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    • 4. 发明授权
    • Liquid developer for electrostatic photography
    • US4618557A
    • 1986-10-21
    • US763112
    • 1985-08-07
    • Shigeyuki DanKazuo IshiiEiichi KatoHidefumi Sera
    • Shigeyuki DanKazuo IshiiEiichi KatoHidefumi Sera
    • G03G9/12G03G9/13
    • G03G9/131
    • An liquid developer for electrostatic photography is described, comprising a carrier liquid having an electric resistance of at least 10.sup.9 .OMEGA..multidot.cm and a dielectric constant of not more than 3.5, and a resin dispersed therein, said resin being obtained by polymerizing a monomer, which is soluble in said carrier liquid but becomes insoluble upon being polymerized, in the presence of at least one kind of a soluble dispersion stabilizing resin, said soluble dispersion stabilizing resin being a copolymer containing at least recurring units represented by following formulae (IIIa) and (IIIb) obtained by applying a reaction for introducing an unsaturated bond into a copolymer obtained by polymerizing a monomer represented by formula (I) and a monomer represented by formula (III) ##STR1## wherein in formula (I), V represents --O--, --S--, --CO--, --CO.sub.2 --, --SO.sub.2 --, --OCO--, --CONH--, --CONR'-- (wherein R' represents a hydrocarbon group), --NHCO--, NHCO.sub.2 --, or --NHCONH--; X represents --CO.sub.2 H, --COCl, --OH, --SH, --NH.sub.2, --NCO, or --SO.sub.2 CH.sub.2 CH.sub.2 Cl; W represents a hydrocarbon group linking said atomic group V and said atomic group X directly or through a hetero atom, or W represents a chemical bond; and a.sub.1, a.sub.2, and a.sub.3 each represents a hydrogen atom, a hydrocarbon group, a carboxy group, or a carboxy group through a hydrocarbon group;in formula (II), Y represents --O--, --S--, --CO--, --CO.sub.2 --, --SO.sub.2 --, --OCO--, CONH--, --CONR"-- (wherein R" represents a hydrocarbon group), --NHCO--, --NHCO.sub.2 --, or --NHCONH--; R represents a hydrocarbon group; and b.sub.1, b.sub.2, and b.sub.3 each represents a hydrocarbon atom, a hydrocarbon group, a carboxy group, or a carboxy group through a hydrocarbon group;in formula (IIIa), a.sub.1, a.sub.2, a.sub.3, V, and W have the same meanings as defined for formula (I); X' represents --CO.sub.2 --, --COS--, --SCO--, --CONH--, --OCO--, --NHCO--, --NHCONH--, --SO.sub.2 --, --O--, or --S--; Z represents a hydrocarbon group linking said atomic group X' and unsaturated bond directly or through a hetero atom, or Z represents a chemical bond; the total number of atoms of the main chain portion of atomic group --V--W--X'--Z-- must, however, be at least 9; and d.sub.1, d.sub.2, and d.sub.3 each represents a hydrocarbon atom, a hydrocarbon group, a carboxy group, or a carboxy group through a hydrocarbon group; andin formula (IIIb), b.sub.1, b.sub.2, b.sub.3, Y, and R have the same meanings as defined for formula (II).
    • 5. 发明授权
    • Method of making liquid developer for electrostatic photography
    • 制备静电摄影用液体显影剂的方法
    • US4842975A
    • 1989-06-27
    • US136517
    • 1987-12-22
    • Eiichi KatoKazuo IshiiHiroshi IshibashiShigeyuki DanHidefumi Sera
    • Eiichi KatoKazuo IshiiHiroshi IshibashiShigeyuki DanHidefumi Sera
    • G03G9/12G03G9/13
    • G03G9/131
    • A liquid developer for electrostatic photography is described, comprising at least a resin dispersed in a non-aqueous solvent having an electric resistance of at least 10.sup.9 ohms.cm and a dielectric constant of not more than 3.5. The resin is a copolymer resin obtained by polymerizing a solution containing at least one monofunctional monomer (A) which is soluble in the non-aqueous solvent but becomes insoluble upon polymerization and at least one specified monomer (B) containing an aliphatic group having at least 8 carbon atoms and being copolymerizable with the monomer (A), in the presense of a resin not containing a grafting group polymerizable with the monomers and being soluble in the non-aqueous solvent. The resin may be colored by dissolving at least one organic dye in the dispersion of the resin and heating the mixture. The developer has excellent dispersion stability, redispersibility, fixability and preservability.
