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1. 发明授权

US4005058A Process for the formation and recovery of poly(bisbenzimidazoenzophenanthroline) 失效
标题翻译：聚（双苯并咪唑并苯并菲菲）的形成和回收方法
公开(公告)号：US4005058A
公开(公告)日：1977-01-25
申请号：US655339
申请日：1976-02-05
申请人： Edward C. Chenevey , Harry T. Hanson
发明人： Edward C. Chenevey , Harry T. Hanson
IPC分类号： C08G73/20 , C08G20/00 , C08G20/20 , C08G20/32 , C08G33/02
CPC分类号： C08G73/20
摘要： An improved overall process is provided wherein poly(bisbenzimidazobenzophenanthroline) is formed on an expeditious basis and is recovered from the reaction mass in substantially pure form. Appropriate quantities of 1,4,5,8-tetracarboxy naphthalene dianhydride and 3,3',4,4' -tetraaminobiphenyl are condensed as defined) in a reaction zone while dissolved in molten antimony trichloride, and the resulting reaction mass containing the dissolved product is discharged into a precipitation zone containing hydrochloric acid (as defined). The resulting solid product is separated and dried. The liquid portion which is separated from the solid product contains antimony trichloride dissolved in hydrochloric acid and is subjected to distillation which substantially separates these components. The antimony trichloride is recycled to the reaction zone, and the hydrochloric acid is recycled to the precipitation zone.
摘要翻译：提供了一种改进的总体方法，其中快速形成聚（双苯并咪唑基苯并菲罗啉），并以基本上纯的形式从反应物质中回收。合适量的1,4,5,8-四羧基萘二酐和3,3'，4,4'-四氨基联苯在反应区中缩合，同时溶解在熔融的三氯化锑中，所得反应物质含有溶解的将产物排入含有盐酸的沉淀区（定义）。将所得固体产物分离并干燥。与固体产物分离的液体部分含有溶解在盐酸中的三氯化锑，并进行基本分离这些组分的蒸馏。将三氯化锑再循环至反应区，将盐酸再循环至沉淀区。

2. 发明授权

US4105634A Production of thermosetting resinous polyepoxides 失效
标题翻译：生产热固性树脂多羟基氧化物
公开(公告)号：US4105634A
公开(公告)日：1978-08-08
申请号：US713622
申请日：1976-08-11
申请人： Harry T. Hanson , Marvin Gordon
发明人： Harry T. Hanson , Marvin Gordon
IPC分类号： C08G59/06 , C08G59/02
CPC分类号： C08G59/066
摘要： In one aspect, thermosetting liquid resinous polyepoxides are upgraded or advanced in molecular weight by a process including (A) providing a catalyst-free mixture of a dihydric phenol, preferably bisphenol-A and a liquid resinous polyepoxide containing 1,2-epoxy groups, preferably a low molecular weight epoxy resin consisting essentially of the diglycidyl ether of bisphenol-A, at a temperature above about a minimum reaction temperature for a catalytic liquid upgrade reaction between the dihydric phenol and the polyepoxide; and (B) subsequently introducing the catlyst, preferably an organic phosphine and most preferably triphenylphosphine, into the mixture of the dihydric phenol and polyepoxide at reaction temperature and maintaining the mixture containing the catalyst at reaction temperature for a time sufficient to produce the upgraded version of the thermosetting resinous polyepoxide. In another aspect, multiple catalyst additions are featured wherein, for example, after a first catalytic amount of a catalyst is introduced into the mixture of dihydric phenol and polyepoxide and the reaction has been maintained for a first period of time, a second catalytic amount of the catalyst is introduced into the mixture while at reaction temperature to upgrade further the polyepoxide. In yet another aspect of the disclosure, thermosetting resinous polyepoxides of improved molecular weight distribution are obtained by a process, preferably a continuous process, which involves (A) providing a catalyst-free mixture of bisphenol-A and a liquid resinous polyepoxide consisting essentially of an aromatic polyepoxide of the structural formula: ##STR1## to a temperature between 120.degree. C. and about 200.degree. C.; and (B) subsequently introducing triphenylphosphine into the mixture of the dihydric phenol and aromatic polyepoxide at a reaction temperature above 120.degree. C. and maintaining the mixture containing the catalyst at reaction temperature for a time between about 5 and about 30 minutes.

