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1. 发明授权

US6084022A Tire tread compositions containing asymmetrically tin-coupled polybutadiene rubber 失效
标题翻译：含有不对称锡偶联聚丁二烯橡胶的轮胎胎面组合物
公开(公告)号：US6084022A
公开(公告)日：2000-07-04
申请号：US935172
申请日：1997-09-22
申请人： Edward John Blok , Paul Harry Sandstrom , Cheryl Ann Losey , Adel Farhan Halasa , Wen-Liang Hsu , David John Zanzig , John Joseph Andre Verthe
发明人： Edward John Blok , Paul Harry Sandstrom , Cheryl Ann Losey , Adel Farhan Halasa , Wen-Liang Hsu , David John Zanzig , John Joseph Andre Verthe
IPC分类号： B60C1/00 , C08C19/44 , C08J3/26 , C08K5/548 , C08L7/00 , C08L9/00 , C08L15/00 , C08L21/00 , C08K3/36
CPC分类号： C08L15/00 , B60C1/0016 , C08C19/44 , C08K5/548 , C08L15/005 , C08L21/00 , C08L7/00 , C08L9/00
摘要： This invention relates to a tire tread compound that is easily processable which can be used to improve the treadwear, rolling resistance and traction characteristics of tires. The tire tread compounds of this invention are a blend of tin-coupled polybutadiene, high vinyl polybutadiene and natural rubber. This blend of low glass transition temperature rubber and high glass transition temperature rubber is surprisingly easy to process which makes the concept of this invention commercially feasible. Thus, the tire tread compounds of this invention can be utilized in making tires having greatly improved traction characteristics and treadwear without sacrificing rolling resistance. These improved properties may be due, in part, to better interaction and compatibility with carbon black and/or silica fillers. The polybutadiene in the blend can be asymmetrical tin-coupled to further improve the cold flow characteristics of the rubber blend. Asymmetrical tin coupling in general also leads to better processability and other beneficial properties. This invention more specifically discloses a tire tread rubber composition which is comprised of (1) from about 20 phr to about 60 phr of tin-coupled polybutadiene rubber, (2) from about 20 phr to about 60 phr of a rubber selected from the group consisting of natural rubber and synthetic polyisoprene and (3) from about 5 phr to about 40 phr of high vinyl polybutadiene rubber.
摘要翻译：本发明涉及一种易于加工的轮胎胎面胶，其可用于改善轮胎的胎面磨损，滚动阻力和牵引特性。本发明的轮胎胎面胶料是锡偶合的聚丁二烯，高乙烯基聚丁二烯和天然橡胶的混合物。这种低玻璃化转变温度橡胶和高玻璃化转变温度橡胶的混合物令人惊奇地易于加工，这使得本发明的概念在商业上可行。因此，本发明的轮胎胎面胶料可用于制造具有极大改善的牵引特性和胎面磨损的轮胎，而不会牺牲滚动阻力。这些改进的性质可能部分是由于与炭黑和/或二氧化硅填料的更好的相互作用和相容性。共混物中的聚丁二烯可以是不对称的锡偶联，以进一步改善橡胶共混物的冷流特性。不对称锡偶联一般也会导致更好的加工性能和其他有益的性能。本发明更具体地公开了一种轮胎胎面橡胶组合物，其包含（1）约20phr至约60phr的锡偶联的聚丁二烯橡胶，（2）约20phr至约60phr的选自下组的橡胶：由天然橡胶和合成聚异戊二烯组成，（3）约5phr至约40phr的高乙烯基聚丁二烯橡胶。

