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1. 发明授权

US06486338B1 Preparation of organosilicon compounds containing &agr;, &bgr;-unsaturated carboxylic acids 失效
标题翻译：制备含有α，β-不饱和羧酸的有机硅化合物
公开(公告)号：US06486338B1
公开(公告)日：2002-11-26
申请号：US09491034
申请日：2000-01-25
申请人： Eckhard Hanelt , Frank Sandmeyer , Norman Häberle , Wolfram Schindler
发明人： Eckhard Hanelt , Frank Sandmeyer , Norman Häberle , Wolfram Schindler
IPC分类号： C02F708
CPC分类号： C09K19/408 , C07F7/0879 , C07F7/0889 , C07F7/14 , C08G77/045
摘要： Organosilicon compounds (P) containing &agr;,&bgr;-unsaturated carboxylic acid radicals, of the general formula (1) —A—O—C(O)—CR═CH2 (1), are prepared by a process in which, in a first step, organosilicon compounds (H) containing hydrogen atoms bonded directly to silicon are reacted with olefinically unsaturated compounds (U) containing a terminal double or triple bond, of the general formula (2) &OHgr;—O—C(O)—CRH—CH2—Z (2), in the presence of metals or compounds from the platinum group as catalyst, to give organosilicon compounds (E) containing radicals of the general formula (3) —A—O—C(O)—CRH—CH2—Z (3), and, in a second step, H—Z compounds are eliminated from organosilicon compounds (E), where A is a divalent organic radical, &OHgr; is a monovalent organic radical containing a terminal double or triple bond, R is an H atom or a methyl radical, and Z is Cl, I, Br or 4-methyltoluenesulfonyl.
摘要翻译：通过以下方法制备含有通式（1）的α，β-不饱和羧酸基团的有机硅化合物（P），其中在第一步中，将含有与硅直接键合的氢原子的有机硅化合物（H）与在由铂族作为催化剂的金属或化合物存在下，通式（2）所示的含有末端双键或三键的烯属不饱和化合物（U），得到含有通式（3）的基团的有机硅化合物（E）），并且在第二步中，从有机硅化合物（E）中除去HZ化合物，其中A是二价有机基团，OMEGA是含有末端双键或三键的单价有机基团，R是H原子或甲基基团，且Z为Cl，I，Br或4-甲基甲苯磺酰基。

2. 发明授权

US06440328B1 Preparation of acrylated liquid-crystalline compounds 有权
标题翻译：丙烯酸酯化液晶化合物的制备
公开(公告)号：US06440328B1
公开(公告)日：2002-08-27
申请号：US09552448
申请日：2000-04-18
申请人： Volker Stanjek , Wolfram Schindler , Thomas Kammel , Norman Häberle
发明人： Volker Stanjek , Wolfram Schindler , Thomas Kammel , Norman Häberle
IPC分类号： C09K1920
CPC分类号： C07C67/31 , C07C67/317 , C07C69/92
摘要： The invention relates to a one-step process for the preparation of acryloyl group-containing liquid-crystalline monomers of the general formula (1) (Z—Y1—A2—Y2—)mM(—O—A1-acrylate)n (1) in which mesogenic alcohols of the general formula (2) (Z—Y1—A2—Y2—)mM(OH)n (2) are reacted with esters of 3-chloropropionic acid of the general formula (3) ClPr—A1—X (3) with elimination of HCl, where acrylate is an acrylate radical, ClPr is a 3-chloropropionate radical, A1 are identical or different alkyl chain spacers having 2-20 carbon atoms, in which the carbon chain may be interrupted by non-adjacent ether, thioether, or imino groups, A2 are radicals A1 or single chemical bonds, M is a mesogenic group, X is a leaving group, Z are alkyl radicals or crosslinkable groups, Y1 and Y2, independently of one another, are a single chemical bond, —O—, —S—, —O—CO—, —CO—O—, —O—CO—O, —CO—NR1—, —NR1—CO—, —O—CO—NR1—, —NR1—CO—O— or —NR1—CO—NR1—, R1 is hydrogen or a C1-C4-alkyl radical, n is 1, 2, 3 or 4, and m is 0, 1, 2 or 3.
摘要翻译：本发明涉及一种制备通式（1）的含丙烯酰基的液晶单体的一步法，其中通式（2）的介晶醇与3-氯丙酸的酯反应消除HCl的通式（3），其中丙烯酸酯是丙烯酸酯基，ClPr是3-氯丙酸酯基，A1是相同或不同的具有2-20个碳原子的烷基链间隔基，其中碳链可被非 - 相邻的醚，硫醚或亚氨基，A2是基团A1或单个化学键，M是介晶基团，X是离去基团，Z是烷基或可交联基团，Y1和Y2彼此独立地是单化学键，-O - ， - S-，-O-CO-，-CO-O-，-O-CO-O，-CO-NR1-，-NR1-CO-，-O-CO-NR1-， -NR1-CO-O-或-NR1-CO-NR1-，R1是氢或C1-C4-烷基，n是1,2,3或4，并且m是0,1,2或3。

