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    • 1. 发明授权
    • Color toner
    • 彩色墨粉
    • US6106986A
    • 2000-08-22
    • US441444
    • 1999-11-17
    • Eiji ShiraiShinichi SataToshihiro HattoriHironobu NagasakiYoshifumi Tokuhisa
    • Eiji ShiraiShinichi SataToshihiro HattoriHironobu NagasakiYoshifumi Tokuhisa
    • G03G9/087G03G9/097G03G9/09
    • G03G9/09725G03G9/08755Y10S430/104
    • A color toner comprising (A) a resin binder comprising a polyester, as a main component, obtained by polycondensing a polyhydric alcohol component and a carboxylic acid component, wherein the polyhydric alcohol component comprises a compound represented by the formula (I): wherein R.sup.1 is an alkylene group having 2 to 4 carbon atoms; x and y are positive numbers, wherein a sum of x and y is from 1 to 16, in an amount of 5% by mol or more of an entire polyhydric alcohol component, and wherein the carboxylic acid component comprises 50% by mol or more of a dicarboxylic acid compound and 50% by mol or less of a tricarboxylic or higher polycarboxylic acid compound; (B) a releasing agent having an average diameter size of dispersed particles in the color toner of from 0.1 to 3 .mu.m; (C) a coloring agent; and (D) an external additive having a particle size of from 4 to 200 nm, wherein the content of the external additive is 1 to 5 parts by weight, based on 100 parts by weight of the toner before treatment with the external additive, wherein the color toner has a glass transition point of from 56.degree. to 75.degree. C., and a water content of from 0.1 to 0.5% by weight.
    • 一种彩色调色剂,其包含(A)一种树脂粘合剂,其包含通过使多元醇组分和羧酸组分缩聚获得的作为主要成分的聚酯,其中所述多元醇组分包含由式(I)表示的化合物:其中R1 是具有2至4个碳原子的亚烷基; x和y是正数,其中x和y之和为1至16,其量为多元醇组分的总量的5摩尔%以上,其中羧酸成分为50摩尔%以上 的二羧酸化合物和50摩尔%以下的三羧酸以上的多元羧酸化合物; (B)在彩色调色剂中分散颗粒的平均直径尺寸为0.1〜3μm的脱模剂; (C)着色剂; 和(D)粒径为4〜200nm的外用添加剂,其中,外加剂的含量相对于外加剂处理前的调色剂100重量份为1〜5重量份,其中, 彩色调色剂的玻璃化转变点为56〜75℃,水分含量为0.1〜0.5重量%。
    • 2. 发明授权
    • Yellow toner
    • 黄色调色剂
    • US06350551B1
    • 2002-02-26
    • US09645362
    • 2000-08-25
    • Shinichi SataEiji Shirai
    • Shinichi SataEiji Shirai
    • G03G909
    • G03G9/0912G03G9/08755G03G9/0922G03G9/0924G03G9/09725G03G9/09783
    • A yellow toner comprising fine resin particles and an external additive being added to surfaces of the fine resin particles, wherein the fine resin particles comprise (a) a resin binder comprising a polyester obtained by polycondensing an alcohol component comprising a compound represented by the formula (I), with a carboxylic acid component comprising a dicarboxylic acid compound and a tricarboxylic or higher polycarboxylic acid compound; (b) a colorant comprising a compound represented by the formula (II); and (c) a charge control agent comprising a compound selected from the group consisting of metal compounds of a salicylic acid derivative represented by the formula (III); and metal compounds of a benzilic acid derivative represented by the formula (IV); and wherein the external additive comprises silica having an average particle size of from 35 to 350 nm.
    • 一种黄色调色剂,其包含在树脂颗粒表面添加的树脂微粒和外部添加剂,其中,所述细小树脂颗粒包含(a)树脂粘合剂,所述树脂粘合剂包括通过使包含由式( I),其中包含二羧酸化合物和三羧酸或更高级多元羧酸化合物的羧酸组分; (b)包含由式(II)表示的化合物的着色剂; 和(c)电荷控制剂,其包含选自由式(III)表示的水杨酸衍生物的金属化合物的化合物; 和由式(IV)表示的苯乙酸衍生物的金属化合物; 并且其中所述外部添加剂包括平均粒径为35至350nm的二氧化硅。
    • 3. 发明授权
    • Toner for full color development
    • 全彩色调色剂
    • US06183928B2
    • 2001-02-06
    • US09537770
    • 2000-03-30
    • Shinichi SataEiji Shirai
    • Shinichi SataEiji Shirai
    • G03G9087
    • G03G9/08795G03G9/08755G03G9/08782G03G9/09716G03G9/09725
    • A toner for full color development comprising (a) a resin binder comprising a polyester; (b) a releasing agent having a melting point of 60° to 115° C.; (c) a colorant; and (d) an external additive, wherein the toner has a sum of an acid value and a hydroxyl value of from 40 to 60 KOH mg/g, a softening point of from 97° to 115° C., and a glass transition point of from 58° to 65° C., and wherein the amount of the external additive is from 1 to 5 parts by weight, based on 100 parts by weight of a toner without a treatment with the external additive. There can be provided a toner for full color development having a wide fixable region, and being excellent in the durability and the color reproducibility.