2. 发明授权

US06350807B1 Silica-reinforced tire tread rubber 失效
标题翻译：二氧化硅增强轮胎胎面橡胶
公开(公告)号：US06350807B1
公开(公告)日：2002-02-26
申请号：US09616270
申请日：2000-07-14
申请人： Edward John Blok , Paul Harry Sandstrom , Wen-Liang Hsu , Adel Farhan Halasa , John Joseph Andre Verthe , Raymond Robert DiRossi
发明人： Edward John Blok , Paul Harry Sandstrom , Wen-Liang Hsu , Adel Farhan Halasa , John Joseph Andre Verthe , Raymond Robert DiRossi
IPC分类号： C08K334
CPC分类号： C08L9/00 , B60C1/0016 , C08K3/04 , C08K3/36 , C08K5/0016 , C08L7/00 , C08L15/00 , Y02T10/862 , C08L2666/08
摘要： The present invention relates to a tire tread compound that is highly loaded with silica. This compound offers the advantages of silica compounding without the need for solution SBR. More specifically, the tire tread rubber formulations of this invention offer an excellent combination of traction, treadwear and rolling resistance characteristics. The subject invention discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of (1) 5 phr to 40 phr of a polyisoprene rubber selected from the group consisting of natural rubber and synthetic polyisoprene, (2) 20 phr to 60 phr of high vinyl polybutadiene rubber having a glass transition temperature which is within the range of −40° C. to 10° C., (3) 20 phr to 60 phr of tin-coupled isoprene-butadiene rubber having a glass transition temperature which is within the range of −90° C. to −70° C., (4) 30 phr to 90 phr of silica, (5) 5 phr to 50 phr of carbon black, (6) 2 phr to 50 phr of processing oil and (7) 0.5 phr to 15 phr of a silica coupling agent.
摘要翻译：本发明涉及高度负载二氧化硅的轮胎胎面胶。该化合物具有二氧化硅复合的优点，无需溶液SBR。更具体地，本发明的轮胎胎面橡胶配方提供牵引力，胎面磨损和滚动阻力特性的优异组合。本发明公开了一种轮胎，其由具有外圆周胎面的大致环形胎体，两个间隔开的胎圈，从胎圈到胎圈延伸的至少一个帘布层以及从所述胎面径向延伸并将所述胎面连接到所述胎圈的侧壁构成; 其中所述胎面适于与地面接触; 其中胎面由（1）5phr至40phr的选自天然橡胶和合成聚异戊二烯的聚异戊二烯橡胶，（2）20phr至60phr的玻璃化转变温度为20phr至60phr的高乙烯基聚丁二烯橡胶在-40℃至10℃的范围内，（3）20phr至60phr的锡偶合异戊二烯 - 丁二烯橡胶，其玻璃化转变温度在-90℃至-70℃的范围内（4）30phr至90phr的二氧化硅，（5）5phr至50phr的炭黑，（6）2phr至50phr的加工油和（7）0.5phr至15phr的二氧化硅偶联剂。