3. 发明授权

US07060760B2 Silane-terminated polydiorganosiloxane urethane copolymer 失效
标题翻译：硅烷封端的聚二有机硅氧烷氨基甲酸酯共聚物
公开(公告)号：US07060760B2
公开(公告)日：2006-06-13
申请号：US10471955
申请日：2002-02-14
申请人： Wolfram Schindler , Oliver Schäfer , Volker Stanjek , Bernd Pachaly
发明人： Wolfram Schindler , Oliver Schäfer , Volker Stanjek , Bernd Pachaly
IPC分类号： C08G77/458 , C08G77/455
CPC分类号： C08G18/289 , C08G18/61 , C08G18/718 , C08G77/458 , C09D183/10 , C09J183/10
摘要： Curable, silane-terminated polydiorganosiloxane-urethane copolymers exhibit the beneficial properties of isocyanate-terminated polysiloxane-urethane copolymers without the detriments associated with free isocyanate groups.
摘要翻译：可固化的硅烷封端的聚二有机硅氧烷 - 氨基甲酸酯共聚物表现出异氰酸酯封端的聚硅氧烷 - 氨基甲酸酯共聚物的有益性质，而没有与游离异氰酸酯基团有关的损害。

4. 发明申请

US20060111505A1 Polymer masses based on alkoxysilane-terminated polymers having a regulatable hardening speed 有权
标题翻译：基于具有可调节硬化速度的烷氧基硅烷封端的聚合物的聚合物质量
公开(公告)号：US20060111505A1
公开(公告)日：2006-05-25
申请号：US10524473
申请日：2003-08-07
申请人： Wolfram Schindler , Volker Stanjek
发明人： Wolfram Schindler , Volker Stanjek
IPC分类号： C08G18/08
CPC分类号： C08G65/336 , C08G18/10 , C08G18/289 , C08G18/718
摘要： Condensation curable systems employ ordinarily highly reactive polymers bearing methylene-linked alkoxysilyl groups. By limiting the amounts of activating compounds during the preparation of such polymers, the reactivity is sharply decreased, yet can be increased by addition of suitable catalysts. As a result, the polymers may be easily processed, yet the moisture curing times may be adjusted readily.
摘要翻译：缩合固化体系使用通常具有亚甲基连接的烷氧基甲硅烷基的高反应性聚合物。通过在制备这种聚合物期间限制活化化合物的量，反应性急剧降低，但可通过加入合适的催化剂而增加。结果，可以容易地处理聚合物，但可以容易地调节湿气固化时间。

5. 发明授权

US08101704B2 Continuous polymer-analogous reaction of reactive silane monomers with functionalized polymers 有权
标题翻译：反应性硅烷单体与官能化聚合物的连续聚合物 - 类似反应
公开(公告)号：US08101704B2
公开(公告)日：2012-01-24
申请号：US11917951
申请日：2006-05-24
申请人： Frank Baumann , Wolfram Schindler , Thomas Frey , Achim Schroeder-Ebensperger
发明人： Frank Baumann , Wolfram Schindler , Thomas Frey , Achim Schroeder-Ebensperger
IPC分类号： C08G77/06
CPC分类号： C08G63/91 , C08G18/22 , C08G18/4825 , C08G18/718 , C08G63/695
摘要： Functional polymers having silyl end groups are prepared in a continuous process by polymer analogous reaction of a reactive polymer and inter-reactive silane. The polymer products are surprisingly uniform in properties and exhibit higher physicochemical properties as well.
摘要翻译：具有甲硅烷基端基的官能聚合物通过反应性聚合物和反应活性硅烷的聚合物类似反应在连续方法中制备。聚合物产品在性能上令人惊讶地均匀，并且表现出较高的物理化学性质。