3. 发明授权

US4766242A Synthesis of substituted aryl sulfides 失效
标题翻译：取代芳基硫化物的合成
公开(公告)号：US4766242A
公开(公告)日：1988-08-23
申请号：US344335
申请日：1982-02-01
申请人： Harry T. Hanson , John B. Sapp, Jr.
发明人： Harry T. Hanson , John B. Sapp, Jr.
IPC分类号： C07C233/16 , C07C103/19
CPC分类号： C07C233/16
摘要： Provided is a novel and effective process for the synthesis of aryl sulfides substituted with an alkanoylamino or (N-alkyl)alkanoylamino substituent. The process comprises reacting an appropriately substituted aromatic compound with a sulfur dihalide, preferably sulfur dichloride, in the presence of an alkali metal tetrafluoroborate catalyst and an ether comprising solvent.
摘要翻译：提供了一种合成由烷酰基氨基或（N-烷基）烷酰基氨基取代基取代的芳基硫化物的新颖有效的方法。该方法包括在碱金属四氟硼酸盐催化剂和包含溶剂的醚的存在下使适当取代的芳族化合物与硫二卤化物，优选二氯化硫反应。

4. 发明授权

US4439590A Acetylene-terminated aromatic enyne resins and method of production thereof 失效
标题翻译：乙炔封端的芳香族烯烃树脂及其制备方法
公开(公告)号：US4439590A
公开(公告)日：1984-03-27
申请号：US369393
申请日：1982-04-19
申请人： Harry T. Hanson
发明人： Harry T. Hanson
IPC分类号： C08G61/12 , C08F138/00
CPC分类号： C08G61/128 , Y10T428/31696 , Y10T428/31931
摘要： Novel poly-aromatic ethynyl-terminated enyne compounds of the formula: ##STR1## are provided together with a method of production thereof, wherein R.sub.1 is a strong electron withdrawing moiety and n is equal to or greater than 1.
摘要翻译：提供下式的新型聚芳族乙炔基封端的炔化合物及其制备方法，其中R1是强吸电子部分，n等于或大于1。

5. 发明授权

US4419504A Method of accelerating cure rates for acetylene-terminated resins and curable compositions employed therein 失效
标题翻译：乙炔封端树脂及其中使用的可固化组合物的固化速度加快的方法
公开(公告)号：US4419504A
公开(公告)日：1983-12-06
申请号：US366445
申请日：1982-04-07
申请人： Harry T. Hanson
发明人： Harry T. Hanson
IPC分类号： C08F290/06 , C08G61/10 , C08K5/01 , C08F238/00
CPC分类号： C08K5/01 , C08F290/06 , C08G61/10
摘要： Accelerated curing rates of certain acetylene-terminated aromatic sulfones and polyimide oligomers are obtained by thermally curing the resins with an effective amount of a diethynylbiphenyl.
摘要翻译：某些乙炔封端的芳族砜和聚酰亚胺低聚物的加速固化速率是通过用有效量的二乙炔基联苯热固化树脂获得的。

6. 发明授权

US4393241A Synthesis of alkoxy and phenoxy substituted aryl sulfides 失效
标题翻译：烷氧基和苯氧基取代的芳基硫化物的合成
公开(公告)号：US4393241A
公开(公告)日：1983-07-12
申请号：US344337
申请日：1982-02-01
申请人： Harry T. Hanson , John B. Sapp, Jr.
发明人： Harry T. Hanson , John B. Sapp, Jr.
IPC分类号： C07C149/32
CPC分类号： C07C323/00
摘要： Provided is a novel process for the synthesis of aryl sulfides substituted with an alkoxy or phenoxy substituent. The process comprises reacting an alkoxy or phenoxy substituted aromatic compound with a sulfur dihalide, preferably sulfur dichloride, in the presence of an alkali metal tetrafluoroborate catalyst, with the amount of said aromatic reactant compound preferably being sufficient to solvate the sulfur dichloride and catalyst sufficiently to allow the reaction to occur.
摘要翻译：提供了用烷氧基或苯氧基取代基取代的芳基硫化物的合成方法。该方法包括在碱金属四氟硼酸盐催化剂的存在下使烷氧基或苯氧基取代的芳族化合物与硫二卤化物，优选二氯化硫反应，所述芳族反应物化合物的量优选足以将二氯化硫和催化剂充分溶解至允许反应发生。

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