3. 发明授权

US5994448A High performance tire tread rubber composition 失效
标题翻译：高性能轮胎胎面胶组成
公开(公告)号：US5994448A
公开(公告)日：1999-11-30
申请号：US133503
申请日：1998-08-12
申请人： Edward John Blok , Paul Harry Sandstrom , Wen-Liang Hsu , Adel Farhan Halasa
发明人： Edward John Blok , Paul Harry Sandstrom , Wen-Liang Hsu , Adel Farhan Halasa
IPC分类号： B60C1/00 , C08C19/44 , C08L9/00 , C08K3/00
CPC分类号： C08C19/44 , B60C1/0016 , C08L9/00 , C08K3/36 , C08L7/00 , C08L9/06
摘要： This invention relates to a tire tread compound that can be used in manufacturing tires having outstanding traction characteristics without compromising treadwear and rolling resistance. The tire tread compounds of this invention are made utilizing an isoprene-butadiene rubber having a high glass transition temperature and having SnR.sub.3 end groups, wherein R represents an alkyl group, such as a tertiary-butyl group. These isoprene-butadiene rubbers are made by reacting an isoprene-butadiene rubber having a glass transition temperature which is within the range of about -50.degree. C. to about 0.degree. C. with a tin compound of the formula SnR.sub.3 X, wherein R represents an alkyl group and wherein X represents a halogen. This invention more specifically discloses a tire tread rubber composition which is comprised of (1) about 60 phr to about 95 phr of an isoprene-butadiene rubber having a glass transition temperature which is within the range of about -50.degree. C. to about 0.degree. C. and having --SnR.sub.3 end groups, (2) about 5 phr to about 30 phr of natural rubber and (3) up to about 25 phr of a rubbery polymer having a low glass transition temperature which is within the range of about -85.degree. C. to about -55.degree. C., with the proviso that the total amount of the natural rubber and the rubbery polymer having a low glass transition temperature does not exceed about 40 phr. The rubbery polymer having a low glass transition temperature will typically be high cis-1,4-polybutadiene, isoprene-butadiene rubber, styrene-butadiene rubber or styrene-isoprene-butadiene rubber.
摘要翻译：本发明涉及一种轮胎胎面胶，其可用于制造具有优异牵引特性的轮胎，而不损害胎面和滚动阻力。本发明的轮胎胎面胶料采用高玻璃化转变温度的异戊二烯 - 丁二烯橡胶制成，并具有SnR 3端基，其中R表示烷基，如叔丁基。这些异戊二烯 - 丁二烯橡胶通过使玻璃化转变温度在约-50℃至约0℃范围内的异戊二烯 - 丁二烯橡胶与式SnR 3 X的锡化合物反应制备，其中R表示烷基，其中X表示卤素。本发明更具体地公开了一种轮胎胎面橡胶组合物，其包含（1）约60phr至约95phr的玻璃化转变温度在约-50℃至约0的范围内的异戊二烯 - 丁二烯橡胶具有-SnR 3端基，（2）约5phr至约30phr的天然橡胶和（3）至多约25phr的玻璃化转变温度低于约 - 约25phr的橡胶状聚合物， 85℃至约-55℃，条件是具有低玻璃化转变温度的天然橡胶和橡胶状聚合物的总量不超过约40phr。具有低玻璃化转变温度的橡胶状聚合物通常是高顺式-1,4-聚丁二烯，异戊二烯 - 丁二烯橡胶，苯乙烯 - 丁二烯橡胶或苯乙烯 - 异戊二烯 - 丁二烯橡胶。

4. 发明授权

US06378582B1 Silica-reinforced tire tread rubber 失效
标题翻译：二氧化硅增强轮胎胎面橡胶
公开(公告)号：US06378582B1
公开(公告)日：2002-04-30
申请号：US09665863
申请日：2000-09-20
申请人： Paul Harry Sandstrom , Adel Farhan Halasa , Wen-Liang Hsu , Edward John Blok
发明人： Paul Harry Sandstrom , Adel Farhan Halasa , Wen-Liang Hsu , Edward John Blok
IPC分类号： B60C1100
CPC分类号： B60C1/0016 , Y02T10/862
摘要： The present invention relates to a tire tread compound that is highly loaded with silica. This compound offers the advantages of silica compounding without the need for solution SBR. More specifically, the tire tread rubber formulations of this invention offer an excellent combination of traction, treadwear and rolling resistance characteristics. The subject invention discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of (1) 10 phr to 35 phr of high vinyl polybutadiene rubber having a glass transition temperature which is within the range of −40° C. to 10° C., (2) 65 phr to 90 phr of tin-coupled isoprene-butadiene rubber having a glass transition temperature which is within the range of −90° C. to −70° C., (3) 30 phr to 90 phr of silica, (4) 5 phr to 50 phr of carbon black, (5) 2 phr to 50 phr of processing oil and (6) 0.5 phr to 15 phr of a silica coupling agent.
摘要翻译：本发明涉及高度负载二氧化硅的轮胎胎面胶。该化合物具有二氧化硅复合的优点，无需溶液SBR。更具体地，本发明的轮胎胎面橡胶配方提供牵引力，胎面磨损和滚动阻力特性的优异组合。本发明公开了一种轮胎，其由具有外圆周胎面的大致环形胎体，两个间隔开的胎圈，从胎圈到胎圈延伸的至少一个帘布层以及从所述胎面径向延伸并将所述胎面连接到所述胎圈的侧壁构成; 其中所述胎面适于与地面接触; 其中所述胎面由（1）10phr至35phr的玻璃化转变温度在-40℃至10℃范围内的高乙烯基聚丁二烯橡胶组成，（2）65phr至90phr至具有玻璃化转变温度在-90℃至-70℃范围内的锡偶联异戊二烯 - 丁二烯橡胶，（3）30phr至90phr二氧化硅，（4）5phr至50phr的炭黑，（5）2phr至50phr的加工油和（6）0.5phr至15phr的二氧化硅偶联剂。

