B01J31/181 , B01J31/2234 , C07C2531/02 , C07C2531/14
摘要： The disclosure describes a process for preparing .alpha.-olefin oligomers, which comprises carrying out oligomerization of an .alpha.-olefin in a solvent by reacting said .alpha.-olefin in a chromium-based catalyst system composed of a combination of at least a chromium compound, an amine or metal amide, and an alkylaluminum compound, in a contacting mode that the chromium compound and the alkylaluminum compound are not previously contacted with each other.
摘要翻译：本公开描述了一种制备α-烯烃低聚物的方法，其包括在溶剂中进行α-烯烃的低聚反应，所述α-烯烃在铬基催化剂体系中反应，所述铬基催化剂体系由至少铬化合物，胺或金属酰胺和烷基铝化合物，其中铬化合物和烷基铝化合物之间未预先接触。

2. 发明授权

US5910619A Process for producing .alpha.-olefin oligomers 失效
标题翻译：制备α-烯烃低聚物的方法
公开(公告)号：US5910619A
公开(公告)日：1999-06-08
申请号：US493234
申请日：1995-06-20
申请人： Hisao Urata , Takayuki Aoshima , Toshiyuki Oshiki , Jun Takahara , Shinji Iwade , Yoshiaki Nanba , Yoshitaka Araki , Hirofumi Nakamura , Takeshi Okano
发明人： Hisao Urata , Takayuki Aoshima , Toshiyuki Oshiki , Jun Takahara , Shinji Iwade , Yoshiaki Nanba , Yoshitaka Araki , Hirofumi Nakamura , Takeshi Okano
IPC分类号： C07C2/32 , C07C2/34 , C07C2/24 , C07C2/26
CPC分类号： C07C2/34 , C07C2/32 , C07C2531/02 , C07C2531/14 , C07C2531/22
摘要： The disclosure described a process for producing an .alpha.-olefin oligomer, which comprises carrying out oligomerization of an .alpha.-olefin in a solvent in the presence of a catalytically effective amount of a chromium-based catalyst system composed of a combination of at least (a) a chromium compound, (b) a nitrogen-containing compound of at least one selected from the group consisting of an amine, an amide and an imide, (c) an alkylaluminum compound and (d) a halogen-containing compound,wherein each of the .alpha.-olefin, the chromium compound (a), the nitrogen-containing compound (b) of at least one selected from the group consisting of an amine, an amide and an imide, the alkylaluminum compound (c) and the halogen-containing compound (d) is supplied to a reaction system in a mode that the chromium compound (a) and the alkylaluminum compound (c) do not contact each other before each of said compounds (a) to (d) and the .alpha.-olefin coexists in the reaction solvent and the oligomerization of an .alpha.-olefin takes place.
摘要翻译：本公开描述了一种制备α-烯烃低聚物的方法，该方法包括在催化有效量的铬基催化剂体系存在下，在溶剂中进行α-烯烃的低聚反应，所述铬基催化剂体系由至少（a ）铬化合物，（b）选自胺，酰胺和酰亚胺中的至少一种的含氮化合物，（c）烷基铝化合物和（d）含卤素化合物，其中每个的α-烯烃，铬化合物（a），含氮化合物（b）中的至少一种选自胺，酰胺和酰亚胺，烷基铝化合物（c）和卤素 - 含有化合物（d）的化合物（d）在所述化合物（a）〜（d）中的每一种之前以铬化合物（a）和烷基铝化合物（c）不彼此接触的方式供给到反应体系中，在反应溶剂和低聚物中共存发生α-烯烃的化学反应。