6. 发明授权

US07091298B2 Alcoxy cross-linking, single-component, moisture-hardening materials 有权
标题翻译： Alcoxy交联，单组分，湿润固化材料
公开(公告)号：US07091298B2
公开(公告)日：2006-08-15
申请号：US10484300
申请日：2002-07-18
申请人： Wolfram Schindler , Andreas Bauer , Volker Stanjek , Bernd Pachaly
发明人： Wolfram Schindler , Andreas Bauer , Volker Stanjek , Bernd Pachaly
IPC分类号： C08G77/04
CPC分类号： C08L101/10 , C08K5/54
摘要： Alkoxy-crosslinking one-component moisture curing compositions contain a polymer bearing (alkoxy)(methyl)silylalkyl-terminal groups, and specific silanes as described herein. The compositions exhibit improved shelf life and yet retain other desirable characteristics.
摘要翻译：烷氧基交联单组分湿固化组合物含有如本文所述的带有（烷氧基）（甲基）甲硅烷基烷基端基的聚合物和特定的硅烷。组合物显示出改进的保存期限并且保持其它期望的特性。

7. 发明授权

US07074875B2 RTV-1 silicone elastomer compositions which crosslink by means of alkoxy groups 失效
标题翻译：通过烷氧基交联的RTV-1有机硅弹性体组合物
公开(公告)号：US07074875B2
公开(公告)日：2006-07-11
申请号：US10483474
申请日：2002-05-29
申请人： Wolfram Schindler , Uwe Scheim , Bernd Pachaly
发明人： Wolfram Schindler , Uwe Scheim , Bernd Pachaly
IPC分类号： C08G77/26
CPC分类号： C08G77/54 , C08L83/14
摘要： Crosslinkable RTV-1 compositions with enhanced physical properties include an alkoxy-functional polydiorganosiloxane having alkoxy-functional silyalkylene groups linked to a polydiorganosiloxane via ureaalkylene groups, prepared by reacting an α,ω-dihydroxyorganopolysiloxane with a silazane and with a silane of formula OCN—X-SirR1a(OR2)3-a, (6) where R0, R1, R2, and R3 are optionally substituted hydrocarbon groups.
摘要翻译：具有增强的物理性质的可交联的RTV-1组合物包括具有烷氧基官能的聚二有机硅氧烷，其具有通过脲，亚烷基与聚二有机硅氧烷连接的烷氧基官能聚硅氧烷基团，其通过α，ω-二羟基有机聚硅氧烷与硅氮烷反应制备，并与式 -line-formula description =“In-line Formulas”end =“lead”？> OCN-X-SirR 3-a <3，（6）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 0， O 1，R 2，R 3和R 3是任选取代的烃基。

8. 发明授权

US07015297B2 Method of increasing the elasticity of moisture-cured elastomers 有权
标题翻译：增加湿固化弹性体弹性的方法
公开(公告)号：US07015297B2
公开(公告)日：2006-03-21
申请号：US10967903
申请日：2004-10-18
申请人： Wolfram Schindler , Elke Schwiebacher
发明人： Wolfram Schindler , Elke Schwiebacher
IPC分类号： C08G77/04
CPC分类号： C08L101/10 , C08G77/18 , C08G77/24 , C08K5/54 , C08L83/04 , C08L2666/44
摘要： The invention provides a method of increasing the elasticity of moisture-cured elastomers, which comprises adding to alkoxy-cross linking one-component compositions comprising an alkoxysilane-terminated polymer (A) containing end groups of the formula (1) -A-Si(R)a(CH3)3-a (1) a silane (B), of the general formula (2) X—CH2—Si(R)2(CH3) (2) where A is a divalent hydrocarbon radical, R is a methoxy or ethoxy group, X is a group R″O—, R″NH—, R′—O—CO—NH, R′—NH—CO—NH— or halogen, R″ is hydrogen, an optionally halogen-substituted C1-18 hydrocarbon radical or a radical R′—O—CO— or R′—NH—CO, R′ is an optionally halogen-substituted C1-8 hydrocarbon radical, and a is 1, 2 or 3.
摘要翻译：本发明提供了增加湿固化弹性体弹性的方法，该方法包括加入含有烷氧基硅烷封端的聚合物（A）的烷氧基交联单组份组合物，该聚合物（A）含有式（1）端基 -formulae description =“In-line Formulas”end =“lead”？ - A-Si（R）＆lt; 3＆gt;（CH 3）3-a < （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>通式（2）中的硅烷（B）<？in-line-formula description = “在线公式”end =“lead”？> X-CH 2 -Si（R）2（CH 3 3）（2））其中A是二价烃基，R是甲氧基或乙氧基，X是基团R'O - ，R 'NH-，R'-O-CO-NH，R'-NH-CO-NH-或卤素，R“是氢，任选卤素取代的C 1-18烃基或基团R'-O-CO-或R'-NH-CO，R'是任选卤素取代的C 1-8烃基团，和是1，2或3。