5. 发明授权

US06204320B1 Liquid isoprene-butadiene rubber 有权
标题翻译：液体异戊二烯 - 丁二烯橡胶
公开(公告)号：US06204320B1
公开(公告)日：2001-03-20
申请号：US09249470
申请日：1999-02-12
申请人： Edward John Blok , Mark Leslie Kralevich, Jr. , Paul Harry Sandstrom , Wen-Liang Hsu , Adel Farhan Halasa
发明人： Edward John Blok , Mark Leslie Kralevich, Jr. , Paul Harry Sandstrom , Wen-Liang Hsu , Adel Farhan Halasa
IPC分类号： C08J2700
CPC分类号： C08F236/08 , B60C1/0016 , C08F236/06 , C08L21/00 , Y10T152/10495 , C08L2666/08
摘要： The subject invention discloses a liquid isoprene-butadiene rubber (IBR) which is particularly valuable for use in making treads for high performance automobile tires, including race tires, that exhibit superior dry traction characteristics and durability. The isoprene-butadiene rubber of this invention is a liquid at room temperature and is comprised of repeat units which are derived from about 5 weight percent to about 95 weight percent isoprene and from about 5 weight percent to about 95 weight percent 1,3-butadiene, wherein the repeat units derived from isoprene and 1,3-butadiene are in essentially random order. The IBR of this invention also has a low number average molecular weight which is within the range of about 3,000 to about 50,000 and has a glass transition temperature which is within the range of about −50° C. to about 20° C. This invention more specifically discloses a tire tread compound which is comprised of (a) a rubbery elastomer, (b) about 20 phr to about 80 phr of an aromatic process oil, (c) about 35 phr to about 130 phr of a filler and (d) about 4 phr to about 40 phr of a liquid isoprene-butadiene rubber having a number average molecular weight which is within the range of about 3,000 to about 50,000 and a glass transition temperature which is within the range of about −50° C. to about 20° C.
摘要翻译：本发明公开了一种特别有价值的液体异戊二烯 - 丁二烯橡胶（IBR），其用于制造具有优异的干牵引特性和耐久性的高性能汽车轮胎（包括赛车轮胎）的胎面。本发明的异戊二烯 - 丁二烯橡胶在室温下为液体，并由衍生自约5重量％至约95重量％的异戊二烯和约5重量％至约95重量％的1,3-丁二烯的重复单元，其中衍生自异戊二烯和1,3-丁二烯的重复单元基本上是随机的。本发明的IBR还具有低于约3,000至约50,000的数均分子量，玻璃化转变温度在约-50℃至约20℃的范围内。本发明更具体地公开了一种轮胎胎面胶，其由（a）橡胶弹性体，（b）约20phr至约80phr的芳族加工油，（c）约35phr至约130phr的填料和（d ）约4phr至约40phr的数均分子量在约3,000至约50,000范围内且玻璃化转变温度在约-50℃至约-50℃范围内的液体异戊二烯 - 丁二烯橡胶约20℃