    • 描述了用于静电摄影的液体显影剂,其至少包含分散在电阻至少为109欧姆·厘米且介电常数不大于3.5的非水溶剂中的树脂。 树脂是通过聚合含有至少一种可溶于非水溶剂但在聚合时变得不溶的单官能单体(A)的溶液和至少一种含至少一个具有至少一个脂族基团的特定单体(B)的溶液而获得的共聚物树脂 8个碳原子并且可与单体(A)共聚,在不含可与单体聚合并可溶于非水溶剂的接枝基团的树脂的存在下。 树脂可以通过将至少一种有机染料溶解在树脂的分散体中并加热混合物而着色。 显影剂具有优异的分散稳定性,再分散性,定影性和保存性。
    • 7. 发明授权
    • Liquid developer for electrostatic photography
    • 静电摄影用液体显影剂
    • US4837102A
    • 1989-06-06
    • US94612
    • 1987-09-09
    • Shigeyuki DanEiichi KatoKazuo IshiiHiroshi IshibashiHidefumi Sera
    • Shigeyuki DanEiichi KatoKazuo IshiiHiroshi IshibashiHidefumi Sera
    • G03G9/13
    • G03G9/131G03G9/133Y10S430/105
    • A liquid developer for electrostatic photography comprising a carrier medium having an electrical resistivity of not less than 10.sup.9 106.cm and a dielectric constant of not more than 3.5 having dispersed therein at least a resin, wherein said resin is a copolymer resin obtained by copolymerizing (1) a solution containing at least one copolymer having an unsaturated bond obtained by copolymerizing at least one monomer (A) represented by formula (I) shown below and at least one monomer (B) represented by formula (II) shown below, and reacting the resulting copolymer with at least one monomer (C) represented by formula (III) shown below, (2) at least one monomer (D) which is soluble in the carrier medium but becomes insoluble upon polymerization, and (3) at least one monomer (E) represented by formula (IV) shown below to obtained a resin dispersion: ##STR1## wherein a.sub.1, a.sub.2 a.sub.3, b.sub.1, b.sub.2, b.sub.3, d.sub.1, d.sub.2, d.sub.3, e.sub.1, e.sub.2, e.sub.3, X, Y, V, Z, L, F, Q, G, R.sub.1, R.sub.2, R.sub.3, T.sub.1, T.sub.2, U, m and n are defined in the specification. The developer is excellent in redispersibility, preservability, stability, image reproducibility, and fixing properties and is capable of producing a master plate for offset printing having excellent printing durability.
    • 一种静电摄影用液体显影剂,其特征在于,具有电阻率为109×106.cm以上且介电常数不超过3.5的载体介质,其中至少分散有树脂,其中所述树脂是通过共聚( 1)含有至少一种具有不饱和键的共聚物的溶液,其通过使至少一种由下述式(I)表示的单体(A)和至少一种如下所示的式(II)表示的单体(B)共聚而获得, 所得共聚物与至少一种由下式(III)表示的单体(C),(2)至少一种可溶于载体介质但在聚合时变得不溶的单体(D),和(3)至少一种 (IV)其中a1,a2 + L,a3(Ⅳ)表示的单体(E),以获得树脂分散体:(ⅰ) ,b1,b2,b3,d1,d2,d3,e1,e2,e3,X,Y,V,Z,L,F,Q,G,R1,R2,R 3,T1,T2,U,m和n在说明书中定义。 显影剂具有优异的再分散性,保存性,稳定性,图像再现性和定影性,并且能够制造具有优异印刷耐久性的胶版印刷母板。