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    • 7. 发明申请
    • Method for leaching gold
    • 浸金方法
    • US20080078269A1
    • 2008-04-03
    • US11896747
    • 2007-09-05
    • Yoshifumi AbeHiroshi Hosaka
    • Yoshifumi AbeHiroshi Hosaka
    • C22B11/00
    • C22B11/04C22B3/10C22B11/06C22B15/0069Y02P10/234Y02P10/236
    • In a method for leaching gold from copper sulfides, the sulfide ores are first subjected to leaching of copper, thereby producing a leaching residue having 7.9% or less of the copper content. This leaching residue is mixed with a leach liquor, which contains the chloride ion and ferric ion and has 1.9 or less of pH.Gold and copper can be effectively leached from the copper sulfide ores. Ordinarily used oxidizing reagents such as hydrogen peroxide or nitric acid are not used. The gold, copper and iron can, therefore, be leached in a single process and by using an identical leaching liquor. The rate of gold leaching reaction can be enhanced by the co-presence of either copper or bromide ion or both together with the chloride and iron ion.
    • 在从硫化铜中浸出金的方法中,首先对硫化物矿石进行铜浸出,由此生成具有7.9%以下铜含量的浸出残渣。 该浸出残渣与含有氯离子和铁离子的浸出液混合,pH为1.9以下。 铜和铜可以有效地从硫化铜矿石中浸出。 不使用通常使用的氧化剂如过氧化氢或硝酸。 因此,金,铜和铁可以在一个单独的过程中浸出并使用相同的浸出液。 金浸出反应的速率可以通过铜或溴离子的共存或二者与氯离子和铁离子的共存来提高。
    • 9. 发明申请
    • Method for recovering metal from ore
    • 从矿石中回收金属的方法
    • US20090241736A1
    • 2009-10-01
    • US12232103
    • 2008-09-10
    • Yoshifumi AbeHiroshi HosakaKazuaki TakebayashiYasunari IshiguroAkira Yoshimura
    • Yoshifumi AbeHiroshi HosakaKazuaki TakebayashiYasunari IshiguroAkira Yoshimura
    • C22B11/00C22B15/00
    • C22B11/048C22B3/0005C22B3/065C22B3/24C22B7/007C22B7/008C22B7/009C22B11/04C22B11/06C22B15/0069C22B15/0093Y02P10/214Y02P10/234Y02P10/236
    • The copper sulfide ore is leached in the halide bath without using a special oxidant but with the use of only air. The copper and gold in the copper sulfide ore can be leached at high leaching ratio.The treating steps are as follows. (1) Copper leaching process (CL). The raw material is charged into the first acidic aqueous solution, which contains cupric chloride, ferric chloride, 7 g/L of hydrochloric acid, and sodium chloride. The post-leach liquor contains copper in cuprous state ions and copper in cupric state ions. (2) Solid-Liquid separation step. The resultant solid and liquid of CL step are separated. (3) Air oxidation step (OX). Air is blown into the post solid-liquid separation liquor. The copper in cuprous state ions are oxidized to the copper in cupric state ions. The iron leached in the step (1) is oxidized. Simultaneously, the impurities leached in the step (2) are precipitated. (4) Copper extracting step (CEX). The copper is recovered from the post-liquor of the step (3) (5) Gold recovering step (AL). The residue separated in the step (2) is added to the leach liquor similar to that of the step (1). The steps (1) and (5) are carried out under the atmospheric pressure and at the temperature of boiling point or lower, while blowing air into the leach liquor.
    • 硫化铜矿石在卤化物浴中浸出,不使用特殊的氧化剂,但仅使用空气。 硫化铜矿中的铜和金可以高浸出率浸出。 处理步骤如下。 (1)铜浸出工艺(CL)。 将原料装入含有氯化铜,氯化铁,7g / L盐酸和氯化钠的第一种酸性水溶液中。 后浸出液含有铜离子中的铜和铜离子中的铜。 (2)固液分离步骤。 将所得的CL步骤的固体和液体分离。 (3)空气氧化步骤(OX)。 将空气吹入后固体分液中。 铜离子中的铜被铜离子氧化成铜。 在步骤(1)中浸出的铁被氧化。 同时,在步骤(2)中浸出的杂质沉淀。 (4)铜提取步骤(CEX)。 从步骤(3)(5)金回收步骤(AL)的后液中回收铜。 在步骤(2)中分离的残余物加入到与步骤(1)相似的浸出液中。 步骤(1)和(5)在大气压力和沸点或更低的温度下进行,同时将空气吹入浸出液中。
    • 10. 发明申请
    • PROCESS OF LEACHING GOLD
    • 浸金工艺
    • US20090241735A1
    • 2009-10-01
    • US12216447
    • 2008-07-03
    • Yoshifumi AbeHiroshi HosakaKazuaki TakebayashiYasunari IshiguroAkira Yoshimura
    • Yoshifumi AbeHiroshi HosakaKazuaki TakebayashiYasunari IshiguroAkira Yoshimura
    • C22B11/00
    • C22B11/04C22B3/24C22B11/06C22B15/0067Y02P10/234Y02P10/236
    • A process of leaching gold comprising the steps of: a) leaching copper from copper sulfide ore material that contains gold or contains silicate ore containing gold until the copper grade is reduced to 7.9 wt % or less; b) mixing the resulting material having a copper grade of 7.9 wt % or less with a gold leaching solution selected from the group consisting of a first solution containing chloride ions and ferric ions, and a second solution containing chloride ions and iron ions, the iron ions having been oxidized to trivalent ferric ions by air bubbled into the second solution; c) adjusting the pH of the gold leaching solution to 1.9 or less with stirring to leach at least gold in the material into the gold leaching solution by the oxidative activity of the ferric ions contained in the gold leaching solution, wherein the concentration of gold is reduced by selectively removing gold from part or all of the gold leaching solution during gold leaching. This process efficiently leaches at least copper and gold from a copper sulfide ore.
    • 一种浸金的方法,包括以下步骤:a)将铜从含有金的硫化铜矿物料中浸出或含有含有含金的硅酸盐矿石,直到铜等级降低至7.9重量%以下; b)将所得到的铜等级为7.9重量%以下的材料与选自含有氯离子和铁离子的第一溶液的金浸出溶液和含有氯离子和铁离子的第二溶液混合, 已经通过鼓泡入第二溶液的空气氧化成三价铁离子的离子; c)通过搅拌将金浸出溶液的pH调节至1.9或更小,通过金浸出溶液中所含的三价铁离子的氧化活性,将材料中的至少金浸入金浸出溶液中,其中金的浓度为 通过在金浸出期间通过选择性地从部分或全部金浸出溶液中除去金而减少。 该方法有效地从硫化铜矿中浸出铜和金。