6. 发明授权

US6025430A Tire tread compositions containing asymmetrically tin-coupled polybutadiene rubber 失效
公开(公告)号：US6025430A
公开(公告)日：2000-02-15
申请号：US388491
申请日：1999-09-02
申请人： Edward John Blok , Paul Harry Sandstrom , Cheryl Ann Losey , Adel Farhan Halasa , Wen-Liang Hsu , David John Zanzig , John Joseph Andre Verthe
发明人： Edward John Blok , Paul Harry Sandstrom , Cheryl Ann Losey , Adel Farhan Halasa , Wen-Liang Hsu , David John Zanzig , John Joseph Andre Verthe
IPC分类号： B60C1/00 , C08C19/44 , C08J3/26 , C08K5/548 , C08L7/00 , C08L9/00 , C08L15/00 , C08L21/00 , C08K3/36
CPC分类号： C08L15/00 , B60C1/0016 , C08C19/44 , C08K5/548 , C08L15/005 , C08L21/00 , C08L7/00 , C08L9/00
摘要： This invention relates to a tire tread compound that is easily processable which can be used to improve the treadwear, rolling resistance and traction characteristics of tires. The tire tread compounds of this invention are a blend of tin-coupled polybutadiene, high vinyl polybutadiene and natural rubber. This blend of low glass transition temperature rubber and high glass transition temperature rubber is surprisingly easy to process which makes the concept of this invention commercially feasible. Thus, the tire tread compounds of this invention can be utilized in making tires having greatly improved traction characteristics and treadwear without sacrificing rolling resistance. These improved properties may be due, in part, to better interaction and compatibility with carbon black and/or silica fillers. The polybutadiene in the blend can be asymmetrical tin-coupled to further improve the cold flow characteristics of the rubber blend. Asymmetrical tin coupling in general also leads to better processability and other beneficial properties. This invention more specifically discloses a tire tread rubber composition which is comprised of (1) from about 20 phr to about 60 phr of tin-coupled polybutadiene rubber, (2) from about 20 phr to about 60 phr of a rubber selected from the group consisting of natural rubber and synthetic polyisoprene and (3) from about 5 phr to about 40 phr of high vinyl polybutadiene rubber.

7. 发明授权

US06562895B2 Liquid isoprene-butadiene rubber 失效
标题翻译：液体异戊二烯 - 丁二烯橡胶
公开(公告)号：US06562895B2
公开(公告)日：2003-05-13
申请号：US09727175
申请日：2000-11-30
申请人： Edward John Blok , Mark Leslie Kralevich, Jr. , Paul Harry Sandstrom , Wen-Liang Hsu , Adel Farhan Halasa
发明人： Edward John Blok , Mark Leslie Kralevich, Jr. , Paul Harry Sandstrom , Wen-Liang Hsu , Adel Farhan Halasa
IPC分类号： C08J2700
CPC分类号： C08F236/08 , B60C1/0016 , C08F236/06 , C08L21/00 , Y10T152/10495 , C08L2666/08
摘要： The subject invention discloses a liquid isoprene-butadiene rubber (IBR) which is particularly valuable for use in making treads for high performance automobile tires, including race tires, that exhibit superior dry traction characteristics and durability. The isoprene-butadiene rubber of this invention is a liquid at room temperature and is comprised of repeat units which are derived from about 5 weight percent to about 95 weight percent isoprene and from about 5 weight percent to about 95 weight percent 1,3-butadiene, wherein the repeat units derived from isoprene and 1,3-butadiene are in essentially random order. The IBR of this invention also has a low number average molecular weight which is within the range of about 3,000 to about 50,000 and has a glass transition temperature which is within the range of about −50° C. to about 20° C. This invention more specifically discloses a tire tread compound which is comprised of (a) a rubbery elastomer, (b) about 20 phr to about 80 phr of an aromatic process oil, (c) about 35 phr to about 130 phr of a filler and (d) about 4 phr to about 40 phr of a liquid isoprene-butadiene rubber having a number average molecular weight which is within the range of about 3,000 to about 50,000, a glass transition temperature which is within the range of about −50° C. to about 20° C., and wherein the liquid isoprene-butadiene polymer exhibits only one glass transition temperature.
摘要翻译：本发明公开了一种特别有价值的液体异戊二烯 - 丁二烯橡胶（IBR），其用于制造具有优异的干牵引特性和耐久性的高性能汽车轮胎（包括赛车轮胎）的胎面。本发明的异戊二烯 - 丁二烯橡胶在室温下为液体，并由衍生自约5重量％至约95重量％的异戊二烯和约5重量％至约95重量％的1,3-丁二烯的重复单元，其中衍生自异戊二烯和1,3-丁二烯的重复单元基本上是随机的。本发明的IBR还具有低于约3,000至约50,000的数均分子量，玻璃化转变温度在约-50℃至约20℃的范围内。本发明更具体地公开了一种轮胎胎面胶，其由（a）橡胶弹性体，（b）约20phr至约80phr的芳族加工油，（c）约35phr至约130phr的填料和（d ）约4phr至约40phr的数均分子量在约3,000至约50,000范围内的液体异戊二烯 - 丁二烯橡胶，玻璃化转变温度在约-50℃至约20℃，并且其中液体异戊二烯 - 丁二烯聚合物仅显示一个玻璃化转变温度。

