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    • 10. 发明授权
    • Process for making crystalline structures having interconnected pores and high refractive index contrasts
    • 具有互连孔和高折射率对比的结晶结构的方法
    • US07168266B2
    • 2007-01-30
    • US10383150
    • 2003-03-06
    • Gang ChenRonen RapaportElsa ReichmanisShu Yang
    • Gang ChenRonen RapaportElsa ReichmanisShu Yang
    • C03B19/12
    • C03B19/12C03B2201/58C03C11/00
    • Techniques for producing a glass structure having interconnected macroscopic pores, employing steps of filling polymerizable glass precursors into pores in a polymeric structure having interconnected macroscopic pores; polymerizing the precursors; and decomposing the polymers to produce a glass oxide structure having interconnected macroscopic pores. Further techniques employ steps of exposing portions of a photosensitive medium including glass precursors to an optical interference pattern; polymerizing or photodeprotecting the exposed portions and removing unpolymerized or deprotected portions; and decomposing the polymerized or deprotected portions to produce a glass structure having interconnected macroscopic pores. Techniques for filling pores of such glass structure with a material having a high refractive index, and for then removing the glass structure. Structures can be produced having interconnected macroscopic pores and high refractive index contrasts, which can be used, for example, as photonic band gaps.
    • 用于生产具有互连的宏观孔的玻璃结构的技术,采用将可聚合的玻璃前体填充到具有互连的宏观孔的聚合物结构的孔中的步骤; 聚合前体; 并分解聚合物以产生具有互连的宏观孔的玻璃氧化物结构。 其他技术采用将包括玻璃前体的光敏介质的部分暴露于光学干涉图案的步骤; 聚合或光致保护暴露部分并除去未聚合或去保护的部分; 并分解聚合或去保护的部分以产生具有互连的宏观孔的玻璃结构。 用具有高折射率的材料填充这种玻璃结构的孔的技术,然后去除玻璃结构。 可以制造具有互连的宏观孔和高折射率对比度的结构,其可以用作例如光子带隙。