    • 一种用于全色显影的调色剂,包括(a)包含聚酯的树脂粘合剂; (b)熔点为60-115℃的脱模剂; (c)着色剂; 和(d)外部添加剂,其中调色剂具有40至60KOH mg / g的酸值和羟值之和,软化点为97°至115℃,玻璃化转变点 为58〜65℃,并且其中外加剂的量为1至5重量份,基于100重量份不用外部添加剂处理的调色剂。 可以提供具有宽的可固定区域的全色显影用调色剂,并且耐久性和颜色再现性优异。
    • 4. 发明授权
    • Process for preparing toner for electrophotography
    • 制备电子照相用调色剂的方法
    • US07887983B2
    • 2011-02-15
    • US11199220
    • 2005-08-09
    • Shinichi SataYoshinobu IshikawaNobumichi Kamiyoshi
    • Shinichi SataYoshinobu IshikawaNobumichi Kamiyoshi
    • G03G9/087
    • G03G9/08755G03G9/0804G03G9/0819G03G9/0821G03G9/08795G03G9/08797
    • The present invention relates to a process for preparing a toner for electrophotography containing a resin binder and a colorant, including the step of preparing fine particles of the resin binder to have a volume-median particle size (D50) of from 0.05 to 3 μm in an aqueous medium in the presence of a nonionic surfactant within a temperature range of from 10° C. below to 10° C. above a cloud point of the nonionic surfactant; and a toner for electrophotography obtained by the process as defined above, wherein the toner contains 60% by weight or more of a crystalline polyester and has a volume-median particle size (D50) of from 1 to 7 μm. The toner obtained according to the process of the present invention can be suitably used, for example, in development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method, or the like.
    • 本发明涉及一种制备含有树脂粘合剂和着色剂的用于电子照相的调色剂的方法,包括以下步骤:制备树脂粘合剂的细颗粒,使体积中值粒径(D50)为0.05-3μm 在非离子表面活性剂的浊点以上10℃以下-10℃以下的非离子表面活性剂存在下的水性介质; 和通过上述方法获得的用于电子照相的调色剂,其中调色剂含有60重量%以上的结晶性聚酯,其体积中值粒径(D50)为1〜7μm。 根据本发明的方法获得的调色剂可以适用于例如在电子照相术,静电记录方法,静电印刷方法等中形成的潜像的显影。
    • 7. 发明授权
    • Polyesters for thermal transfer image-receiving sheets
    • 聚酯用于热转印图像接收纸
    • US08277875B2
    • 2012-10-02
    • US12503276
    • 2009-07-15
    • Nobumichi KamiyoshiTakashi MukaiYuuta MatsumotoShinichi SataYoshiaki Ban
    • Nobumichi KamiyoshiTakashi MukaiYuuta MatsumotoShinichi SataYoshiaki Ban
    • B41M3/12B41M5/50C08G61/02C08G63/00
    • C08L67/025C08L67/02C08L67/03C08L2666/18
    • The present invention relates to a polyester for thermal transfer image-receiving sheets which includes a polyester A produced from an alcohol component containing 50 mol % or more of an alkyleneoxide adduct of 2,2-bis(4-hydroxyphenyl)propane and an acid component containing 80 mol % or more of an aliphatic carboxylic acid and/or an alicyclic carboxylic acid as a total amount thereof, and a polyester B produced from an alcohol component containing 80 mol % or more of the alkyleneoxide adduct of 2,2-bis(4-hydroxyphenyl)propane and an acid component containing 10 to 35 mol % of a trivalent or higher valent aromatic polycarboxylic acid; a resin dispersion containing the polyester; a process for producing the resin dispersion; a thermal transfer image-receiving sheet using the polyester; and a process for producing the thermal transfer image-receiving sheet. The thermal transfer image-receiving sheet is capable of satisfying all of a dyeability, a light resistance and a releasability at the same time.