8. 发明授权

US6017988A Tire tread compositions containing asymmetrically tin-coupled polybutadiene rubber and silica coupling agent 失效
标题翻译：含有不对称锡偶联聚丁二烯橡胶和二氧化硅偶联剂的轮胎胎面组合物
公开(公告)号：US6017988A
公开(公告)日：2000-01-25
申请号：US366236
申请日：1999-08-03
申请人： Edward John Blok , Paul Harry Sandstrom , Cheryl Ann Losey , Adel Farhan Halasa , Wen-Liang Hsu , David John Zanzig , John Joseph Andre Verthe
发明人： Edward John Blok , Paul Harry Sandstrom , Cheryl Ann Losey , Adel Farhan Halasa , Wen-Liang Hsu , David John Zanzig , John Joseph Andre Verthe
IPC分类号： B60C1/00 , C08C19/44 , C08J3/26 , C08K5/548 , C08L7/00 , C08L9/00 , C08L15/00 , C08L21/00 , C08K3/04 , C08K3/36
CPC分类号： C08L15/00 , B60C1/0016 , C08C19/44 , C08K5/548 , C08L15/005 , C08L21/00 , C08L7/00 , C08L9/00
摘要： This invention relates to a tire tread compound that is easily processable which can be used to improve the treadwear, rolling resistance and traction characteristics of tires. The tire tread compounds of this invention are a blend of tin-coupled polybutadiene, high vinyl polybutadiene and natural rubber. This blend of low glass transition temperature rubber and high glass transition temperature rubber is surprisingly easy to process which makes the concept of this invention commercially feasible. Thus, the tire tread compounds of this invention can be utilized in making tires having greatly improved traction characteristics and treadwear without sacrificing rolling resistance. These improved properties may be due, in part, to better interaction and compatibility with carbon black and/or silica fillers. The polybutadiene in the blend can be asymmetrical tin-coupled to further improve the cold flow characteristics of the rubber blend. Asymmetrical tin coupling in general also leads to better processability and other beneficial properties. This invention more specifically discloses a tire tread rubber composition which is comprised of (1) from about 20 phr to about 60 phr of tin-coupled polybutadiene rubber, (2) from about 20 phr to about 60 phr of a rubber selected from the group consisting of natural rubber and synthetic polyisoprene and (3) from about 5 phr to about 40 phr of high vinyl polybutadiene rubber.
摘要翻译：本发明涉及一种易于加工的轮胎胎面胶，其可用于改善轮胎的胎面磨损，滚动阻力和牵引特性。本发明的轮胎胎面胶料是锡偶合的聚丁二烯，高乙烯基聚丁二烯和天然橡胶的混合物。这种低玻璃化转变温度橡胶和高玻璃化转变温度橡胶的混合物令人惊奇地易于加工，这使得本发明的概念在商业上可行。因此，本发明的轮胎胎面胶料可用于制造具有极大改善的牵引特性和胎面磨损的轮胎，而不会牺牲滚动阻力。这些改进的性质可能部分是由于与炭黑和/或二氧化硅填料的更好的相互作用和相容性。共混物中的聚丁二烯可以是不对称的锡偶联，以进一步改善橡胶共混物的冷流特性。不对称锡偶联一般也会导致更好的加工性能和其他有益的性能。本发明更具体地公开了一种轮胎胎面橡胶组合物，其包含（1）约20phr至约60phr的锡偶联的聚丁二烯橡胶，（2）约20phr至约60phr的选自下组的橡胶：由天然橡胶和合成聚异戊二烯组成，（3）约5phr至约40phr的高乙烯基聚丁二烯橡胶。

