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    • 2. 发明申请
    • MANUFACTURING METHOD FOR POLYESTER PARTICLE DISPERSION LIQUID
    • 聚酯颗粒分散液的制造方法
    • US20110177445A1
    • 2011-07-21
    • US13061912
    • 2009-09-07
    • Shoichi MurataHiroshi MizuhataNobumichi KamiyoshiEiji Shirai
    • Shoichi MurataHiroshi MizuhataNobumichi KamiyoshiEiji Shirai
    • G03G9/08
    • G03G9/08797C08J3/05C08J3/07C08J2367/00G03G9/0804G03G9/08755
    • The present invention relates to a process for producing a dispersion of polyester particles which includes the step of emulsifying mixed polyester containing (1) an amorphous polyester containing a constitutional unit derived from a trivalent or higher-valent carboxylic acid in an amount of from 2.0 to 12.0 mol % on the basis of whole constitutional units of the whole amorphous polyester and (2) a crystalline polyester, in an aqueous medium in a single vessel, or the step of mixing the mixed polyester with an organic solvent and then adding the aqueous medium to the resulting mixture to emulsify the mixed polyester in a single vessel. The present invention also relates to a dispersion of polyester particles produced by the above production process, as well as a toner for electrophotography which is produced by subjecting the dispersion of the polyester particles to aggregation and coalescence and is excellent in both of a low-temperature fusing property and an anti-hot offset property, and a process for producing the toner.
    • 本发明涉及一种聚酯粒子分散体的制造方法,其特征在于,包括将含有(1)含有来源于三价以上羧酸的结构单元的无定形聚酯的混合聚酯的工序 基于整个无定形聚酯的全部结构单元为12.0摩尔%,(2)结晶性聚酯,在单一容器中的水性介质中,或将混合聚酯与有机溶剂混合,然后添加水性介质 与所得混合物在单一容器中乳化混合的聚酯。 本发明还涉及通过上述制备方法制备的聚酯颗粒的分散体,以及通过使聚酯颗粒的分散体进行聚集和聚结而制备的电子照相用调色剂,并且在低温 熔融性和抗热粘合性,以及调色剂的制造方法。
    • 5. 发明授权
    • Resin binders for toners
    • 调色剂树脂粘合剂
    • US08389189B2
    • 2013-03-05
    • US13038607
    • 2011-03-02
    • Eiji ShiraiShoichi Murata
    • Eiji ShiraiShoichi Murata
    • G03G9/093G03G9/087
    • G03G9/08755G03G9/08797G03G9/09328G03G9/09371G03G9/09392
    • The present invention relates to a resin binder for toners which includes core/shell particles each including a core portion containing a crystalline polyester obtained by polycondensing an alcohol component containing an aliphatic diol having 2-12 carbon atoms and a carboxylic acid component containing an aliphatic dicarboxylic acid compound having 8-12 carbon atoms in an amount of 70-100 mol %, and a non-crystalline resin (A) obtained by polycondensing an alcohol component and a carboxylic acid component containing at least one succinic acid compound selected from the group consisting of an alkyl (C9-C18) succinic acid and an alkenyl (C9-C18) succinic acid in an amount of 3-60 mol %; and a shell portion containing a non-crystalline resin (B) obtained by polycondensing a carboxylic acid component and an alcohol component containing an aliphatic dialcohol having 2-5 carbon atoms in an amount of 80 mol % or more.
    • 本发明涉及一种用于调色剂的树脂粘合剂,其包括核/壳颗粒,每个核/壳颗粒包含含有通过缩聚含有2-12个碳原子的脂族二醇的醇组分和含有脂族二羧酸的羧酸组分而获得的结晶聚酯的芯部分 具有70-100摩尔%的8-12个碳原子的酸性化合物和通过将醇组分和含有至少一种琥珀酸化合物的羧酸组分缩聚得到的非结晶树脂(A),所述琥珀酸化合物选自 的3-60摩尔%的烷基(C 9 -C 18)琥珀酸和烯基(C 9 -C 18)琥珀酸; 以及含有通过使羧酸成分缩聚得到的非结晶性树脂(B)和含有碳原子数为2-5的脂肪族二醇的醇成分的壳部,其含量为80摩尔%以上。
    • 6. 发明申请
    • PROCESS FOR PRODUCTION OF ELECTROPHOTOGRAPHIC TONER
    • 电印技术生产工艺
    • US20120258392A1
    • 2012-10-11
    • US13516990
    • 2010-12-17
    • Shoichi MurataEiji ShiraiHiroshi MizuhataManabu Suzuki
    • Shoichi MurataEiji ShiraiHiroshi MizuhataManabu Suzuki
    • G03G9/08
    • G03G9/0804G03G9/08755G03G9/08797G03G9/09733
    • A method for producing an electrophotographic toner, including (1) a step of preparing a thermally treated resin particle dispersion by retaining, for one hour or longer at a temperature satisfying a specific formula, a dispersion of resin particles (A) having a volume median particle size of 0.02 μm to 2 μm and containing a resin containing a crystalline polyester (a1) in an amount of 1 to 50 wt % and an amorphous polyester (b1); (2) a step of preparing an aggregated particle dispersion by aggregating thermally treated resin particles contained in the thermally treated resin particle dispersion prepared through step 1; (2a) a step of preparing resin-fine-particle-attached aggregated particles by adding, to the aggregated particle dispersion prepared through step 2, a dispersion of resin fine particles (B) containing an amorphous polyester (b2) in an amount of 70 wt % or more; and (3) a step of unifying the resin-fine-particle-attached aggregated particles prepared through step 2a.