3. 发明授权

US5750816A Process for the preparation of .alpha.-olefin oligomers 失效
标题翻译：制备α-烯烃低聚物的方法
公开(公告)号：US5750816A
公开(公告)日：1998-05-12
申请号：US609431
申请日：1996-03-01
申请人： Yoshitaka Araki , Takashi Ishikawa , Hirofumi Nakamura , Akio Tsuboi , Yoshiaki Nanba , Takeshi Okano , Takayuki Aoshima , Shinji Iwade
发明人： Yoshitaka Araki , Takashi Ishikawa , Hirofumi Nakamura , Akio Tsuboi , Yoshiaki Nanba , Takeshi Okano , Takayuki Aoshima , Shinji Iwade
IPC分类号： B01J31/02 , B01J31/04 , B01J31/12 , B01J31/14 , C07C2/30 , C07C11/02
CPC分类号： C07C11/02 , B01J31/0237 , B01J31/0244 , B01J31/0247 , B01J31/04 , B01J31/143 , C07C2/30 , B01J2231/20 , C07C2531/02 , C07C2531/04 , C07C2531/14
摘要： An oligomerization of .alpha.-olefins is carried out in a solvent using a chromium-based catalyst system comprising at least (a) a chromium compound, (b) at least one nitrogen-containing compound selected from amines, amides and imides, and (c) an alkylaluminum compound, and the catalyst components and by-product polymers are recovered simultaneously from the reaction solution. Such process is an industrially advantageous process for producing .alpha.-olefin oligomers by using a chromium-based catalyst, and is simple and capable of efficiently recovering the by-product polymers and the catalyst components simultaneously.
摘要翻译： α-烯烃的低聚反应在溶剂中使用至少包含（a）铬化合物的铬基催化剂体系，（b）至少一种选自胺，酰胺和酰亚胺的含氮化合物和（c ）烷基铝化合物，并且从反应溶液中同时回收催化剂组分和副产物聚合物。这种方法是通过使用铬基催化剂生产α-烯烃低聚物的工业上有利的方法，并且简单且能够同时有效地回收副产物聚合物和催化剂组分。

4. 发明授权

US6133495A Process for producing .alpha.-olefin oligomer 失效
标题翻译：制备α-烯烃低聚物的方法
公开(公告)号：US6133495A
公开(公告)日：2000-10-17
申请号：US952746
申请日：1998-01-02
申请人： Hisao Urata , Takayuki Aoshima , Sugio Nishimura
发明人： Hisao Urata , Takayuki Aoshima , Sugio Nishimura
IPC分类号： C07C2/30 , C07C2/32 , C08F4/69 , C08F10/00 , C07C2/24 , C07C2/08 , C07D207/00
CPC分类号： C08F10/00 , C07C2/30 , C07C2/32 , C07C2531/02 , C07C2531/14 , C07C2531/22
摘要： A process for producing an .alpha.-olefin oligomer, comprising subjecting an .alpha.-olefin to oligomerization in a reaction solution containing a chromium-based catalyst produced by bringing at least a chromium compound (a), a pyrrole ring-containing compound (b), an alkyl aluminum compound (c) and a halogen-containing compound (d) into contact with each other, wherein the chromium-based catalyst is a catalyst produced by bringing the pyrrole ring-containing compound (b), the alkyl aluminum compound (c) and the halogen-containing compound (d) into contact with each other in a hydrocarbon and/or halogenated hydrocarbon solvent, and then bringing the resultant mixed solution into contact with the chromium compound (a); or a catalyst produced by bringing the chromium compound (a), the pyrrole ring-containing compound (b), the alkyl aluminum compound (c) and the halogen-containing compound (d) into contact with each other in a hydrocarbon and/or halogenated hydrocarbon solvent in the absence of .alpha.-olefin under such a condition that the concentration of the chromium compound (a) is adjusted to not more than 8.times.10.sup.-3 mol/liter. In accordance with the present invention, an .alpha.-olefin oligomer such as 1-hexene can be produced from .alpha.-olefin such as ethylene with a high yield and a high selectivity.
摘要翻译： PCT No.PCT / JP97 / 00766 Sec。 371日期1998年1月2日 102（e）日期1998年1月2日PCT 1997年3月12日PCT公布。出版物WO97 / 33924 PCT 日本公报1997年9月18日制造α-烯烃低聚物的方法，包括使α-烯烃在含有铬系催化剂的反应溶液中低聚，所述反应溶液含有至少含有铬化合物（a），含吡咯环化合物（b），烷基铝化合物（c）和含卤素化合物（d）彼此接触，其中铬基催化剂是通过使含吡咯环的化合物（b），烷基铝化合物（c）和含卤素化合物（d）在烃和/或卤代烃溶剂中彼此接触，然后使所得混合溶液与铬化合物（a）接触; 或通过使铬化合物（a），含吡咯环的化合物（b），烷基铝化合物（c）和含卤素化合物（d）在烃和/或其中进行接触而制备的催化剂在不存在α-烯烃的条件下，将铬化合物（a）的浓度调节至不超过8×10 -3 mol /升的条件下的卤代烃溶剂。根据本发明，α-烯烃低聚物如1-己烯可以以高产率和高选择性从α-烯烃如乙烯制备。