9. 发明申请

US20050101753A1 Method of increasing the elasticity of moisture-cured elastomers 有权
标题翻译：增加湿固化弹性体弹性的方法
公开(公告)号：US20050101753A1
公开(公告)日：2005-05-12
申请号：US10967903
申请日：2004-10-18
申请人： Wolfram Schindler , Elke Schwiebacher
发明人： Wolfram Schindler , Elke Schwiebacher
IPC分类号： C08J3/24 , C08G77/04 , C08G77/42 , C08G77/50 , C08K5/54 , C08K5/541 , C08L23/04 , C08L33/14 , C08L67/00 , C08L71/00 , C08L75/04 , C08L83/04 , C08L83/06 , C08L83/14 , C08L101/10
CPC分类号： C08L101/10 , C08G77/18 , C08G77/24 , C08K5/54 , C08L83/04 , C08L2666/44
摘要： The invention provides a method of increasing the elasticity of moisture-cured elastomers, which comprises adding to alkoxy-cross linking one-component compositions comprising an alkoxysilane-terminated polymer (A) containing end groups of the formula (1) -A-Si(R)a(CH3)3-a (1) a silane (B), of the general formula (2) X—CH2—Si(R)2(CH3) (2) where A is a divalent hydrocarbon radical, R is a methoxy or ethoxy group, X is a group R″O—, R″NH—, R′—O—CO—NH, R′—NH—CO—NH— or halogen, R″ is hydrogen, an optionally halogen-substituted C1-18 hydrocarbon radical or a radical R′—O—CO— or R′—NH—CO, R′ is an optionally halogen-substituted C1-8 hydrocarbon radical, and a is 1, 2 or 3.
摘要翻译：本发明提供了增加湿固化弹性体弹性的方法，该方法包括加入含有烷氧基硅烷封端的聚合物（A）的烷氧基交联单组份组合物，该聚合物（A）含有式（1）端基 -formulae description =“In-line Formulas”end =“lead”？ - A-Si（R）＆lt; 3＆gt;（CH 3）3-a < （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>通式（2）中的硅烷（B）<？in-line-formula description = “在线公式”end =“lead”？> X-CH 2 -Si（R）2（CH 3 3）（2））其中A是二价烃基，R是甲氧基或乙氧基，X是基团R'O - ，R 'NH-，R'-O-CO-NH，R'-NH-CO-NH-或卤素，R“是氢，任选卤素取代的C 1-18烃基或基团R'-O-CO-或R'-NH-CO，R'是任选卤素取代的C 1-18烃基，以及 a是1,2或3。

10. 发明申请

US20120107626A1 Adhesive or sealing compounds containing alkoxysilane-terminated polymers 审中-公开
标题翻译：含有烷氧基硅烷封端的聚合物的粘合剂或密封剂
公开(公告)号：US20120107626A1
公开(公告)日：2012-05-03
申请号：US13381277
申请日：2010-06-22
申请人： Wolfram Schindler , Volker Stanjek
发明人： Wolfram Schindler , Volker Stanjek
IPC分类号： B32B9/04 , C09J183/16
CPC分类号： C09J171/02 , C08G65/336 , Y10T428/31663
摘要： Two-component adhesive or sealing compounds (K), comprising a first component (K1), containing silane-terminated prepolymers (A), which have end groups of the general formula (II) —O—CO—NH—(CH2)y—SiR23-x(OR1)x (II), where R1 and R2 independently from each other are hydrocarbon groups having 1-18 carbon atoms or ω-oxaalkyl-alkyl groups having in total 2-20 carbon atoms, x is 2 or 3, and y is a number from 1 to 10, and a second component (K2), containing water, provided that at least 50% of all prepolymer molecules (A) do not have any additional urethane or urea units in the backbone of the prepolymer chain.
摘要翻译：双组分粘合剂或密封化合物（K），其包含含有硅烷封端的预聚物（A）的第一组分（K1），其具有通式（II）的端基-O-CO-NH-（CH 2）y -SiR 23-x（OR 1）x（II），其中R 1和R 2彼此独立地为具有1-18个碳原子的烃基或具有总共2-20个碳原子的ω-氧杂烷基 - 烷基，x为2或3 ，y为1〜10的数，和含有水的第二成分（K2），条件是预聚物分子（A）的至少50％在预聚物的主链中不具有任何附加的氨基甲酸酯或脲单元链。

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