    • 一种电子照相调色剂的制造方法,其特征在于,包括:(1)通过在满足特定式的温度下保持1小时以上制备热处理树脂颗粒分散液的步骤,具有体积中值 粒径为0.02〜2μm,含有含有1〜50重量%的结晶性聚酯(a1)的树脂和无定形聚酯(b1); (2)通过聚集通过步骤1制备的热处理树脂颗粒分散体中包含的热处理树脂颗粒来制备凝聚颗粒分散体的步骤; (2a)通过向通过步骤2制备的凝集颗粒分散体中加入含有非晶形聚酯(b2)的树脂细颗粒(B)的分散体70,制备树脂 - 细颗粒附着凝集颗粒的步骤 重量%以上; 和(3)将通过步骤2a制备的树脂 - 细颗粒附着的凝集粒子统一的工序。
    • 7. 发明授权
    • Manufacturing method for polyester particle dispersion liquid
    • 聚酯颗粒分散液的制造方法
    • US08652746B2
    • 2014-02-18
    • US13061912
    • 2009-09-07
    • Shoichi MurataHiroshi MizuhataNobumichi KamiyoshiEiji Shirai
    • Shoichi MurataHiroshi MizuhataNobumichi KamiyoshiEiji Shirai
    • G03G5/00
    • G03G9/08797C08J3/05C08J3/07C08J2367/00G03G9/0804G03G9/08755
    • The present invention relates to a process for producing a dispersion of polyester particles which includes the step of emulsifying mixed polyester containing (1) an amorphous polyester containing a constitutional unit derived from a trivalent or higher-valent carboxylic acid in an amount of from 2.0 to 12.0 mol % on the basis of whole constitutional units of the whole amorphous polyester and (2) a crystalline polyester, in an aqueous medium in a single vessel, or the step of mixing the mixed polyester with an organic solvent and then adding the aqueous medium to the resulting mixture to emulsify the mixed polyester in a single vessel. The present invention also relates to a dispersion of polyester particles produced by the above production process, as well as a toner for electrophotography which is produced by subjecting the dispersion of the polyester particles to aggregation and coalescence and is excellent in both of a low-temperature fusing property and an anti-hot offset property, and a process for producing the toner.
    • 本发明涉及一种聚酯粒子分散体的制造方法,其特征在于,包括将含有(1)含有来源于三价以上羧酸的结构单元的无定形聚酯的混合聚酯的工序 基于整个无定形聚酯的全部结构单元为12.0摩尔%,(2)结晶性聚酯,在单一容器中的水性介质中,或将混合聚酯与有机溶剂混合,然后添加水性介质 与所得混合物在单一容器中乳化混合的聚酯。 本发明还涉及通过上述制备方法制备的聚酯颗粒的分散体,以及通过使聚酯颗粒的分散体进行聚集和聚结而制备的电子照相用调色剂,并且在低温 熔融性和抗热粘合性,以及调色剂的制造方法。
    • 9. 发明申请
    • Printer
    • 打印机
    • US20060151118A1
    • 2006-07-13
    • US11317355
    • 2005-12-23
    • Shoichi MurataHideki KawakamiMasahiko YamadaTomoaki Kimura
    • Shoichi MurataHideki KawakamiMasahiko YamadaTomoaki Kimura
    • B65C11/02B32B37/00
    • B41J15/04B41J3/4075Y10T156/16Y10T156/1702Y10T156/1994
    • A printer with a peeler mechanism 1 for peeling labels from a web, the printer having a movable web pressure roller 24 which may be moved from a web pressure position 24A in which pressure is applied to a platen roller 20 to a retracted position 24B in which pressure is not applied. The printer also has a photosensor 21 and photoreceptor having an emitter/receptor surface 21a for detecting the presence and absence of labels peeled from the web. A window 22b in the label guide surface 22a becomes covered to shield the photosensor output for defining a no-label detection stateWhether the peeler mechanism is set to operate in the label peeling mode or is set to a retracted position defining a non-peeling continuous label dispensing mode of operation can be determined based on the output of the label detection photosensor 21, and the label dispensing mode can be set to the label peeling mode or continuous label dispensing mode based on this determination.
    • 一种具有剥离机构1的打印机,用于从卷筒纸上剥离标签,该打印机具有可移动的卷筒纸加压辊24,其可从卷筒压力位置24A移动,其中压力施加到压纸辊20到缩回位置24B 其中不施加压力。 打印机还具有光电传感器21和感光体,其具有用于检测从纸幅剥离的标签的存在和不存在的发射器/受体表面21a。 标签引导表面22a中的窗口22b被覆盖以屏蔽光传感器输出以限定无标签检测状态。即使剥离器机构被设置为在标签剥离模式下操作或被设置为限定非剥离的缩回位置 可以基于标签检测光传感器21的输出来确定连续标签分送操作模式,并且可以基于该确定将标签分配模式设置为标签剥离模式或连续标签分配模式。