5. 发明授权

US09290614B2 Biomass-resource-derived polyurethane, method for producing same, and biomass-resource-derived polyester polyol 有权
标题翻译：生物质源资源聚氨酯，其生产方法和生物质源资源聚酯多元醇
公开(公告)号：US09290614B2
公开(公告)日：2016-03-22
申请号：US13871414
申请日：2013-04-26
申请人： Teruhiko Ohara , Naoki Suzuki , Yasuko Nakajima , Hiroto Itou , Takayuki Aoshima , Naoki Sugai , Takanao Matsumoto
发明人： Teruhiko Ohara , Naoki Suzuki , Yasuko Nakajima , Hiroto Itou , Takayuki Aoshima , Naoki Sugai , Takanao Matsumoto
IPC分类号： C08G63/60 , C08G63/06 , C08G63/20 , C07C69/34 , C07C69/40 , C07C69/66 , C07C69/675 , C07C69/70 , C07C69/704 , A43B13/04 , C08G18/66 , C08G18/76 , C08G18/42 , C07C59/245 , C08G101/00
CPC分类号： C08G18/4238 , A43B1/00 , A43B1/14 , A43B13/04 , C07C59/245 , C07C69/34 , C07C69/40 , C07C69/66 , C07C69/675 , C07C69/70 , C07C69/704 , C08G18/14 , C08G18/4241 , C08G18/4286 , C08G18/664 , C08G18/7657 , C08G18/7671 , C08G63/06 , C08G63/16 , C08G63/20 , C08G63/60 , C08G2101/0008 , C08G2410/00 , C09D175/06 , C09J175/06
摘要： The invention relates to a method for producing a biomass-resource-derived polyurethane, which comprises: reacting a dicarboxylic acid and an aliphatic diol to produce a polyester polyol; and reacting the polyester polyol and a polyisocyanate compound, wherein the dicarboxylic acid contains at least one component derived from biomass resources, a content of an organic acid in the dicarboxylic acid is more than 0 ppm and not more than 1,000 ppm relative to the dicarboxylic acid, and a pKa value of the organic acid at 25° C. is not more than 3.7.
摘要翻译：本发明涉及一种用于生产生物质源的聚氨酯的制备方法，其包括：使二羧酸和脂肪族二醇反应制备聚酯多元醇; 并使聚酯多元醇和多异氰酸酯化合物反应，其中二羧酸含有至少一种源自生物质资源的成分，二羧酸中有机酸的含量相对于二羧酸大于0ppm且不大于1,000ppm 25℃下的有机酸的pKa值不大于3.7。

6. 发明授权

US07985566B2 Biomass-resource-derived polyester and production process thereof 有权
标题翻译：生物质源资源聚酯及其生产工艺
公开(公告)号：US07985566B2
公开(公告)日：2011-07-26
申请号：US11912212
申请日：2006-04-21
申请人： Takayuki Aoshima , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
发明人： Takayuki Aoshima , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
IPC分类号： C12P7/48
CPC分类号： C08G63/16 , C08G63/20 , C08G63/78 , C08L1/00 , C08L3/00 , C08L5/00 , C08L67/02 , C08L99/00 , C08L2201/06 , C08L2666/02
摘要： The present invention provides a resin capable of contributing greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and having physical properties suited for practical use.The polyester according to the present invention has a diol and a dicarboxylic acid as constituent components and has an amount of terminal acid of 50 equivalents/metric ton or less.
摘要翻译：本发明提供能够大大有助于解决与化石燃料资源耗尽有关的环境问题和具有适用于实际应用的物理特性的树脂。本发明的聚酯具有二醇和二羧酸作为构成成分，其末端酸的量为50当量/吨以下。