    • 本发明涉及一种热转印图像接收片用聚酯,其包含由含有50摩尔%以上的2,2-双(4-羟苯基)丙烷的环氧烷烃加成物和酸成分的醇成分制成的聚酯A 含有80摩尔%以上的脂肪族羧酸和/或脂环族羧酸的总量,以及由含有80摩尔%以上的2,2-双( 4-羟基苯基)丙烷和含有10〜35摩尔%的三价以上的芳族多元羧酸的酸成分; 含有聚酯的树脂分散体; 树脂分散体的制造方法; 使用该聚酯的热转印图像接收片; 以及制造热转印图像接收片的方法。 热转印图像接收片材能够同时满足所有的染色性,耐光性和脱模性。
    • 8. 发明申请
    • METHOD FOR PRODUCING RESIN EMULSION
    • 生产树脂乳液的方法
    • US20100316947A1
    • 2010-12-16
    • US12525834
    • 2008-01-25
    • Hiroshi MizuhataNobumichi KamiyoshiShinichi Sata
    • Hiroshi MizuhataNobumichi KamiyoshiShinichi Sata
    • G03G9/087C08L67/00
    • G03G9/0806C08J3/05C08J2367/00G03G9/08755G03G9/08791G03G9/08795G03G9/08797
    • The present invention relates to a resin emulsion which has a good emulsification performance even when produced by using a crosslinked polyester resin having a good fusing ability and a good durability, and also is capable of producing a toner having an excellent heat-resistant storage property therefrom; and a process for producing the resin emulsion. The process for producing a resin emulsion according to the present invention, includes the steps of: (a) mixing a resin containing a polyester having a constitutional unit derived from at least one component selected from the group consisting of a trivalent or higher-valent alcohol component and a trivalent or higher-valent carboxylic acid component, an anionic surfactant, and a nonionic surfactant with each other at a temperature which is not lower than a temperature lower by 10° C. than a softening point of the resin, the nonionic surfactant being used in an amount of more than 1.0 part by weight and less than 5 parts by weight on the basis of 100 parts by weight of the resin; and (b) neutralizing the resulting mixture obtained in the step (a) with a basic compound in an aqueous medium at a temperature not higher than the softening point of the resin.
    • 本发明涉及一种具有良好乳化性能的树脂乳液,即使通过使用具有良好的定影能力和良好的耐久性的交联聚酯树脂制造,也能够生产具有优异的耐热储存性能的调色剂 ; 以及树脂乳液的制造方法。 本发明的树脂乳液的制造方法包括以下工序:(a)将含有具有来自选自三价以上的醇中的至少一种以上的成分构成的聚酯的树脂混合, 组分和三价或更高价羧酸组分,阴离子表面活性剂和非离子表面活性剂在不低于比树脂的软化点低10℃的温度的温度下进行,非离子表面活性剂 基于100重量份的树脂,其用量大于1.0重量份且小于5重量份; 和(b)在水介质中在不高于树脂软化点的温度下用碱性化合物中和所得步骤(a)中得到的混合物。
    • 9. 发明申请
    • Process for preparing toner for electrophotography
    • 制备电子照相用调色剂的方法
    • US20060105262A1
    • 2006-05-18
    • US11266329
    • 2005-11-04
    • Shinichi SataYoshinobu IshikawaNobumichi Kamiyoshi
    • Shinichi SataYoshinobu IshikawaNobumichi Kamiyoshi
    • G03G9/087
    • G03G9/08755G03G9/0804G03G9/0819
    • A process for preparing a toner for electrophotography comprising a resin binder and a colorant, including the steps of (1) forming primary particles containing the resin binder and the colorant in an aqueous medium in the presence of a nonionic surfactant; and (2) aggregating the primary particles, and unifying the aggregated particle; and a toner for electrophotography obtainable by the process defined above, containing a crystalline polyester in an amount of 60% by weight or more in the toner, wherein the toner has a volume-median particle size (D50) of from 1 to 7 μm. The toner for electrophotography obtained by the present invention can be suitably used in, for example, development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method, or the like.
    • 一种制备电子照相用调色剂的方法,包括树脂粘合剂和着色剂,其包括以下步骤:(1)在非离子表面活性剂存在下,在含水介质中形成含有树脂粘合剂和着色剂的一次颗粒; 和(2)聚集一次颗粒,并使凝聚颗粒均匀; 和通过上述方法获得的用于电子照相的调色剂,其含有在调色剂中为60重量%以上的结晶聚酯,其中调色剂具有体积中值粒径(D≤50) )为1〜7粒。 通过本发明获得的用于电子照相的调色剂可以适用于例如在电子照相术,静电记录方法,静电印刷方法等中形成的潜像的显影。