9. 发明授权

US06429245B1 Tire tread with elastomers of spatially defined Tg's 失效
标题翻译：轮胎胎面与空间定义的Tg的弹性体
公开(公告)号：US06429245B1
公开(公告)日：2002-08-06
申请号：US08931169
申请日：1997-09-16
申请人： William Paul Francik , Edward John Blok , Paul Harry Sandstrom , John Joseph Andre Verthe , David John Zanzig , Adel Farhan Halasa
发明人： William Paul Francik , Edward John Blok , Paul Harry Sandstrom , John Joseph Andre Verthe , David John Zanzig , Adel Farhan Halasa
IPC分类号： C08K524
CPC分类号： C08L9/00 , B60C1/0016 , C08K3/36 , C08K5/372 , C08L9/06 , Y10T152/10495 , C08L2666/08
摘要： The invention relates to a tire with a tread. The tread is composed of at least two defined elastomers having Tg's spaced apart by at least 55° C. to the exclusion of elastomers having Tg's between −30° and −85° C. The tread composition can be reinforced with either carbon black or a combination of carbon black and silica reinforcing fillers.
摘要翻译：本发明涉及一种具有胎面的轮胎。胎面由至少两个限定的具有Tg间隔至少55℃的弹性体组成，排除Tg在-30℃和-85℃之间的弹性体。胎面组合物可以用炭黑或炭黑和二氧化硅增强填料的组合。

10. 发明授权

US5859133A Tire tread compound 失效
标题翻译：轮胎胎面复合物
公开(公告)号：US5859133A
公开(公告)日：1999-01-12
申请号：US617234
申请日：1996-03-18
申请人： David John Zanzig , Adel Farhan Halasa , Wen-Liang Hsu , Paul Harry Sandstrom , Laurie Elizabeth Austin
发明人： David John Zanzig , Adel Farhan Halasa , Wen-Liang Hsu , Paul Harry Sandstrom , Laurie Elizabeth Austin
IPC分类号： B60C1/00 , C08L9/00 , C08L21/00 , C08L53/00 , C08L53/02 , C08F236/08 , C08F236/06
CPC分类号： C08L21/00 , B60C1/0016 , C08F297/04 , C08L53/00 , C08L9/00 , C08L9/06
摘要： The subject invention discloses a pneumatic tire having an outer circumferential tread wherein said tread is a sulfur-cured rubber composition comprised of (a) an isoprene-butadiene diblock rubber, said isoprene-butadiene diblock rubber being comprised of a butadiene block and an isoprene-butadiene block, wherein said butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene diblock rubber has essentially one glass transition temperature which is within the range of about -100.degree. C. to about -70.degree. C., wherein said isoprene-butadiene diblock polymer has a Mooney ML-4 viscosity at 100.degree. C. which is within the range of about 50 to about 140, and wherein the repeat units derived from isoprene and 1,3-butadiene in the isoprene-butadiene block are in essentially random order; and (b) a second rubber selected from the group consisting of high vinyl polybutadiene rubber, styrene-isoprene-butadiene rubber, solution styrene-butadiene rubber and emulsion styrene-butadiene rubber.
摘要翻译：本发明公开了一种具有外周胎面的充气轮胎，其中所述胎面是由（a）异戊二烯 - 丁二烯二嵌段橡胶组成的硫固化橡胶组合物，所述异戊二烯 - 丁二烯二嵌段橡胶由丁二烯嵌段和异戊二烯 - 丁二烯嵌段，其中所述丁二烯嵌段的数均分子量在约25,000至约350,000的范围内，其中所述异戊二烯 - 丁二烯嵌段的数均分子量在约25,000至约350,000的范围内，其中所述异戊二烯 - 丁二烯二嵌段橡胶具有在约-100℃至约-70℃范围内的基本上一个玻璃化转变温度，其中所述异戊二烯 - 丁二烯二嵌段聚合物在100℃下具有门尼ML-4粘度，其在约50至约140的范围内，并且其中衍生自异戊二烯和1,3-丁二烯的异戊二烯 - 丁二烯嵌段中的重复单元基本上为兰德呃订单和（b）选自高乙烯基聚丁二烯橡胶，苯乙烯 - 异戊二烯 - 丁二烯橡胶，溶剂苯乙烯 - 丁二烯橡胶和乳液丁苯橡胶的第二橡胶。

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