7. 发明授权

US06939644B2 Lithium secondary cell 有权
标题翻译：锂二次电池
公开(公告)号：US06939644B2
公开(公告)日：2005-09-06
申请号：US10683285
申请日：2003-10-14
申请人： Takayuki Aoshima , Iwao Soga
发明人： Takayuki Aoshima , Iwao Soga
IPC分类号： H01M2/02 , H01M4/02 , H01M4/52 , H01M4/525 , H01M10/052 , H01M10/0565 , H01M10/0567 , H01M10/0569 , H01M10/36 , H01M10/42 , H01M10/40
CPC分类号： H01M10/052 , H01M2/021 , H01M2/0275 , H01M4/525 , H01M10/0565 , H01M10/0567 , H01M10/0569 , H01M2004/021 , H01M2010/4292 , H01M2300/0085
摘要： To increase safety against overcharging of a lithium secondary cell which uses a lithium-nickel compound oxide as a positive electrode active material. A lithium secondary cell comprises a casing (2,3) and a lithium secondary cell element (1) using a lithium-nickel compound oxide as a positive electrode active material, accommodated in the casing. The specific surface area of the lithium-nickel compound oxide is from 0.1 to 10 m2/g, and a surface area capacity ratio S/C, i.e. a ratio of a cell surface area S (cm2) to a cell capacity (mAh), is from 0.05 to 5.
摘要翻译：为了提高使用锂镍复合氧化物作为正极活性物质的锂二次电池的过充电的安全性。锂二次电池包括容纳在壳体中的壳体（2,3）和使用锂镍复合氧化物作为正极活性物质的锂二次电池元件（1）。锂 - 镍复合氧化物的比表面积为0.1〜10m 2 / g，表面积容量比S / C即电池表面积S（cm < SUP> 2 ）至电池容量（mAh）为0.05至5。

8. 发明授权

US08969507B2 Aliphatic polyester resin and its production method 有权
标题翻译：脂肪族聚酯树脂及其制备方法
公开(公告)号：US08969507B2
公开(公告)日：2015-03-03
申请号：US13618144
申请日：2012-09-14
申请人： Toyomasa Hoshino , Shinichiro Matsuzono , Hiroyuki Kaneko , Toshiyuki Hamano , Takayuki Aoshima , Tadashi Ueda
发明人： Toyomasa Hoshino , Shinichiro Matsuzono , Hiroyuki Kaneko , Toshiyuki Hamano , Takayuki Aoshima , Tadashi Ueda
IPC分类号： C08G63/52 , C08G63/78 , B01J19/18 , B01J19/20 , C08G63/60 , C08G63/16
CPC分类号： C08G63/785 , B01J19/18 , B01J19/1862 , B01J19/20 , B01J2219/182 , B01J2219/1943 , C08G63/52 , C08G63/60
摘要： A method of producing an aliphatic polyester resin by continuously esterifying and melt polycondensing an aliphatic dicarboxylic acid and an aliphatic diol; and at least one aliphatic hydroxycarboxylic acid; and at least one of an aliphatic unsaturated dicarboxylic acid and cis- and trans-isomers of aliphatic unsaturated tricarboxylic acids, wherein the total amount of the at least one aliphatic hydroxycarboxylic acid and the at least one of aliphatic unsaturated dicarboxylic acid and cis- and trans-isomers of aliphatic unsaturated tricarboxylic acids is from 0.0010 to 0.50 mol % of the total amount of the aliphatic polyester resin; and the total amount of the at least one aliphatic hydroxycarboxylic acid is from 1.0 to 7.0 in terms of a molar ratio to the total amount of the at least one of aliphatic unsaturated dicarboxylic acid and cis- and trans-isomers of aliphatic unsaturated tricarboxylic acids.
摘要翻译：通过连续酯化和熔融缩聚脂族二羧酸和脂族二醇来制备脂族聚酯树脂的方法; 和至少一种脂族羟基羧酸; 和脂族不饱和三羧酸的脂族不饱和二羧酸和顺式 - 和反式异构体中的至少一种，其中至少一种脂族羟基羧酸和至少一种脂族不饱和二羧酸和顺式 - 和反式 - 脂肪族不饱和三元羧酸的异构体为脂肪族聚酯树脂总量的0.0010〜0.50摩尔％并且所述至少一种脂族羟基羧酸的总量以与脂族不饱和三羧酸的脂族不饱和二羧酸和顺式 - 和反式异构体的至少一种的总量的摩尔比计为1.0-7.0。

9. 发明授权

US08318893B2 Aliphatic polyester resin and its production method 有权
标题翻译：脂肪族聚酯树脂及其制备方法
公开(公告)号：US08318893B2
公开(公告)日：2012-11-27
申请号：US12747664
申请日：2008-12-10
申请人： Toyomasa Hoshino , Shinichiro Matsuzono , Hiroyuki Kaneko , Toshiyuki Hamano , Takayuki Aoshima , Tadashi Ueda
发明人： Toyomasa Hoshino , Shinichiro Matsuzono , Hiroyuki Kaneko , Toshiyuki Hamano , Takayuki Aoshima , Tadashi Ueda
IPC分类号： C08G63/12 , C08G63/16 , C08G63/52
CPC分类号： C08G63/785 , B01J19/18 , B01J19/1862 , B01J19/20 , B01J2219/182 , B01J2219/1943 , C08G63/52 , C08G63/60
摘要： An aliphatic polyester resin having excellent moldability and its production method are provided. When the amount of specific structural units contained in an aliphatic polyester resin is adjusted to an optimum amount, an aliphatic polyester resin having sufficient melt tension at the time of molding and excellent moldability than in the past and its production method is provided.
摘要翻译：提供了具有优异成型性的脂肪族聚酯树脂及其制造方法。当脂肪族聚酯树脂中包含的特定结构单元的量被调节到最佳量时，提供了在成型时具有足够的熔融张力并且成型性优于过去的脂族聚酯树脂及其制备方法。

10. 发明授权

US06908712B2 Lithium secondary cell 失效
标题翻译：锂二次电池
公开(公告)号：US06908712B2
公开(公告)日：2005-06-21
申请号：US10227812
申请日：2002-08-27
申请人： Takayuki Aoshima , Iwao Soga , Mitsuharu Kobayashi
发明人： Takayuki Aoshima , Iwao Soga , Mitsuharu Kobayashi
IPC分类号： H01M2/02 , H01M2/14 , H01M2/18 , H01M2/22 , H01M2/26 , H01M4/52 , H01M4/525 , H01M6/16 , H01M6/18 , H01M10/052 , H01M10/0565 , H01M10/0567 , H01M10/0569 , H01M10/36 , H01M10/42
CPC分类号： H01M2/22 , H01M2/021 , H01M2/0275 , H01M2/0277 , H01M2/0287 , H01M2/266 , H01M4/525 , H01M6/168 , H01M10/052 , H01M10/0565 , H01M10/0567 , H01M10/0569 , H01M10/4235 , Y10T29/4911
摘要： To improve an impregnation property of an electrolyte and the cycle characteristics, which have been a problem in the case of employing a casing having a variable shape. A lithium secondary cell comprising a casing having a variable shape, and a cell element having a positive electrode, a negative electrode and an electrolyte, sealed in the casing, wherein a compound represented by following formula (1) is contained in the lithium secondary cell: A1-X-A2 (1) (wherein X is a Group VI element in the periodic table, and A1 and A2 represent an aromatic group, provided that A1 and A2 may be the same or different, and may be connected each other to constitute a ring.)
摘要翻译：为了提高电解质的浸渍性和循环特性，在使用具有可变形状的壳体的情况下，这是一个问题。一种锂二次电池，包括具有可变形状的壳体和密封在壳体中的具有正极，负极和电解质的电池元件，其中在锂二次电池中包含下式（1）表示的化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> A1-X-A2（1）<？in-line-formula description =“In-line Formulas”end =“tail “其中X是元素周期表中的VI族元素，并且A1和A2表示芳族基团，条件是A1和A2可以相同或不同，并且可以彼此连接以构成环。

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